CN1051927A - Anti-sleeve and the heat-resisting support let out of synthesis gas - Google Patents
Anti-sleeve and the heat-resisting support let out of synthesis gas Download PDFInfo
- Publication number
- CN1051927A CN1051927A CN90108598A CN90108598A CN1051927A CN 1051927 A CN1051927 A CN 1051927A CN 90108598 A CN90108598 A CN 90108598A CN 90108598 A CN90108598 A CN 90108598A CN 1051927 A CN1051927 A CN 1051927A
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- China
- Prior art keywords
- gas
- cylindrical shell
- sleeve
- vertical
- annular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/485—Entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/86—Other features combined with waste-heat boilers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S48/00—Gas: heating and illuminating
- Y10S48/02—Slagging producer
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
The present invention relates to a top partial oxidation gas generator and a bottom radiating gas water cooler, gas takes place flow to the lower gas water cooler by the fire-resistant throat of a vertical tubular downwards from the upper gas producer, the anti-sleeve of letting out of vertical steel tubular gas has the bottom that has flange that centers on the passage setting of fire-resistant throat, makes the unlikely anti-sleeve outside rest district of letting out of gas that leaks into of gas.Fire-resistant throat lets out sleeve and makes vertical support by flanged (FLGD) gas is anti-, and supporting member is connected on the upper gas producer cylindrical shell, lets out sleeve and its lower end is moved freely when the expanded by heating in order to supporting gas is anti-.
Description
The present invention relates to partial oxidation gas generator and gas cooler in general.Or rather, the present invention relates to anti-sleeve and the cylinder stent let out of composite gas, the leaking of thick generation hot gas flow that this support prevents to flow through fire-resistant throat passage downwards, fire-resistant throat passage then connects producer gas generator and gas cooler.
Partial oxidation process is that be familiar with liquid carbon hydrogen fuel (as oil) and solid carbonaceous fuel (as coal and refinery coke) are changed into of a kind of people contains H
2The method of the mixed gas of+CO.Generation gas from producer gas generator is called synthesis gas, reducing gas or inflammable gas according to its actual constituent.This respect can consult 3,544,291,3,607 157,3,998, and 609 and 4,289, No. 502 United States Patent (USP)s.
Partial oxidation reaction is to carry out in being lined with the vertical straight-through steel pressure cylindrical shell of refractory materials, and this can consult United States Patent (USP) 4,525, No. 176.Can cool off in the water in the chilling case the thick generation hot gas flow from producer gas generator, this can consult United States Patent (USP) 4,605, No. 423.This hot gas flow also can be in radiation formula or contraflow cooler by and boiler feed water between indirect heat exchange cool off, this can consult 4,377,132 and 4,462, No. 339 United States Patent (USP)s.Therefore, the objective of the invention is to bound gas producer and syngas cooler provides a kind of composite gas anti-sleeve and the cylinder stent let out, the leaking of thick generation hot gas flow that this support prevents to flow through fire-resistant throat passage downwards, fire-resistant throat passage then connects producer gas generator and gas cooler.
Put it briefly, the present invention is used in combination with a high temperature gas generator and a Vertical Steel pressing pressure cylindrical shell; High temperature gas generator have one be lined with refractory materials, the vertical pressure cylindrical shell, with so that liquid carbon hydrogen fuel or solid carbonaceous fuel partial oxidation and produce and contain H
2The mixed gas of+CO, the following square coaxial line of producer gas generator are connecting a steel vertical pressure cylindrical shell.Below the pressure cylindrical shell in establish a gas cooler and waste heat boiler, in order to by the indirect heat exchange cooling carried out with boiler feed water thick generation hot gas flow from producer gas generator.The present invention includes in order to the transom that connects above-mentioned two cylindrical shells, one and prevent letting out sleeve around fire-resistant Hou Bu And with the vertical long tubular steel gas of its coaxial line the fire-resistant throat of vertical long tubular of the first and second cylindrical shell Zhi Jian And and its coaxial line and one.Gas is anti-let out sleeve have in its lower end one with the annular flange of its coaxial line, its part that extends internally is in order to support fire-resistant throat lower end.In addition, also have the anti-sleeve of letting out of gas is connected coupling device and tightness system first cylindrical shell under, make that gas is anti-lets out annular quiescent centre of formation between peripheral and two cylinder inboard walls of telescopic.According to the present invention, gas is anti-let out sleeve allow in various degree axially and (or) radial growth.But the thick generation gas of the fire-resistant throat that flows through in fact but can not leak into annular quiescent centre.
