CN105198030B - A kind of method of chlorion in utilization garlic waste removing water - Google Patents
A kind of method of chlorion in utilization garlic waste removing water Download PDFInfo
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- CN105198030B CN105198030B CN201410264357.0A CN201410264357A CN105198030B CN 105198030 B CN105198030 B CN 105198030B CN 201410264357 A CN201410264357 A CN 201410264357A CN 105198030 B CN105198030 B CN 105198030B
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- silver ion
- garlic
- garlic waste
- water
- chlorion
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- 235000004611 garlic Nutrition 0.000 title claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000002699 waste material Substances 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 24
- 241000370738 Chlorion Species 0.000 title claims abstract description 21
- 244000245420 ail Species 0.000 title 1
- 240000002234 Allium sativum Species 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 33
- 239000002250 absorbent Substances 0.000 claims abstract description 23
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims abstract description 22
- 230000002745 absorbent Effects 0.000 claims abstract description 22
- 239000002028 Biomass Substances 0.000 claims abstract description 18
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 12
- 238000001914 filtration Methods 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 12
- 229910017604 nitric acid Inorganic materials 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 9
- 238000013019 agitation Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 5
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- XRRQZKOZJFDXON-UHFFFAOYSA-N nitric acid;silver Chemical compound [Ag].O[N+]([O-])=O XRRQZKOZJFDXON-UHFFFAOYSA-N 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 239000001099 ammonium carbonate Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000012265 solid product Substances 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000002351 wastewater Substances 0.000 claims description 3
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 2
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 206010013786 Dry skin Diseases 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 2
- 229960005070 ascorbic acid Drugs 0.000 claims description 2
- 235000010323 ascorbic acid Nutrition 0.000 claims description 2
- 239000011668 ascorbic acid Substances 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 235000013877 carbamide Nutrition 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 2
- 238000001291 vacuum drying Methods 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims 1
- 238000006298 dechlorination reaction Methods 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 10
- 238000010521 absorption reaction Methods 0.000 abstract description 9
- 238000001179 sorption measurement Methods 0.000 abstract description 8
- 239000007864 aqueous solution Substances 0.000 abstract description 6
- 239000012535 impurity Substances 0.000 abstract description 2
- 229910052709 silver Inorganic materials 0.000 abstract description 2
- 239000004332 silver Substances 0.000 abstract description 2
- 239000002594 sorbent Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 15
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 8
- 239000003463 adsorbent Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229910001961 silver nitrate Inorganic materials 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000000909 electrodialysis Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 241000675108 Citrus tangerina Species 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 240000006053 Garcinia mangostana Species 0.000 description 1
- 235000017048 Garcinia mangostana Nutrition 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- -1 sodium hypophosphites Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Landscapes
- Water Treatment By Sorption (AREA)
Abstract
The method that the present invention provides chlorion in a kind of utilization garlic waste removing water, belongs to the adsorbing and removing technical field of chlorion in water.Garlic waste sorbent material is carried out Contact-sorption reaction by this method with the aqueous solution containing finite concentration silver ion, obtains the garlic waste biomass absorbent material of load silver ion；By the garlic waste biomass absorbent material of prepared load silver ion, after carrying out haptoreaction for a period of time with the aqueous solution containing chlorion, you can reach the purpose of chlorion in removing water.The garlic waste biomass absorbent material of the load silver ion reacted passes through subsequent treatment, can reclaim silver in powder form.This method is simple, easy, and significantly, adsorption operations are very easy for adsorption effect, and new impurity will not be introduced to pending water source, and the absorption dechlorination time is short, is easy to extensive implementation.
Description
Technical field
The present invention relates to the adsorbing and removing technical field of chlorion in water, one kind is particularly related to using garlic waste removing
The method of chlorion in water.
Background technology
Chlorion is common a kind of anion in water, and its concentration causes drinking water poor taste, metal water delivery compared with Gao Shihui
The problems such as corrosive pipeline, therefore there are many occasions to have the demand for removing chlorion in water in industrial quarters and life.
There is the method for chlorion in common removing water：1) precipitation method：Precipitating reagent is done using silver nitrate, by the chlorine in water from
Son filtering and removing in the way of precipitating.The effect of this method removing chloride ion is good, and shortcoming is also obvious, such as nitric acid argentum reagent compared with
Expensive, precipitation particles is often very tiny to cause separation of solid and liquid difficult, and in order to ensure that it is many that chlorion removal effect often has
Remaining silver ion is remained in water and causes secondary pollution, and silver nitrate can also bring nitrate anion into as antichlor in addition, and feedwater is made
Into secondary pollution and the content of nitrogen in water is increased, although therefore this method principle is simple, it is still limited using scope.
