CN105254096A - Preprocessing method and device for gasification ammonia-cyanide-phenol-contained circulating water - Google Patents

Preprocessing method and device for gasification ammonia-cyanide-phenol-contained circulating water Download PDF

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CN105254096A
CN105254096A CN201510652075.2A CN201510652075A CN105254096A CN 105254096 A CN105254096 A CN 105254096A CN 201510652075 A CN201510652075 A CN 201510652075A CN 105254096 A CN105254096 A CN 105254096A
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water
oil
air flotation
flotation pool
phenol
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CN201510652075.2A
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CN105254096B (en
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蒋远华
杨晓勤
卢钢
张战利
黄登兵
朱洪波
李天方
冯加新
杨晓华
黄志亮
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湖北宜化集团有限责任公司
新疆宜化化工有限公司
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Abstract

The invention provides a preprocessing method for gasification ammonia-cyanide-phenol-contained circulating water. Particularly, slag scraping and oil removal are performed on gasification circulating water through advective oil separation pool, then, a coagulant, magnetic powder, an oil emulsion separated out by a flocculating agent, colloid and suspended solid sediments are added, the sediments can remove oil pollutants in water, and the magnetic powder can be recycled; coagulation, flocculation and air flotation are performed at the upper portion of a settling pond, the coagulant is added so that destabilization of the oil emulsion, the colloid and the suspended solid can be achieved, small alumen ustum is generated, the flocculating agent is added into sewage obtained after coagulation, the alumen ustum is gathered into firmer alumen ustum, flocculation water and circulating water with rich microbubbles are mixed and then enter a floatation tank, and uniform oil sludge cakes are formed on the surface of the floatation tank; processed water flows into a suction well and is recycled to an inlet of the floatation tank, and the preprocessing process of the gasification circulating water is completed. The gasification circulating water is preprocessed, the content of oil in water is decreased, and the loading coagulation oil remover and floatation technology are adopted to remove floating oil and dispersed oil in the water.

Description

A kind of gas making contains recirculated water pretreatment process and the device of phenol containing cyanogen containing ammonia

Technical field

The present invention relates to a kind of circulating water for gasification pretreatment unit and pretreatment process, belong to field of water pollution control in Chemical Manufacture.

Background technology

The pretreatment technology that current synthetic ammonia industry gas making water major part adopts is: recirculated water enters gas making horizontal flow basin, by part dust tar natural subsidence, scrapes slag through the oil removing of tar oil trap, and water part internal recycling, part are sent outside.

This processing mode, circulating water for gasification water quality does not obtain basic process and improvement.And circulation causes water quality poor for a long time, cause the easy fouling of pipeline, shower nozzle easily blocks up, and it is passive to produce.Meanwhile, while environmental requirement is increased day by day, realize water correction, sewage zero-discharge is the important goal of producing.

Summary of the invention

The present invention is directed to the problems referred to above, provide a kind of combination unit loading coagulation oil removal plant and air flotation pool and pre-treatment is carried out to circulating water for gasification.Wherein, load coagulation oil removal plant to be mainly used in removing the oil slick in gas making water and thick dispersed oil; Air supporting make machinery with the fat liquor unstability of chemistry and being removed, adopt microbubble to guarantee effective air supporting.

Circulating water for gasification has different components along with the difference of feed coal, but oily substance is ubiquitous greatest problem, and oil removing is that pre-treatment is crucial.Gas making of the present invention, comprises the steps: containing the recirculated water pretreatment process of cyanogen containing phenol containing ammonia

1) circulating water for gasification is scraped after slag oil removing through advection oil separation tank, oil in water emulsion is taken off steady, coalescent by adding emulsion splitter, again dosing coagulant, magnetic, flocculation agent accelerate to separate out fat liquor, colloid and suspended solids throw out, this throw out is delivered to settling tank, by the oil pollutant removing in water, the magnetic of settling tank bottom realizes recycle by Separation and Recovery;

This technology is the object utilizing the work of additional settling agent magnetic to reach high-efficiency sedimentation and filtration in order to strengthen flocculation.Its principle in sewage, adds a small amount of coagulating agent, settling agent magnetic etc. flocculate with pollutent and be combined into one, and then filtered by High-rate sedimentation and settling agent and removed by the oil pollutant in water, settling agent magnetic realizes recycling by Separation and Recovery.