To be further described above-mentioned purpose of the present invention, other purposes and advantage in conjunction with following preferred embodiment and accompanying drawing thereof.
Description of drawings is as follows.
Fig. 1 is the diagrammatic sectional view of producer gas generator, and this illustrates the producer gas generator that is coaxially set with gas cooler, also shows the anti-support of letting out sleeve and fire-resistant throat passage of structure, gas that the present invention connects throat.
Fig. 2 is " A " portion profile among Fig. 1, and this illustrates laryngeal structure of the present invention, the anti-support of letting out sleeve and heat-resisting throat passage of gas.
Fig. 1 shows the long cylindrical shell 1 of the first vertical high temperature steel pressing pressure briefly, this cylindrical shell has a lower end 2 and a upper end 4 of inwardly shrinking, lower end 2 has an outlet at bottom passage 3 along this cylindrical shell central longitudinal axis, upper end 4 has a coaxial line access road 5, in order to the gasification nozzle (not shown) of a common downward venting of plug-in mounting.Cylindrical shell 1 is the shell of the refractory materials 6 in partial oxidation gas generator internal reaction district 7, and this producer gas generator is in order to produce synthesis gas, reducing gas or inflammable gas.The lower flange 15 of cylindrical shell 1 is connected with the upper flange 16 of the long cylindrical shell 8 of the second vertical high temperature steel pressing pressure.Cylindrical shell 8 is shells of a gas cooler and waste heat boiler.By plain bolt and (or) clamper one class transom (not shown) is connected to each other the upper flange 16 of the lower flange 15 of first cylindrical shell and second cylindrical shell and makes this two cylindrical shell have common central longitudinal axis.The fire-resistant throat 17 of vertical long tubular is coaxially set with it between first and second cylindrical shells, makes thick generation hot gas flow be able to advance the interior radiation formula gas cooler of cylindrical shell 8 from reaction zone 7 downward Channel Group.Together the anti-sleeve 18 of letting out of axis normal steel gas is provided with around the periphery 19 of fire-resistant throat 17, and this has been made more clearly diagram in " A " portion enlarged view.
Fig. 2 is the enlarged view of " A " portion among Fig. 1.Vertical pressure cylindrical shell 1 has the central lower exit passageway 3 in partial oxidation reaction district, and flange 15 and 16 is clamped together can make cylindrical shell 1 link together with the vertical cylindrical outer casing 8 of gas cooler and waste heat boiler 9.Can consult United States Patent (USP) 4,377, No. 132 about this medium-sized gas cooler and waste heat boiler 9.In gas cooler 9, be provided with the fire-resistant access road 14 of coaxial line, and with the steam drum 11 of annular water wall 12 and other gas cooling pipe coupling.Boiler feed water is introduced the width of cloth penetrate in the water wall tube of boiler, in water wall tube, produce steam, thereby heat is taken away from the thermal synthesis gas of inflow gas water cooler by evaporation of water.Solidified slag body can be drained it in the bottom that the width of cloth is penetrated boiler in the air-flow.Water wall can be made of the parallel water pipe of band fin also can connect to parallel water pipe vertical cylindrical surface (consulting the label 15 and 23 in the United States Patent (USP) accompanying drawing 4,377, No. 132) and two planar annular surface 12, thereby constitutes water wall.The fire-resistant throat 17 of vertical coaxial line extends to the top 13 that the width of cloth is penetrated water cooler 9 fire-resistant access roades 14 by the lower end of the outlet at bottom passage 3 that is lined with refractory materials.
The gas of metal is anti-lets out sleeve 18 has a coaxial line in its lower end planar annular flange 20, and flange has radially inner part 21 and radially outer part 22.The bottom of the inside fire-resistant throat 17 of part 21 supports vertical tubulars.
