CN105311936B - A kind of long-acting air pollution treatment agent and its application - Google Patents
A kind of long-acting air pollution treatment agent and its application Download PDFInfo
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- CN105311936B CN105311936B CN201510837490.5A CN201510837490A CN105311936B CN 105311936 B CN105311936 B CN 105311936B CN 201510837490 A CN201510837490 A CN 201510837490A CN 105311936 B CN105311936 B CN 105311936B
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- Prior art keywords
- jello
- treatment agent
- air pollution
- pollution treatment
- long
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- 238000003915 air pollution Methods 0.000 title claims abstract description 53
- 239000000376 reactant Substances 0.000 claims abstract description 61
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 60
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000004155 Chlorine dioxide Substances 0.000 claims abstract description 16
- 235000019398 chlorine dioxide Nutrition 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims abstract description 9
- 239000000809 air pollutant Substances 0.000 claims abstract description 7
- 231100001243 air pollutant Toxicity 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 55
- 239000000499 gel Substances 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 14
- 229920002472 Starch Polymers 0.000 claims description 13
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 13
- 239000008107 starch Substances 0.000 claims description 13
- 235000019698 starch Nutrition 0.000 claims description 13
- 239000007853 buffer solution Substances 0.000 claims description 12
- 229920001817 Agar Polymers 0.000 claims description 10
- 241000206672 Gelidium Species 0.000 claims description 10
- 235000010419 agar Nutrition 0.000 claims description 10
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229960002218 sodium chlorite Drugs 0.000 claims description 8
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 7
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 7
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 7
- 239000012188 paraffin wax Substances 0.000 claims description 7
- 239000008055 phosphate buffer solution Substances 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- 239000002952 polymeric resin Substances 0.000 claims description 6
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 229920003002 synthetic resin Polymers 0.000 claims description 6
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 4
- -1 DBSA Substances 0.000 claims description 4
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 4
- 239000000872 buffer Substances 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 4
- 239000001630 malic acid Substances 0.000 claims description 4
- 235000011090 malic acid Nutrition 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- HDMGAZBPFLDBCX-UHFFFAOYSA-M potassium;sulfooxy sulfate Chemical compound [K+].OS(=O)(=O)OOS([O-])(=O)=O HDMGAZBPFLDBCX-UHFFFAOYSA-M 0.000 claims description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- SPOMEWBVWWDQBC-UHFFFAOYSA-K tripotassium;dihydrogen phosphate;hydrogen phosphate Chemical compound [K+].[K+].[K+].OP(O)([O-])=O.OP([O-])([O-])=O SPOMEWBVWWDQBC-UHFFFAOYSA-K 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims description 3
- 229940092714 benzenesulfonic acid Drugs 0.000 claims description 3
- CBMPTFJVXNIWHP-UHFFFAOYSA-L disodium;hydrogen phosphate;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Na+].[Na+].OP([O-])([O-])=O.OC(=O)CC(O)(C(O)=O)CC(O)=O CBMPTFJVXNIWHP-UHFFFAOYSA-L 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- LRWJZGCOPMDWFZ-UHFFFAOYSA-N phthalic acid;hydrochloride Chemical compound Cl.OC(=O)C1=CC=CC=C1C(O)=O LRWJZGCOPMDWFZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- BUCIWTBCUUHRHZ-UHFFFAOYSA-K potassium;disodium;dihydrogen phosphate;hydrogen phosphate Chemical compound [Na+].[Na+].[K+].OP(O)([O-])=O.OP([O-])([O-])=O BUCIWTBCUUHRHZ-UHFFFAOYSA-K 0.000 claims description 3
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 claims description 3
- XPFJYKARVSSRHE-UHFFFAOYSA-K trisodium;2-hydroxypropane-1,2,3-tricarboxylate;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Na+].[Na+].[Na+].OC(=O)CC(O)(C(O)=O)CC(O)=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O XPFJYKARVSSRHE-UHFFFAOYSA-K 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 235000009508 confectionery Nutrition 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 229940075529 glyceryl stearate Drugs 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- ALYXOEGGPMWBCL-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium;hydrochloride Chemical compound [Na].Cl.OC(=O)CC(O)(C(O)=O)CC(O)=O ALYXOEGGPMWBCL-UHFFFAOYSA-N 0.000 claims 1
- 239000004925 Acrylic resin Substances 0.000 claims 1
- HFEWAGKDZLEFCT-UHFFFAOYSA-L C(C)C(COP(=O)(OCC(CCCC)CC)[O-])CCCC.P(=O)(O)([O-])O.[Na+].[Na+] Chemical compound C(C)C(COP(=O)(OCC(CCCC)CC)[O-])CCCC.P(=O)(O)([O-])O.[Na+].[Na+] HFEWAGKDZLEFCT-UHFFFAOYSA-L 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical compound [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 230000000704 physical effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 238000002955 isolation Methods 0.000 abstract description 2
- 238000012423 maintenance Methods 0.000 abstract description 2