2) ion-exchange：Chlorion is removed using resin anion (R.A.), the method is simple, convenient, but to the friendship of chlorion
Changing operation needs complicated early stage pretreatment, and the cleanliness factor to water etc. requires higher, otherwise can block resin micropore and
Dechlorination is caused to fail, therefore there is also certain limitation.3) membrane separating method：Using the method for electrodialysis or counter-infiltration by chlorine
Ion is removed, and this method removing chloride ion effect is good, but electrodialysis or reverse osmosis unit is more expensive, maintenance cost is also higher, limit
It has been made to widely use.4) Electro Sorb method：Apply the chlorion in an external electric field, forced water to the aqueous solution towards with opposite
Electrode movement, the concentration of electric charge and remove, with dechlorination effect is good, the low advantage of operating cost, but the power consumption of its operation compared with
Greatly, special device is needed.Therefore, exploiting economy, advanced technology that is efficient, easily removing chlorion in water are very necessary.
The invention discloses one kind using garlic waste be raw material, to prepare sorbing material, dedicated for chlorine in water from
The deep removal of son, the dechlorination effect with highly significant.
The content of the invention
The technical problem to be solved in the present invention is to provide the method for chlorion in a kind of utilization garlic waste removing water.
This method is concretely comprised the following steps：
First, 0.1mol/L nitric acid silver ion solution is taken, gold is adjusted with 0.1mol/L nitric acid and sodium hydroxide solution
The pH for belonging to solion is that after 4~5, nitrogen gas stirring or logical nitrogen use mechanical agitation 30min simultaneously, with every liter of silver nitrate from
Sub- solution adds 20~50g consumption, adds garlic waste sorbing material, continue under the conditions of lucifuge stirring reaction 10~
After 24h, sorbing material is filtered, after distillation water washing 3 times, 6h is dried in the baking oven for being put into 60 DEG C, gained dries adsorbent powder
End is the garlic waste biomass absorbent material of load silver ion；
Then, the garlic waste biomass absorbent material of load silver ion is added 0.1 with every liter of chloride ion-containing waste water
~150g consumption is added in waste water, after 10~100min of mechanical agitation or air stirring, filtering, reach removing water in chlorine from
The purpose of son；
Finally, the garlic waste biomass absorbent material ammoniacal liquor of the load silver ion after filtering soaked, stir 30
After~50min, filtering, addition hydrazine hydrate, potassium borohydride, formaldehyde, ascorbic acid, sodium hypophosphite are gone back in obtained filtrate
Former agent, is heated to after 40~60 DEG C, and insulation reaction 60min filters, obtains silver powder again；After obtained silver powder nitric acid dissolves,
Continue on for preparing the garlic waste biomass absorbent material of load silver ion.
Wherein, the preparation method for the garlic waste sorbing material that the above method is used is according to patent No. ZL：
Prepared by the method disclosed in 201210019530.1, contain-COOH ,-SH ,-NH2 ,-(phenol) OH isoreactivity work(after will washing
The biomass that can be rolled into a ball, such as garlic residue, mangosteen slag, marine alga, vinasse, tangerine slag, apple skin, pomelo peel and alkali, water are according to 1：0.05-
0.2：0.5-2 mass ratio is stirred hybrid reaction, stirs 12~24 hours, and filtering obtains solid product, wherein, it is described
Alkali is lithium, sodium, potassium, calcium, the oxide of magnesium, hydroxide, carbonate, bicarbonate or ammonium carbonate, ammonium hydrogen carbonate, urea, ammonia
One or two or more kinds of mixing in water；Above solid product is washed with water until neutral, feeding vacuum drying oven, is 60 in temperature
~120 DEG C of dryings, drying object is smashed, sieved, and the following powder collection of 40 mesh obtains biomass absorbent agent material.
The above-mentioned technical proposal of the present invention has the beneficial effect that：
In such scheme, the preparation method of sorbing material is simple, easy, and significantly, adsorption operations are very easy for adsorption effect,
Avoid directly using various shortcoming of the silver nitrate as antichlor, new impurity will not be introduced to pending water source, and
Adsorb the dechlorination time very short, it is only necessary to several minutes；Silver-colored chlorine compound after absorption, the method that powder reducing process can be used
Reclaimed, and circulate the preparation of the biomass absorbent material for load silver ion, so as to greatly reduce silver as absorption
The cost of material.
Embodiment
To make the technical problem to be solved in the present invention, technical scheme and advantage clearer, below in conjunction with specific implementation
Example is described in detail.
The present invention is for the existing method for removing chlorion in water using being limited in scope, and there is provided one for the problems such as cost is high
Plant the method that chlorion in water is removed using garlic waste.