2) the water outlet gravity flow on settling tank top enters air flotation pool, coagulation, flocculation, air supporting three phases is divided in air flotation pool, in coagulation basin, dosing coagulant makes fat liquor, colloid and suspended solids de-steady, produce little alumen ustum, sewage after coagulation flows into flocculation basin, add flocculation agent in pond alumen ustum to be assembled for larger, more all even firmly alumen ustum, air flotation pool is entered after flocculation water mixes with the recirculated water being full of microbubble, alumen ustum and microbubble flock together, form uniform greasy filth cake on air flotation pool surface, then greasy filth cake is scraped into a receiving tank; Water after treatment flows in suction well, and the part water yield in suction well, by under the effect of pump, is circulated to air flotation pool entrance by dissolving;

3) through step 2) circulation after, the water outlet in air flotation pool is discharged through outlet conduit, enters vapo(u)rization system; Bed mud bottom air flotation pool sends into sludge sump, that is, complete the pretreated process of circulating water for gasification.

The described recirculated water being full of microbubble is at completing steps 2) process after, air is injected in dissolving through air compression plant, dissolve in recirculated water, then the water containing saturated air delivers to the entrance release of pressure of air flotation pool by Pressure-relief Device, this pressure-release assembly produces the bubble of 50 to 80 microns, can obtain the recirculated water being full of microbubble, this recirculated water being full of microbubble is easily attached on alumen ustum.

Described emulsion splitter is one or more in polyoxyethylene, polyoxypropylene or alkyl phenolic resin, and its addition is 50-120ppm.

Described coagulating agent is polymer alumina, and its addition is 50-120ppm.

Described flocculation agent is one or more in polyacrylamide, bodied ferric sulfate or polymerize aluminum chloride, wherein, step 1) in add-on be 1-3ppm; Step 2) in add-on be 0.5-1ppm.

The residence time of coagulation basin is 3min; The residence time in the pond of flocculation basin is 10min; The water cycle ratio of air flotation pool is 40%.

Described vapo(u)rization system is by the water outlet in air flotation pool, with 20m after namely pretreated circulating water for gasification is warming up to 60 DEG C 2the flow of/h is delivered to reboiler tube side by feeding pump and is carried out evaporation concentration, and the heating chamber course that the saturated raw steam simultaneously come by boiler enters reboiler carries out heat exchange condensation, and condensed water of condensation returns in boiler house through hot water pump again and re-uses; Circulating water for gasification is sent in flashing chamber after evaporation concentration again, and producing a large amount of secondary steams in flashing chamber after pressure control, temperature control, two secondary steam send into reprocessing in Gas-making Furnace through flashing chamber top after overheated, voltage stabilizing.

The pressure of raw steam controls as 0.618MPa, and raw vapor temperature controls to be 160 DEG C; The circulating water for gasification steam output sent into again after evaporation concentration in flashing chamber controls as 19800kg/h; Two secondary steam pressures control as 0.199MPa, and two secondary vapor temperatures control to be 120 DEG C; In flashing chamber, liquidus temperature controls is 125 DEG C, and wherein, the effective temperature difference of liquid phase and gas phase controls to be 34 DEG C; Flashing chamber overhead vapor pressure-controlling is 0.199MPa, and flashing chamber inner top controls as 17680m to the secondary steam amount of Gas-making Furnace 3/ h.

