CN105185451A - Marine anti-aging and corrosion resistant cable - Google Patents
Marine anti-aging and corrosion resistant cable Download PDFInfo
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- CN105185451A CN105185451A CN201510607808.0A CN201510607808A CN105185451A CN 105185451 A CN105185451 A CN 105185451A CN 201510607808 A CN201510607808 A CN 201510607808A CN 105185451 A CN105185451 A CN 105185451A
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Abstract
A marine anti-aging and corrosion resistant cable disclosed by the present invention comprises a wire core, and the wire core comprises two insulating conducting wires. Each insulating conducting wire comprises a conductor and an insulating layer wrapping on the outside of the conductor, and a sheath layer wraps on the outside of the wire core, wherein the sheath layer is prepared by a modified nitrile rubber, and the raw materials of the modified nitrile rubber comprise the nitrile rubber, a chloroprene rubber, a ethylene propylene terpolymer, a fluorinated silicone rubber, a vulcanizing agent PDM, a vulcanizing agent HTDM, a vulcanization accelerator M, a vulcanization accelerator D, an antiager AW, an antiager RD, an antiager BLE, a tall oil, a pine tar, a white oil, carbon black, mica powder, zeolite powder, a composite ceramic glass microsphere, an adhesive A and sodium carboxymethylcellulose. The marine anti-aging and corrosion resistant cable of the present invention has the very excellent aging resistance, corrosion resistance and mechanical property.
Description
Technical field
The present invention relates to mining cable technical field, particularly relate to a kind of anti-aging corrosion proof cable peculiar to vessel.
Background technology
Well-known no matter from mechanicalness, heat-resisting, corrosion-resistant and disaster prevention angle consideration, the elastomeric material that boats and ships use plays vital effect in maintenance boats and ships normally operation, in embody rule process, elastomeric material must can resist weather conditions that are aging, corrosion, still can temporarily ensure that it normally runs by under strong external force collision simultaneously.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of anti-aging corrosion proof cable peculiar to vessel, anti-aging, corrosion-resistant and mechanical property is very excellent.
The one anti-aging corrosion proof cable peculiar to vessel that the present invention proposes, comprise core, core comprises two insulated conductors, and insulated conductor comprises conductor and is coated on the insulating barrier composition outside conductor, be coated with restrictive coating at core, wherein restrictive coating adopts modified butadiene acrylonitrile rubber preparation.
Preferably, the raw material of modified butadiene acrylonitrile rubber comprises by weight: acrylonitrile-butadiene rubber 20-40 part, neoprene 30-40 part, ethylene propylene diene rubber 5-15 part, fluorosioloxane rubber 5-10 part, vulcanizing agent PDM0.5-1.5 part, vulcanizing agent HTDM1-2 part, accelerator M 0.5-0.8 part, accelerator D 0.5-1.2 part, antioxidant A W1-2 part, anti-aging agent RD 1-4 part, antioxidant BLE 1-2 part, tall oil 1-2 part, pine tar 1-2 part, white oil 1-2 part, carbon black 40-60 part, mica powder 15-30 part, zeolite powder 5-15 part, composite ceramics glass microsphere 30-40 part, adhesive A 5-8 part, sodium carboxymethylcellulose 1-5 part.
Preferably, composite ceramics glass microsphere adopts following technique to prepare: glass microsphere, ceramic particle are put into sodium carbonate liquor and stirred, and filters, and washing is to neutral, send in hydrochloric acid and stir, filter, washing, to neutral, is dried, send in Muffle furnace and calcine, cooling, obtains preliminary treatment material; Hydroxyl endblocked polydimethylsiloxane ethanol is diluted, adds dimethyl silicone polymer, beta-schardinger dextrin-, preliminary treatment material, trifluoroacetic acid stirring, filter, dry, obtain composite ceramics glass microsphere.