- 239000000686 essence Substances 0.000 description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 238000002156 mixing Methods 0.000 description 18
- 239000000203 mixture Substances 0.000 description 15
- 235000015165 citric acid Nutrition 0.000 description 8
- 229920002125 Sokalan® Polymers 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 6
- 235000019799 monosodium phosphate Nutrition 0.000 description 5
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 5
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 235000006679 Mentha X verticillata Nutrition 0.000 description 4
- 235000002899 Mentha suaveolens Nutrition 0.000 description 4
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 4
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 4
- 235000019796 monopotassium phosphate Nutrition 0.000 description 4
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 4
- 239000008363 phosphate buffer Substances 0.000 description 4
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000013268 sustained release Methods 0.000 description 4
- 239000012730 sustained-release form Substances 0.000 description 4
- LEAHFJQFYSDGGP-UHFFFAOYSA-K trisodium;dihydrogen phosphate;hydrogen phosphate Chemical compound [Na+].[Na+].[Na+].OP(O)([O-])=O.OP([O-])([O-])=O LEAHFJQFYSDGGP-UHFFFAOYSA-K 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 150000003926 acrylamides Chemical class 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000011167 hydrochloric acid Nutrition 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 241000220317 Rosa Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- AYBSICMEDZIQTK-UHFFFAOYSA-K dipotassium sodium phosphoric acid phosphate Chemical compound [Na+].[K+].[K+].OP(O)(O)=O.[O-]P([O-])([O-])=O AYBSICMEDZIQTK-UHFFFAOYSA-K 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- HXMWJLVXIHYART-UHFFFAOYSA-M sodium;2-hydroxypropane-1,2,3-tricarboxylic acid;hydroxide;hydrochloride Chemical compound [OH-].[Na+].Cl.OC(=O)CC(O)(C(O)=O)CC(O)=O HXMWJLVXIHYART-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- JNMCQUJGQWZYMW-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium Chemical compound [Na].OC(=O)CC(O)(C(O)=O)CC(O)=O.OC(=O)CC(O)(C(O)=O)CC(O)=O JNMCQUJGQWZYMW-UHFFFAOYSA-N 0.000 description 1
- OQVYMXCRDHDTTH-UHFFFAOYSA-N 4-(diethoxyphosphorylmethyl)-2-[4-(diethoxyphosphorylmethyl)pyridin-2-yl]pyridine Chemical compound CCOP(=O)(OCC)CC1=CC=NC(C=2N=CC=C(CP(=O)(OCC)OCC)C=2)=C1 OQVYMXCRDHDTTH-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- NHYCGSASNAIGLD-UHFFFAOYSA-N Chlorine monoxide Chemical compound Cl[O] NHYCGSASNAIGLD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- XINCECQTMHSORG-UHFFFAOYSA-N Isoamyl isovalerate Chemical compound CC(C)CCOC(=O)CC(C)C XINCECQTMHSORG-UHFFFAOYSA-N 0.000 description 1
- 235000010676 Ocimum basilicum Nutrition 0.000 description 1
- 240000007926 Ocimum gratissimum Species 0.000 description 1
- 241000255964 Pieridae Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical class [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229960001631 carbomer Drugs 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- QSLMXDUZJAJNJO-UHFFFAOYSA-L disodium hydrogen phosphate phosphoric acid Chemical compound [Na+].[Na+].OP(O)(O)=O.OP(O)(O)=O.OP([O-])([O-])=O QSLMXDUZJAJNJO-UHFFFAOYSA-L 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000003694 hair properties Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000007968 orange flavor Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229940056211 paraffin Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 description 1
- 229910000343 potassium bisulfate Inorganic materials 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of long-acting air pollution treatment agent, it is made up of jello A and jello B, jello A and jello B include reactant, carrier and conditioner；Conditioner includes the pH conditioners of regulation jello pH value and the character conditioner of regulation jello character.A kind of long-acting air pollution treatment agent provided by the invention, using pH cushioning liquid maintenance system pH, ensure that reaction is at the uniform velocity carried out, chlorine dioxide rate of release is more stable；Gel Biodegradable, use rear noresidue；Not comprising the acid for having severe corrosive, accumulating and use are safer；One of application of air pollution treatment agent of the present invention is dispensed using isolation in removing air pollutants in micro- space, is not contacted between jello, ensure that the storing and transporting security of product, substantially prolongs the shelf-life.
Description
Technical field
The present invention relates to a kind of long-acting air pollution treatment agent and its application, air pollution treatment agent field is particularly belonged to.
Background technology
In the prior art, for just fit up interior, new car, formaldehyde in micro- space such as new furniture, benzene, dimethylbenzene and other
Mainly active charcoal absorption, the photocatalyst degraded etc. of TVOCs (total volatile organism) administration way.Charcoal absorption takes effect
Slowly, and there is saturability, and the release polluted is lasting within a period of time.The sustainable reaction of photocatalyst, but it is strong by illumination
Degree limitation, treatment effeciency is relatively low, and has pollution to utensil.
