CN105191915A - Benzene-series solvent substitute sulfonated kerosene and application of sulfonated kerosene in beta-cypermethrin emulsifiable concentrate - Google Patents
Benzene-series solvent substitute sulfonated kerosene and application of sulfonated kerosene in beta-cypermethrin emulsifiable concentrate Download PDFInfo
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- CN105191915A CN105191915A CN201510379571.5A CN201510379571A CN105191915A CN 105191915 A CN105191915 A CN 105191915A CN 201510379571 A CN201510379571 A CN 201510379571A CN 105191915 A CN105191915 A CN 105191915A
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- sulfonated kerosene
- benzene
- beta
- emulsifiable concentrate
- cypermethrin
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Abstract
The invention relates to the field of pesticide preparations, and discloses a benzene-series solvent substitute sulfonated kerosene and application of sulfonated kerosene in beta-cypermethrin emulsifiable concentrate. According to the invention, sulfonated kerosene in the formula can well substitute benzene-series solvents common in beta-cypermethrin emulsifiable concentrate, and the obtained emulsifiable concentrate has better stability and dispersity; use amount of benzene, methylbenzene and xylene in pesticide emulsifiable concentrate can be reduced, poison to the human body and pollution to the environment caused by benzene-series solvents can be reduced, and besides, the production cost of the emulsifiable concentrate is reduced.
Description
Technical field
The present invention relates to field of pesticide preparation, relate to a kind of benzene-series solvent replacements sulfonated kerosene and the application in r thereof specifically.
Background technology
Missible oil refers to and is dissolved in organic solvent by a certain percentage by former medicine (crude oil or former powder), then adds a certain amount of agricultural chemicals emulsifier special and other auxiliary agents, the oily liquids of formulated a kind of homogeneous phase transparent.After the large water gaging dilution of general use, stable emulsion can be become.Emulsifier in missible oil uses the mixture of nonionic and anion surfactant mostly, and solvent adopts benzene,toluene,xylene or mixed benzene etc. mostly, also uses the alcohols solvents such as hexone class and isopropyl alcohol in addition.
Missible oil is the main formulations of pesticide of current China, and solvent is important component indispensable in such formulation, wherein based on benzene-series solvent (benzene,toluene,xylene or mixed benzene class).The benzene-series solvent used in missible oil is inflammable and explosive, and poisonous, and these organic solvents easily to environment, and also exist potential hidden danger to the producer and the healthy of user.Therefore, the use of benzene-series solvent is more and more restricted.
Because sulfonated kerosene has, toxicity is little, Environmental compatibility good, resource is sufficient, low cost and other advantages, meets the requirement of pesticide in future formulation development to solvent, therefore can substitute benzene-series solvent in traditional pesticidal preparations.
Summary of the invention
The invention provides a kind of sulfonated kerosene and replace the emulsifiable concentrate formulation of benzene-series solvent and the application in r thereof, the missible oil obtained has good stability and dispersiveness, thus provide a kind of replacement solvent, reduce missible oil cost, and decrease the harm that benzene-series solvent causes environment and human health.
Emulsifiable concentrate formulation of the present invention is after being dissolved by former for beta-cypermethrin medicinal alternative solvent sulfonated kerosene, then adds appropriate emulsifier and mix, thus obtains a kind of stability and the good missible oil of dispersiveness.
In certain embodiments as preferred, the percentage by weight that alternative solvent sulfonated kerosene of the present invention accounts for described emulsifiable concentrate formulation is 75% ~ 89.5%, the percentage by weight that emulsifier accounts for described emulsifiable concentrate formulation is 8% ~ 20%, and the percentage by weight that the former medicine of beta-cypermethrin accounts for described emulsifiable concentrate formulation is 2.5% ~ 5%.
Preferably, emulsifier of the present invention be farm chemical emulgent monomer 500#, 1601,1602, OP-7,600,600-1,600-2,600-3, BY-110, BY-112, BY-120, BY-130, BY-140,400,403, one or more in emulsification agent, be preferably emulsifier 500#, 1601, OP-7, emulsification agent mixture, being more preferably the percentage by weight that emulsifier mixture accounts for described emulsifiable concentrate formulation is 12%.