The gas of metal prevents that letting out sleeve 18 gives vertical support by a supporting device.The upper end of supporting device is fixed on the cylindrical shell 1, and its lower end then can move freely when expanded by heating.In a preferred embodiment of supporting device, the vertical edges of trilateral gusset plate 26 is welded on the medial surface of cylindrical shell 1, extend and make its other side make radial level.Can adopt the gusset plate 26 of 4 apart 90 ° of settings.One vertical annular concentric part 27 is stood on the below of gusset plate 26, be fixed on the outward extending part 22 of annular flange 20.Have that end-fitting 29 is connected gusset plate 26 with 4 vertical suspension rods 28 of 30 with annular element 27 and removable.Vertical concentric annular element 23 is positioned at the radially outer slightly part of annular element 27 and is fixed on by appropriate means (for example welding) also annular element 23 to be fixed on the certain position of annular water wall 12 and keeps its position on the annulus 31.Annulus 31 horizontal positioned, its periphery is weldingly fixed on the inwall of cylindrical shell 8.
Lower gas elastic sealing device 35 is that the relative both sides with concentric resilient U-shaped metal sheet annular element 36 are fixed on the outer surface of upwardly extending annular concentric part 27 and on the inner surface of upwardly extending annular concentric part 23 and constitute.Upper gas elastic sealing device 37 is that the relative both sides with concentric resilient U-shaped metal sheet annular element 38 are fixed on the anti-sleeve 18 of letting out of gas near constituting on the outer surfaces of upper end with on the inner surface of the vertical annular concentric part 39 that suspends.Annular element 39 is positioned at the anti-radially outer slightly part of letting out sleeve 18 of the vertically extending gas that makes progress and is welded on the outside surface of producer gas generator 1 bottom serrated end 40.Flow through fire-resistant throat 17 thick generation gas in fact not can by bottom elastic sealing device 35 and (or) top elastic sealing device 37 flows in the tubular quiescent centre 41.This quiescent centre is positioned at that gas anti-is let out beyond sleeve 18 peripheries, producer gas generator 1 is near week of its lower end and cylindrical shell 8 in the week near its upper end.Gap 42 and the gap 43 between annular flange 20 peripheries and vertically extending coaxial annular spare 23 between the lower surface of anti-upper end of letting out sleeve 18 of gas and bottom serrated end 40 have sizable width, be enough to make tubular gas barrier spare be generally can do axially under 1700-2800 the high temperature and (or) radial extent.
In another embodiment, the anti-mechanism of letting out sleeve 18 of supporting metal gas is that upper end with suspension rod 28 extends upward and is fixed on the interior lower end 2 of (for example by welding) producer gas generator 1 and constitutes.So just saved gusset plate 26.Other characteristics of this supporting device second embodiment are identical with above-mentioned supporting device substantially.But, the board-like supporting device of above-mentioned connection is comparatively reasonable, because this can reduce to act on the total load of producer gas generator bottom serrated end 40.
Prevent that by producer gas generator supporting gas it is favourable letting out sleeve 18.So just can build the refractory materials (comprising throat) of whole producer gas generator again by laying bricks or stones, and can before producer gas generator is loaded onto gas cooler, partly carry out preheating.Therefore, can shorten the stoppage time of entire equipment.
Although more than a kind of feasible specific embodiment of the present invention has been done sufficient explanation, also just for the ease of the present invention is made an explanation, the present invention never should be so limited for this.
Claims (9)
1, a kind of producer gas generator, it has:
The vertical long cylindrical shell of the first high temperature steel pressing pressure (1), this cylindrical shell has along its central longitudinal center line: the upper entrance passage (5) in order to plug-in mounting one downward nozzle of exitting of an outlet at bottom passage (3) and a coaxial line.This first cylindrical shell is one in order to produce synthesis gas, reducing gas or inflammable gas and to be lined with the housing in the partial oxidation gas generator internal reaction district (7) of refractory materials;
The vertical long cylindrical shell of the second high temperature steel pressing pressure (8), this cylindrical shell are in order to the housing of cooling from the gas cooler (9) of the thick generation hot gas stream of reaction zone (7);
In order to the upper end of the lower end that connects first cylindrical shell (1) and second cylindrical shell (8) and make it make vertical coaxillay aligned web member (15,16) along this cylindrical shell central longitudinal axis respectively; One with first and second cylindrical shells (1,8) coaxial line, between this two cylindrical shell and make thick generation hot gas stream flow to the fire-resistant throat of vertical long tubular (17) of gas cooler (9) from reaction zone (7) unobstructedly;
It is characterized in that: this producer has:
The anti-sleeve (18) of letting out of vertical coaxial line metal gas along its length around fire-resistant throat (17) periphery setting, this sleeve has an annular lower flange (20), this flange has the part of extending internally and the part (21,22) that stretches out, the support of the part that extends internally as the fire-resistant throat of supporting (17);
In order to the anti-sleeve (18) of letting out of gas is connected connection mechanism (26-30) on first cylindrical shell (1).