Chlorine dioxide under a kind of a kind of unique generally state as, with safe disinfection agent existing for gaseous state, having wide spectrum, peace
Entirely, efficient good characteristic.But because its own is unstable, in, often it is made into the dosage forms such as liquid or solid and enters
Row application.Solid preparation of chlorine dioxide expands two because it has the advantages that easy to use, safe, stability is good, is readily transported
The application of chlorine monoxid, it has also become the ideal form of chlorine dioxide civil applications.
A kind of sheet being pressed into by sodium chlorite, acidifying sustained release agent, stabilizer is disclosed in patent CN100539846C
Chlorine dioxide slow-release preparation agent；One kind is disclosed in CN101384507B is by chlorite, sodium dihydrogen phosphate, citric acid, tartaric acid
Main component, moisture sustained release agent, deliquescent agent, the material of gel are added, control slow reaction to generate dioxy by moisture sustained release agent
Change chlorine；It is polymeric PTC materials layer that one kind is disclosed in CN102160552B by outer layer, and internal layer is that sodium chlorite is tied with the double-deck of acid
Structure sustained release agent；A kind of chlorine dioxide slow-release that sodium chlorite and solid acid are wrapped up by polyvinyl alcohol is disclosed in CN102791621B
Agent, it must be reacted in the environment with water during use；One kind is disclosed in CN102811946B by sodium chlorite, cellulose, acid, fibre
It is raw material to tie up element, and chlorine dioxide occurs, and is absorbed by surfactant etc., then is discharged by porous jar.
Above-mentioned patented product has following one or more deficiencies：(1) chlorine dioxide rate of release is unstable；(2) use
The matrix residues such as rear acrylic acid, acrylamide are not degradable, not environmentally；(3) shelf-life is shorter, apt to deteriorate；(4) use
In easily contacted with reactant, security is poor；(5) potential safety hazard be present containing the strong component that is corrosive in reaction raw materials.Cause
This, invents a kind of long-acting air pollution treatment agent that can solve the problem that drawbacks described above, it appears particularly necessary.
The content of the invention
To solve the deficiencies in the prior art, it is an object of the invention to provide a kind of long-acting air pollution treatment agent and its answer
With the long-acting air pollution treatment agent can keep chlorine dioxide rate of release stable, can be used for removing sky in micro- space
Gas pollutant.
In order to realize above-mentioned target, the present invention adopts the following technical scheme that：
A kind of long-acting air pollution treatment agent, is made up of jello A and jello B, and jello A and jello B are included
There are reactant, carrier and conditioner；The conditioner includes the pH conditioners and regulation jello character of regulation jello pH value
Character conditioner；The reactant of the jello A be sodium chlorite, sodium chlorate, potassium hydrogen persulfate composite salts, hydrogen peroxide or
One or more in potassium permanganate, wherein at least including one kind in sodium chlorite or sodium chlorate；The reaction of the jello B
Thing is citric acid, malic acid, trifluoromethanesulfonic acid, benzene sulfonic acid, pyrovinic acid, DBSA, oxalic acid, malonic acid or formic acid
In one or more.
In foregoing long-acting air pollution treatment agent, jello A and jello B are prepared according to following steps：
S1, prepare reactant solution A, reactant solution B and pH conditioner；
S2, pH conditioners are added into reactant solution, reactant solution A, reactant solution B pH value are adjusted to respectively
5~7,2~5, carrier and character conditioner are added, stirring gel produces.
In foregoing long-acting air pollution treatment agent, carrier is agar-agar, CMS polymer resin, starch graft acrylic acid
One or more in salt resin, starch graft acrylamide resin or hydroxyethyl cellulose graft acrylamide polymer.
In foregoing long-acting air pollution treatment agent, pH conditioners are glycine-HCI buffer solution, phthalic acid-hydrochloric acid
Cushioning liquid, disodium hydrogen phosphate-citric acid solution, citric acid-sodium hydroxide-hydrochloric acid buffer solution, citric acid-citric acid
Sodium cushioning liquid, NaAc_HAc buffer solution, disodium hydrogen phosphate-sodium dihydrogen phosphate buffer, disodium hydrogen phosphate-phosphoric acid
In potassium dihydrogen cushioning liquid, dipotassium hydrogen phosphate-potassium dihydrogen phosphate buffer solution or dipotassium hydrogen phosphate-phosphate sodium dihydrogen buffer solution
It is a kind of.
In foregoing long-acting air pollution treatment agent, character conditioner is carbomer, paraffin, glyceryl stearate, carboxymethyl
One or more in sodium cellulosate, hexadecanol or octadecyl alcolol.