Preferably, emulsification agent of the present invention is polyoxyethylene alkylphenol ether compound, it is nonionic, thick pale yellow shape liquid, pH is 6 ~ 7, the distilled water solution oil drop of 1% 60 ~ 80 DEG C, soluble in water, all very stable in acid, alkali, oxidant, there is the functions such as emulsification, purification, de-oiling, decontamination, to animals and plants and mineral greasy dirt cleansing power very strong, mainly as dye leveller and refining agent in printing and dyeing industry, one of component making finish in synthetic fibers, except display emulsifiability, also has antistatic effect.
Preferably, the percentage by weight that alternative solvent sulfonated kerosene of the present invention accounts for described emulsifiable concentrate formulation is 83.5%.
Result of the test shows, the organic solvent of patent of the present invention substitutes solvent sulfonated kerosene, the former medicine of beta-cypermethrin can be dissolved well, and with the missible oil obtained after emulsifier mixing has good stability and dispersiveness, thus decrease the usage amount of benzene-series solvent in missible oil, and reduce the pollution level of benzene-series solvent to environment.
The object of the present invention is to provide the emulsifiable concentrate formulation of organic solvent in a kind of alternative r, mixed by above-mentioned alternative solvent sulfonated kerosene, emulsifier and the former medicine of beta-cypermethrin.
The invention has the beneficial effects as follows: the alternative solvent sulfonated kerosene of patent of the present invention, the former medicine of beta-cypermethrin can be dissolved well, and with the missible oil obtained after emulsifier mixing has good stability and dispersiveness, thus decrease the usage amount of benzene-series solvent in missible oil, and the pollution of the murder by poisoning reduced people and environment.
Embodiment
The embodiment of the invention discloses a kind of sulfonated kerosene and replace the emulsifiable concentrate formulation of benzene-series solvent and the application in r thereof.Those skilled in the art can use for reference present disclosure, and suitable improving technique parameter realizes.Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the art, they are all deemed to be included within category of the present invention.Product of the present invention is described by preferred embodiment, related personnel obviously can not depart from content of the present invention, spirit and scope product as herein described is changed or suitably change with combination, realize and apply the technology of the present invention.
In order to understand the present invention further, be described in detail below in conjunction with the application of embodiment to a kind of alternative solvent sulfonated kerosene provided by the invention.
The using method of alternative solvent sulfonated kerosene of the present invention is, after first being dissolved with appropriate sulfonated kerosene by former for beta-cypermethrin medicine, then adds appropriate emulsifier mixing, finally with sulfonated kerosene polishing.The missible oil that the method obtains has good stability and dispersiveness, can reduce the usage amount of benzene-series solvent in missible oil, the harm that reduction environmental pollution and health cause.
embodiment 1the application of sulfonated kerosene in 2.5% r
First take by weight percentage: the former medicine 2.5% of beta-cypermethrin, emulsifier 8%, surplus is sulfonated kerosene.
The preparation method of this missible oil: first take each raw material by above-mentioned percentage by weight, then after former for beta-cypermethrin medicinal a small amount of sulfonated kerosene being dissolved, add emulsifier to mix, finally use sulfonated kerosene polishing to 100%, be i.e. obtained missible oil of the present invention.
embodiment 2the application of control solvent dimethylbenzene in 2.5% r
First take by weight percentage: the former medicine 2.5% of beta-cypermethrin, emulsifier 8%, surplus is dimethylbenzene.
The preparation method of this missible oil: first take each raw material by above-mentioned percentage by weight, then by after former for beta-cypermethrin medicinal a small amount of xylene soluble, adds emulsifier and mixes, finally use dimethylbenzene polishing to 100%, i.e. obtained missible oil of the present invention.
embodiment 3the application of sulfonated kerosene in 4.5% r
First take by weight percentage: the former medicine 4.5% of beta-cypermethrin, emulsifier 12%, surplus is sulfonated kerosene.
The preparation method of this missible oil: first take each raw material by above-mentioned percentage by weight, then after former for beta-cypermethrin medicinal a small amount of sulfonated kerosene being dissolved, add emulsifier to mix, finally use sulfonated kerosene polishing to 100%, be i.e. obtained missible oil of the present invention.
embodiment 4the application of control solvent toluene in 4.5% r
First take by weight percentage: the former medicine 4.5% of beta-cypermethrin, emulsifier 12%, surplus is dimethylbenzene.
The preparation method of this missible oil: first take each raw material by above-mentioned percentage by weight, then by after former for beta-cypermethrin medicinal a small amount of xylene soluble, adds emulsifier and mixes, finally use dimethylbenzene polishing to 100%, i.e. obtained missible oil of the present invention.
embodiment 5the application of sulfonated kerosene in 5% r
First take by weight percentage: the former medicine 5% of beta-cypermethrin, emulsifier 20%, surplus is sulfonated kerosene.
