CN105304834A - Aluminum plastic film capable of detecting battery leakage - Google Patents
Aluminum plastic film capable of detecting battery leakage Download PDFInfo
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- CN105304834A CN105304834A CN201510645992.8A CN201510645992A CN105304834A CN 105304834 A CN105304834 A CN 105304834A CN 201510645992 A CN201510645992 A CN 201510645992A CN 105304834 A CN105304834 A CN 105304834A
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- layer
- plastic film
- aluminum plastic
- acid
- base indicator
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 63
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 239000002985 plastic film Substances 0.000 title claims abstract description 58
- 229920006255 plastic film Polymers 0.000 title claims abstract description 58
- 239000002696 acid base indicator Substances 0.000 claims abstract description 45
- 239000011230 binding agent Substances 0.000 claims abstract description 19
- 239000004677 Nylon Substances 0.000 claims abstract description 17
- 229920001778 nylon Polymers 0.000 claims abstract description 17
- 239000010410 layer Substances 0.000 claims description 71
- 239000012790 adhesive layer Substances 0.000 claims description 46
- 239000005030 aluminium foil Substances 0.000 claims description 11
- 239000004745 nonwoven fabric Substances 0.000 claims description 3
- 239000003792 electrolyte Substances 0.000 abstract description 14
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052744 lithium Inorganic materials 0.000 abstract description 6
- 238000001514 detection method Methods 0.000 abstract description 5
- 239000011888 foil Substances 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 239000004743 Polypropylene Substances 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 238000011109 contamination Methods 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 238000000034 method Methods 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000282941 Rangifer tarandus Species 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002457 bidirectional effect Effects 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920006332 epoxy adhesive Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 description 1
- 229940012189 methyl orange Drugs 0.000 description 1
- CEQFOVLGLXCDCX-WUKNDPDISA-N methyl red Chemical compound C1=CC(N(C)C)=CC=C1\N=N\C1=CC=CC=C1C(O)=O CEQFOVLGLXCDCX-WUKNDPDISA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/088—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Manufacturing & Machinery (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Abstract
The invention discloses an aluminum plastic film capable of detecting battery leakage. The aluminum plastic film capable of detecting battery leakage mainly aims to solve the problem that the existing lithium battery aluminum plastic film leakage detection speed is slow. The aluminum plastic film capable of detecting battery leakage provided by the invention sequentially comprises a PP layer, a binder layer A, an aluminum foil layer, a binder layer B, an acid-base indicator layer, a binder layer C and a nylon layer from inside to outside. The invention also provides another structure of the aluminum plastic film capable of detecting battery leakage, which comprises a PP layer, a binder layer A, an aluminum foil layer, a binder layer B, a nylon layer, a binder layer C, an acid-base indicator layer, a binder layer D and a PET layer from inside to outside. According to the aluminum plastic film capable of detecting battery leakage, the acid-base indicator layer is added in a laminated structure of the aluminum plastic film, when leakage occurs, the electrolyte is changed in color through being soaked by an acid-base indicator, so that whether the aluminum plastic film is damaged or not can be judged through naked eyes, simplicity and convenience are realized, and an extra operation is not needed.
Description
Technical field
The present invention relates to lithium battery production field, particularly relate to a kind of aluminum plastic film that can detect battery leakage.
Background technology
Soft package lithium battery has the advantages such as thickness is thin, lightweight, fail safe is good, is widely used in the fields such as various mobile device, electric automobile, electric tool.Lithium ion battery generally uses aluminum plastic film as shell, and aluminum plastic film is composited by three layers, the CPP layer of outermost nylon layer, middle aluminium foil layer, inner side usually, and their gross thickness is at 80 ~ 150 μm.The outermost nylon of aluminum plastic film has good anti-wear, breakage-proof function, and middle aluminium foil layer works the function intercepting air, moisture, and the CPP layer of inner side then plays isolated electrolytic corrosion, merges the effect of sealing.
Aluminum plastic film in punching course may owing to rushing, the shell degree of depth is excessively dark, Design of Dies improper to cause in aluminum plastic film layer polypropylene or outer nylon damaged, this breakage cannot to detect by an unaided eye resolution rushing the shell stage, if use this aluminum plastic film as shell packaged battery, after battery completes, the leakage of housing burn into can be caused, thus produce potential safety hazard.For eliminating this potential safety hazard, need to detect stamping forming plastic-aluminum shell.Detection method many employings copper sulphate is tested, and this experiment is equivalent to an electrolytic cell, is contacted by external power supply positive pole with plastic-aluminum shell aluminium lamination, external power supply negative pole and the aluminum plastic film that will detect are connected by copper-bath, if aluminum plastic film has breakage, then electrolytic cell conducting, has copper to separate out at breakage.