In foregoing long-acting air pollution treatment agent, reactant solution A concentration is 100~800mg/L, according to volume ratio,
Reactant solution A:PH conditioner=1~10:1~5；Reactant solution B concentration is 50~1000mg/L, according to volume ratio,
Reactant solution B:PH conditioner=1~10:1~5.
In foregoing long-acting air pollution treatment agent, in jello A and jello B, according to mass volume ratio, carrier and character
The gross mass of conditioner:Volume=0.1 of reactant solution~1g/mL；In jello A, according to mass ratio, carrier:Character is adjusted
Manage agent=0.5~5:0.1~1；In jello B, according to mass ratio, carrier:Character conditioner=2~5:0.1~1.
In foregoing long-acting air pollution treatment agent, also include additive, the additive in jello A and/or jello B
Include daily chemical essence and essence solubilizer；Preferably, the additive also includes ethanol, and waving for essence can be improved by adding ethanol
Hair property.
In foregoing long-acting air pollution treatment agent, according to volume ratio, reactant solution:Daily chemical essence:Ethanol:Essence solubilising
Agent=50~1000:1~8:5~20:1~2.
Application of the long-acting air pollution treatment agent of the present invention in micro- space removal air pollutants.
The application of foregoing long-acting air pollution treatment agent, specifically includes following steps：Jello A and jello B is distinguished
It is placed in the lower floor and rotatable upper strata of double-deck box, there is passage rotatable upper strata upper surface, and upper strata bottom and lower floor top are
Provided with size is identical, position equidistant space accordingly；Two layers of space shifts to install, and rotating upper layer causes two layers of space to overlap,
Jello A and jello B haptoreactions, chlorine dioxide is discharged from passage, air pollutants are removed in micro- space.
Implement a kind of device of long-acting air pollution treatment agent application, be a kind of double-deck box, including rotatable upper strata is with
Layer, the upper surface on rotatable upper strata are provided with passage, the bottom on rotatable upper strata be equipped with that size is identical, position at the top of lower floor
Put corresponding equidistant space；Two layers of space shifts to install.
Schematic device is as depicted in figs. 1 and 2.The jello A and jello B of long-acting air pollution treatment agent are respectively placed in
In rotatable the upper and lower, the space in two layers is shifted to install so that jello A and jello B are not contacted.In use, rotation
Turning upper strata so that two layers of space overlaps, and jello A and jello B haptoreactions, chlorine dioxide is discharged from passage,
Air pollutants are removed in micro- space.
The time that the long-acting air pollution treatment agent of the present invention can stablize release is at least up to more than 20 days, and release profiles are such as
Shown in Fig. 3.By taking 30 square metres of the interior space within formaldehyde and exceeded 5 times of benzene difference as an example, the length of the 200g present invention is used
Effect air pollution treatment agent can make air quality up to standard in 30 minutes.
The present invention is advantageous in that：A kind of long-acting air pollution treatment agent provided by the invention, buffered using pH molten
Liquid maintenance system pH, ensures that reaction is at the uniform velocity carried out, makes reaction more abundant, chlorine dioxide rate of release is more as conditioner
It is stable, ensure air pollution treatment effect；Gel Biodegradable in the present invention, using rear noresidue, secondary dirt is not produced
Dye, there is the characteristic of environmental protection；The acid for having severe corrosive is not included in reaction raw materials, accumulating and use are safer；The present invention's
Preparation method is simple to operate, easily realizes；One of application of air pollution treatment agent of the present invention is empty in being removed in micro- space
Gas pollutant, dispensed using isolation, do not contacted between jello, do not react, also without the generation of chlorine dioxide, ensure that
The storing and transporting security of product, substantially prolongs the shelf-life；Jello maintains immobilising curdled appearance always in itself, avoids and human body
Contact, improves security.
Brief description of the drawings
Fig. 1 is the encapsulation schematic diagram using a kind of device of the long-acting air pollution treatment agent of the present invention；
Fig. 2 is the use state diagram using a kind of device of the long-acting air pollution treatment agent of the present invention；
Fig. 3 is the releasing curve diagram of long-acting air pollution treatment agent；
The implication of reference in figure：The rotatable upper stratas of 1-, 2- lower floors, 3- passages, 4- spaces, 5- bilayer boxes.
Embodiment
The present invention is further introduced below in conjunction with specific embodiment.
All reagents are commercially available prod in the present invention.
Embodiment 1
A kind of long-acting air pollution treatment agent, is made up of jello A and jello B.
Jello A is through the following steps that prepare：
S1, the dipotassium hydrogen phosphate for taking 10mL0.2mol/L mix with 90mL0.3mol/L potassium dihydrogen phosphate, are configured to
100mLpH=5.9 dipotassium hydrogen phosphate-potassium dihydrogen phosphate buffer solution as pH conditioners；100mg sodium chlorites are taken to add 1L
Reactant solution A is prepared in water；
S2, take 20mL reactant solution A and 20mL the mixing of pH conditioners, add 1.67g agar-agars and 0.33g card ripples
Nurse, stirring gel produce jello A.
