CN105196200A - Rare earth ceramic bonding agent and manufacturing method of grinding wheel by using bonding agent - Google Patents

Rare earth ceramic bonding agent and manufacturing method of grinding wheel by using bonding agent Download PDF

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Publication number
CN105196200A
CN105196200A CN201510581074.3A CN201510581074A CN105196200A CN 105196200 A CN105196200 A CN 105196200A CN 201510581074 A CN201510581074 A CN 201510581074A CN 105196200 A CN105196200 A CN 105196200A
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Prior art keywords
bonding agent
rare
rare earth
earth
earth ceramic
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CN201510581074.3A
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CN105196200B (en
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朱国乔
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Huangshan Anka grinding New Material Co.,Ltd.
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Huangshan Anka Heavy Duty Wheel Co Ltd
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Abstract

The invention discloses a rare earth ceramic bonding agent. The rare earth ceramic bonding agent comprises a rare earth oxide material, a siliceous material, an aluminum-containing material and boric acid. The invention further discloses a manufacturing method of a grinding wheel by using the bonding agent. The manufacturing method comprises the steps of mixing the rare earth oxide material with the siliceous material and the aluminum-containing material, then performing smelting, performing cooling, ball milling and screening, then mixing with a grinding material, performing sintering and then performing trimming by turning. Through the method, the invention can enable the grinding wheel to have the characteristics of high strength, high self-sharpening performance and long service life.

Description

A kind of rare-earth ceramic bonding agent and use the manufacture method of emery wheel of this bonding agent
Technical field
The present invention relates to a kind of rare-earth ceramic bonding agent, belong to field of new; Also relate to the manufacture method of the emery wheel using this bonding agent simultaneously.
Background technology
Emery wheel is a topmost class grinding tool in grinding.Emery wheel adds bonding agent in abrasive material, the porous body made through pressed compact, drying and roasting.Because abrasive material, bonding agent and manufacturing process are different, the characteristic difference of emery wheel is very large, therefore to the crudy of grinding, productivity ratio and economy important.
At present, roller abrasive wheel conventional on market generally adopts resinoid bond, and its intensity is not high, the life-span is low, sharpness is general, and duration of work can produce ammonia serious environment pollution, infringement workman is healthy; And a small amount of vitrified bonded grinding wheel exists that intensity is not high, the life-span general and the more high unfavorable factor of cost, thus have impact on its application commercially.
Summary of the invention
For overcoming above-mentioned deficiency, the object of the invention is to provide a kind of rare-earth ceramic bonding agent and uses the manufacture method of emery wheel of this bonding agent.The emery wheel produced effectively can improve the shortcomings such as the intensity of existing emery wheel is low, the life-span is low, sharpness is low, self-sharpening is poor, cost performance is low, environmental pollution.
The solution of the present invention is as follows: a kind of rare-earth ceramic bonding agent, it is characterized in that comprising following heavy part raw material: the rare earth oxide material of 5-15%, 50-60% siliceous material, 15-20% alumina-bearing material and 15-20% boric acid.
Further, described rare earth oxide material is one, two or three in neodymia, yittrium oxide and lanthana.
Further, described siliceous material is the one, two or three in quartz sand, albite, pyrophillite, prodan.
Further, described alumina-bearing material is the one, two or three in aluminium powder, aluminium oxide, aluminium hydroxide, sodium metaaluminate four kinds of materials.
A kind of manufacture method of the emery wheel of rare-earth ceramic bonding agent that uses is as follows:
(1) rare earth oxide material is mixed with siliceous, alumina-bearing material and boric acid;
(2) mixed rare earth and siliceous raw material are put into high temperature melting furnace melting 1-3 hour, form liquid rare earth vitrified bond;
(3) poured into by liquid rare earth vitrified bond in the container of inert gas and carry out cooling crystallization, after control flow rate of gas makes bonding agent crystallization, granularity is 300-500 order;
(4) bonding agent is mixed with two or three abrasive material in CBN, SiC, Al2O3;
(5) poured in roller abrasive wheel hot pressing die by the raw material after mixed and sinter, Stress control is at 5-10MPa, and sintering time is 20-40 minute, and sintering temperature controls at 600-800 DEG C;
(6) the burned rear turning of emery wheel is trimmed to qualified size, encapsulation warehouse-in;
Further, described inert gas is the one in nitrogen, argon gas or helium.
Further, hot pressing die material is the one in graphite, heat resisting steel or boron nitride material.
Present invention achieves three high characteristics of the high strength of roller abrasive wheel, high life, high sharpness, and there is environmental friendliness, outstanding advantage that cost performance is excellent.Rare earth bonding agent is smelted into liquid phase by the present invention, and realizes cooling and crystallization by inert gas, and make each species distribution of emery wheel after producing even, stability, intensity are better.
Detailed description of the invention
embodiment 1
Following raw material is used to make rare-earth ceramic bonding agent:
Lanthana 2 parts, yittrium oxide 3 parts, albite 15 parts, quartz sand 45 parts, aluminium powder 5 parts, 13 parts, aluminium oxide, boric acid 17 parts.
Use the method for above-mentioned bonding agent manufacture emery wheel as follows:
After high melt, cooling crystallization, ball milling cross 320 mesh sieves, mix with 46# corundum and Al2O3, bonding agent and abrasive material ratio are 3:7, pour graphite jig into after mixed, and pressurization resistance sintering, pressure is 6MP, and firing temperature is 650 DEG C, and the time is 30 minutes.
embodiment 2
Following raw material is used to make rare-earth ceramic bonding agent:
Lanthana 2 parts, yittrium oxide 3 parts, cerium oxide 3 parts, pyrophillite 15 parts, quartz sand 25 parts, prodan 15 parts, aluminium powder 4 parts, 15 parts, aluminium hydroxide, boric acid 18 parts.
Above-mentioned bonding agent is used to manufacture the method for emery wheel with embodiment 1.Difference be in, abrasive material is SiC and Al2O3.
embodiment 3
Following raw material is used to make rare-earth ceramic bonding agent:
Yittrium oxide 3 parts, cerium oxide 2 parts, receives feldspar 18 parts, prodan 40 parts, aluminium powder 5 parts, 6 parts, aluminium oxide, 7 parts, aluminium hydroxide, boric acid 19 parts.
Above-mentioned bonding agent is used to manufacture the method for emery wheel with embodiment 1.Difference be in, abrasive material is CBN and SiC.
Use the obtained emery wheel of above embodiment to be arranged on roll grinder and carry out grinding test, experimental condition is: emery wheel uses linear velocity to be 60m/s, and the speed of table is 15m/min, and grinding fluid is cooling water.
Grinding result is as table 1:
can find out that grinding wheel performance of the present invention is excellent by table 1 data, super common roller abrasive wheel far away, practical value is large.
embodiment 4
Use and example one same composition bonding agent, pressure changes 8MP and 10MP into respectively, and sintering temperature is respectively 700 DEG C and 750 DEG C, and all the other technological parameters are with embodiment 1.
Grinding result is as table 2:
can find out that rare earth binding agent sand wheel all can well grinding by table 2 data, performance is significantly better than common roller abrasive wheel, can for actual., implement and result from above example, use the rare-earth ceramic bonding agent of the embodiment of the present invention, under 5-10MP pressure, carry out low-temperature sintering, sintering temperature is 600-800 DEG C, and its serviceability is significantly better than plain wheel, and practical value is higher meanwhile.
Although give detailed description and explanation to the specific embodiment of the present invention above; but what should indicate is; we can carry out various equivalence according to conception of the present invention to above-mentioned embodiment and change and amendment; its function produced do not exceed that description contains yet spiritual time, all should within protection scope of the present invention.

