CN105219151A - Paint remover that a kind of environmental protection is stable and preparation method thereof - Google Patents
Paint remover that a kind of environmental protection is stable and preparation method thereof Download PDFInfo
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- CN105219151A CN105219151A CN201510751796.9A CN201510751796A CN105219151A CN 105219151 A CN105219151 A CN 105219151A CN 201510751796 A CN201510751796 A CN 201510751796A CN 105219151 A CN105219151 A CN 105219151A
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- paint remover
- environmental protection
- stable
- paint
- stir
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- 239000003973 paint Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims abstract description 33
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 22
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000011105 stabilization Methods 0.000 claims abstract description 18
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920005479 Lucite® Polymers 0.000 claims abstract description 13
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 13
- YMWUJEATGCHHMB-UHFFFAOYSA-N methylene dichloride Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- -1 turps Chemical compound 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 12
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 11
- 239000001110 calcium chloride Substances 0.000 claims abstract description 11
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 11
- 239000001913 cellulose Substances 0.000 claims abstract description 11
- 229920002678 cellulose Polymers 0.000 claims abstract description 11
- 239000012153 distilled water Substances 0.000 claims abstract description 11
- 235000019253 formic acid Nutrition 0.000 claims abstract description 11
- 239000012188 paraffin wax Substances 0.000 claims abstract description 11
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 11
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 35
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 claims description 20
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 15
- 230000003078 antioxidant Effects 0.000 claims description 10
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 239000000194 fatty acid Substances 0.000 claims description 10
- 239000012467 final product Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 241000779819 Syncarpia glomulifera Species 0.000 abstract description 2
- 229940036248 Turpentine Drugs 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 230000002708 enhancing Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 239000001739 pinus spp. Substances 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920000180 Alkyd Polymers 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N Chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;N-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002522 swelling Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Abstract
The invention discloses stable paint remover of a kind of environmental protection and preparation method thereof, relate to paint remover technical field, make primarily of butyl acrylate, methylene dichloride, diethyl carbonate, turps, methyl alcohol, formic acid, benzotriazole, dimethyl sulfoxide (DMSO), calcium chloride, Sodium dodecylbenzene sulfonate, hydrogen peroxide, paraffin, lucite powder, water soluble cellulose, distilled water, stabilization aid.Paint remover environmental protection of the present invention, paint removal efficiency are high, butyl acrylate, methylene dichloride, diethyl carbonate are with the use of, stable in properties, and volatility is little, stabilization aid, lucite powder, turpentine wet goods composition are corrosion-free to base material, enhance performance and the paint removing effect of paint remover.
Description
Technical field
The present invention relates to paint remover technical field, is more particularly stable paint remover of a kind of environmental protection and preparation method thereof.
Background technology
Paint remover: have another name called and take off paint agent, paint scrubber or paint remover, mixed by hydrochloric ether, ketone, ester, alcohol, benzene homologues equal solvent.Utilize solvent to have Permeation Swelling effect to coverture, effectively can remove various substrate surface paint, coating etc., removable coat type a wider range, be applicable to the various paint such as alkyd, nitro, poly(urea formaldehyde) rubber-type ethene, epoxy, polyester, urethane.
Now, the kind of paint remover can be divided into following a few class: 1. acid paint remover 2. basic paint remover 3. solvent stripper.Wherein acid and basic paint remover all can produce corrosion to matrix, and the harm of sewage to environment of the acidity produced or alkalescence is large.And solvent stripper is main solvent mainly with ordinary organic solvents greatly, corrosion-free to matrix, therefore more welcome in recent years.But inevitably, these organic solvents are all with certain toxicity, and volatilization is fast, polluted air.
Summary of the invention
The object of the invention is to make up the deficiencies in the prior art, paint remover providing a kind of environmental protection stable and preparation method thereof.