Jello B through the following steps that prepare：
S1, the glycine for taking 50mL0.2mol/L and 5mL0.2mol/L mixed in hydrochloric acid, add water to 200mL and be configured to pH
=3.6 glycine-HCI cushioning liquid is as pH conditioners；Take 50mg citric acids to add and reactant solution B is prepared in 1L water；
S2, take 20mL reactant solution B and 100mL the mixing of pH conditioners, add 0.4g CMSs polymerization tree
Fat and 1.6g paraffin, stirring gel produce jello B.
Embodiment 2
A kind of long-acting air pollution treatment agent, is made up of jello A and jello B.
Jello A is through the following steps that prepare：
S1, the dipotassium hydrogen phosphate for taking 15mL0.2mol/L mix with 85mL0.3mol/L sodium dihydrogen phosphate, are configured to
100mLpH=6.1 dipotassium hydrogen phosphate-sodium dihydrogen phosphate buffer as pH conditioners；800mg sodium chlorate is taken to add 1L water
Middle preparation reactant solution A；
S2, take 30mL reactant solution A and 150mL pH conditioners mixing, add 10g starch grafted acrylate trees
Fat glue and 20g glyceryl stearates, stirring gel produce jello A.
Jello B through the following steps that prepare：
S1, the phthalic acid for taking 50mL0.2mol/L and 20mL0.2mol/L mixed in hydrochloric acid, add water and are diluted to
200mL, 200mLpH=3 phthalic acid-hydrochloric acid buffer solution is configured to as pH conditioners；Take 1000mg fluoroform sulphurs
Acid, which adds, prepares reactant solution B in 1L water；
S2, take 30mL reactant solution B and 30mL pH conditioners mixing, add 0.55g starch graft acrylamides
Resin and 5.45g sodium carboxymethylcelluloses, stirring gel produce jello B.
Embodiment 3
A kind of long-acting air pollution treatment agent, is made up of jello A and jello B.
Jello A is through the following steps that prepare：
S1, the disodium hydrogen phosphate for taking 10mL1/15mol/L mix with 90mL1/15mol/L sodium dihydrogen phosphate, are configured to
100mLpH=5.91 disodium hydrogen phosphate-sodium dihydrogen phosphate buffer as pH conditioners；Take 150mg sodium chlorites and
150mg hydrogen peroxide, which adds, prepares reactant solution A in 1L water；
S2, take 40mL reactant solution A and 4mL pH conditioners mixing, then add 0.2mL daily chemical essences and
0.2mL essence solubilizer mixes, and adds 19.6g hydroxyethyl cellulose graft acrylamide polymer and 0.4g hexadecanols, stirs
Mix gel and produce jello A.
Jello B through the following steps that prepare：
S1, the disodium hydrogen phosphate for taking 71mL0.2mol/L mix with 129mL0.1mol/L citric acid, are configured to
200mLpH=3.8 disodium hydrogen phosphate-citric acid solution as pH conditioners；Take 500mg benzene sulfonic acids to add in 1L water to match somebody with somebody
Reactant solution B processed；
S2, take 20mL reactant solution B and 10mL the mixing of pH conditioners, then add the mixing of 5mL ethanol, add
10g hydroxyethyl cellulose graft acrylamide polymer and 4g octadecyl alcolols, stirring gel produce jello B.
Embodiment 4
A kind of long-acting air pollution treatment agent, is made up of jello A and jello B.
Jello A is through the following steps that prepare：
S1, the disodium hydrogen phosphate for taking 61mL0.2mol/L mix with 39mL0.3mol/L potassium dihydrogen phosphate, are configured to
100mLpH=7 disodium hydrogen phosphate-potassium dihydrogen phosphate buffer solution is as pH conditioners；Take 400mg sodium chlorate and 200mg high
Potassium manganate, which adds, prepares reactant solution A in 1L water；
S2, take 50mL reactant solution A and 25mL the mixing of pH conditioners, add 10g agar-agars, 15g CMSs
Polymer resin, 3g carbomers and 2g paraffin, stirring gel produce jello A.
Jello B through the following steps that prepare：
S1, take 210g citric acids, 83g sodium hydroxides to be mixed with the concentrated hydrochloric acids of 106mL 37%, be diluted to 10L, be configured to
10LpH=3.3 citric acid-sodium hydroxide-hydrochloric acid buffer solution as pH conditioners；Take 350mg pyrovinic acids and 250mg ten
Dialkyl benzene sulfonic acids, which add, prepares reactant solution B in 1L water；
S2, take 30mL reactant solution B and 3mL pH conditioners mixing, add 1.5g starch grafted acrylate trees
Fat, 6g starch graft acrylamides resin, 1.5g glyceryl stearates, 2g sodium carboxymethylcelluloses and 4g hexadecanols, are stirred into
Gel produces jello B.
Embodiment 5
A kind of long-acting air pollution treatment agent, is made up of jello A and jello B.
