CN105330192A - Interface processing agent and preparation method thereof - Google Patents
Interface processing agent and preparation method thereof Download PDFInfo
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- CN105330192A CN105330192A CN201510688128.6A CN201510688128A CN105330192A CN 105330192 A CN105330192 A CN 105330192A CN 201510688128 A CN201510688128 A CN 201510688128A CN 105330192 A CN105330192 A CN 105330192A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 82
- 230000007797 corrosion Effects 0.000 claims abstract description 58
- 238000005260 corrosion Methods 0.000 claims abstract description 58
- 239000002253 acid Substances 0.000 claims abstract description 52
- 230000003628 erosive effect Effects 0.000 claims abstract description 36
- 230000005764 inhibitory process Effects 0.000 claims abstract description 23
- 239000003729 cation exchange resin Substances 0.000 claims abstract description 20
- -1 fluoric acid compound Chemical class 0.000 claims abstract description 20
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 15
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims abstract description 9
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 7
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 5
- 239000010452 phosphate Substances 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 29
- 238000003756 stirring Methods 0.000 claims description 23
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 21
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 15
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 12
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 12
- 229910021538 borax Inorganic materials 0.000 claims description 10
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000011775 sodium fluoride Substances 0.000 claims description 10
- 235000013024 sodium fluoride Nutrition 0.000 claims description 10
- 239000004328 sodium tetraborate Substances 0.000 claims description 10
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 9
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 8
- 150000003840 hydrochlorides Chemical class 0.000 claims description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 6
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 6
- 239000004317 sodium nitrate Substances 0.000 claims description 6
- 235000010344 sodium nitrate Nutrition 0.000 claims description 6
- 229940001516 sodium nitrate Drugs 0.000 claims description 6
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 6
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract description 70
- 239000000463 material Substances 0.000 abstract description 36
- 229960002050 hydrofluoric acid Drugs 0.000 abstract description 33
- 230000000694 effects Effects 0.000 abstract description 28
- 239000007864 aqueous solution Substances 0.000 abstract description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 3
- 239000001257 hydrogen Substances 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- 239000003518 caustics Substances 0.000 abstract 2
- 230000001133 acceleration Effects 0.000 abstract 1
- DVBJBNKEBPCGSY-UHFFFAOYSA-M cetylpyridinium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 DVBJBNKEBPCGSY-UHFFFAOYSA-M 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 description 36
- 239000003153 chemical reaction reagent Substances 0.000 description 23
- 239000000956 alloy Substances 0.000 description 14
- 238000005530 etching Methods 0.000 description 14
- 239000005341 toughened glass Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 239000004579 marble Substances 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- 229910052710 silicon Inorganic materials 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000004566 building material Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000013543 active substance Substances 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 5
- 229940023913 cation exchange resins Drugs 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000116 mitigating effect Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 238000005341 cation exchange Methods 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011814 protection agent Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229940126680 traditional chinese medicines Drugs 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229910000914 Mn alloy Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910000978 Pb alloy Inorganic materials 0.000 description 1
- RAGWOVJSLFRHNO-UHFFFAOYSA-N [N+](=O)([O-])Cl.[Na] Chemical compound [N+](=O)([O-])Cl.[Na] RAGWOVJSLFRHNO-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002706 dry binder Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
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- 125000000524 functional group Chemical group 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
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Landscapes
- Detergent Compositions (AREA)
- Chemical Treatment Of Metals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides an interface processing agent and a preparation method thereof. Cation exchange resin and a fluoric acid compound are taken as a corrosive agent, and hydrofluoric acid is generated in an aqueous solution, elements in a material is effectively corroded, the smoothness of the material interface is destroyed, the interface effective surface area is enlarged, and the adhesive force of the material surface is increased. Also, when the corrosion type interface processing agent is used, a phosphate compound, a hydrochloride compound and a nitrate compound form a mixed acid, and thus corrosion of the single acid hydrofluoric acid is avoided and corrosion acceleration effect is reached. The invention also provides a corrosion inhibition type interface processing agent and a preparation method thereof. Cation exchange resin and a fluoric acid compound are taken as a corrosive agent, the interface effective surface area is enlarged and the interface adhesive force is increased. A surfactant 1227, hexadecyl trimethyl ammonium bromide and hexadecylpyridinium bromide effectively prevent hydrofluoric acid from generating erosion and hydrogen osmosis effects on the material surface, reduce corrosion efficiency and reach corrosion inhibition effect.