Preferably, composite ceramics glass microsphere adopts following technique to prepare: take 20-40 part glass microsphere by weight, to put into 50-70 part concentration be that the sodium carbonate liquor of 0.2-0.5mol/L stirs 20-40min to 10-25 part ceramic particle, whipping temp is 40-50 DEG C, filter, washing is to neutral, send into the hydrochloric acid stirring 15-30min that 60-70 part concentration is 1-2mol/L, whipping temp is 30-37 DEG C, filters, and washing is to neutral, dry, send in Muffle furnace and calcine, calcination time is 2-3h, and calcining heat is 500-550 DEG C, cooling, obtains preliminary treatment material; By weight 15-30 part hydroxyl endblocked polydimethylsiloxane 50-60 part ethanol is diluted, add 1-3 part dimethyl silicone polymer, 10-15 part beta-schardinger dextrin-, 40-80 part preliminary treatment material, 0.5-3 part trifluoroacetic acid stirring 40-60min, whipping temp is 70-90 DEG C, filter, dry, obtain composite ceramics glass microsphere.
Preferably, the weight ratio of acrylonitrile-butadiene rubber, neoprene, ethylene propylene diene rubber and fluorosioloxane rubber is 30-34:32-35:10-12:6-8.
Preferably, the weight ratio of vulcanizing agent PDM, vulcanizing agent HTDM, accelerator M and accelerator D is 1-1.2:1.4-1.8:0.6-0.64:0.8-1.
Preferably, the weight ratio of carbon black, mica powder, zeolite powder and composite ceramics glass microsphere is 50-54:20-25:8-12:34-37.
Preferably, the raw material of modified butadiene acrylonitrile rubber comprises by weight: acrylonitrile-butadiene rubber 30-34 part, neoprene 32-35 part, ethylene propylene diene rubber 10-12 part, fluorosioloxane rubber 6-8 part, vulcanizing agent PDM1-1.2 part, vulcanizing agent HTDM1.4-1.8 part, accelerator M 0.6-0.64 part, accelerator D 0.8-1 part, antioxidant A W1.4-1.6 part, anti-aging agent RD 2-3.4 part, antioxidant BLE 1.2-1.5 part, tall oil 1.6-1.9 part, pine tar 1.5-1.7 part, white oil 1.4-1.6 part, carbon black 50-54 part, mica powder 20-25 part, zeolite powder 8-12 part, composite ceramics glass microsphere 34-37 part, adhesive A 6-7 part, sodium carboxymethylcellulose 2-4 part.
In the present invention, above-mentioned modified butadiene acrylonitrile rubber adopts preparation technology's preparation of ordinary rubber, and namely raw material prepare → plasticate → mixing → shaping → sulfuration → rest and reorganization → inspection.
The present invention adopts acrylonitrile-butadiene rubber, neoprene, ethylene propylene diene rubber and fluorosioloxane rubber as major ingredient, and adopt vulcanizing agent PDM, vulcanizing agent HTDM, accelerator M, accelerator D, as vulcanizing system, ensures the anti-aging of goods, decay resistance, and mechanical property is very excellent, tall oil, pine tar and white oil and said components act synergistically, and Article Stiffness Determination and toughness are all higher, by adding appropriate carbon black, mica powder, zeolite powder and composite ceramics glass microsphere are collaborative as filling reinforcing material, can strengthen the anti-aging and mechanical property of goods further, be suitable at ship environment, and in composite ceramics glass microsphere, by certain way at glass microsphere, ceramic particle area load hydroxyl endblocked polydimethylsiloxane, dimethyl silicone polymer, beta-schardinger dextrin-etc., large by loaded article specific area, special cavity body structure, extremely strong to the material absorption affinity around it, with other raw material actings in conjunction, goods not only quality are light, and mechanical property, corrosion-resistant and ageing resistace strengthens further.
Accompanying drawing explanation
Fig. 1 is the structural representation of the anti-aging corrosion proof cable a kind of peculiar to vessel that the present invention proposes.
Embodiment
As shown in Figure 1, Fig. 1 is the structural representation of the anti-aging corrosion proof cable a kind of peculiar to vessel that the present invention proposes.
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
With reference to Fig. 1, a kind of anti-aging corrosion proof cable peculiar to vessel, comprises core, core comprises two insulated conductors, insulated conductor comprises conductor 1 and the insulating barrier 2 be coated on outside conductor 1 forms, and be coated with restrictive coating 3 at core, wherein restrictive coating 3 adopts modified butadiene acrylonitrile rubber to prepare.
