CN105312794A - Honeycomb structure - Google Patents

Honeycomb structure Download PDF

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Publication number
CN105312794A
CN105312794A CN201510731425.4A CN201510731425A CN105312794A CN 105312794 A CN105312794 A CN 105312794A CN 201510731425 A CN201510731425 A CN 201510731425A CN 105312794 A CN105312794 A CN 105312794A
Authority
CN
China
Prior art keywords
alloy
honeycomb
brazing
base alloy
cellular core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510731425.4A
Other languages
Chinese (zh)
Inventor
杜静
金莹
曲伸
孔庆吉
张磊先
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenyang Liming Aero Engine Group Co Ltd
Original Assignee
Shenyang Liming Aero Engine Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenyang Liming Aero Engine Group Co Ltd filed Critical Shenyang Liming Aero Engine Group Co Ltd
Priority to CN201510731425.4A priority Critical patent/CN105312794A/en
Publication of CN105312794A publication Critical patent/CN105312794A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/32Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C
    • B23K35/325Ti as the principal constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/008Soldering within a furnace
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00Articles made by soldering, welding or cutting
    • B23K2101/02Honeycomb structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/08Non-ferrous metals or alloys
    • B23K2103/10Aluminium or alloys thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/18Dissimilar materials

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention provides a honeycomb structure and belongs to the technical field of welding. The honeycomb structure is composed of a Ti3Al-based alloy ring and a GH536 alloy honeycomb core. Ti-based brazing filler metal is adopted. The Ti3Al-based alloy ring and the GH536 alloy honeycomb core are connected into a whole through a brazing welding connection method to form the honeycomb structure. According to the honeycomb structure, brazing welding connection of the Ti3Al-based alloy ring and the GH536 alloy honeycomb core is achieved. In addition, the weight is light, the specific strength is high, and the temperature tolerance is good. The brazing welding quality of the honeycomb structure meets the acceptance standard requirement.