Chinese patent publication No. CN104390957A, disclose a kind of detection method of aluminum plastic film, this aluminum plastic film comprises the insulating plastic layer of aluminium lamination and encapsulating aluminium lamination, and the cavity had for accommodating battery core, comprise the following steps: get an aluminum plastic film to be measured, in the cavity of aluminum plastic film to be measured, inject copper-bath; Settle anode ear and negative electrode lug to aluminum plastic film to be measured, make positive and negative lug and copper-bath conducting, then will the plastic film cavity encapsulation of copper-bath be marked with, positive and negative lug is fixed and protrudes from outside aluminum plastic film; Positive and negative lug is connected respectively a positive source and negative pole, after the energising scheduled time, open aluminum plastic film to be measured and detect whether have RED sector, if any then judging that there is breakage at this position of aluminum plastic film.The method is equipped with lug on aluminum plastic film, lug and copper-bath conducting, and be connected on power supply, whether energising detects aluminum plastic film has RED sector, can judge that whether aluminum plastic film is qualified, easy and simple to handle, detect accurately, but it is slow that the method exists detection speed, detect the shortcomings such as rear sample cannot use.
Summary of the invention
Object of the present invention, mainly for the problem that existing lithium battery aluminum-plastic film leakage detection speed is slow, provides a kind of aluminum plastic film that can identify lithium battery leakage fast.
Concrete technical scheme of the present invention is: a kind of aluminum plastic film that can detect battery leakage, is characterized in that, described aluminum plastic film is followed successively by PP layer, adhesive layer A, aluminium foil layer, adhesive layer B, acid-base indicator layer, adhesive layer C, nylon layer from the inside to the outside.
Another kind of technical scheme of the present invention is: a kind of aluminum plastic film that can detect battery leakage, it is characterized in that, described aluminum plastic film is followed successively by PP layer, adhesive layer A, aluminium foil layer, adhesive layer B, nylon layer, adhesive layer C, acid-base indicator layer, adhesive layer D, pet layer from the inside to the outside.
The electrolyte of lithium battery is generally acidity or alkalescence, and when leakage occurs for it, electrolyte can infiltrate acid-base indicator by damaged aluminum plastic film, and therefore acid-base indicator shows different sour looks or alkaline color, can judge battery whether leakage thus.Outer field pet layer or nylon layer, then can prevent the material such as oxygen, steam, carbon dioxide in air to the destruction of acid-base indicator, and the colour developing that when also can prevent fluid injection, electrolyte contamination causes to outside batteries is simultaneously judged by accident.
As preferably, described acid-base indicator layer is mixed by acid-base indicator, binding agent and inserts.Mixed with filler by acid-base indicator, can ensure using under less acid-base indicator condition, the area of acid-base indicator layer is larger.In actual use, according to the change of the electrolyte ph of seepage, suitable acid-base indicator can be selected.
As preferably, described inserts is selected from the one in nonwoven fabrics, PE, EVA, PP, EPE.
As preferably, described acid-base indicator layer thickness is 0.1 ~ 50 μm.Acid-base indicator layer thickness is too thick, if aluminum plastic film breakage is very little, leakage infiltration can be very slow, and may cause can not Timeliness coverage leakage, affects testing result.
The invention has the beneficial effects as follows: by increasing acid-base indicator layer in aluminum plastic film layer structure, when there is leakage, electrolyte is by infiltrating acid-base indicator, thus there is color change, can judge whether aluminum plastic film has breakage by naked eyes, simple and convenient, without the need to operation bidirectional.
Accompanying drawing explanation
Fig. 1 is a kind of structural representation of aluminum plastic film of the present invention;
Fig. 2 is the another kind of structural representation of aluminum plastic film of the present invention.
In figure: 1-1-adhesive layer A, 1-2-adhesive layer B, 1-3-adhesive layer C, 1-4-adhesive layer D, 2-PP layer, 3-aluminium foil layer, 4-acid-base indicator layer, 5-nylon layer, 6-PET layer.
Embodiment
Below in conjunction with accompanying drawing also by specific embodiment, technical scheme of the present invention is described further.