The present invention also provide a kind of gas making containing ammonia containing cyanogen containing the recirculated water pretreatment process of phenol treatment unit used, this pretreatment unit comprises loading coagulation oil removal plant, air-floating apparatus and evaporation unit, wherein, load coagulation oil removal plant and comprise mixing pit, the dosing pond of emulsion splitter, flocculation basin, settling tank; Settling tank top is connected with air flotation pool device through carrier pipe, is connected bottom settling tank after pipeline is connected with pump with magnetic withdrawing can again, magnetic withdrawing can again with sludge dehydration device; Air flotation pool device comprises coagulation basin and flocculation basin, and be connected through the bottom of carrier pipe with the carrier pipe in the middle of air flotation pool bottom flocculation basin, air flotation pool upper end is provided with outlet conduit, and bottom air flotation pool and bottom is also provided with the pipeline to sludge sump.

Described evaporation unit comprises reboiler, flashing chamber, and saturated raw steam is connected with reboiler top through carrier pipe, and parallel connection passes to heating chamber shell side and connects; Pretreated circulating water for gasification is connected parallel connection through carrier pipe with the bottom of reboiler and passes to reboiler tube side; Reboiler top is connected with flashing chamber through carrier pipe, and flashing chamber top is connected to Gas-making Furnace through carrier pipe; After carrier pipe converges, feed reservoir is connected to bottom flashing chamber with bottom reboiler; Reboiler bottom is connected to boiler house through carrier pipe.

After device of the present invention puts into operation, circulating water for gasification is through pre-treatment, reduce the content (oil-in-water mainly exists with oil in water emulsion form, the oil slick that surfactant suspension is a small amount of) of oil-in-water, adopt loading coagulation oil eliminator and air-float technology to be mainly used in removing the oil slick in water and dispersed oil.

Accompanying drawing explanation

Fig. 1 is for loading coagulation oil removal plant structural representation.

Fig. 2 is air-floating apparatus structural representation.

Fig. 3 is evaporation unit

Embodiment

Embodiment 1

After the present invention takes to scrape SS in slag, breakdown of emulsion precipitation, pneumatically supported pretreatment process removing circulating water for gasification, oil slick, oil in water emulsion, the remaining material such as ammonia, cyanogen, phenol enters vapo(u)rization system with aqueous phase, ammonia, cyanogen, phenol etc. to be brought in steam by malleation evaporation and enter gasification system as vaporization agent, ammonia, cyanogen, phenol etc. sinter and reduce in Gas-making Furnace.The method using containing ammonia containing cyanogen containing the circulating water for gasification of phenol send into after pre-treatment vapo(u)rization system produce steam, after send into gasification system as vaporization agent, eliminate objectionable impurities ammonia, cyanogen and the phenol etc. that contain in circulating water for gasification, reduce the deterioration to system process links such as gas making cooling, washings that objectionable impurities causes in the circulation of gasification system.

Gas making containing ammonia containing cyanogen containing the recirculated water pretreatment process of phenol treatment unit used, this energy sewage pre-treatment device comprises loading coagulation oil removal plant, air-floating apparatus and evaporation unit, wherein, loads coagulation oil removal plant and comprises mixing pit, the dosing pond of emulsion splitter, flocculation basin, settling tank.

Settling tank top is connected with air flotation pool device through carrier pipe, is connected bottom settling tank after pipeline is connected with pump with magnetic withdrawing can again, magnetic withdrawing can again with sludge dehydration device.

Air flotation pool device comprises coagulation basin and flocculation basin, and be connected through the bottom of carrier pipe with the carrier pipe in the middle of air flotation pool bottom flocculation basin, air flotation pool upper end is provided with outlet conduit, and bottom air flotation pool and bottom is also provided with the pipeline to sludge sump.

Evaporation unit comprises reboiler, flashing chamber, and saturated raw steam is connected with reboiler top through carrier pipe, and parallel connection passes to heating chamber shell side and connects; Pretreated circulating water for gasification is connected parallel connection through carrier pipe with the bottom of reboiler and passes to reboiler tube side; Reboiler top is connected with flashing chamber through carrier pipe, and flashing chamber top is connected to Gas-making Furnace through carrier pipe; After carrier pipe converges, feed reservoir is connected to bottom flashing chamber with bottom reboiler; Reboiler bottom is connected to boiler house through carrier pipe.