Be positioned at the anti-radially upper and lower elasticity connection tightness system (35,37) between the tubular quiescent centre, outside (41) of sleeve (18) and its of letting out of gas; The thick generation gas stream of fire-resistant throat (17) of flowing through can not leak in the tubular quiescent centre (41) substantially.
2, by the described producer gas generator of claim 1, it is characterized in that: this producer gas generator has Flexible Connector (35,37), in order to the anti-telescopic top and bottom of letting out of sealed gas.
3,, it is characterized in that by the described producer gas generator of claim 2: this producer gas generator gas anti-let out sleeve (18) and and first, second two pressure cylindrical shell (1,8) adjacent members between have gap (42,43) so as the anti-upper and lower ends of letting out sleeve (18) of gas to be done axially and (or) radial growth.
4, by the described producer gas generator of arbitrary requirement among the claim 1-3, it is characterized in that: gas is anti-to be let out sleeve (18) and makes vertical support by supporting device (26-30), the lower end that this supporting device has the upper end that is fixed on first cylindrical shell (1) and need move freely because of expanded by heating.
5, by the described producer gas generator of claim 4, it is characterized in that: supporting device has some gusset plates (26) on cylindrical shell (1) internal surface, of being welded in and goes up vertical annular concentric part (27) and one and it is connected to each other and knock-down vertical suspension rod (28) between each gusset plate and each vertical annular element being fixed on plain-straight-face flange (20) part (22) that stretches out under the gusset plate (26).
6, by the described producer gas generator of claim 4, it is characterized in that: supporting device has one and is fixed on plain-straight-face flange (20) vertical annular concentric part (27) and the some vertical suspension rod (28) of part on (22) that stretch out, the lower end of this suspension rod is connected with vertical annular element (27) and is removable, and its upper end is fixed on the interior lower end (2) of first cylindrical shell (1) contraction.
7, by the described producer gas generator of arbitrary requirement among the claim 1-6, it is characterized in that: bottom elasticity connects air seal set to be had one and is fixed on stretch out the vertically disposed first annular concentric part (27) on the part (22) of plain-straight-face flange (20), one has some water cooling tubes welded together (9) and has bubble-tight horizontal annular water wall (12), one first annular element (27) radially slightly outside the place be provided with and be fixed on the vertically disposed second annular concentric part (23) and a U-shaped elastic metallic thin plate annular concentric part (35) on the annular water wall (12), the relative both sides of this annular element (36) are separately fixed on the outer surface of first annular element (27) on the inner surface with second annular element (23).
8, by the described producer gas generator of arbitrary requirement among the claim 1-6, it is characterized in that: bottom elasticity connects sealing gland mechanism to be had one and is fixed on stretch out vertically disposed concentric first annular element (27) on the part (22) of plain-straight-face flange (20), periphery is fixed on the tabular annulus (31) on the gas cooler inwall, one to first annular element (27) radially slightly outside the place be provided with and be fixed on the vertically disposed second annular concentric part (23) and a U-shaped elastic metallic thin plate annular concentric part (35) on the tabular annulus (31), the relative both sides of this annular element (36) are separately fixed on the outer surface of first annular element (27) on the inner surface with second annular element (23).