Jello A is through the following steps that prepare：
S1, the dipotassium hydrogen phosphate for taking 31.5mL0.2mol/L mix with 68.5mL0.3mol/L potassium dihydrogen phosphate, prepare
Into 100mLpH=6.5 dipotassium hydrogen phosphate-potassium dihydrogen phosphate buffer solution as pH conditioners；Take 100mg sodium chlorites,
50mg sodium chlorate and 250mg potassium hydrogen persulfate composite salts, which add, prepares reactant solution A in 1L water；
S2, take 40mL reactant solution A and 24mL pH conditioners mixing, then add 0.05mL daily chemical essences and
0.1mL essence solubilizer mixes, and adds 10.3g agar-agars, 0.8g paraffin and 0.9g octadecyl alcolols, and stirring gel produces gel
Thing A.
Jello B through the following steps that prepare：
S1, the citric acid for taking 82mL0.1mol/L mix with 118mL0.1mol/L sodium citrate, are configured to 200mLpH
=5 citric acid-sodium citrate buffer is as pH conditioners；400mg oxalic acid, 200mg malonic acid and 100mg formic acid is taken to add
Enter and reactant solution B is prepared in 1L water；
S2, take 60mL reactant solution B and 80mL pH conditioners mixing, then add 0.1mL daily chemical essences and
0.2mL essence solubilizer mixes, and adds 6g agar-agars, 4g CMSs polymer resin, 3.7g starch grafted acrylate trees
Fat, 2.3g paraffin and 8g octadecyl alcolols, stirring gel produce jello B.
Embodiment 6
A kind of long-acting air pollution treatment agent, is made up of jello A and jello B.
Jello A is through the following steps that prepare：
S1, the disodium hydrogen phosphate for taking 55mL0.2mol/L mix with 45mL0.3mol/L sodium dihydrogen phosphate, are configured to
100mLpH=6.9 disodium hydrogen phosphate-sodium dihydrogen phosphate buffer as pH conditioners；Take 250mg sodium chlorites, 200mg
Sodium chlorate, 50mg hydrogen peroxide and 200mg potassium hydrogen persulfate composite salts, which add, prepares reactant solution A in 1L water；
S2, take 20mL reactant solution A and 5mL pH conditioners to mix, then add 0.5mL daily chemical essences, 0.2mL
Essence solubilizer and 5mL ethanol mixing, add 9.6g hydroxyethyl cellulose graft acrylamides polymer, 2.4g carbomers and
4g sodium carboxymethylcelluloses, stirring gel produce jello A.
Jello B through the following steps that prepare：
S1, the acetic acid for taking 18mL0.2mol/L mix with 82mL0.3mol/L sodium acetate, are configured to 100mLpH=4's
NaAc_HAc buffer solution is as pH conditioners；Take 50mg citric acids, 50mg malic acid, 50mg trifluoromethanesulfonic acids and 150mg
Benzene sulfonic acid, which adds, prepares reactant solution B in 1L water；
S2, take 50mL reactant solution B and 30mL the mixing of pH conditioners, then add 0.05mL daily chemical essences,
0.1mL essence solubilizer and the mixing of 1mL ethanol, it is sweet to add 5g agar-agars, 5g starch grafted acrylates resin, 12g stearic acid
Grease and 8g hexadecanols, stirring gel produce jello B.
Embodiment 7
A kind of long-acting air pollution treatment agent, is made up of jello A and jello B.
Jello A is through the following steps that prepare：
S1, take 37.5mL0.2mol/L disodium hydrogen phosphates to be mixed with 62.5mL0.3mol/L sodium dihydrogen phosphates, be configured to
100mLpH=6.6 disodium hydrogen phosphate-phosphate sodium dihydrogen buffer solution as pH conditioners.Take 200mg sodium chlorites and 50mg mistakes
One potassium acid sulfate complex salt, which adds, prepares reactant solution A in 1L water；
S2, take 30mL reactant solution A and 10mL pH conditioners mixing, then add 0.5mL daily use chemicals Mint Essences
Mixed with 1mL essence solubilizer, add 2g CMSs polymer resin, 1g agar-agars, 0.5g hexadecanols and 1g carbomers, stir
Mix gel and produce jello A.
Jello B through the following steps that prepare：
S1, the glycine for taking 50mL 0.2mol/L mix with 44mL 0.2mol/L HCl, then add pure water to be diluted to
200mL, 200mLpH=2.0 glycine-HCI cushioning liquid is configured to as pH conditioners；300mg malic acid is taken to add 1L
Reactant solution B is prepared in water；
S2, take 30mL reactant solution B and 10mL pH conditioners mixing, then add 0.3mL daily use chemicals Mint Essences
With 0.5mL essence solubilizer mix, add 3g CMSs polymer resin, 1g agar-agars, 0.5g hexadecanols, 1g carbomers and
1g glyceryl stearates, stirring gel produce jello B.