Embodiment 2

A kind of typical gas making sewage COD:8000 ~ 10000mg/L; Ammonia nitrogen: 2000 ~ 3000mg/L; Phenol: 1000 ~ 1100mg/L; Cyanogen: 0.8 ~ 1.1mg/L; PH: weakly alkaline; Water temperature: 60 ~ 80 DEG C.

Perform above-mentioned pretreatment process, comprise the steps:

1) circulating water for gasification and energy sewage are scraped after slag oil removing through advection oil separation tank, oil in water emulsion is taken off steady, coalescent by adding emulsion splitter, again dosing coagulant, magnetic, flocculation agent accelerate to separate out fat liquor, colloid and suspended solids throw out, this throw out is delivered to settling tank, by the oil pollutant removing in water, the magnetic of settling tank bottom realizes recycle by Separation and Recovery.

This technology is the object utilizing the work of additional settling agent magnetic to reach high-efficiency sedimentation and filtration in order to strengthen flocculation.Its principle in sewage, adds a small amount of coagulating agent, settling agent magnetic etc. flocculate with pollutent and be combined into one, and then filtered by High-rate sedimentation and settling agent and removed by the oil pollutant in water, settling agent magnetic realizes recycling by Separation and Recovery.

Mixing pit in this programme is divided into emulsion splitter dosing pond, coagulation basin, loading coagulation basin, flocculation basin.Wherein emulsion splitter adds in pond and adds emulsion splitter, destroys emulsus oil, solid phase is assembled, be convenient to the removal of oil.

2) the water outlet gravity flow on settling tank top enters air flotation pool, coagulation, flocculation, air supporting three phases is divided in air flotation pool, in coagulation basin, dosing coagulant makes fat liquor, colloid and suspended solids de-steady, produce little alumen ustum, sewage after coagulation flows into flocculation basin, add flocculation agent in pond alumen ustum to be assembled for larger, more all even firmly alumen ustum, air flotation pool is entered after flocculation water mixes with the recirculated water being full of microbubble, alumen ustum and microbubble flock together, form uniform greasy filth cake on air flotation pool surface, then greasy filth cake is scraped into a receiving tank; Water after treatment flows in suction well, and the part water yield in suction well, by under the effect of pump, is circulated to air flotation pool entrance by dissolving.

3) through step 2) circulation after, the water outlet in air flotation pool is discharged through outlet conduit, and the water of discharge enters vapo(u)rization system; Bed mud bottom air flotation pool sends into sludge sump, that is, complete the pretreated process of circulating water for gasification.

The described recirculated water being full of microbubble is at completing steps 2) process after, air is injected in dissolving through air compression plant, dissolve in recirculated water, then the water containing saturated air delivers to the entrance release of pressure of air flotation pool by Pressure-relief Device, this pressure-release assembly produces the bubble of 50 to 80 microns, can obtain the recirculated water being full of microbubble, this recirculated water being full of microbubble is easily attached on alumen ustum.

Described emulsion splitter is one or more in polyoxyethylene, polyoxypropylene or alkyl phenolic resin, and its addition is 50-120ppm.

Described coagulating agent is polymer alumina, and its addition is 50-120ppm.

Described flocculation agent is one or more in polyacrylamide, bodied ferric sulfate or polymerize aluminum chloride, wherein, step 1) in add-on be 1-3ppm; Step 2) in add-on be 0.5-1ppm.

The present invention's its parameter in actual moving process is as follows:

Parameter Unit Design load Coagulation basin Seat 2 Single pond residence time min 3 Single pond useful volume m 3 1

Parameter Unit Design load Flocculation basin Seat 2 Single pond residence time min 10 Single pond useful volume m 3 3.5

Parameter Unit Design load Air flotation pool Seat 2 Effective diameter m 3 Water cycle ratio m 40％

In medicine system

Coagulating agent

Design adopts solid PAC as coagulating agent.Be added in corresponding process pool by dosing pump after being configured to liquid by configured pool.