9, by the described producer gas generator of arbitrary requirement among the claim 1-8, it is characterized in that: top elasticity connects sealing gland mechanism to be had one and is provided with and is welded in the first pressure cylindrical shell (1) and shrinks concentric first annular element (39) that vertically suspends and a U-shaped elastic metallic thin plate annular concentric part (38) on the outer surface of lower end (2) at the anti-radially outer slightly place of sleeve (18) of letting out of gas, and the relative both sides of this annular element (38) are separately fixed on the anti-inner surface of letting out on the close outer surface of upper end of sleeve (18) with first annular element (39) of vertical tubular gas.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US440,836 | 1989-11-24 | ||
US07/440,836 US4948387A (en) | 1989-11-24 | 1989-11-24 | Synthesis gas barrier and refractory support |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1051927A true CN1051927A (en) | 1991-06-05 |
CN1025866C CN1025866C (en) | 1994-09-07 |
Family
ID=23750376
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN90108598A Expired - Lifetime CN1025866C (en) | 1989-11-24 | 1990-10-23 | Synthesis gas barrier and refractory support |
Country Status (5)
Country | Link |
---|---|
US (1) | US4948387A (en) |
EP (1) | EP0435424B1 (en) |
JP (1) | JP2967495B2 (en) |
CN (1) | CN1025866C (en) |
DE (1) | DE69004549T2 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5464592A (en) * | 1993-11-22 | 1995-11-07 | Texaco Inc. | Gasifier throat |
US5851497A (en) * | 1994-11-18 | 1998-12-22 | Texaco Inc. | Gasifier throat |
DE19533912C2 (en) * | 1995-09-13 | 1998-09-24 | Gutehoffnungshuette Man | Refractory lining for a synthesis gas plant |
US20040006917A1 (en) * | 2002-07-09 | 2004-01-15 | Wakefield David W. | Clean fuel gas made by the gasification of coal |
US7547423B2 (en) | 2005-03-16 | 2009-06-16 | Pratt & Whitney Rocketdyne | Compact high efficiency gasifier |
US8603202B2 (en) | 2005-09-05 | 2013-12-10 | Stichting Energieonderzoek Centrum Nederland | Device for producing a product gas from biomass |
US7451591B2 (en) * | 2006-05-08 | 2008-11-18 | Econo-Power International Corporation | Production enhancements on integrated gasification combined cycle power plants |
NL2000520C2 (en) | 2007-03-05 | 2008-09-08 | Stichting Energie | Device for manufacturing a product gas from a fuel, such as biomass. |
US20100031570A1 (en) * | 2008-08-07 | 2010-02-11 | Wei Chen | Method and system for an integrated gasifier and syngas cooler |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1512677A (en) * | 1975-11-27 | 1978-06-01 | British Gas Corp | Quench chambers in coal gasification plant |
DE2951153C2 (en) * | 1979-12-19 | 1981-11-12 | M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 4200 Oberhausen | Device for cleaning and synthesis gas produced by coal gasification |
DE3009851C2 (en) * | 1980-03-14 | 1983-09-15 | Karrena GmbH, 4000 Düsseldorf | Reactor containers, in particular for gasifying fossil fuels |
US4377132A (en) * | 1981-02-12 | 1983-03-22 | Texaco Development Corp. | Synthesis gas cooler and waste heat boiler |
US4605423A (en) * | 1982-04-12 | 1986-08-12 | Texaco Development Corporation | Apparatus for generating and cooling synthesis gas |
US4525176A (en) * | 1983-08-29 | 1985-06-25 | Texaco Inc. | Preheating and deslagging a gasifier |
US4462339A (en) * | 1983-08-29 | 1984-07-31 | Texaco Development Corporation | Gas cooler for production of saturated or superheated steam, or both |
CH670501A5 (en) * | 1986-07-02 | 1989-06-15 | Sulzer Ag | |
DE3623604A1 (en) * | 1986-07-12 | 1988-01-14 | Krupp Koppers Gmbh | DEVICE FOR THE GASIFICATION OF FINE-DIVISION, IN PARTICULAR SOLID FUELS UNDER INCREASED PRESSURE |
-
1989
- 1989-11-24 US US07/440,836 patent/US4948387A/en not_active Expired - Lifetime
-
1990
- 1990-09-07 DE DE90309852T patent/DE69004549T2/en not_active Expired - Lifetime
- 1990-09-07 EP EP90309852A patent/EP0435424B1/en not_active Expired - Lifetime
- 1990-10-23 CN CN90108598A patent/CN1025866C/en not_active Expired - Lifetime
- 1990-10-26 JP JP2287371A patent/JP2967495B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US4948387A (en) | 1990-08-14 |
DE69004549D1 (en) | 1993-12-16 |
JPH03172390A (en) | 1991-07-25 |
JP2967495B2 (en) | 1999-10-25 |
EP0435424B1 (en) | 1993-11-10 |
CN1025866C (en) | 1994-09-07 |
DE69004549T2 (en) | 1994-03-10 |
EP0435424A1 (en) | 1991-07-03 |
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C15 | Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993) | ||
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Expiration termination date: 20101023 Granted publication date: 19940907 |