CN105315405A - Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent - Google Patents
Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent Download PDFInfo
- Publication number
- CN105315405A CN105315405A CN201510785458.7A CN201510785458A CN105315405A CN 105315405 A CN105315405 A CN 105315405A CN 201510785458 A CN201510785458 A CN 201510785458A CN 105315405 A CN105315405 A CN 105315405A
- Authority
- CN
- China
- Prior art keywords
- preparation
- fast
- polyacrylamide paper
- paper
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paper (AREA)
Abstract
The invention discloses a preparation method of a quick-dissolving polyacrylamide paper-making dispersing agent. The preparation method comprises the following steps: preparing a solution from 180-280 parts of acrylamide, 120-250 parts of a sodium acrylate solution, 0.5-2 parts of a surfactant, 10-20 parts of an additive and 550-650 parts of deionized water, and properly adjusting the temperature and the pH value, and then transferring the adjusted solution into a reaction kettle; pumping nitrogen gas into the reaction kettle to completely remove oxygen, and adding 0.03-0.06 part of a chain transfer agent, 0.1-0.5 part of a water-soluble azo-type initiator and 0.08-0.12 part of a redox initiator to arouse a polymerization reaction; granulating a colloidal polymer, obtained after the reaction is finished, with a granulator, drying the colloidal particles at 65-75 DEG C, and then crushing the colloidal particles to obtain the quick-dissolving polyacrylamide paper-making dispersing agent. The quick-dissolving polyacrylamide paper-making dispersing agent has the advantages of being high in dissolving speed and viscosity, good in solubility and dispersion effect, degradation-resistant, nontoxic and the like.
Description
Technical field
The present invention relates to a kind of preparation method of paper-making dispersant agent, be specifically related to a kind of preparation method of fast-solving polyacrylamide paper-making dispersant agent.
Background technology
At present, polyacrylamide is because containing carboxyl in molecular chain, and there is the capillary effect of reduction, contribute to moistening to solid of water, this is advantageous particularly for the dispersion in water such as fiber, filler, when polyacrylamide adds slurry, fiber, filling surface can be made to form bimolecular structure, extreme and the water of outer dispersion agent has stronger avidity, adds the degree that the solids such as fiber, filler are spontaneously wet out by water.Between the solid particulate such as fiber, filler because of electrostatic repulsion away from, reach good dispersion effect.Although anionic polyacrylamide dispersion agent is used widely because of cost advantage, and quality product is uneven, the problems such as ubiquity dissolution rate is slow, poorly soluble, easy degraded.
Summary of the invention
Object of the present invention is exactly the defect existed for prior art, a kind of preparation method of fast-solving polyacrylamide paper-making dispersant agent is provided, it is high and stable that this product has viscosity, solvability is good, and dispersion effect is good, anti-degraded, nontoxic, dissolution rate fast (having in 30min is that solubilized is complete, and the energy consumption that obvious shortening dissolution time and reduction dissolved product cause improves production efficiency).
The present invention is achieved through the following technical solutions:
By the acrylamide of 180-280 part, the sodium acrylate solution of 120-250 part, 0.5-2 part tensio-active agent, the additive of 10-20 part, 550-650 part deionized water is mixed with solution, proceeds to reactor after adjusting temperature, pH value; Pass into nitrogen, oxygen is eliminated, then add the chain-transfer agent of 0.03-0.06 part, the redox initiator of 0.08-0.12 part, the water-soluble azo class initiator initiated polymerization of 0.1-0.5 part; Obtain gum polymers after reaction terminates, by gum polymers granulator granulation, micelle carries out drying in 65-75 DEG C, namely obtains product after drying through pulverizer fragmentation.
The additive sodium vinyl sulfonate that the present invention introduces, improve the wetting ability of polymkeric substance and anti-degradation property, as paper-making dispersant agent, dispersion efficiency is high, and improves gloss and the surface property of coating; For paper, this coating makes its wear resistance be improved.
Embodiment
Embodiment 1
Parts by weight of raw materials is: acrylamide 200g, sodium acrylate solution 170g, NP-100.5g, anti-SVS10g, deionized water 620g, lauryl mercaptan 0.03g, Sunmorl N 60S 0.015g, V500.1, Potassium Persulphate 0.03, sodium bisulfite 0.03;
Acrylamide, ammonium acrylate solution, NP-10, SVS, deionized water are joined successively in 1000 ml beakers; After stirring, adjustment PH to 6.5, temperature to 5 DEG C;
The solution prepared is proceeded in vacuum flask, logical nitrogen 40min deoxygenation; Add lauryl mercaptan, Sunmorl N 60S, V50, Potassium Persulphate, bisulfite sodium polymerization successively;
Obtain gum polymers after reaction terminates, by gum polymers granulator granulation, micelle carries out drying 3 hours in 65-75 DEG C, namely obtains product after drying through pulverizer fragmentation.