Claims (7)

1. a rare-earth ceramic binding agent sand wheel, is characterized in that comprising following heavy part raw material: the rare earth oxide material of 5-15%, 50-60% siliceous material, 15-20% alumina-bearing material and 15-20% boric acid.
2. a kind of rare-earth ceramic bonding agent according to claim 1, is characterized in that described rare earth oxide material is one, two or three in neodymia, yittrium oxide and lanthana.
3. a kind of rare-earth ceramic bonding agent according to claim 1, is characterized in that described siliceous material is the one, two or three in quartz sand, albite, pyrophillite, prodan.
4. a kind of rare-earth ceramic bonding agent according to claim 1, is characterized in that described alumina-bearing material is the one, two or three in aluminium powder, aluminium oxide, aluminium hydroxide, sodium metaaluminate.
5. one kind uses the manufacture method of the emery wheel of rare-earth ceramic bonding agent as follows:
(1) rare earth oxide material is mixed with siliceous, alumina-bearing material and boric acid;
(2) mixed rare earth and siliceous raw material are put into high temperature melting furnace melting 1-3 hour, form liquid rare earth vitrified bond;
(3) poured into by liquid rare earth vitrified bond in the container of inert gas and carry out cooling crystallization, after control flow rate of gas makes bonding agent crystallization, granularity is 300-500 order;
(4) bonding agent is mixed with two or three abrasive material in CBN, SiC, Al2O3;
(5) poured in roller abrasive wheel hot pressing die by the raw material after mixed and sinter, Stress control is at 5-10MPa, and sintering time is 20-40 minute, and sintering temperature controls at 600-800 DEG C;
(6) the burned rear turning of emery wheel is trimmed to qualified size, encapsulation warehouse-in.
6. the manufacture method of a kind of rare-earth ceramic emery wheel according to claim 5, is characterized in that, described inert gas is the one in nitrogen, argon gas or helium.
7. the manufacture method of a kind of rare-earth ceramic emery wheel according to claim 5, is characterized in that, hot pressing die material is the one in graphite, heat resisting steel or boron nitride material.
CN201510581074.3A 2015-09-14 2015-09-14 A kind of manufacture method of the emery wheel of rare-earth ceramic bonding agent and the use bonding agent Active CN105196200B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497515A (en) * 2016-10-25 2017-03-15 河南醒狮供应链管理有限公司 For grinding the carbide superhard material of sapphire wafer
CN107297689A (en) * 2017-07-28 2017-10-27 义乌市台荣超硬制品有限公司 A kind of ceramic bond diamond or CBN tool tyre case powder
CN110117480A (en) * 2019-06-01 2019-08-13 安徽齐鑫新材料科技有限公司 A kind of preparation method of rare earth silicon carbide abrasive
CN114752352A (en) * 2022-04-13 2022-07-15 河南天马新材料股份有限公司 High-self-sharpening aluminum oxide abrasive powder and preparation method thereof
TWI782854B (en) * 2022-01-14 2022-11-01 中國砂輪企業股份有限公司 Non-sintered or low-temperature-sintered grinding wheel and preparation method thereof