The raw material of modified butadiene acrylonitrile rubber comprises by weight: acrylonitrile-butadiene rubber 40 parts, neoprene 30 parts, ethylene propylene diene rubber 15 parts, fluorosioloxane rubber 5 parts, vulcanizing agent PDM1.5 part, vulcanizing agent HTDM1 part, accelerator M 0.8 part, accelerator D 0.5 part, antioxidant A W2 part, anti-aging agent RD 1 part, antioxidant BLE 2 parts, tall oil 1 part, pine tar 2 parts, white oil 1 part, carbon black 60 parts, mica powder 15 parts, zeolite powder 15 parts, composite ceramics glass microsphere 30 parts, adhesive A 8 parts, sodium carboxymethylcellulose 1 part.
Embodiment 2
With reference to Fig. 1, a kind of anti-aging corrosion proof cable peculiar to vessel, comprises core, core comprises two insulated conductors, insulated conductor comprises conductor 1 and the insulating barrier 2 be coated on outside conductor 1 forms, and be coated with restrictive coating 3 at core, wherein restrictive coating 3 adopts modified butadiene acrylonitrile rubber to prepare.
The raw material of modified butadiene acrylonitrile rubber comprises by weight: acrylonitrile-butadiene rubber 20 parts, neoprene 40 parts, ethylene propylene diene rubber 5 parts, fluorosioloxane rubber 10 parts, vulcanizing agent PDM0.5 part, vulcanizing agent HTDM2 part, accelerator M 0.5 part, accelerator D 1.2 parts, antioxidant A W1 part, anti-aging agent RD 4 parts, antioxidant BLE 1 part, tall oil 2 parts, pine tar 1 part, white oil 2 parts, carbon black 40 parts, mica powder 30 parts, zeolite powder 5 parts, composite ceramics glass microsphere 40 parts, adhesive A 5 parts, sodium carboxymethylcellulose 5 parts.
Embodiment 3
With reference to Fig. 1, a kind of anti-aging corrosion proof cable peculiar to vessel, comprises core, core comprises two insulated conductors, insulated conductor comprises conductor 1 and the insulating barrier 2 be coated on outside conductor 1 forms, and be coated with restrictive coating 3 at core, wherein restrictive coating 3 adopts modified butadiene acrylonitrile rubber to prepare.
The raw material of modified butadiene acrylonitrile rubber comprises by weight: acrylonitrile-butadiene rubber 34 parts, neoprene 32 parts, ethylene propylene diene rubber 12 parts, fluorosioloxane rubber 6 parts, vulcanizing agent PDM1.2 part, vulcanizing agent HTDM1.4 part, accelerator M 0.64 part, accelerator D 0.8 part, antioxidant A W1.6 part, anti-aging agent RD 2 parts, antioxidant BLE 1.5 parts, tall oil 1.6 parts, pine tar 1.7 parts, white oil 1.4 parts, carbon black 54 parts, mica powder 20 parts, zeolite powder 12 parts, composite ceramics glass microsphere 34 parts, adhesive A 7 parts, sodium carboxymethylcellulose 2 parts.
Composite ceramics glass microsphere adopts following technique to prepare: take 40 parts of glass microspheres by weight, to put into 70 parts of concentration be that the sodium carbonate liquor of 0.2mol/L stirs 40min for 10 parts of ceramic particles, whipping temp is 40 DEG C, filters, washing is to neutral, and send into the hydrochloric acid stirring 30min that 70 parts of concentration are 1mol/L, whipping temp is 30 DEG C, filter, washing, to neutral, is dried, and sends in Muffle furnace and calcines, calcination time is 3h, calcining heat is 500 DEG C, and cooling, obtains preliminary treatment material; By weight 30 parts of hydroxyl endblocked polydimethylsiloxanes, 50 parts of ethanol are diluted, add 3 parts of dimethyl silicone polymers, 10 parts of beta-schardinger dextrin-s, 80 parts of preliminary treatment material, 0.5 part of trifluoroacetic acid stir 60min, whipping temp is 70 DEG C, filters, dry, obtain composite ceramics glass microsphere.
Embodiment 4
With reference to Fig. 1, a kind of anti-aging corrosion proof cable peculiar to vessel, comprises core, core comprises two insulated conductors, insulated conductor comprises conductor 1 and the insulating barrier 2 be coated on outside conductor 1 forms, and be coated with restrictive coating 3 at core, wherein restrictive coating 3 adopts modified butadiene acrylonitrile rubber to prepare.