Load coagulation oil eliminator dosage: 100mg/l, with pure Al 2o 3meter.

Unibub tMair flotation pool dosage: 100mg/l, with pure Al 2o 3meter.

Flocculation agent

Adopt solid polypropylene acid amides as flocculation agent.In dosing, the polymer preparing apparatus installing automatization adds dissolution of solid polymer to be become the liquid polymers of 2g/l.Be added to after liquid polymers on-line dilution to 0.1 ~ 0.2g/L again in water.Adopt 90% pure solid powder.

Load coagulation oil eliminator flocculation basin dosage: 2mg/l.

Unibub tMair supporting flocculation basin dosage: 1mg/l.

Emulsion splitter

Employing polyoxyethylene is emulsion splitter, loads coagulation oil eliminator emulsion splitter dosage: 100mg/l.

Magnetic

Magnetic adds and adds for disposable, follow-up regularly a small amount of replenish loss amount, the magnetic rate of recovery 90% ~ 95%.

Sludge yield

Mud main source:

Load coagulation oil eliminator and produce mud;

Unibub tMthe bed mud of air flotation pool and scum silica frost;

Sludge output: 310DSkg/d

Because mud amount is less, not independent set handling system, unifies sludge treating system by place and processes.

Design effluent quality: SS≤30mg/L, non-solubility oil≤100mg/L.

Embodiment 3

Water outlet in embodiment 2 in air flotation pool, with 20m after namely pretreated circulating water for gasification is warming up to 60 DEG C 2the flow of/h is delivered to reboiler tube side by feeding pump and is carried out evaporation concentration, and the heating chamber course that the saturated raw steam simultaneously come by boiler enters reboiler carries out heat exchange condensation, and condensed water of condensation returns in boiler house through hot water pump again and re-uses; Circulating water for gasification is sent in flashing chamber after evaporation concentration again, and producing a large amount of secondary steams in flashing chamber after pressure control, temperature control, two secondary steam send into reprocessing in Gas-making Furnace through flashing chamber top after overheated, voltage stabilizing.This process device used is evaporation unit, and the treatment capacity of its evaporation unit is 20m 3/ h, the quality parameter of water outlet in air supporting: composition: SS<30mg/L; Oil: naked eyes are not seen; Phenol: 700 ~ 1000mg/L; Specific conductivity: 25 μ S/cm; Salinity: 1%; Raw material proportion: 1000kg/m 3; PH value: 8 ~ 9; Treatment capacity: 20m 3/ h.

Reboiler two (carbon steel, a titanium material), flashing chamber carbon steel.

Have a small amount of salt in evaporative process to analyze, need regular extraction reprocessing.

In this process, the pressure of raw steam controls as 0.618MPa, and raw vapor temperature controls to be 160 DEG C; The circulating water for gasification steam output sent into again after evaporation concentration in flashing chamber controls as 19800kg/h; Two secondary steam pressures control as 0.199MPa, and two secondary vapor temperatures control to be 120 DEG C; In flashing chamber, liquidus temperature controls is 125 DEG C, and wherein, the effective temperature difference of liquid phase and gas phase controls to be 34 DEG C; Flashing chamber overhead vapor pressure-controlling is 0.199MPa, and flashing chamber inner top controls as 17680m to the secondary steam amount of Gas-making Furnace 3/ h.

A small amount of non-condensable gas can be produced in native system, long term accumulation can be partially formed higher concentration in condensation side, heat transfer efficiency is caused obviously to decline, so be provided with special noncondensable gas relief outlet at reboiler heating chamber, in evaporative process, open non-condensable gas valve at any time regularly discharge, to improve heat transfer efficiency.