Description
Technical field
The present invention relates to building materials technology field, particularly relate to a kind of interface treating agent and preparation method thereof.
Background technology
Ceramic tile, toughened glass, alloy material are the important materials of modem architectural ornament, the advantage such as generally have high strength, high rigidity, high temperature resistant, smooth surface is easy to clean.Wherein, ceramic tile is primarily of the kaolin containing compositions such as silicon, aluminium, potassium, sodium, calcium, magnesium, iron, marble, quartz, spectra raw material composition.Along with the continuous quickening of civilization of human society pace of progress; the progress increasingly of the production of ceramic tile and technique; the kind of ceramic tile is more and more come many; its development reaches its maturity; the scope of application is more and more extensive, such as exterior wall tile, internal wall brick, vitrified tile, Antique Imitation Tiles, ornamental brick and become the marble ceramic tile of building material industry focus in recent years.
The main component of toughened glass is silicon-dioxide and silicate, submember is the metallic elements such as potassium, sodium, calcium, magnesium, be generally used for furniture decorative appearance, the various glass door and windows of such as furniture, bathroom, kitchen lamp home decoration, and Discussion on architecture metope decoration.Toughened glass is widely applied at architectural decoration, and it merges with building gradually, becomes the integral part that building is indispensable.
Alloy material is of a great variety, as magnesium alloy, aluminium alloy, lead alloy, manganese alloy etc., is widely used in building trade at present.The composition of alloy is relatively simple, is generally formed by two kinds or more of metallic combination.Alloy material relates to the various fields of the required and economic society of the people's livelihood, and being the important raw and processed materials of national economy and development, is one of base mateiral of modern architecture.
As everyone knows, ceramic tile, toughened glass and alloy material are when using as building materials, and their surface is general all very smooth.If be directly coated with spread coated paint or putty on its surface when carrying out renewal and reform, very easily cause obscission.Way traditional is at present rough being knocked out, then carries out the work being coated with the surfacing such as Puttying or coating, cost of labor so not only can be caused to increase and construction trouble, and can cause serious pollution from environmental noise, affect the orthobiosis of nearby residents.Therefore design a kind of building materials interface treating agent tool simple, noise is little of constructing to be of great significance and good market outlook.
At present, Chinese patent publication discloses the scheme of two ceramic tile interface treatment agents, such as, application number be 02138448.7 Chinese patent literature report a kind of ceramic tile interface treatment agent and preparation method thereof, its technical scheme is: by used in combination according to corresponding ratio to cement, mineral aggregate, admixture and a small amount of impurity; Wherein, ore gathers materials for sand and quartz sand, and admixture is dry binder, is Vinyl Acetate Copolymer family macromolecule polymkeric substance.Application number be 201410243081.8 Chinese patent literature report a kind of ceramic tile interface treatment agent, mixed by following raw material: cement 400 parts, quartz sand 400 parts, super-fine silicon micro-powder 50 parts, first level flour coal ash 127 parts, 3 parts, 200,000 viscosity cellulose ether, redispersable latex powder 20 parts, hydrophober 2 parts, poly-carboxyl water reducer 8 parts.Above patent documentation all adopts tackiness agent to improve ceramic tile surface sticking power, and ceramic tile surface does not change, and namely the surface adhesion force of ceramic tile does not change, and is only that the tackiness agent adulterated in treatment agent pastes ceramic tile surface.Therefore, the treatment agent of above-mentioned prior art report does not change the sticking power of ceramic tile surface, just allow the putty of the tackiness agent in treatment agent and new brushing or coating be stained with glutinous together with, but not coating or putty are directly together with ceramic tile interface cohesion, the sticking power of ceramic tile surface is poor, and thus coating or putty are still easy comes off from ceramic tile surface.