The object of the invention is to be achieved through the following technical solutions:
The paint remover that environmental protection is stable, is made up of following raw material: butyl acrylate 6-8, methylene dichloride 55-65, diethyl carbonate 2-4, turps 1-3, methyl alcohol 2-4, formic acid 1-3, benzotriazole 0.4-0.6, dimethyl sulfoxide (DMSO) 0.3-0.5, calcium chloride 2-4, Sodium dodecylbenzene sulfonate 1-2, hydrogen peroxide 1-3, paraffin 2-3, lucite powder 1-2, water soluble cellulose 0.4-0.6, distilled water are appropriate, stabilization aid 2-4; Wherein stabilization aid is made up of following raw material: Sunmorl N 60S 0.8-1, alizarin assistant 1-2, rosin 1-3, octylisothiazolinone 0.4-0.6, titanium dioxide 1-3, sorbic anhydride fatty acid ester 2-4, Yelkin TTS 1-3, glycol ether 1-3, antioxidant 300 0.3-0.5; Preparation method is: 1. first join in container by titanium dioxide, sorbic anhydride fatty acid ester, Yelkin TTS, Sunmorl N 60S, octylisothiazolinone, glycol ether, then the water bath with thermostatic control heated and stirred 0.3-0.8 hour of 30-50 DEG C is placed in, make it mix, then add alizarin assistant, rosin, antioxidant 300 continue in the water bath with thermostatic control of 30-50 DEG C, stir 0.5-1 hour, make it fully mix and get final product.
A preparation method for the paint remover that environmental protection is stable, comprises the following steps:
(1) stir: heating paraffin is melted, in insulation, adds butyl acrylate, methylene dichloride, diethyl carbonate while stirring, continue to stir 5-15 minute;
(2) then methyl alcohol, formic acid are added in the solution after stirring in step (1), stir 10-20 minute to obtain compound;
(3) Sodium dodecylbenzene sulfonate, water soluble cellulose and appropriate distilled water are uniformly mixed, then add benzotriazole, dimethyl sulfoxide (DMSO), hydrogen peroxide, calcium chloride, at temperature is 20-40 DEG C, is incubated 1-2 hour;
(4) by mixing such as the compound in lucite powder, turps, stabilization aid, step (2) and the raw materials in step (3), vigorous stirring 20-30 minute, dispersed and get final product to solids.
The invention has the advantages that:
Paint remover environmental protection of the present invention, paint removal efficiency are high, butyl acrylate, methylene dichloride, diethyl carbonate are with the use of, stable in properties, and volatility is little, stabilization aid, lucite powder, turpentine wet goods composition are corrosion-free to base material, enhance performance and the paint removing effect of paint remover.
Embodiment
Embodiment 1, the paint remover that environmental protection is stable, is made up of following weight (kg) raw material: butyl acrylate 6, methylene dichloride 55, diethyl carbonate 2, turps 1, methyl alcohol 2, formic acid 1, benzotriazole 0.4, dimethyl sulfoxide (DMSO) 0.3, calcium chloride 2, Sodium dodecylbenzene sulfonate 1, hydrogen peroxide 1, paraffin 2, lucite powder 1, water soluble cellulose 0.4, distilled water are appropriate, stabilization aid 2; Wherein stabilization aid is made up of following raw material: Sunmorl N 60S 0.8, alizarin assistant 1, rosin 1, octylisothiazolinone 0.4, titanium dioxide 1, sorbic anhydride fatty acid ester 2, Yelkin TTS 1, glycol ether 1, antioxidant 300 0.3; Preparation method is: 1. first join in container by titanium dioxide, sorbic anhydride fatty acid ester, Yelkin TTS, Sunmorl N 60S, octylisothiazolinone, glycol ether, then the water bath with thermostatic control heated and stirred 0.3 hour of 30 DEG C is placed in, make it mix, then add alizarin assistant, rosin, antioxidant 300 continue in the water bath with thermostatic control of 30 DEG C stir 0.5 hour, make it fully mix and get final product.
A preparation method for the paint remover that environmental protection is stable, comprises the following steps:
(1) stir: heating paraffin is melted, in insulation, adds butyl acrylate, methylene dichloride, diethyl carbonate while stirring, continue stirring 5 minutes;
(2) then methyl alcohol, formic acid are added in the solution after stirring in step (1), stir 10 minutes to obtain compound;
(3) Sodium dodecylbenzene sulfonate, water soluble cellulose and appropriate distilled water are uniformly mixed, then add benzotriazole, dimethyl sulfoxide (DMSO), hydrogen peroxide, calcium chloride, at temperature is 20 DEG C, is incubated 1 hour;
(4) by mixing such as the compound in lucite powder, turps, stabilization aid, step (2) and the raw materials in step (3), vigorous stirring 20 minutes, dispersed and get final product to solids.