For feed liquid physical property and evaporation object, requirement, natural-circulation evaporator selected by vaporizer, natural-circulation evaporator in evaporative process, feed liquid enter oven heats heat up, owing to not reaching the temperature of saturation under this state, solution does not seethe with excitement.Along with heating and the reduction of intraductal pressure, when after the saturated pressure under the temperature of solution reaches this state, come to life, thus produce a large amount of bubble, the density of solution also reduces thereupon, the density difference existed between the feed liquid of the not boiling of the liquid-vapor mixture like this in boiling tube and circulation tube side, defines the circulation impellent of external-heat natural-circulation evaporator.In order to prevent fouling and partial crystallization, heating tube should operate under complete submerged state.This vaporizer is applicable to the evaporation concentration of the not serious and less solution of corrodibility of fouling, and its advantage is that structure is simple, and be convenient to manufacture, power consumption is low.The energy consumption produced in this process is: system throughput: 20m 3/ h; System steam output: 19.8t/h; Steam consumption: 26.1t/h; Installed power: 16.5kw.

Claims (10)

1. gas making is containing ammonia containing the recirculated water pretreatment process of cyanogen containing phenol, it is characterized in that, comprises the steps:
Circulating water for gasification is scraped after slag oil removing through advection oil separation tank, oil in water emulsion is taken off steady, coalescent by adding emulsion splitter, again dosing coagulant, magnetic, flocculation agent accelerate to separate out fat liquor, colloid and suspended solids throw out, this throw out is delivered to settling tank, by the oil pollutant removing in water, the magnetic of settling tank bottom realizes recycle by Separation and Recovery;
The water outlet gravity flow on settling tank top enters air flotation pool, coagulation, flocculation, air supporting three phases is divided in air flotation pool, in coagulation basin, dosing coagulant makes fat liquor, colloid and suspended solids de-steady, produce little alumen ustum, sewage after coagulation flows into flocculation basin, add flocculation agent in pond alumen ustum to be assembled for larger, more all even firmly alumen ustum, air flotation pool is entered after flocculation water mixes with the recirculated water being full of microbubble, alumen ustum and microbubble flock together, form uniform greasy filth cake on air flotation pool surface, then greasy filth cake is scraped into a receiving tank; Water after treatment flows in suction well, and the part water yield in suction well, by under the effect of pump, is circulated to air flotation pool entrance by dissolving;
Through step 2) circulation after, the water outlet in air flotation pool is discharged through outlet conduit, enters vapo(u)rization system; Bed mud bottom air flotation pool sends into sludge sump, that is, complete the pretreated process of circulating water for gasification.
2. gas making according to claim 1 contains the recirculated water pretreatment process of phenol containing cyanogen containing ammonia, it is characterized in that, the described recirculated water being full of microbubble is at completing steps 2) process after, air is injected in dissolving through air compression plant, dissolve in recirculated water, then the water containing saturated air delivers to the entrance release of pressure of air flotation pool by Pressure-relief Device, this pressure-release assembly produces the bubble of 50 to 80 microns, can obtain the recirculated water being full of microbubble, this recirculated water being full of microbubble is easily attached on alumen ustum.
3. gas making according to claim 1 containing ammonia containing cyanogen containing the recirculated water pretreatment process of phenol, it is characterized in that, described emulsion splitter is one or more in polyoxyethylene, polyoxypropylene or alkyl phenolic resin, and its addition is 50-120ppm.
4. gas making according to claim 1 is containing ammonia containing the recirculated water pretreatment process of cyanogen containing phenol, and it is characterized in that, described coagulating agent is polymer alumina, and its addition is 50-120ppm.
5. gas making according to claim 1 contains the recirculated water pretreatment process of phenol containing cyanogen containing ammonia, it is characterized in that, described flocculation agent is one or more in polyacrylamide, bodied ferric sulfate or polymerize aluminum chloride, wherein, step 1) in add-on be 1-3ppm; Step 2) in add-on be 0.5-1ppm.