Summary of the invention
The technical problem that the present invention solves is to provide a kind of interface treating agent and preparation method thereof, and this interface treating agent can corrosion material surface, improves the sticking power of material surface.
In view of this, the invention provides a kind of increasing erosion type interface treating agent, comprise following composition:
Preferably, described Zeo-karb is storng-acid cation exchange resin, and fluorate compounds is Sodium Fluoride.
Preferably, described phosphate compound is tripoly phosphate sodium STPP, and described hydrochloride compounds is sodium-chlor, and described nitrate-based compound is SODIUMNITRATE.
Accordingly, the present invention also provides a kind of preparation method increasing erosion type interface treating agent, comprise the following steps: at 15-30 DEG C, 80-85 weight part acid type Zeo-karb, 15-20 weight part fluorate compounds, 0.1-0.2 parts by weight of phosphoric acid salt compounds, 0.1-0.2 weight part hydrochloride compounds, 0.1-0.2 weight part nitrate-based compound and 0.2 part by weight of boric acid salt compounds are mixed, stir in solid particulate agitator, obtain increasing erosion type interface treating agent.
Preferably, described acid type Zeo-karb is prepared as follows: immersed by Zeo-karb in hydrochloric acid soln, and within every 1-3 hour, stir once, soak more than 12 hours, clear water obtains acid type Zeo-karb after rinsing.
The present invention also provides a kind of corrosion inhibition type interface treating agent, comprises following composition:
Preferably, described Zeo-karb is storng-acid cation exchange resin, and fluorate compounds is Sodium Fluoride.
Preferably, described boric acid compound is Sodium Tetraborate.
Accordingly, the present invention also provides a kind of preparation method of corrosion inhibition type interface treating agent, comprise the following steps: at 15-30 DEG C, 80-85 weight part acid type Zeo-karb, 15-20 weight part fluorate compounds, 0.1-0.2 parts surfactant 1227,0.1-0.2 weight part cetyl trimethylammonium bromide, 0.1-0.2 weight part brocide and 0.2 part by weight of boric acid salt compounds are mixed, stir in solid particulate agitator, obtain corrosion inhibition type interface treating agent.
Preferably, described acid type Zeo-karb is prepared as follows: immersed by Zeo-karb in hydrochloric acid soln, and within every 1-3 hour, stir once, soak more than 12 hours, clear water obtains acid type Zeo-karb after rinsing.
The invention provides a kind of increasing erosion type interface treating agent and preparation method thereof, with Zeo-karb and fluorate compounds for etching reagent, it generates hydrofluoric acid in aqueous, effectively the silicon in ceramic tile, toughened glass, alloy modern material composition and metallic element are corroded, destroy the slickness of material interface, make it to become concavo-convex unordered, expand interface effective surface area, thus increase the sticking power of material surface.Secondly, when increasing the use of erosion type interface treating agent, phosphate compound, hydrochloride compounds, nitrate-based compound can form mixing acid, thus avoid the corrosion of the single acid of hydrofluoric acid, reach and increase erosion effect.
The present invention also provides a kind of corrosion inhibition type interface treating agent and preparation method thereof, with Zeo-karb and fluorate compounds for etching reagent, it generates hydrofluoric acid in aqueous, can effectively corrode the silicon in ceramic tile, toughened glass, alloy modern material composition and metallic element, thus destroy the slickness of material interface, make it to become concavo-convex unordered, thus expand interface effective surface area, increase interfacial adhesion.Secondly, tensio-active agent 1227, cetyl trimethylammonium bromide and brocide effectively can block hydrofluoric acid and cause erosion and hydrogen osmosis to material surface, reduce corrosion efficiency, reach corrosion mitigating effect.