Description

A kind of honeycomb
Technical field
The invention belongs to welding technology field, particularly relate to a kind of honeycomb.
Background technology
Metal honeycomb structure is that high-temperature fuel gas machine is obturaged parts, and conventional honeycomb is that metal honeycomb core and housing adopt brazing to form, and honeycomb core and case material are generally stainless steel or high temperature alloy.Ti 3al base alloy at high temperature (800 ~ 850 DEG C) has good high-temperature behavior, and density is lower, can weight reduction 40% compared with nickel base superalloy, therefore, and Ti 3al base alloy components has good application prospect.Ti 3al base alloy cellular structure is by Ti 3al base alloy hoop and GH536 alloy cellular core link together.At present, study more to the soldering processes of stainless steel, iron-base superalloy, nickel base superalloy and GH536 alloy both at home and abroad, Joining Technology relative maturity, but for Ti 3the soldering processes of Al base alloy and GH536 alloy have no report.The soldering processes of existing stainless steel, iron-base superalloy, nickel base superalloy and GH536 alloy, soldering solder is nickel-based solder, and technology is comparatively ripe, but nickel-based solder is to Ti 3the wetability of Al base alloy and GH536 alloy-junction and joint filling are all undesirable, and the intensity of soldered fitting is lower, can not meet instructions for use.
Summary of the invention
For prior art Problems existing, the invention provides a kind of lightweight, specific strength is high, temperature tolerance is good honeycomb, the brazing quality of this honeycomb meets acceptance criteria requirement.
To achieve these goals, the present invention adopts following technical scheme, and a kind of honeycomb, by Ti 3al base alloy hoop and GH536 alloy cellular core composition, adopt titanium based solder, by soldering connecting method by Ti 3al base alloy hoop and GH536 alloy cellular core link into an integrated entity, and form honeycomb.
The composition of described titanium based solder is by weight percentage:
Ti:37~78%,Cu:12~30%,Ni:8~23%,Cr:2~10%。
The composition of described titanium based solder is by weight percentage:
Ti:47%,Cu:20%,Ni:23%,Cr:10%。
The composition of described titanium based solder is by weight percentage:
Ti:58%,Cu:30%,Ni:10%,Cr:2%。
The composition of described titanium based solder is by weight percentage:
Ti:49%,Cu:25%,Ni:20%,Cr:6%。
The composition of described titanium based solder is by weight percentage:
Ti:68%,Cu:15%,Ni:13%,Cr:4%。
Beneficial effect of the present invention:
Honeycomb of the present invention achieves Ti 3the brazing of Al base alloy hoop and GH536 alloy cellular core, and lightweight, specific strength is high, temperature tolerance good, the brazing quality of this honeycomb meets acceptance criteria requirement.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
A kind of honeycomb, by Ti 3al base alloy hoop and GH536 alloy cellular core composition, adopt titanium based solder, by soldering connecting method by Ti 3al base alloy hoop and GH536 alloy cellular core link into an integrated entity, and form honeycomb.The composition of described titanium based solder is by weight percentage: Ti:37 ~ 78%, Cu:12 ~ 30%, Ni:8 ~ 23%, Cr:2 ~ 10%.
This titanium based solder is to Ti 3al base alloy and GH536 alloy all have good wetability and joint filling.
Embodiment 1
1) by matrix powder solder by weight percentage Ti:47%, Cu:20%, Ni:23%, Cr:10% binding agent be in harmonious proportion, and make adhesive tape, adhesive tape thickness is 0.7 ~ 1.0mm;
2) sticky brazing filler material is placed in GH536 alloy cellular core and Ti 3between Al base alloy hoop, and entirety is placed on fixture, makes GH536 alloy cellular core and Ti 3al base alloy hoop fits tightly;
3) by GH536 alloy cellular core and Ti 3al base alloy hoop is put into vacuum brazing furnace together with fixture and is carried out vacuum brazing, brazing process parameter: 980 DEG C, insulation 40min, and postwelding cools to less than 500 DEG C with the furnace and carries out rapid cooling;
4) GH536 alloy cellular core and Ti is checked 3al base alloy hoop brazing quality, ratio of brazing area is greater than 90%.
Embodiment 2
1) by matrix powder solder by weight percentage Ti:58%, Cu:30%, Ni:10%, Cr:2% binding agent be in harmonious proportion, and make adhesive tape, adhesive tape thickness is 0.7 ~ 1.0mm;
2) sticky brazing filler material is placed in GH536 alloy cellular core and Ti 3between Al base alloy hoop, and entirety is placed on fixture, makes GH536 alloy cellular core and Ti 3al base alloy hoop fits tightly;
3) by GH536 alloy cellular core and Ti 3al base alloy hoop is put into vacuum brazing furnace together with fixture and is carried out vacuum brazing, brazing process parameter: 950 DEG C, insulation 60min, and postwelding cools to less than 500 DEG C with the furnace and carries out rapid cooling;
4) GH536 alloy cellular core and Ti is checked 3al base alloy hoop brazing quality, ratio of brazing area is greater than 90%.
Embodiment 3
1) by matrix powder solder by weight percentage Ti:49%, Cu:25%, Ni:20%, Cr:6% binding agent be in harmonious proportion, and make adhesive tape, adhesive tape thickness is 0.7 ~ 1.0mm;
2) sticky brazing filler material is placed in GH536 alloy cellular core and Ti 3between Al base alloy hoop, and entirety is placed on fixture, makes GH536 alloy cellular core and Ti 3al base alloy hoop fits tightly;
3) by GH536 alloy cellular core and Ti 3al base alloy hoop is put into vacuum brazing furnace together with fixture and is carried out vacuum brazing, brazing process parameter: 960 DEG C, insulation 50min, and postwelding cools to less than 500 DEG C with the furnace and carries out rapid cooling;
4) GH536 alloy cellular core and Ti is checked 3al base alloy hoop brazing quality, ratio of brazing area is greater than 90%.
Embodiment 4
1) by matrix powder solder by weight percentage Ti:68%, Cu:15%, Ni:13%, Cr:4% binding agent be in harmonious proportion, and make adhesive tape, adhesive tape thickness is 0.7 ~ 1.0mm;
2) sticky brazing filler material is placed in GH536 alloy cellular core and Ti 3between Al base alloy hoop, and entirety is placed on fixture, makes GH536 alloy cellular core and Ti 3al base alloy hoop fits tightly;
3) by GH536 alloy cellular core and Ti 3al base alloy hoop is put into vacuum brazing furnace together with fixture and is carried out vacuum brazing, brazing process parameter: 970 DEG C, insulation 45min, and postwelding cools to less than 500 DEG C with the furnace and carries out rapid cooling;
4) GH536 alloy cellular core and Ti is checked 3al base alloy hoop brazing quality, ratio of brazing area is greater than 90%.
Soldered fitting the performance test results:
The hot strength of table 1 soldered fitting
The shear strength of table 2 soldered fitting
The hoc scenario of soldered fitting:
Metallographic structure from soldered fitting: joint clearance of brazing filled by solder, and continuous, fine and close, solder is at Ti 3there is obvious diffusion transition district Al base alloy side, simultaneously solder and the counterdiffusion of matrix material element phase, and form metallurgical binding, brazing quality is better.