Embodiment 1
2 liters of the nitric acid silver ion solution of 0.1mol/L concentration is prepared, is adjusted with 0.1mol/L nitric acid and sodium hydroxide solution
The pH for saving metal ion solution is after 4, nitrogen gas stirring or logical nitrogen simultaneously using mechanical agitation 30min after, input 200 mesh grain
The garlic waste adsorbent 100g of degree, continues to react 24h, is operated during whole adsorption reaction in the environment of lucifuge, will
Absorbent filtering, after distillation water washing 3 times, is put into 60 DEG C of baking oven and dries 6 hours, it is negative that gained, which dries absorbent powder,
The dechlorination agent material of silver ion is carried.
500 milliliters of aqueous solution, wherein chloride ion-containing 1000mg/L are taken, negative silver-colored garlic waste absorption powder material 3 is added
Gram, stirring reaction is after 30 minutes, filtering, and it is 60mg/L to measure chloride ion-containing concentration in the solution after absorption, it is seen that the dechlorination is inhaled
Significantly, dechlorination rate is up to more than 94% for attached dose of effect.
By the adsorbent being collected by filtration, after 1mol/L 50 milliliters of immersions of ammoniacal liquor, stirring 30min, filtering, by filtrate
5 milliliters of hydrazine hydrates of middle addition, are heated to insulation reaction 60min after 50 DEG C, and filtering can obtain silver powder.0.1mol/L concentration is used again
The mixing of 50 milliliters of nitric acid, the garlic waste biomass absorbent material for continuing to prepare load silver ion.
Embodiment 2
2 liters of the nitric acid silver ion solution of 0.1mol/L concentration is prepared, is adjusted with 0.1mol/L nitric acid and sodium hydroxide solution
The pH for saving metal ion solution is after 5, nitrogen gas stirring or logical nitrogen simultaneously using mechanical agitation 30min after, input 40 mesh grain
The garlic waste adsorbent 50g of degree, continues to react 24h, operates, will be inhaled in the environment of lucifuge during whole adsorption reaction
Attached dose of filtering, after distillation water washing 3 times, is put into hot blast in 60 DEG C of baking oven and dries 6 hours, gained dries absorbent powder and is
The dechlorination agent material of silver ion is loaded.
500 milliliters of aqueous solution, wherein chloride ion-containing 1000mg/L are taken, negative silver-colored garlic waste absorption powder material 3 is added
Gram, stirring reaction is after 30 minutes, filtering, and it is 28mg/L to measure chloride ion-containing concentration in the solution after absorption, it is seen that the dechlorination is inhaled
Significantly, dechlorination rate is up to more than 97% for attached dose of effect.
By the adsorbent being collected by filtration, after 1mol/L 50 milliliters of immersions of ammoniacal liquor, stirring 30min, filtering, by filtrate
5 milliliters of hydrazine hydrates of middle addition, are heated to insulation reaction 60min after 50 DEG C, and filtering can obtain silver powder.0.1mol/L concentration is used again
The mixing of 50 milliliters of nitric acid, the garlic waste biomass absorbent material for continuing to prepare load silver ion.
Embodiment 3
2 liters of the nitric acid silver ion solution of 0.1mol/L concentration is prepared, is adjusted with 0.1mol/L nitric acid and sodium hydroxide solution
The pH for saving metal ion solution is after 4.6, nitrogen gas stirring or logical nitrogen simultaneously using mechanical agitation 30min after, put into 300 mesh
After garlic waste the adsorbent 60g, stirring reaction 10h of granularity, operated during whole adsorption reaction in the environment of lucifuge,
By absorbent filtering, after distillation water washing 3 times, 6h is dried in the baking oven for being put into 60 DEG C, it is negative that gained, which dries absorbent powder,
The dechlorination agent material of silver ion is carried.
500 milliliters of aqueous solution, wherein chloride ion-containing 1000mg/L are taken, negative silver-colored garlic waste absorption powder material 3 is added
Gram, stirring reaction is after 30 minutes, filtering, and it is 15mg/L to measure chloride ion-containing concentration in the solution after absorption, it is seen that the dechlorination is inhaled
Significantly, dechlorination rate is up to more than 98% for attached dose of effect.
By the adsorbent being collected by filtration, after 1mol/L 50 milliliters of immersions of ammoniacal liquor, stirring 30min, filtering, by filtrate
3 grams of sodium hypophosphites of middle addition, are heated to insulation reaction 60min after 50 DEG C, and filtering can obtain silver powder.It is dense with 0.1mol/L again
50 milliliters of the nitric acid mixing of degree, the garlic waste biomass absorbent material for continuing to prepare load silver ion.