Embodiment 2, the paint remover that environmental protection is stable, is made up of following weight (kg) raw material: butyl acrylate 7, methylene dichloride 60, diethyl carbonate 3, turps 2, methyl alcohol 3, formic acid 2, benzotriazole 0.5, dimethyl sulfoxide (DMSO) 0.4, calcium chloride 3, Sodium dodecylbenzene sulfonate 1, hydrogen peroxide 2, paraffin 3, lucite powder 2, water soluble cellulose 0.5, distilled water are appropriate, stabilization aid 3; Wherein stabilization aid is made up of following raw material: Sunmorl N 60S 0.9, alizarin assistant 1, rosin 2, octylisothiazolinone 0.5, titanium dioxide 2, sorbic anhydride fatty acid ester 3, Yelkin TTS 2, glycol ether 2, antioxidant 300 0.4; Preparation method is: 1. first join in container by titanium dioxide, sorbic anhydride fatty acid ester, Yelkin TTS, Sunmorl N 60S, octylisothiazolinone, glycol ether, then the water bath with thermostatic control heated and stirred 0.5 hour of 40 DEG C is placed in, make it mix, then add alizarin assistant, rosin, antioxidant 300 continue in the water bath with thermostatic control of 40 DEG C stir 0.8 hour, make it fully mix and get final product.
A preparation method for the paint remover that environmental protection is stable, comprises the following steps:
(1) stir: heating paraffin is melted, in insulation, adds butyl acrylate, methylene dichloride, diethyl carbonate while stirring, continue stirring 10 minutes;
(2) then methyl alcohol, formic acid are added in the solution after stirring in step (1), stir 15 minutes to obtain compound;
(3) Sodium dodecylbenzene sulfonate, water soluble cellulose and appropriate distilled water are uniformly mixed, then add benzotriazole, dimethyl sulfoxide (DMSO), hydrogen peroxide, calcium chloride, at temperature is 30 DEG C, is incubated 1.5 hours;
(4) by mixing such as the compound in lucite powder, turps, stabilization aid, step (2) and the raw materials in step (3), vigorous stirring 25 minutes, dispersed and get final product to solids.
Embodiment 3, the paint remover that environmental protection is stable, is made up of following weight (kg) raw material: butyl acrylate 8, methylene dichloride 65, diethyl carbonate 4, turps 3, methyl alcohol 4, formic acid 3, benzotriazole 0.6, dimethyl sulfoxide (DMSO) 0.5, calcium chloride 4, Sodium dodecylbenzene sulfonate 2, hydrogen peroxide 3, paraffin 3, lucite powder 2, water soluble cellulose 0.6, distilled water are appropriate, stabilization aid 4; Wherein stabilization aid is made up of following raw material: Sunmorl N 60S 1, alizarin assistant 2, rosin 3, octylisothiazolinone 0.6, titanium dioxide 3, sorbic anhydride fatty acid ester 4, Yelkin TTS 3, glycol ether 3, antioxidant 300 0.5; Preparation method is: 1. first join in container by titanium dioxide, sorbic anhydride fatty acid ester, Yelkin TTS, Sunmorl N 60S, octylisothiazolinone, glycol ether, then the water bath with thermostatic control heated and stirred 0.8 hour of 50 DEG C is placed in, make it mix, then add alizarin assistant, rosin, antioxidant 300 continue in the water bath with thermostatic control of 50 DEG C stir 1 hour, make it fully mix and get final product.
A preparation method for the paint remover that environmental protection is stable, comprises the following steps:
(1) stir: heating paraffin is melted, in insulation, adds butyl acrylate, methylene dichloride, diethyl carbonate while stirring, continue stirring 15 minutes;
(2) then methyl alcohol, formic acid are added in the solution after stirring in step (1), stir 20 minutes to obtain compound;
(3) Sodium dodecylbenzene sulfonate, water soluble cellulose and appropriate distilled water are uniformly mixed, then add benzotriazole, dimethyl sulfoxide (DMSO), hydrogen peroxide, calcium chloride, at temperature is 40 DEG C, is incubated 2 hours;
(4) by mixing such as the compound in lucite powder, turps, stabilization aid, step (2) and the raw materials in step (3), vigorous stirring 30 minutes, dispersed and get final product to solids.