Accompanying drawing explanation
Fig. 1 is design sketch before the corrosion of embodiment of the present invention marble ceramic tile;
Fig. 2 is the marble ceramic tile corrosive effect figure after increasing erosion type interface treating agent corrosion prepared by the embodiment of the present invention 1;
Fig. 3 is the marble ceramic tile corrosive effect figure after corrosion inhibition type interface treating agent corrosion prepared by the embodiment of the present invention 6;
Fig. 4 is the marble ceramic tile corrosive effect figure after interface treating agent corrosion prepared by comparative example 1.
Embodiment
In order to understand the present invention further, below in conjunction with embodiment, the preferred embodiment of the invention is described, but should be appreciated that these describe just for further illustrating the features and advantages of the present invention, instead of limiting to the claimed invention.
All containing metallic elements such as element silicon and aluminium, potassium, sodium, calcium, magnesium, iron in the composition of ceramic tile, toughened glass, alloy modern material, these components can with hydrofluoric acid generation chemical reaction, that is, easily be subject to the acid corrosion such as hydrofluoric acid, thus, appropriate hydrofluoric acid reagent is sprayed at these material surfaces, it is uneven that the surface that ceramic tile, toughened glass, alloy material can be caused smooth becomes, thus the contact area significantly added with coating or putty, fundamentally improve its surface adhesion force, reach the mechanic effect of beaing interface.According to this principle, the present invention reacts the hydrofluoric acid of generation as etching reagent in aqueous using by storng-acid cation exchange resin and fluoric acid salt, again according to the difference of Material texture and corrosion speed, add and increase erosion agent or inhibiter controls its etching time.
The embodiment of the invention discloses a kind of increasing erosion type interface treating agent, comprise following composition:
Preferably, the hydrofluoric acid that the present invention is generated in aqueous by Zeo-karb and fluorate compounds, it is as etching reagent.Described Zeo-karb is preferably 732 storng-acid cation exchange resins, and described fluorate compound is preferably Sodium Fluoride.Zeo-karb and fluorate compounds are key ingredient, can effectively corrode the silicon in ceramic tile, toughened glass, alloy modern material composition and metallic element, destroy the slickness of material interface, make it to become concavo-convex unordered, thus expand interface effective surface area, increase interfacial adhesion.
Preferably, described phosphate compound is tripoly phosphate sodium STPP, and hydrochloride compounds is sodium-chlor, and nitrate-based compound is SODIUMNITRATE.The present invention is preferably using tripoly phosphate sodium STPP, sodium-chlor, SODIUMNITRATE as increasing erosion agent, and this component is key ingredient.At storng-acid cation exchange resin and fluoric acid salt in aqueous, the mixing acid of hydrofluoric acid, phosphoric acid, hydrochloric acid and nitric acid can be formed, thus avoid the corrosion of the single acid of hydrofluoric acid, reach and increase erosion effect.
Preferably, described borate family compound is Sodium Tetraborate.Borate family compound, in the present invention as corrosion protection agent, is key ingredient.At storng-acid cation exchange resin and fluoric acid salt in aqueous, Sodium Tetraborate can be combined and generates weak acid boric acid by hydrogen ion in solution, boric acid can with fluorion generation complex reaction, thus reduce the harm of hydrofluoric acid, play the effect of protection.
Accordingly, the present invention also provides a kind of preparation method increasing erosion type interface treating agent, comprise the following steps: at 15-30 DEG C, 80-85 weight part acid type Zeo-karb, 15-20 weight part fluorate compounds, 0.1-0.2 parts by weight of phosphoric acid salt compounds, 0.1-0.2 weight part hydrochloride compounds, 0.1-0.2 weight part nitrate-based compound and 0.2 part by weight of boric acid salt compounds are mixed, stir in solid particulate agitator, obtain increasing erosion type interface treating agent.
Preferably, described acid type Zeo-karb is prepared as follows: immersed by Zeo-karb in hydrochloric acid soln, within every 1-3 hour, stirs once, soak more than 12 hours, clear water obtains acid type Zeo-karb after rinsing, preferred, within every 2 hours, stirs once.
