CN105326653A - Refreshing type hair conditioner - Google Patents
Refreshing type hair conditioner Download PDFInfo
- Publication number
- CN105326653A CN105326653A CN201510780604.7A CN201510780604A CN105326653A CN 105326653 A CN105326653 A CN 105326653A CN 201510780604 A CN201510780604 A CN 201510780604A CN 105326653 A CN105326653 A CN 105326653A
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- CN
- China
- Prior art keywords
- hair conditioner
- sulfonic acid
- hair
- acid sodium
- alkene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a refreshing type hair conditioner. The specific combination of sodium sulfonate surfactant and inner sodium -olefinsulfonate is adopted for the refreshing type hair conditioner. In the hair washing process, the foaming speed is high, washing is thorough, and people feel refreshed after hair is washed.
Description
Technical field
The present invention relates to a kind of hair conditioner, particularly a kind of light hair conditioner.
Background technology
Hair conditioner is also known as Rinsing, and general and shampoo uses in pairs.After hair washing by appropriate hair conditioner uniform application on hair, gently rub about one minute, then use clear water rinsed clean, therefore also have person for rinsing conditioner, belong to hair cosmetic.Send out element and be divided into transparent type and emulsion-type two kinds from mode of appearance, comparatively commonly emulsion type products on market.
It is generally acknowledged, hair is with negative charge.After shampoo (mainly anionic detergent, soap also belongs to this type of) hair washing, hair can be made with more negative charge, thus produce electrostatic, cause combing inconvenience.Employ hair conditioner, main component cation quaternary ammonium salt wherein can neutralize the molecule remaining in hair surface band anion, and leave the uniform monomolecular film of one deck, this layer of marvellous thing can bring a series of benefit to hair: softness, gloss, be easy to combing, antistatic, and the mechanical damage of hair and chemistry scalded, perm, damage that hair dye brings is by reparation to a certain extent.
Hair conditioner is mainly made up of surfactant, cosurfactant, cation opsonizing agent, fatting agent, oil content, chelating agen, antiseptic, pigment, essence and other active component.Wherein, surfactant mainly plays emulsifying, antistatic, bacteriostasis; Cosurfactant can co-emulsifier; Cation opsonizing agent enemy can be initiated to softness, antistatic, moisturizing and opsonic action; Fatting agent can improve hair nutrition situation as lanoline, olive oil, silicone oil etc. in hair conditioner, makes hair light, easy combing; Other active component dandruffs, moistening, sun-proof, vitamin, hydrolyzed protein, plant extraction liquid etc. give hair conditioner various function, market common are dandruff hair conditioner, containing Aloe or the hair conditioner etc. containing Radix Ginseng.
Summary of the invention
The object of the invention is to propose a kind of light hair conditioner, make in the process of cleaning hair, lather quickness is fast, and washing is thorough and rear sensation of having had one's hair wash is salubrious.
For reaching this object, the present invention by the following technical solutions:
A kind of light hair conditioner, it comprises following component by weight percentage:
(1) the octadecyloxypropyl trimethyl ammonium chloride of 8-15%;
(2) stearyl alcohol of 2-7%;
(3) methyl parahydroxybenzoate of 0.1-0.5%;
(4) C of 2-7%
4f
7cH
2cF
2cH
2cH
2sO
3na;
(5) the C14 inner olefin sulfonic acid sodium of 2-7%, the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in described inner olefin sulfonic acid sodium is 93/7;
(6) water of surplus.
In described hair conditioner, preferably, the content of octadecyloxypropyl trimethyl ammonium chloride is preferably 9-12%, further preferred 10-11.5%.
Preferably, the content of described stearyl alcohol is 3-5%, preferably 4%.
Preferably, described inner olefin sulfonic acid sodium and C
4f
7cH
2cF
2cH
2cH
2sO
3the content of Na is 3-6%, and further preferably 5%.
Light hair conditioner of the present invention, it adopts the combination of specific sulfonate surfactants and inner olefin sulfonic acid sodium, and in the process of cleaning hair, lather quickness is fast, and washing is thorough and rear sensation of having had one's hair wash is salubrious.
Detailed description of the invention
The present invention is described hair conditioner of the present invention by following embodiment.
Embodiment 1
A kind of light hair conditioner, it comprises following component by weight percentage:
The octadecyloxypropyl trimethyl ammonium chloride of (1) 10%;
The stearyl alcohol of (2) 5%;
The methyl parahydroxybenzoate of (3) 0.3%;
The C of (4) 3%
4f
7cH
2cF
2cH
2cH
2sO
3na;
The C14 inner olefin sulfonic acid sodium of (5) 5%, the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in described inner olefin sulfonic acid sodium is 93/7;
(6) water of surplus.
Described internal olefin sulphonates is known compound, and it is typical but non-limiting, and to prepare example as follows:
Add 1-tetradecylene " Linealene14 " (Idemitsu Kosen Co., Ltd.'s manufacture) 6000g (26.7 moles), protic beta-zeolite " CP-814E " (Zeolyst company) 180g (be 3 quality %s relative to raw material alpha-olefin) as solid acid catalyst in the flask of agitating device, under agitation, at 120 DEG C, reaction 20 hours is carried out.Then, thick internal alkene is moved in distillation flask, distills under 124-136 DEG C/7.5mmHg, obtain thus alkene purity be 100% carbon number be the internal alkene of 14.The double bond of the internal alkene obtained be distributed as C1 position 1.3 quality %, C2 position 31.8 quality %, C3 position 23.8 quality %, C4 position 21.0 quality %, C5 position 8.6 quality %, C6,7 add up to 13.6 quality %.