The salient features detected result of the paint remover that above-described embodiment 1-3 obtains is as shown in the table:
Action time (min) | Depainting rate (%) | |
Embodiment 1 | 5 | 89 |
Embodiment 2 | 6 | 90 |
Embodiment 3 | 6 | 89 |
Claims (2)
1. the paint remover that environmental protection is stable, is characterized in that: be made up of following raw material: butyl acrylate 6-8, methylene dichloride 55-65, diethyl carbonate 2-4, turps 1-3, methyl alcohol 2-4, formic acid 1-3, benzotriazole 0.4-0.6, dimethyl sulfoxide (DMSO) 0.3-0.5, calcium chloride 2-4, Sodium dodecylbenzene sulfonate 1-2, hydrogen peroxide 1-3, paraffin 2-3, lucite powder 1-2, water soluble cellulose 0.4-0.6, distilled water are appropriate, stabilization aid 2-4; Wherein stabilization aid is made up of following raw material: Sunmorl N 60S 0.8-1, alizarin assistant 1-2, rosin 1-3, octylisothiazolinone 0.4-0.6, titanium dioxide 1-3, sorbic anhydride fatty acid ester 2-4, Yelkin TTS 1-3, glycol ether 1-3, antioxidant 300 0.3-0.5; Preparation method is: 1. first join in container by titanium dioxide, sorbic anhydride fatty acid ester, Yelkin TTS, Sunmorl N 60S, octylisothiazolinone, glycol ether, then the water bath with thermostatic control heated and stirred 0.3-0.8 hour of 30-50 DEG C is placed in, make it mix, then add alizarin assistant, rosin, antioxidant 300 continue in the water bath with thermostatic control of 30-50 DEG C, stir 0.5-1 hour, make it fully mix and get final product.
2. the preparation method of the paint remover that a kind of environmental protection according to claim 1 is stable, is characterized in that: comprise the following steps:
(1) stir: heating paraffin is melted, in insulation, adds butyl acrylate, methylene dichloride, diethyl carbonate while stirring, continue to stir 5-15 minute;
(2) then methyl alcohol, formic acid are added in the solution after stirring in step (1), stir 10-20 minute to obtain compound;
(3) Sodium dodecylbenzene sulfonate, water soluble cellulose and appropriate distilled water are uniformly mixed, then add benzotriazole, dimethyl sulfoxide (DMSO), hydrogen peroxide, calcium chloride, at temperature is 20-40 DEG C, is incubated 1-2 hour;
(4) by mixing such as the compound in lucite powder, turps, stabilization aid, step (2) and the raw materials in step (3), vigorous stirring 20-30 minute, dispersed and get final product to solids.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510751796.9A CN105219151A (en) | 2015-11-09 | 2015-11-09 | Paint remover that a kind of environmental protection is stable and preparation method thereof |
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CN201510751796.9A CN105219151A (en) | 2015-11-09 | 2015-11-09 | Paint remover that a kind of environmental protection is stable and preparation method thereof |
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CN201510751796.9A Pending CN105219151A (en) | 2015-11-09 | 2015-11-09 | Paint remover that a kind of environmental protection is stable and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106833103A (en) * | 2017-04-06 | 2017-06-13 | 苏州市金纳润特科技有限公司 | A kind of special paint stripper of harbour capital construction |
CN106893398A (en) * | 2017-04-06 | 2017-06-27 | 苏州市金纳润特科技有限公司 | A kind of paint stripper used for vehicle |
CN106893395A (en) * | 2017-03-24 | 2017-06-27 | 苏州市金纳润特科技有限公司 | A kind of ship of high-efficiency environment friendly depainting cream |
CN107760092A (en) * | 2017-11-20 | 2018-03-06 | 广东三和化工科技有限公司 | A kind of preparation method of aerial fog type without wax paint stripper |
-
2015
- 2015-11-09 CN CN201510751796.9A patent/CN105219151A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106893395A (en) * | 2017-03-24 | 2017-06-27 | 苏州市金纳润特科技有限公司 | A kind of ship of high-efficiency environment friendly depainting cream |
CN106833103A (en) * | 2017-04-06 | 2017-06-13 | 苏州市金纳润特科技有限公司 | A kind of special paint stripper of harbour capital construction |
CN106893398A (en) * | 2017-04-06 | 2017-06-27 | 苏州市金纳润特科技有限公司 | A kind of paint stripper used for vehicle |
CN107760092A (en) * | 2017-11-20 | 2018-03-06 | 广东三和化工科技有限公司 | A kind of preparation method of aerial fog type without wax paint stripper |
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