The present invention also provides a kind of corrosion inhibition type interface treating agent, comprises following composition:
Preferably, the hydrofluoric acid that the present invention is generated in aqueous by Zeo-karb and fluorate compounds, it is as etching reagent.Described Zeo-karb is preferably 732 storng-acid cation exchange resins, and described fluorate compound is preferably Sodium Fluoride.Zeo-karb and fluorate compounds are key ingredient, can effectively corrode the silicon in ceramic tile, toughened glass, alloy modern material composition and metallic element, destroy the slickness of material interface, make it to become concavo-convex unordered, thus expand interface effective surface area, increase interfacial adhesion.
According to the present invention, tensio-active agent 1227, cetyl trimethylammonium bromide and brocide, as inhibiter, effectively can block hydrofluoric acid and cause erosion and hydrogen osmosis to ceramic tile, toughened glass, alloy material surface.Wherein, tensio-active agent 1227, cetyl trimethylammonium bromide, brocide have synergy to hydrofluoric acid corrosion mitigating effect.The group that these tensio-active agents contain unsaturated double-bond and π key or the polar functional group contained centered by the atoms such as large N, S, the O of electronegativity; protective membrane is formed by physical adsorption; the hydrogen ion of hydrofluoric acid can be caused to be difficult to close to surface; thus reduce corrosion efficiency, reach corrosion mitigating effect.
Preferably, described borate family compound is Sodium Tetraborate.Borate family compound, in the present invention as corrosion protection agent, is key ingredient.At storng-acid cation exchange resin and fluoric acid salt in aqueous, Sodium Tetraborate can be combined and generates weak acid boric acid by hydrogen ion in solution, boric acid can with fluorion generation complex reaction, thus reduce the harm of hydrofluoric acid, serve the effect of protection.
Accordingly, the present invention also provides a kind of preparation method of corrosion inhibition type interface treating agent, comprise the following steps: at 15-30 DEG C, 80-85 weight part acid type Zeo-karb, 15-20 weight part fluorate compounds, 0.1-0.2 parts surfactant 1227,0.1-0.2 weight part cetyl trimethylammonium bromide, 0.1-0.2 weight part brocide and 0.2 part by weight of boric acid salt compounds are mixed, stir in solid particulate agitator, obtain corrosion inhibition type interface treating agent.
Preferably, described acid type Zeo-karb is prepared as follows: immersed by Zeo-karb in hydrochloric acid soln, within every 1-3 hour, stirs once, soak more than 12 hours, clear water obtains acid type Zeo-karb after rinsing, preferred, within every 2 hours, stirs once.
Preferably, the concentration of etching reagent hydrofluoric acid respectively roughly 5% and 3% in described increasing erosion type interface treating agent and the use procedure of corrosion inhibition type interface treating agent, relative concentration is lower, be fluoric acid salt with silicon in material and metallic element generation chemical reaction product, this kind of material is general all very easily water-soluble, and clear water can be used to rinse out; After the corrosion of etching reagent hydrofluoric acid, its concentration can reduce further, thus reduces the harm to people.
Interface treating agent provided by the invention is applicable to the surface treatment of multiple different types of material of construction, and range of application is wider; The hydrofluoric acid that etching reagent adopts storng-acid cation exchange resin and fluoric acid salt to generate in aqueous, the mineral acid directly using this harm of hydrofluoric acid larger can be avoided like this, by adjusting the ratio of interfacial agent of the present invention and water, can the concentration of flexible modulation hydrofluoric acid, eliminate the harm of the hydrofluoric acid using high density; The present invention used increasing erosion agent and inhibiter component concentration very low, little to environmental hazard.
In sum, the material interface promoting agent used in the technical program has the following advantages:
1, are all the features having the metallic element such as element silicon and aluminium, potassium, sodium, calcium, magnesium, iron in the composition according to ceramic tile, toughened glass, alloy modern material, corrosive effect is there is in etching reagent hydrofluoric acid to it, thus destroy the slickness at its interface, make it to become concavo-convex unordered, thus expand interface effective surface area, increase interfacial adhesion.