Embodiment 1
As shown in Figure 1, a kind of aluminum plastic film that can detect battery leakage, be followed successively by PP layer 2, adhesive layer A1-1, aluminium foil layer 3, adhesive layer B1-2, acid-base indicator layer 4, adhesive layer C1-3, nylon layer 5 from the inside to the outside, the binding agent that wherein adhesive layer A1-1, adhesive layer B1-2, adhesive layer C1-3 adopt is polyvinylidene fluoride binding agent.
Acid-base indicator layer 4 is mixed by methyl red indicator, polyvinylidene fluoride binding agent and nonwoven fabrics, and its thickness is 0.1 μm.Outer field nylon layer 5, can prevent the materials such as the oxygen in air, steam, carbon dioxide to the destruction of acid-base indicator, and the colour developing that when also can prevent fluid injection, electrolyte contamination causes to outside batteries is simultaneously judged by accident.When there is leakage, electrolyte can infiltrate the acid-base indicator in acid-base indicator layer 4 by damaged aluminum plastic film, thus variable color occurs, and can judge battery whether leakage thus.
Embodiment 2
A kind of aluminum plastic film that can detect battery leakage, be followed successively by PP layer 2, adhesive layer A1-1, aluminium foil layer 3, adhesive layer B1-2, acid-base indicator layer 4, adhesive layer C1-3, nylon layer 5 from the inside to the outside, the binding agent that wherein adhesive layer A1-1, adhesive layer B1-2, adhesive layer C1-3 adopt is polyurethane adhesive.
Acid-base indicator layer 4 is mixed by methyl orange indicator, polyvinylidene fluoride binding agent and PE, and its thickness is 50 μm.Outer field nylon layer 5, can prevent the materials such as the oxygen in air, steam, carbon dioxide to the destruction of acid-base indicator, and the colour developing that when also can prevent fluid injection, electrolyte contamination causes to outside batteries is simultaneously judged by accident.When there is leakage, electrolyte can infiltrate the acid-base indicator in acid-base indicator layer 4 by damaged aluminum plastic film, thus variable color occurs, and can judge battery whether leakage thus.
Embodiment 3
As shown in Figure 2, a kind of aluminum plastic film that can detect battery leakage, be followed successively by PP layer 2, adhesive layer A1-1, aluminium foil layer 3, adhesive layer B1-2, nylon layer 5, adhesive layer C1-3, acid-base indicator layer 4, adhesive layer D1-4, pet layer 6 from the inside to the outside, the binding agent that wherein adhesive layer A1-1, adhesive layer B1-2, adhesive layer C1-3, adhesive layer D1-4 adopt is acrylic resin binder.
Acid-base indicator layer 4 is mixed by reindeer moss indicator, acrylic resin binder and EVA, and its thickness is 0.1 μm.Outer field pet layer 6, can prevent the materials such as the oxygen in air, steam, carbon dioxide to the destruction of acid-base indicator, and the colour developing that when also can prevent fluid injection, electrolyte contamination causes to outside batteries is simultaneously judged by accident.When there is leakage, electrolyte can infiltrate the acid-base indicator in acid-base indicator layer 4 by damaged aluminum plastic film, thus variable color occurs, and can judge battery whether leakage thus.
Embodiment 4
A kind of aluminum plastic film that can detect battery leakage, be followed successively by PP layer 2, adhesive layer A1-1, aluminium foil layer 3, adhesive layer B1-2, nylon layer 5, adhesive layer C1-3, acid-base indicator layer 4, adhesive layer D1-4, pet layer 6 from the inside to the outside, the binding agent that wherein adhesive layer A1-1, adhesive layer B1-2, adhesive layer C1-3, adhesive layer D1-4 adopt is acrylic resin binder.
Acid-base indicator layer 4 is mixed by phenolphthalein indicator, epoxy adhesive and EPE, and its thickness is 50 μm.Outer field pet layer 6, can prevent the materials such as the oxygen in air, steam, carbon dioxide to the destruction of acid-base indicator, and the colour developing that when also can prevent fluid injection, electrolyte contamination causes to outside batteries is simultaneously judged by accident.When there is leakage, electrolyte can infiltrate the acid-base indicator in acid-base indicator layer 4 by damaged aluminum plastic film, thus variable color occurs, and can judge battery whether leakage thus.
Claims (5)
1. can detect an aluminum plastic film for battery leakage, it is characterized in that, described aluminum plastic film is followed successively by PP layer, adhesive layer A, aluminium foil layer, adhesive layer B, acid-base indicator layer, adhesive layer C, nylon layer from the inside to the outside.