By described carbon number be 14 internal olefin be added in outside and have in the diaphragm type sulfonation reactor of chuck, circulate the cooling water of 20 DEG C in reactor external jacket, uses sulfur trioxide gas to carry out sulfonating reaction under this condition.SO during sulfonating reaction
3the mol ratio of/internal alkene is set as 1.09.Obtained sulfonated bodies is made an addition in the aqueous solution prepared with the sodium hydroxide relative to theoretical acid number being 1.5 moles of times amount, carry out stirring at 30 DEG C in and 1 hour.Corrective is heated 1 hour in autoclave at 160 DEG C, is hydrolyzed thus, obtains C14 inner olefin sulfonic acid sodium crude product.This crude product 300g is moved to separatory funnel, after adding ethanol 300mL, adds petroleum ether 300mL every 1 time, extract the oil-soluble impurity of removing.Now, because the inorganic compound (main constituent is Natrii Sulfas) being added on oil-water interfaces precipitation of ethanol is also separated removing by oil-water separation operation from aqueous phase.Carry out three these extractions removing operation.Solid by aqueous phase side is evaporated, obtain C14 inner olefin sulfonic acid sodium.The mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in the inner olefin sulfonic acid sodium obtained is 93/7.In addition, the content of the raw material internal alkene in the internal alkene sodium sulfonate obtained is 0.5 quality % lower than 100ppm (lower than GC Monitoring lower-cut), inorganic compound.Further, sulfonic group is present in the content of the internal alkene sulfonate of 2 is 21.7 quality %.
Described C
4f
7cH
2cF
2cH
2cH
2sO
3na is similarly known compound, and it is typical but non-limiting, and to prepare example as follows:
Ethylene (25g, 0.53 mole) is joined and is filled with C
4f
9cH
2cF
2in the autoclave of I (217g, 0.87 mole) and d-(+)-limonene (1g), reactor is then made to heat 12 hours at 240 DEG C.By vacuum distilling under about 81 to 91 DEG C and 19 to 24mmHg (2533 to 3200Pa), obtain product C
4f
7cH
2cF
2cH
2cH
2i, yield 62%.By C
4f
7cH
2cF
2cH
2cH
2i (140g, 0.33 mole) joins in the mixture of ethanol (165mL) and water (165mL).Add sodium sulfite (83g, 0.66 mole), then add 8g copper.By reactant mixture vigorous stirring one week under reflux.Add 500mL water, and filter at 75 DEG C.Filtrate is cooled, and by collecting by filtration white solid product C
4f
7cH
2cF
2cH
2cH
2sO
3na (112g, 84%).
10 professional evaluators try out hair conditioner of the present invention, and all evaluate it and bubble fast, washing is thorough and rear sensation of having had one's hair wash is salubrious.
Comparative example 1
Only containing component (4), not containing component (5), all the other conditions are constant, after 10 professional evaluators are on probation, all evaluate its lather quickness slightly slow, feel clouding after having had one's hair wash.
Comparative example 2
Only containing component (5), not containing component (4), all the other conditions are constant, after 10 professional evaluators are on probation, all evaluate its lather quickness slightly slow, feel clouding after having had one's hair wash.
Above-described embodiment and comparative example explanation, hair conditioner of the present invention, composite by two kinds of dissimilar sodium sulfonates, under same amount prerequisite, its lather quickness and salubrious degree are better than being used alone of two kinds of components far away, prove to create cooperative effect between two kinds of sodium sulfonates that the present invention adopts.
Applicant states, the present invention illustrates hair conditioner of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned special formulation, does not namely mean that the present invention must rely on above-mentioned detailed component and formula could be implemented.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (4)
1. a light hair conditioner, it comprises following component by weight percentage:
(1) the octadecyloxypropyl trimethyl ammonium chloride of 8-15%;
(2) stearyl alcohol of 2-7%;
(3) methyl parahydroxybenzoate of 0.1-0.5%;
(4) C of 2-7%
4f
7cH
2cF
2cH
2cH
2sO
3na;
(5) the C14 inner olefin sulfonic acid sodium of 2-7%, the mass ratio of the hydroxyl body (hydroxyl alkane sulfonic acid sodium)/alkene body (alkene sulfonic acid sodium) in described inner olefin sulfonic acid sodium is 93/7;
(6) water of surplus.
2. light hair conditioner as claimed in claim 1, is characterized in that, the content of octadecyloxypropyl trimethyl ammonium chloride is preferably 9-12%, further preferred 10-11.5%.
3. light hair conditioner as claimed in claim 1, the content of described stearyl alcohol is 3-5%, preferably 4%.
4. light hair conditioner as claimed in claim 1, described inner olefin sulfonic acid sodium and C
4f
7cH
2cF
2cH
2cH
2sO
3the content of Na is 3-6%, and further preferably 5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510780604.7A CN105326653A (en) | 2015-11-14 | 2015-11-14 | Refreshing type hair conditioner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510780604.7A CN105326653A (en) | 2015-11-14 | 2015-11-14 | Refreshing type hair conditioner |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105326653A true CN105326653A (en) | 2016-02-17 |
Family
ID=55277566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510780604.7A Withdrawn CN105326653A (en) | 2015-11-14 | 2015-11-14 | Refreshing type hair conditioner |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105326653A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102216345A (en) * | 2008-11-13 | 2011-10-12 | 纳幕尔杜邦公司 | Fluorosulfonates |
| CN104661640A (en) * | 2012-09-20 | 2015-05-27 | 花王株式会社 | Cleansing composition for skin or hair |
-
2015
- 2015-11-14 CN CN201510780604.7A patent/CN105326653A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102216345A (en) * | 2008-11-13 | 2011-10-12 | 纳幕尔杜邦公司 | Fluorosulfonates |
| CN104661640A (en) * | 2012-09-20 | 2015-05-27 | 花王株式会社 | Cleansing composition for skin or hair |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20160217 |