2, etching reagent adopts the hydrofluoric acid that storng-acid cation exchange resin and fluoric acid salt generate in aqueous, can avoid the mineral acid directly using this harm of hydrofluoric acid larger like this, and the reagent concentration related to is low, solubility is high, without harm.
3, by increasing erosion agent and the use of inhibiter, can control corrosion rate effect effectively, material interface promoting agent of the present invention is applied to dissimilar material, expands range of application.
4, the prices of raw and semifnished materials that relate to of material interface promoting agent of the present invention inexpensively, advantage of lower cost, and easy construction is effective, relatively traditional the mechanical means such as to beat, and avoids the generation of noise, can not cause the negative feeling of neighbours.
In order to understand the present invention further, be described in detail to technical scheme provided by the invention below in conjunction with embodiment, protection scope of the present invention is not limited by the following examples.
The manufacturer of the raw material that the embodiment of the present invention is main and model as follows:
732 strongly acidic styrene type cation exchange resins: Langfang Jin Nan resin company limited;
Sodium Fluoride: analytical pure, Tianjin Ke Miou chemical reagent company limited;
Tripoly phosphate sodium STPP: analytical pure, Tianjin Ke Miou chemical reagent company limited;
Sodium-chlor: analytical pure, Luoyang chemical reagent factory;
SODIUMNITRATE: analytical pure, Luoyang chemical reagent factory;
Sodium Tetraborate: analytical pure, Luoyang chemical reagent factory;
Tensio-active agent 1227: analytical pure, Shanghai Aladdin biochemical technology limited-liability company;
Cetyl trimethylammonium bromide: analytical pure, traditional Chinese medicines group (Shanghai) chemical reagent company limited;
Brocide: analytical pure, traditional Chinese medicines group (Shanghai) chemical reagent company limited.
Embodiment 1
The hydrofluoric acid corrosion type slowly building materials such as clay ceramic tile, glass are adopted and increases erosion type interface treating agent
732 storng-acid cation exchange resins are processed into acid type: 732 storng-acid cation exchange resins are put into the hydrochloric acid soln of 50%, soak more than 12 hours, within every 2 hours, stir once, finally rinse more than 8 times, dry for standby with clear water.
Increase the preparation of erosion type interface treating agent: by the acid type 732 storng-acid cation exchange resin 83.4kg after process, Sodium Fluoride 16.0kg, tripoly phosphate sodium STPP 0.2kg, sodium-chlor 0.2kg, SODIUMNITRATE 0.2kg, Sodium Tetraborate 0.2kg, abundant stirring and evenly mixing in solid particulate agitator, obtains increasing erosion type interface treating agent.
Use front preparation work: above-mentioned preparation is increased erosion type interface treating agent and be dissolved in 400kg water, use solid-liquid agitator fully to stir more than 30 minutes, leave standstill 20 minutes.
Adopt atomizer to be sprayed onto by the aqueous solution of previous step and need interface to be processed, after waiting question response to terminate, use its surface of clean water, to make etc. to be dried.
The temperature in above stage controls at 15-30 DEG C.
Increase erosion type interface treating agent according to the formulated shown in table 1, adopt the method for embodiment 1 to prepare, objective for implementation is loam mould ceramic tile.
Table 1 increases erosion type interface treating agent recipe ratio
| Ingredient names | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Zeo-karb | 80kg | 80kg | 85kg | 85kg |
| Fluoric acid salt | 15g | 15g | 20kg | 20kg |
| Phosphoric acid salt | 0.1kg | 0.2kg | 0.1kg | 0.2kg |
| Hydrochloric acid salt | 0.1kg | 0.2kg | 0.1kg | 0.2kg |
| Nitrates | 0.1kg | 0.2kg | 0.1kg | 0.2kg |
| Borate family | 0.2kg | 0.2kg | 0.2kg | 0.2kg |
Embodiment 6
Corrosion inhibition type interface treating agent is adopted for hydrofluoric acid corrosion type soon building materials such as marble ceramic tile, alloys
732 strongly acidic cation-exchanges are processed into acid type: 732 strongly acidic cation-exchanges are put into 50% hydrochloric acid soln, soak more than 12 hours, within every 2 hours, stir once, finally rinse more than 8 times, dry for standby with clear water.