Embodiment 2
Parts by weight of raw materials is: acrylamide 220g, sodium acrylate solution 200g, NP-101g, anti-SVS15g, deionized water 565g, lauryl mercaptan 0.04g, Sunmorl N 60S 0.02g, V500.2, Potassium Persulphate 0.02, sodium bisulfite 0.01;
Acrylamide, ammonium acrylate solution, NP-10, SVS, deionized water are joined successively in 1000 ml beakers; After stirring, adjustment PH to 6.5, temperature to 5 DEG C;
The solution prepared is proceeded in vacuum flask, logical nitrogen 40min deoxygenation; Add lauryl mercaptan, Sunmorl N 60S, V50, Potassium Persulphate, bisulfite sodium polymerization successively;
Obtain gum polymers after reaction terminates, by gum polymers granulator granulation, micelle carries out drying 3 hours in 65-75 DEG C, namely obtains product after drying through pulverizer fragmentation.
Embodiment 3
Parts by weight of raw materials is: acrylamide 245g, sodium acrylate solution 189g, NP-102g, anti-SVS16g, deionized water 550g, lauryl mercaptan 0.038g, Sunmorl N 60S 0.019g, V500.23, Potassium Persulphate 0.035, sodium bisulfite 0.021;
Acrylamide, ammonium acrylate solution, NP-10, SVS, deionized water are joined successively in 1000 ml beakers; After stirring, adjustment PH to 6.5, temperature to 5 DEG C;
The solution prepared is proceeded in vacuum flask, logical nitrogen 40min deoxygenation; Add lauryl mercaptan, Sunmorl N 60S, V50, Potassium Persulphate, bisulfite sodium polymerization successively;
Obtain gum polymers after reaction terminates, by gum polymers granulator granulation, micelle carries out drying 3 hours in 65-75 DEG C, namely obtains product after drying through pulverizer fragmentation.
Above-described is only the preferred embodiment of the present invention, it should be pointed out that for the person of ordinary skill of the art, without departing from the concept of the premise of the invention, can also make some distortion and improvement, all belong to protection scope of the present invention.
Claims (7)
1. the preparation method of a fast-solving polyacrylamide paper-making dispersant agent, it is characterized in that: comprise following preparation process: by the acrylamide of 180-280 part, the sodium acrylate solution of 120-250 part, 0.5-2 part tensio-active agent, the additive of 10-20 part, 550-650 part deionized water is mixed with solution, proceeds to reactor after adjusting temperature, pH value; Pass into nitrogen, oxygen is eliminated, then add the chain-transfer agent of 0.03-0.06 part, the water-soluble azo class initiator of 0.1-0.5 part, the redox initiator initiated polymerization of 0.08-0.12 part; Obtain gum polymers after reaction terminates, by gum polymers granulator granulation, micelle carries out drying in 65-75 DEG C, namely obtains product after drying through pulverizer fragmentation.
2. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, is characterized in that: the concentration of described sodium acrylate solution is 23%.
3. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, is characterized in that: described tensio-active agent is alkylphenol polyoxyethylene (NP-10).
4. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, is characterized in that: described additive is sodium vinyl sulfonate (SVS).
5. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, it is characterized in that: described chain-transfer agent is lauryl mercaptan and Sunmorl N 60S, mass ratio is 2:1.
6. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, it is characterized in that: described temperature of reaction is 4-6 DEG C, pH value is 6.5-7.0.
7. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, it is characterized in that: described initiator is redox and azo-initiator composition composite initiation system, wherein oxygenant is the one in Potassium Persulphate, hydrogen peroxide, reductive agent is sodium bisulfite, and described water-soluble azo class initiator is V50.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510785458.7A CN105315405A (en) | 2015-11-17 | 2015-11-17 | Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510785458.7A CN105315405A (en) | 2015-11-17 | 2015-11-17 | Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105315405A true CN105315405A (en) | 2016-02-10 |
Family
ID=55243790
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510785458.7A Pending CN105315405A (en) | 2015-11-17 | 2015-11-17 | Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105315405A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050234176A1 (en) * | 2000-12-20 | 2005-10-20 | Coatex S.A.S. | Grinding and/or dispersing aid of mineral materials in aqueous suspension, resulting aqueous suspensions and uses thereof |
| CN1950336A (en) * | 2004-07-28 | 2007-04-18 | 可泰克斯有限合伙公司 | Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof |
| CN101532266A (en) * | 2008-12-29 | 2009-09-16 | 北京希涛技术开发有限公司 | Synthesis and production method for star polymer for paper making dispersant |
| CN104059194A (en) * | 2013-12-15 | 2014-09-24 | 安徽巨成精细化工有限公司 | Preparation method of rapidly-soluble papermaking dispersant polyacrylamide |
| CN104404824A (en) * | 2014-11-07 | 2015-03-11 | 安徽天润化学工业股份有限公司 | Star-shaped polymer papermaking dispersant and preparation method thereof |
| CN105315402A (en) * | 2014-07-04 | 2016-02-10 | 山东诺尔生物科技有限公司 | Preparation method of quick-dissolving polyacrylamide papermaking dispersant |
-
2015
- 2015-11-17 CN CN201510785458.7A patent/CN105315405A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050234176A1 (en) * | 2000-12-20 | 2005-10-20 | Coatex S.A.S. | Grinding and/or dispersing aid of mineral materials in aqueous suspension, resulting aqueous suspensions and uses thereof |
| CN1950336A (en) * | 2004-07-28 | 2007-04-18 | 可泰克斯有限合伙公司 | Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof |
| CN101532266A (en) * | 2008-12-29 | 2009-09-16 | 北京希涛技术开发有限公司 | Synthesis and production method for star polymer for paper making dispersant |
| CN104059194A (en) * | 2013-12-15 | 2014-09-24 | 安徽巨成精细化工有限公司 | Preparation method of rapidly-soluble papermaking dispersant polyacrylamide |
| CN105315402A (en) * | 2014-07-04 | 2016-02-10 | 山东诺尔生物科技有限公司 | Preparation method of quick-dissolving polyacrylamide papermaking dispersant |
| CN104404824A (en) * | 2014-11-07 | 2015-03-11 | 安徽天润化学工业股份有限公司 | Star-shaped polymer papermaking dispersant and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105315402A (en) | Preparation method of quick-dissolving polyacrylamide papermaking dispersant | |
| CN102976657B (en) | Slushing agent for concrete and preparation method thereof | |
| CN102060965B (en) | Preparation method of partially hydrolyzed polyacrylamide with improved temperature and salt resisting performances | |
| CN112694574B (en) | Polycarboxylate superplasticizer with high mud resistance and high slump loss resistance and preparation method thereof | |
| CN104479084B (en) | Polycarboxylate based anti-mud agent and preparation method thereof | |
| CN104479066A (en) | Concrete viscosity adjusting agent and preparation method thereof | |
| CN105037648A (en) | Slump-retaining water-reducing polycarboxylic acid water reducing agent and low-temperature quick preparation method thereof | |
| CN101747885B (en) | Method for preparing high molecular weight salt-resistant polymer oil displacement agents | |
| CN105418839A (en) | Preparation method of anion water-in-water type polyacrylamide | |
| CN101735387B (en) | Preparation method of anionic polyacrylamide | |
| CN106832113A (en) | A kind of temperature-resistant anti-salt flooding polymers containing nano particle | |
| CN104987469A (en) | Preparing method for high dispersion type polycarboxylate water reducing agent | |
| CN110642994A (en) | Preparation method of stone powder adaptive polycarboxylate superplasticizer | |
| JP7174162B2 (en) | Acrylamide copolymer and its production method and application | |
| CN108046653B (en) | External admixture for shield single-liquid synchronous grouting | |
| CN112661914A (en) | Novel polycarboxylate superplasticizer special for machine-made sand and preparation method thereof | |
| CN103087236A (en) | Method for preparing high-molecular-weight anionic polyacrylamide through ultralow-temperature initiation | |
| CN104926996A (en) | Preparation method for amphoteric ion modified starch for well drilling fluid | |
| CN105315405A (en) | Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent | |
| CN109627394A (en) | A kind of polycarboxylate concrete dehydragent and preparation method thereof being adapted to Machine-made Sand | |
| CN102060950A (en) | Method for preparing homopolymer and copolymer of dimethyl diallyl ammonium chloride | |
| CN112126017B (en) | Acrylamide functional polymer, and preparation method and application thereof | |
| CN102219879B (en) | Method for producing polyacrylamide emulsion | |
| CN105384874A (en) | Preparation method of water-in-water emulsion-type cation polysaccharide biological flocculant | |
| CN114479798B (en) | Hydrophobic association polymer type plugging agent and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160210 |