2. can detect an aluminum plastic film for battery leakage, it is characterized in that, described aluminum plastic film is followed successively by PP layer, adhesive layer A, aluminium foil layer, adhesive layer B, nylon layer, adhesive layer C, acid-base indicator layer, adhesive layer D, pet layer from the inside to the outside.
3. a kind of aluminum plastic film that can detect battery leakage according to claim 1 and 2, it is characterized in that, described acid-base indicator layer is mixed by acid-base indicator, binding agent and inserts.
4. a kind of aluminum plastic film that can detect battery leakage according to claim 3, it is characterized in that, described inserts is selected from the one in nonwoven fabrics, PE, EVA, PP, EPE.
5. a kind of aluminum plastic film that can detect battery leakage according to claim 3, is characterized in that, described acid-base indicator layer thickness is 0.1 ~ 50 μm.
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Cited By (11)
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CN106198521A (en) * | 2016-07-01 | 2016-12-07 | 天能电池集团有限公司 | A kind of method detecting lead battery acid adding effect |
CN106353371A (en) * | 2016-09-30 | 2017-01-25 | 珠海市鹏辉电池有限公司 | Aluminum plastic film detection method for lithium ion battery |
CN106450490A (en) * | 2016-12-16 | 2017-02-22 | 天津力神电池股份有限公司 | Method for analyzing and detecting failure reasons of micropores of flexibly packaged lithium batteries |
CN108303413A (en) * | 2017-12-30 | 2018-07-20 | 惠州亿纬锂能股份有限公司 | A kind of heat-shrinkable T bush and its preparation method and application |
CN108896427A (en) * | 2018-06-29 | 2018-11-27 | 广东天劲新能源科技股份有限公司 | A kind of measurement method of electrodes of lithium-ion batteries rate of liquid aspiration and liquid absorption amount |
CN109103352A (en) * | 2017-06-20 | 2018-12-28 | 北京小米移动软件有限公司 | Battery and equipment |
CN109367155A (en) * | 2018-10-18 | 2019-02-22 | 常州斯威克光伏新材料有限公司 | A kind of dynamic lithium battery aluminum plastic film and preparation method thereof |
CN111136970A (en) * | 2019-12-19 | 2020-05-12 | 深圳市海盈科技有限公司 | Aluminum plastic film for lithium ion battery and lithium ion battery |
CN111540848A (en) * | 2020-05-14 | 2020-08-14 | 华鼎国联四川动力电池有限公司 | Lithium ion battery aluminum plastic film and preparation method thereof |
CN112394012A (en) * | 2020-11-06 | 2021-02-23 | 东莞市卓越新材料科技有限公司 | Method for detecting moisture permeability of polypropylene film for lithium battery aluminum plastic film |
CN112744402A (en) * | 2020-12-29 | 2021-05-04 | 江苏中兴派能电池有限公司 | Lithium ion battery packaging pole piece heat-sealing bag and preparation method thereof |
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CN106450490B (en) * | 2016-12-16 | 2019-06-07 | 天津力神电池股份有限公司 | The analyzing detecting method of soft package lithium battery microvia failure reason |
CN106450490A (en) * | 2016-12-16 | 2017-02-22 | 天津力神电池股份有限公司 | Method for analyzing and detecting failure reasons of micropores of flexibly packaged lithium batteries |
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CN108303413A (en) * | 2017-12-30 | 2018-07-20 | 惠州亿纬锂能股份有限公司 | A kind of heat-shrinkable T bush and its preparation method and application |
CN108896427A (en) * | 2018-06-29 | 2018-11-27 | 广东天劲新能源科技股份有限公司 | A kind of measurement method of electrodes of lithium-ion batteries rate of liquid aspiration and liquid absorption amount |
CN109367155A (en) * | 2018-10-18 | 2019-02-22 | 常州斯威克光伏新材料有限公司 | A kind of dynamic lithium battery aluminum plastic film and preparation method thereof |
CN111136970A (en) * | 2019-12-19 | 2020-05-12 | 深圳市海盈科技有限公司 | Aluminum plastic film for lithium ion battery and lithium ion battery |
CN111540848A (en) * | 2020-05-14 | 2020-08-14 | 华鼎国联四川动力电池有限公司 | Lithium ion battery aluminum plastic film and preparation method thereof |
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CN112394012A (en) * | 2020-11-06 | 2021-02-23 | 东莞市卓越新材料科技有限公司 | Method for detecting moisture permeability of polypropylene film for lithium battery aluminum plastic film |
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