The preparation of corrosion inhibition type interface treating agent: calculate with weight ratio, by the acid type 732 storng-acid cation exchange resin 83.3kg after process, Sodium Fluoride 16.4kg, tensio-active agent 12270.1kg, cetyl trimethylammonium bromide 0.1kg, brocide 0.1kg, Sodium Tetraborate 0.2kg, in solid particulate agitator, abundant stirring and evenly mixing, obtains corrosion inhibition type interface treating agent.
Use front preparation work: the increasing erosion type interface treating agent of above-mentioned preparation is dissolved in 666kg water, use solid-liquid agitator fully to stir more than 30 minutes, leave standstill 20 minutes.
Adopt atomizer to be sprayed onto by the aqueous solution of previous step and need interface to be processed, after waiting question response to terminate, use its surface of clean water, wait to be dried.
The temperature in above stage controls at 15-30 DEG C.
Preparation corrosion inhibition type interface treating agent according to shown in table 2: adopt the method for embodiment 6 to prepare, objective for implementation is marble type ceramic tile.
Table 2 corrosion inhibition type interface treating agent recipe ratio
Comparative example 1
732 strongly acidic cation-exchanges are processed into acid type: 732 strongly acidic cation-exchanges are put into 50% hydrochloric acid soln, soak more than 12 hours, within every 2 hours, stir once, finally rinse more than 8 times, dry for standby with clear water.
Add inhibiter and increase the generic interface treatment agent preparation of losing agent: calculate with weight ratio, by acid type 732 storng-acid cation exchange resin 83.3kg, Sodium Fluoride 16.4kg and the Sodium Tetraborate 0.2kg abundant stirring and evenly mixing in solid particulate agitator after process, obtain coventional type interface treating agent.
Use front preparation work: the interface treating agent of above-mentioned preparation is dissolved in 666kg water, use solid-liquid agitator fully to stir more than 30 minutes, leave standstill 20 minutes.
Adopt atomizer to be sprayed onto by the aqueous solution of previous step and need interface to be processed, after waiting question response to terminate, use its surface of clean water, wait to be dried.
The temperature in above stage controls at 15-30 DEG C.
As follows the performance of the interface treating agent of above-mentioned preparation is detected:
Weighting method measures the classical way of material corrosion effect, is also the basis of other measuring methods.Bodies lost weight Δ W=W0-W can be obtained, the erosion rate V=Δ W/S/t of corrosion material by experiment.When reaction times t and area S is fixing, bodies lost weight Δ W can reflect the quality of corrosive effect, and Δ W is larger, and the corrosive effect of etching reagent is better, and Δ W is less, and the corrosion mitigating effect of etching reagent is better.
W0 is the quality (g) before material corrosion;
W is the quality (g) after material corrosion;
S is the area (m of material
2);
T is the reaction times (s).
Get 3 same sizes and ganoid marble ceramic tile, clean with distilled water flushing, weigh after oven dry, spray the increasing erosion type interface treating agent, the corrosion inhibition type interface treating agent of embodiment 6 preparation and the interface treating agent of comparative example 1 preparation that add embodiment 1 and prepare on its surface by the specific implementation method of above-mentioned example respectively.Accurate corrosion, after 2 hours, takes out ceramics, re-uses distilled water flushing clean, weighs, calculate weight loss after oven dry, as shown in table 3, and takes pictures with camera.
Table 3 corrosive effect table
| Reagent | ΔW(g) | Corrosive effect |
| Embodiment 1 | 352 | Have and increase erosion effect |
| Embodiment 6 | 142 | There is corrosion mitigating effect |
| Comparative example 1 | 281 | Averaging effect |
Effect before the corrosion of marble ceramic tile as shown in Figure 1, effect after increasing erosion type interface treating agent corrosion prepared by embodiment 1 as shown in Figure 2, as shown in Figure 3, the effect after interface treating agent corrosion prepared by comparative example 1 as shown in Figure 4 for effect after corrosion inhibition type interface treating agent corrosion prepared by embodiment 6.