Described above is the preferred embodiment of the present invention, it is noted that for those skilled in the art
For, on the premise of principle of the present invention is not departed from, some improvements and modifications can also be made, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (1)
1. a kind of method of chlorion in utilization garlic waste removing water, it is characterised in that：
First, 0.1mol/L nitric acid silver ion solution is taken, with 0.1mol/L nitric acid and 0.1mol/L sodium hydroxide solution
The pH for adjusting metal ion solution is that after 4~5, nitrogen gas stirring or logical nitrogen use mechanical agitation 30min, every liter of nitric acid simultaneously
20~50g garlic waste sorbing material is added in silver ion solution, is continued after 10~24h of stirring reaction, by sorbing material
Filtering, after distillation water washing 3 times, dries 6h, it is load silver ion that gained, which dries absorbent powder, in the baking oven for being put into 60 DEG C
Garlic waste biomass absorbent material；
Then, every liter of chloride ion-containing waste water adds the garlic waste biomass absorbent that 0.1~150g is the load silver ion
After material, 10~100min of mechanical agitation or air stirring, filtering reaches the purpose of chlorion in removing water；
Finally, the garlic waste biomass absorbent material ammoniacal liquor of the load silver ion after filtering is soaked, stir 30~
After 50min, one in hydrazine hydrate, potassium borohydride, formaldehyde, ascorbic acid, sodium hypophosphite is added in filtering in obtained filtrate
Plant and make reducing agent, be heated to after 40~60 DEG C, insulation reaction 60min filters, obtains silver powder again；Obtained silver powder nitric acid
After dissolving, continue on for preparing the garlic waste biomass absorbent material of load silver ion；
The garlic waste biomass absorbent material for preparing load silver ion is carried out under conditions of lucifuge；
The preparation method of described garlic waste sorbing material is：By the garlic residue after washing and alkali, water according to 1：0.05-
0.2：0.5-2 mass ratio is stirred hybrid reaction, stirs 12~24 hours, and filtering obtains solid product, wherein, it is described
Alkali is lithium, sodium, potassium, calcium, the oxide of magnesium, hydroxide, carbonate, bicarbonate or ammonium carbonate, ammonium hydrogen carbonate, urea, ammonia
One or two or more kinds of mixing in water；Above solid product is washed with water until neutral, feeding vacuum drying oven, is 60 in temperature
~120 DEG C of dryings, drying object is smashed, sieved, and the following powder collection of 40 mesh obtains garlic waste sorbing material.
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| CN201410264357.0A CN105198030B (en) | 2014-06-13 | 2014-06-13 | A kind of method of chlorion in utilization garlic waste removing water |
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| CN201410264357.0A CN105198030B (en) | 2014-06-13 | 2014-06-13 | A kind of method of chlorion in utilization garlic waste removing water |
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| CN105198030A CN105198030A (en) | 2015-12-30 |
| CN105198030B true CN105198030B (en) | 2017-10-20 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105771922A (en) * | 2016-05-25 | 2016-07-20 | 北京科技大学 | Preparation and application methods of copper ion adsorbent |
| CN108970586A (en) * | 2017-05-31 | 2018-12-11 | 南京博络金环保科技有限公司 | A method of utilizing low-concentration ammonia-nitrogen in biological adsorption removing water body |
| CN109331787B (en) * | 2018-10-22 | 2021-03-16 | 北京科技大学 | Method for manufacturing section bar capable of simultaneously sterilizing and removing heavy metal |
| CN109331786B (en) * | 2018-10-22 | 2021-06-01 | 北京科技大学 | Method for preparing sterilizing water purification material by using garlic straw waste |
| CN109289786B (en) * | 2018-10-22 | 2020-12-08 | 北京科技大学 | Preparation and use method of adsorption material for simultaneously removing anions and cations in water |
| CN109289783B (en) * | 2018-10-22 | 2021-03-05 | 北京科技大学 | Arsenic-removing compound adsorbing material prepared from garlic straw waste and using method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009098083A (en) * | 2007-10-19 | 2009-05-07 | National Institute For Materials Science | Iodine storage body |
| CN102557181A (en) * | 2012-01-20 | 2012-07-11 | 北京科技大学 | Method for adsorption and removal of heavy metals and dye of waste water by garlic waste |
| CN103371429A (en) * | 2012-04-22 | 2013-10-30 | 朱大恒 | Tobacco dechlorinating method, application of tobacco dechlorinating method and tobacco dechlorinating device |
| CN103831086A (en) * | 2012-11-19 | 2014-06-04 | 株式会社东芝 | Halogen adsorbent, tank for water treatment, and water treatment system |
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2014
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009098083A (en) * | 2007-10-19 | 2009-05-07 | National Institute For Materials Science | Iodine storage body |
| CN102557181A (en) * | 2012-01-20 | 2012-07-11 | 北京科技大学 | Method for adsorption and removal of heavy metals and dye of waste water by garlic waste |
| CN103371429A (en) * | 2012-04-22 | 2013-10-30 | 朱大恒 | Tobacco dechlorinating method, application of tobacco dechlorinating method and tobacco dechlorinating device |
| CN103831086A (en) * | 2012-11-19 | 2014-06-04 | 株式会社东芝 | Halogen adsorbent, tank for water treatment, and water treatment system |
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