The preparation method of this missible oil: first take each raw material by above-mentioned percentage by weight, then after former for beta-cypermethrin medicinal a small amount of sulfonated kerosene being dissolved, add emulsifier to mix, finally use sulfonated kerosene polishing to 100%, be i.e. obtained missible oil of the present invention.
embodiment 6the application of control solvent dimethylbenzene in 5% r
First take by weight percentage: the former medicine 5% of beta-cypermethrin, emulsifier 20%, surplus is toluene.
The preparation method of this missible oil: first take each raw material by above-mentioned percentage by weight, then by after former for beta-cypermethrin medicinal a small amount of xylene soluble, adds emulsifier and mixes, finally use dimethylbenzene polishing to 100%, i.e. obtained missible oil of the present invention.
The qualification of the missible oil obtained being carried out every quality control index detects.Measure its emulsifying dispersivity, dilution stability, thermodynamic stability, cold storage stability and flash-point respectively.
table 1the quality control index testing result of prepared missible oil
The explanation of above embodiment just understands product of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
Claims (3)
1. substitute a formula for benzene-series solvent in r with sulfonated kerosene, it is characterized in that, this missible oil is made up of the former medicine of beta-cypermethrin, emulsifier and sulfonated kerosene.
2. emulsifiable concentrate formulation according to claim 1, it is characterized in that, the percentage by weight that the former medicine of described beta-cypermethrin accounts for missible oil is 2.5% ~ 5%, and the percentage by weight that emulsifier accounts for missible oil is 8% ~ 20%, and the percentage by weight that sulfonated kerosene accounts for missible oil is 75% ~ 89.5%.
3. emulsifiable concentrate formulation according to claim 1, its preparation method is be dissolved according to a certain percentage in a small amount of sulfonated kerosene by former for beta-cypermethrin medicine, then mixes with emulsifier, finally with sulfonated kerosene polishing to 100% and get final product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510379571.5A CN105191915B (en) | 2015-07-02 | 2015-07-02 | A kind of benzene-series solvent replacements sulfonated kerosene and its application in Beta-cypermethrin EC |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510379571.5A CN105191915B (en) | 2015-07-02 | 2015-07-02 | A kind of benzene-series solvent replacements sulfonated kerosene and its application in Beta-cypermethrin EC |
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| CN105191915A true CN105191915A (en) | 2015-12-30 |
| CN105191915B CN105191915B (en) | 2018-08-14 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078855A (en) * | 1992-05-22 | 1993-12-01 | 铁汉 | Environment friendly agricultural |
| EP0648414A2 (en) * | 1993-10-01 | 1995-04-19 | Rohm And Haas Company | Fully water-dilutable microemulsions |
| CN1267451A (en) * | 1999-03-23 | 2000-09-27 | 王玉万 | Mineral oil-containing pesticide for protecting plant |
-
2015
- 2015-07-02 CN CN201510379571.5A patent/CN105191915B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078855A (en) * | 1992-05-22 | 1993-12-01 | 铁汉 | Environment friendly agricultural |
| EP0648414A2 (en) * | 1993-10-01 | 1995-04-19 | Rohm And Haas Company | Fully water-dilutable microemulsions |
| CN1267451A (en) * | 1999-03-23 | 2000-09-27 | 王玉万 | Mineral oil-containing pesticide for protecting plant |
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| CN105191915B (en) | 2018-08-14 |
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Address after: 061000 Cangdong Economic Development Zone, Cangxian, Cangzhou, Hebei Applicant after: Hebei Tian hair Biological Technology Co.,Ltd. Applicant after: Zhang Jinlin Applicant after: Zhao Bin Address before: 061000 Cangdong Economic Development Zone, Cangxian, Cangzhou, Hebei Applicant before: HEBEI TIANFA CHEMICAL TECHNOLOGY CO.,LTD. Applicant before: Zhang Jinlin Applicant before: Zhao Bin |
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Application publication date: 20151230 Assignee: HEBEI GANGEN BIOTECHNOLOGY CO.,LTD. Assignor: Hebei Tian hair Biological Technology Co.,Ltd. Contract record no.: X2023980039674 Denomination of invention: A Benzene Series Solvent Substitute Sulfonated Kerosene and Its Application in High Efficiency Cypermethrin Emulsion Granted publication date: 20180814 License type: Common License Record date: 20230814 |
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