Can be found out by above-mentioned table 3 and Fig. 1-4, etching reagent prepared by application the present invention can corrode the surface of building materials effectively, and increase erosion agent and have increase corrosive effect, inhibiter effectively can reduce corrosive effect.Can flexible modulation corrosive effect by the application of increasing being lost to agent and inhibiter.
Performance measurement is carried out to interface treating agent prepared by other embodiments, as shown in table 4.
Table 4 specific embodiment corrosive effect table
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
To the above-mentioned explanation of the disclosed embodiments, professional and technical personnel in the field are realized or uses the present invention.To be apparent for those skilled in the art to the multiple amendment of these embodiments, General Principle as defined herein can without departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention can not be restricted to these embodiments shown in this article, but will meet the widest scope consistent with principle disclosed herein and features of novelty.
Claims (10)
1. increase an erosion type interface treating agent, it is characterized in that, comprise following composition:
2. increasing erosion type interface treating agent according to claim 1, it is characterized in that, described Zeo-karb is storng-acid cation exchange resin, and fluorate compounds is Sodium Fluoride.
3. increasing erosion type interface treating agent according to claim 1, it is characterized in that, described phosphate compound is tripoly phosphate sodium STPP, and described hydrochloride compounds is sodium-chlor, and described nitrate-based compound is SODIUMNITRATE.
4. increase a preparation method for erosion type interface treating agent, it is characterized in that, comprise the following steps:
At 15-30 DEG C, 80-85 weight part acid type Zeo-karb, 15-20 weight part fluorate compounds, 0.1-0.2 parts by weight of phosphoric acid salt compounds, 0.1-0.2 weight part hydrochloride compounds, 0.1-0.2 weight part nitrate-based compound and 0.2 part by weight of boric acid salt compounds are mixed, stir in solid particulate agitator, obtain increasing erosion type interface treating agent.
5. preparation method according to claim 4, is characterized in that, described acid type Zeo-karb is prepared as follows:
Immersed by Zeo-karb in hydrochloric acid soln, within every 1-3 hour, stir once, soak more than 12 hours, clear water obtains acid type Zeo-karb after rinsing.
6. a corrosion inhibition type interface treating agent, is characterized in that, comprises following composition:
7. corrosion inhibition type interface treating agent according to claim 6, is characterized in that, described Zeo-karb is storng-acid cation exchange resin, and fluorate compounds is Sodium Fluoride.
8. corrosion inhibition type interface treating agent according to claim 6, is characterized in that, described boric acid compound is Sodium Tetraborate.
9. a preparation method for corrosion inhibition type interface treating agent, is characterized in that, comprises the following steps:
At 15-30 DEG C, 80-85 weight part acid type Zeo-karb, 15-20 weight part fluorate compounds, 0.1-0.2 parts surfactant 1227,0.1-0.2 weight part cetyl trimethylammonium bromide, 0.1-0.2 weight part brocide and 0.2 part by weight of boric acid salt compounds are mixed, stir in solid particulate agitator, obtain corrosion inhibition type interface treating agent.
10. preparation method according to claim 9, is characterized in that, described acid type Zeo-karb is prepared as follows:
Immersed by Zeo-karb in hydrochloric acid soln, within every 1-3 hour, stir once, soak more than 12 hours, clear water obtains acid type Zeo-karb after rinsing.
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| CN113814801A (en) * | 2021-11-25 | 2021-12-21 | 佛山市东鹏陶瓷有限公司 | Anti-skid antifouling ceramic tile with polished surface and production process and application thereof |
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| CN101134666A (en) * | 2007-07-20 | 2008-03-05 | 肥城润东建材有限公司 | Dried powder boundary additive |
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| CN113814801A (en) * | 2021-11-25 | 2021-12-21 | 佛山市东鹏陶瓷有限公司 | Anti-skid antifouling ceramic tile with polished surface and production process and application thereof |
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