Embodiment 8
A kind of long-acting air pollution treatment agent, is made up of jello A and jello B.
Jello A is through the following steps that prepare：
S1, the disodium hydrogen phosphate for taking 6mL1/15mol/L mix with 4mL1/15mol/L potassium dihydrogen phosphate, are configured to
10mLpH=6.98 disodium hydrogen phosphate-potassium dihydrogen phosphate buffer solution is as pH conditioners；Take 220mg sodium chlorate, 20mg double
Oxygen water and 20mg potassium permanganate complex salt, which add, prepares reactant solution A in 1L water；
S2, take 30mL reactant solution A and 10mL pH conditioners mixing, then add 0.1mL daily use chemicals flavoring rose essences
Mixed with 0.15mL essence solubilizer, add 2g starch grafted acrylates resin, 1g hydroxyethyl cellulose grafted propylene acyls
Amine, 1g paraffin, 0.5g octadecyl alcolols and 1g carbomers, stirring gel produce jello A.
Jello B through the following steps that prepare：
S1, the citric acid for taking 13.1mL0.1mol/L mix with 6.9mL0.1mol/L sodium citrate, are configured to 20mLpH
=4 citric acid-sodium citrate buffer is as pH conditioners；Take 350mg pyrovinic acids to add in 1L water and prepare reactant
Solution B；
S2, take 30mL reactant solution B and 10mL pH conditioners mixing, then add 0.1mL daily use chemicals flavoring rose essences
Mixed with 0.15mL essence solubilizer, add 2g starch grafted acrylates resin, 1g hydroxyethyl cellulose grafted propylene acyls
Amine, 1g agar-agars, 0.5g hexadecanols, 1g carbomers and 1g glyceryl stearates, stirring gel produce jello B.
In embodiment 1~8, essence solubilizer can be：PEG40, PGCO40, PP or MK-202；Essence can be daily use chemicals
Mint Essence, food Mint Essence, orange flavor, sweet basil essence, Lancome essence or flavoring apple essence.
The long-acting air pollution treatment agent that embodiment 1~8 is prepared can be applied by the methods described of embodiment 9.
Embodiment 9
The application of long-acting air pollution treatment agent, specifically includes following steps：Jello A and jello B are respectively placed in
In the lower floor of double-deck box and rotatable upper strata, there is passage rotatable upper strata upper surface, is equipped with the top of upper strata bottom and lower floor
Size is identical, position equidistant space accordingly；Two layers of space shifts to install, and rotating upper layer causes two layers of space to overlap, gel
Thing A and jello B haptoreactions, chlorine dioxide is discharged from passage, air pollutants are removed in micro- space.
Embodiment 10 is a kind of device for the long-acting air pollution treatment agent that Application Example 1~8 is prepared.
Embodiment 10
It is a kind of double-deck box 5 using a kind of device used described in embodiment 9, including rotatable upper strata 1 and lower floor 2, can
The upper surface of rotating upper layer 1 is provided with passage 3, and the bottom on rotatable upper strata 1 and the top of lower floor 2 are equipped with that size is identical, position
Put corresponding equidistantly space 4；Two layers of space 4 shifts to install.
The jello A and jello B of long-acting air pollution treatment agent are respectively placed in rotatable upper strata 1 and lower floor 2, two layers
In space 4 shift to install so that jello A and jello B are not contacted.In use, rotating upper layer 1 so that two layers of space 4
Overlap, jello A and jello B haptoreactions, discharge chlorine dioxide from passage 3, air pollution is removed in micro- space
Thing.
Claims (9)
- A kind of 1. long-acting air pollution treatment agent, it is characterised in that：It is made up of jello A and jello B, jello A and gel Thing B includes reactant, carrier and conditioner；The conditioner includes the pH conditioners of regulation jello pH value and regulation is coagulated The character conditioner of glue physical property shape；The reactant of the jello A be sodium chlorite, sodium chlorate, potassium hydrogen persulfate composite salts, One or more in hydrogen peroxide or potassium permanganate, wherein at least including one kind in sodium chlorite or sodium chlorate；The gel Thing B reactant is citric acid, malic acid, trifluoromethanesulfonic acid, benzene sulfonic acid, pyrovinic acid, DBSA, oxalic acid, third One or more in diacid or formic acid；Reactant solution A concentration is 100~800mg/L, molten according to volume ratio, reactant Liquid A:PH conditioner=1~10:1~5；Reactant solution B concentration is 50~1000mg/L, molten according to volume ratio, reactant Liquid B:PH conditioner=1~10:1~5；In jello A and jello B, according to mass volume ratio, carrier and character conditioner Gross mass:Volume=0.1 of reactant solution~1g/mL；In jello A, according to mass ratio, carrier:Character conditioner=0.5 ~5:0.1~1；In jello B, according to mass ratio, carrier:Character conditioner=2~5:0.1~1.