Claims (6)

1. a honeycomb, is characterized in that by Ti 3al base alloy hoop and GH536 alloy cellular core composition, adopt titanium based solder, by soldering connecting method by Ti 3al base alloy hoop and GH536 alloy cellular core link into an integrated entity, and form honeycomb.
2. honeycomb according to claim 1, is characterized in that the composition of described titanium based solder is by weight percentage: Ti:37 ~ 78%, Cu:12 ~ 30%, Ni:8 ~ 23%, Cr:2 ~ 10%.
3. honeycomb according to claim 2, is characterized in that the composition of described titanium based solder is by weight percentage: Ti:47%, Cu:20%, Ni:23%, Cr:10%.
4. honeycomb according to claim 2, is characterized in that the composition of described titanium based solder is by weight percentage: Ti:58%, Cu:30%, Ni:10%, Cr:2%.
5. honeycomb according to claim 2, is characterized in that the composition of described titanium based solder is by weight percentage: Ti:49%, Cu:25%, Ni:20%, Cr:6%.
6. honeycomb according to claim 2, is characterized in that the composition of described titanium based solder is by weight percentage: Ti:68%, Cu:15%, Ni:13%, Cr:4%.
CN201510731425.4A 2015-10-30 2015-10-30 Honeycomb structure Pending CN105312794A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510731425.4A CN105312794A (en) 2015-10-30 2015-10-30 Honeycomb structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510731425.4A CN105312794A (en) 2015-10-30 2015-10-30 Honeycomb structure

Publications (1)

Publication Number Publication Date
CN105312794A true CN105312794A (en) 2016-02-10

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108500510A (en) * 2018-03-29 2018-09-07 西北有色金属研究院 A kind of titanium-base alloy cored solder containing chromium
CN113145962A (en) * 2021-03-09 2021-07-23 哈尔滨工业大学(威海) Heterogeneous metal material honeycomb sandwich structure and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63192592A (en) * 1987-02-05 1988-08-09 Daido Steel Co Ltd Brazing filler material
WO2005007336A1 (en) * 2003-07-14 2005-01-27 Honeywell International Inc. Low cost brazes for titanium
CN101439447A (en) * 2008-12-30 2009-05-27 沈阳黎明航空发动机(集团)有限责任公司 Solder
CN102107307A (en) * 2009-12-23 2011-06-29 沈阳黎明航空发动机(集团)有限责任公司 Vacuum brazing process for honeycomb structure of heavy-duty combustion engine
CN103173657A (en) * 2013-03-11 2013-06-26 中国航空工业集团公司北京航空材料研究院 Intermediate layer for brazing connection of Ti3Al-based alloy and high-temperature alloy honeycomb structure
CN103567666A (en) * 2013-11-15 2014-02-12 中国航空工业集团公司北京航空制造工程研究所 Strip-shaped brazing filler metal for titanium alloy brazing and Ti2AlNb alloy brazing, preparation method thereof and brazing method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63192592A (en) * 1987-02-05 1988-08-09 Daido Steel Co Ltd Brazing filler material
WO2005007336A1 (en) * 2003-07-14 2005-01-27 Honeywell International Inc. Low cost brazes for titanium
CN101439447A (en) * 2008-12-30 2009-05-27 沈阳黎明航空发动机(集团)有限责任公司 Solder
CN102107307A (en) * 2009-12-23 2011-06-29 沈阳黎明航空发动机(集团)有限责任公司 Vacuum brazing process for honeycomb structure of heavy-duty combustion engine
CN103173657A (en) * 2013-03-11 2013-06-26 中国航空工业集团公司北京航空材料研究院 Intermediate layer for brazing connection of Ti3Al-based alloy and high-temperature alloy honeycomb structure
CN103567666A (en) * 2013-11-15 2014-02-12 中国航空工业集团公司北京航空制造工程研究所 Strip-shaped brazing filler metal for titanium alloy brazing and Ti2AlNb alloy brazing, preparation method thereof and brazing method

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Title
中国机械工程学会焊接学报编: "《焊接手册 第一卷 焊接方法及设备(第三版)》", 31 January 2008 *
李晓红等: "《先进航空材料焊接技术》", 31 January 2012, 国防工业出版社 *
陈波等: "采用Ti-Zr-Cu-Ni真空钎焊Ti3Al/Ti3Al和Ti3Al/GH536接头组织及性能", 《航空材料学报》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108500510A (en) * 2018-03-29 2018-09-07 西北有色金属研究院 A kind of titanium-base alloy cored solder containing chromium
CN113145962A (en) * 2021-03-09 2021-07-23 哈尔滨工业大学(威海) Heterogeneous metal material honeycomb sandwich structure and preparation method thereof
CN113145962B (en) * 2021-03-09 2022-12-06 哈尔滨工业大学(威海) Heterogeneous metal material honeycomb sandwich structure and preparation method thereof

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Application publication date: 20160210

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