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JP2003181764A (en) * 2001-12-19 2003-07-02 Noritake Co Ltd Method for manufacturing porous vitrified grinding stone and pore forming agent
CN101870091A (en) * 2010-06-17 2010-10-27 大连理工大学 Method for preparing ultra-fine diamond grinding wheel of vitrified bond
CN103551971A (en) * 2013-10-28 2014-02-05 博深工具股份有限公司 Ceramic binding agent for ceramic grinding block and preparation method thereof
CN103600308A (en) * 2013-11-26 2014-02-26 常熟市巨力砂轮有限责任公司 Preparation method of composite binding agent diamond grinding wheel
CN103753413A (en) * 2014-01-10 2014-04-30 苏州赛力精密工具有限公司 Peripheral edge grinding wheel for machining PCBN (polycrystalline cubic boron nitride) blades
CN103770028A (en) * 2014-01-10 2014-05-07 当涂县南方红月磨具磨料有限公司 Ceramic zirconium corundum grinding wheel

Patent Citations (6)

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Publication number Priority date Publication date Assignee Title
JP2003181764A (en) * 2001-12-19 2003-07-02 Noritake Co Ltd Method for manufacturing porous vitrified grinding stone and pore forming agent
CN101870091A (en) * 2010-06-17 2010-10-27 大连理工大学 Method for preparing ultra-fine diamond grinding wheel of vitrified bond
CN103551971A (en) * 2013-10-28 2014-02-05 博深工具股份有限公司 Ceramic binding agent for ceramic grinding block and preparation method thereof
CN103600308A (en) * 2013-11-26 2014-02-26 常熟市巨力砂轮有限责任公司 Preparation method of composite binding agent diamond grinding wheel
CN103753413A (en) * 2014-01-10 2014-04-30 苏州赛力精密工具有限公司 Peripheral edge grinding wheel for machining PCBN (polycrystalline cubic boron nitride) blades
CN103770028A (en) * 2014-01-10 2014-05-07 当涂县南方红月磨具磨料有限公司 Ceramic zirconium corundum grinding wheel

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497515A (en) * 2016-10-25 2017-03-15 河南醒狮供应链管理有限公司 For grinding the carbide superhard material of sapphire wafer
CN107297689A (en) * 2017-07-28 2017-10-27 义乌市台荣超硬制品有限公司 A kind of ceramic bond diamond or CBN tool tyre case powder
CN110117480A (en) * 2019-06-01 2019-08-13 安徽齐鑫新材料科技有限公司 A kind of preparation method of rare earth silicon carbide abrasive
TWI782854B (en) * 2022-01-14 2022-11-01 中國砂輪企業股份有限公司 Non-sintered or low-temperature-sintered grinding wheel and preparation method thereof
CN114752352A (en) * 2022-04-13 2022-07-15 河南天马新材料股份有限公司 High-self-sharpening aluminum oxide abrasive powder and preparation method thereof

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Address after: 245200 No.7, Jinghe Road, Shexian Economic Development Zone, Huangshan City, Anhui Province

Patentee after: Huangshan Anka grinding New Material Co.,Ltd.

Address before: 245200 No.7, Jinghe Road, Shexian Economic Development Zone, Huangshan City, Anhui Province

Patentee before: HUANGSHAN ANKA HEAVY DUTY WHEEL Co.,Ltd.

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Denomination of invention: The invention relates to a rare earth ceramic binder and a manufacturing method of a grinding wheel using the binder

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