- 2. long-acting air pollution treatment agent according to claim 1, it is characterised in that：Jello A and jello B according to It is prepared by lower step：S1, prepare reactant solution A, reactant solution B and pH conditioner；S2, pH conditioners are added into reactant solution, reactant solution A, reactant solution B pH value are adjusted to 5 respectively~ 7th, 2~5, carrier and character conditioner are added, stirring gel produces.
- 3. long-acting air pollution treatment agent according to claim 1 or 2, it is characterised in that：The carrier is agar-agar, carboxylic first Base starch polymer resin, starch grafted acrylate resin, starch graft acrylamide resin or hydroxyethyl cellulose grafting third One or more in acrylamide polymer.
- 4. long-acting air pollution treatment agent according to claim 1 or 2, it is characterised in that：The pH conditioners are sweet ammonia Acid-hydrochloride buffer, phthalic acid-hydrochloric acid buffer solution, disodium hydrogen phosphate-citric acid solution, citric acid-hydroxide Sodium-hydrochloric acid buffer solution, citric acid-sodium citrate buffer, NaAc_HAc buffer solution, disodium hydrogen phosphate-di(2-ethylhexyl)phosphate Hydrogen sodium cushioning liquid, disodium hydrogen phosphate-potassium dihydrogen phosphate buffer solution, dipotassium hydrogen phosphate-potassium dihydrogen phosphate buffer solution or phosphorus One kind in sour hydrogen dipotassium-phosphate sodium dihydrogen buffer solution.
- 5. long-acting air pollution treatment agent according to claim 1 or 2, it is characterised in that：The character conditioner is card One or more in ripple nurse, paraffin, glyceryl stearate, sodium carboxymethylcellulose, hexadecanol or octadecyl alcolol.
- 6. long-acting air pollution treatment agent according to claim 1, it is characterised in that：The jello A and/or jello Also include additive in B, the additive includes daily chemical essence and essence solubilizer.
- 7. long-acting air pollution treatment agent according to claim 6, it is characterised in that：The additive also includes ethanol.
- 8. long-acting air pollution treatment agent according to claim 7, it is characterised in that：According to volume ratio, reactant solution: Daily chemical essence:Ethanol:Essence solubilizer=50~1000:1~8:5~20:1~2.
- 9. the long-acting air pollution treatment agent as described in any one of claim 1~8 is removed in micro- space in air pollutants Using, it is characterised in that：Comprise the following steps：By jello A and jello B be respectively placed in double-deck box lower floor and it is rotatable on In layer, there is a passage rotatable upper strata upper surface, between being equipped with that size is identical, position is corresponding at the top of upper strata bottom and lower floor etc. Away from space；Two layers of space shifts to install, and rotating upper layer causes two layers of space to overlap, jello A and jello B haptoreactions, from Chlorine dioxide is discharged in passage, air pollutants are removed in micro- space.
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| JP2018080062A (en) * | 2015-06-26 | 2018-05-24 | 株式会社アイ・イー・ジェー | Chlorine dioxide generator and production method thereof |
| CN105746587B (en) * | 2016-03-10 | 2018-05-18 | 深圳普沃德环保科技有限公司 | A kind of indoor and interior sustained release air treating agent |
| CN106614555A (en) * | 2016-10-08 | 2017-05-10 | 南京斯泰尔医药科技有限公司 | Slow release type chlorine dioxide solid disinfectant and preparation method thereof |
| CN111097270A (en) * | 2018-10-26 | 2020-05-05 | 浙江地球村环保科技有限公司 | Air purification gel box and use method and application thereof |
| CN109607483B (en) * | 2019-01-22 | 2022-07-05 | 一扫清（上海）环境科技有限公司 | Disinfectant generating device |
| CN111514354B (en) * | 2020-05-09 | 2022-03-15 | 南京协心健康科技有限公司 | Chlorine dioxide gel air disinfection device capable of adjusting release amount |
| CN111869677B (en) * | 2020-07-29 | 2021-11-19 | 江苏时光之箭健康科技有限公司 | Chlorine dioxide purification gel powder and preparation method thereof |
| CN113396901B (en) * | 2021-06-25 | 2022-11-04 | 新乡市康大消毒剂有限公司 | Gel for slowly releasing chlorine dioxide and preparation method thereof |
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| CN2841013Y (en) * | 2005-10-28 | 2006-11-29 | 河北科技大学 | Air-disinfecting clearing box for slow-release chlorinedioxide gas |
| US9333475B1 (en) * | 2011-11-25 | 2016-05-10 | Juan Carlos Baselli | Portable chlorine dioxide generator |
| CN203754416U (en) * | 2014-02-24 | 2014-08-06 | 重庆昆顶生物技术有限公司 | Chlorine dioxide generator |
| CN104707463A (en) * | 2015-03-13 | 2015-06-17 | 华阳新兴科技（天津）集团有限公司 | Chlorine dioxide air purification sustained release preparation added with tea polyphenol |
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