6. gas making according to claim 1 is containing ammonia containing the recirculated water pretreatment process of cyanogen containing phenol, and it is characterized in that, the residence time of coagulation basin is 3min; The residence time in the pond of flocculation basin is 10min; The water cycle ratio of air flotation pool is 40%.
7. gas making according to claim 1 contains the recirculated water pretreatment process of phenol containing cyanogen containing ammonia, it is characterized in that, described vapo(u)rization system is by the water outlet in air flotation pool, namely deliver to reboiler tube side with the flow of 20 ㎡/h by feeding pump after pretreated circulating water for gasification is warming up to 60 DEG C and carry out evaporation concentration, the heating chamber course that the saturated raw steam simultaneously come by boiler enters reboiler carries out heat exchange condensation, and condensed water of condensation returns in boiler house through hot water pump again and re-uses; Circulating water for gasification is sent in flashing chamber after evaporation concentration again, and producing a large amount of secondary steams in flashing chamber after pressure control, temperature control, two secondary steam send into reprocessing in Gas-making Furnace through flashing chamber top after overheated, voltage stabilizing.
8. gas making according to claim 7 is containing ammonia containing the recirculated water pretreatment process of cyanogen containing phenol, it is characterized in that, the pressure of raw steam controls as 0.618MPa, and raw vapor temperature controls to be 160 DEG C; The circulating water for gasification steam output sent into again after evaporation concentration in flashing chamber controls as 19800kg/h; Two secondary steam pressures control as 0.199MPa, and two secondary vapor temperatures control to be 120 DEG C; In flashing chamber, liquidus temperature controls is 125 DEG C, and wherein, the effective temperature difference of liquid phase and gas phase controls to be 34 DEG C; Flashing chamber overhead vapor pressure-controlling is 0.199MPa, and flashing chamber inner top controls as 17680m to the secondary steam amount of Gas-making Furnace 3/ h.
9. the gas making described in any one of claim 1-8 containing ammonia containing cyanogen containing the recirculated water pretreatment process of phenol treatment unit used, it is characterized in that, this pretreatment unit comprises loading coagulation oil removal plant, air-floating apparatus and evaporation unit, wherein, load coagulation oil removal plant and comprise mixing pit, the dosing pond of emulsion splitter, flocculation basin, settling tank; Settling tank top is connected with air flotation pool device through carrier pipe, is connected bottom settling tank after pipeline is connected with pump with magnetic withdrawing can again, magnetic withdrawing can again with sludge dehydration device; Air flotation pool device comprises coagulation basin and flocculation basin, and be connected through the bottom of carrier pipe with the carrier pipe in the middle of air flotation pool bottom flocculation basin, air flotation pool upper end is provided with outlet conduit, and bottom air flotation pool and bottom is also provided with the pipeline to sludge sump.
10. gas making according to claim 9 contains the recirculated water pretreatment unit of phenol containing cyanogen containing ammonia, it is characterized in that, described evaporation unit comprises reboiler, flashing chamber, and saturated raw steam is connected with reboiler top through carrier pipe, and parallel connection passes to heating chamber shell side and connects; Pretreated circulating water for gasification is connected parallel connection through carrier pipe with the bottom of reboiler and passes to reboiler tube side; Reboiler top is connected with flashing chamber through carrier pipe, and flashing chamber top is connected to Gas-making Furnace through carrier pipe; After carrier pipe converges, feed reservoir is connected to bottom flashing chamber with bottom reboiler; Reboiler bottom is connected to boiler house through carrier pipe.
CN201510652075.2A 2015-10-10 2015-10-10 A kind of gas making is containing ammonia containing circulation water pretreatment process and device of the cyanogen containing phenol CN105254096B (en)

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CN105776476A (en) * 2016-04-25 2016-07-20 广饶康达环保水务有限公司 Magnetic-coagulation water treatment device and treatment process
CN108793555A (en) * 2018-06-13 2018-11-13 苏州永峰联环保科技有限公司 Remained ammonia treatment process and its processing system
CN109354139A (en) * 2018-09-26 2019-02-19 同济大学 A method of waste emulsion liquid is processed using magnetic-particle fast processor tool

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