The raw material of modified butadiene acrylonitrile rubber comprises by weight: acrylonitrile-butadiene rubber 30 parts, neoprene 35 parts, ethylene propylene diene rubber 10 parts, fluorosioloxane rubber 8 parts, vulcanizing agent PDM1 part, vulcanizing agent HTDM1.8 part, accelerator M 0.6 part, accelerator D 1 part, antioxidant A W1.4 part, anti-aging agent RD 3.4 parts, antioxidant BLE 1.2 parts, tall oil 1.9 parts, pine tar 1.5 parts, white oil 1.6 parts, carbon black 50 parts, mica powder 25 parts, zeolite powder 8 parts, composite ceramics glass microsphere 37 parts, adhesive A 6 parts, sodium carboxymethylcellulose 4 parts.
Composite ceramics glass microsphere adopts following technique to prepare: take 20 parts of glass microspheres by weight, to put into 50 parts of concentration be that the sodium carbonate liquor of 0.5mol/L stirs 20min for 25 parts of ceramic particles, whipping temp is 50 DEG C, filters, washing is to neutral, and send into the hydrochloric acid stirring 15min that 60 parts of concentration are 2mol/L, whipping temp is 37 DEG C, filter, washing, to neutral, is dried, and sends in Muffle furnace and calcines, calcination time is 2h, calcining heat is 550 DEG C, and cooling, obtains preliminary treatment material; By weight 15 parts of hydroxyl endblocked polydimethylsiloxanes, 60 parts of ethanol are diluted, add 1 part of dimethyl silicone polymer, 15 parts of beta-schardinger dextrin-s, 40 parts of preliminary treatment material, 3 parts of trifluoroacetic acids stir 40min, whipping temp is 90 DEG C, filters, dry, obtain composite ceramics glass microsphere.
Embodiment 5
With reference to Fig. 1, a kind of anti-aging corrosion proof cable peculiar to vessel, comprises core, core comprises two insulated conductors, insulated conductor comprises conductor 1 and the insulating barrier 2 be coated on outside conductor 1 forms, and be coated with restrictive coating 3 at core, wherein restrictive coating 3 adopts modified butadiene acrylonitrile rubber to prepare.
The raw material of modified butadiene acrylonitrile rubber comprises by weight: acrylonitrile-butadiene rubber 32 parts, neoprene 34 parts, ethylene propylene diene rubber 11.5 parts, fluorosioloxane rubber 7.6 parts, vulcanizing agent PDM1.15 part, vulcanizing agent HTDM1.7 part, accelerator M 0.62 part, accelerator D 0.952 part, antioxidant A W1.5 part, anti-aging agent RD 3.2 parts, antioxidant BLE 1.4 parts, tall oil 1.8 parts, pine tar 1.6 parts, white oil 1.53 parts, carbon black 53 parts, mica powder 22 parts, zeolite powder 11.5 parts, composite ceramics glass microsphere 35 parts, adhesive A 6.2 parts, sodium carboxymethylcellulose 3.6 parts.
Composite ceramics glass microsphere adopts following technique to prepare: take 35 parts of glass microspheres by weight, to put into 65 parts of concentration be that the sodium carbonate liquor of 0.45mol/L stirs 36min for 21 parts of ceramic particles, whipping temp is 46 DEG C, filters, washing is to neutral, and send into the hydrochloric acid stirring 18min that 67 parts of concentration are 1.6mol/L, whipping temp is 34 DEG C, filter, washing, to neutral, is dried, and sends in Muffle furnace and calcines, calcination time is 2.5h, calcining heat is 525 DEG C, and cooling, obtains preliminary treatment material; By weight 26 parts of hydroxyl endblocked polydimethylsiloxanes, 56 parts of ethanol are diluted, add 2.5 parts of dimethyl silicone polymers, 12 parts of beta-schardinger dextrin-s, 72 parts of preliminary treatment material, 2.6 parts of trifluoroacetic acids stir 55min, whipping temp is 72 DEG C, filters, dry, obtain composite ceramics glass microsphere.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. an anti-aging corrosion proof cable peculiar to vessel, it is characterized in that, comprise core, core comprises two insulated conductors, insulated conductor comprises conductor (1) and is coated on conductor (1) insulating barrier outward (2) composition, is coated with restrictive coating (3) at core; Wherein restrictive coating (3) adopts modified butadiene acrylonitrile rubber preparation.
2. anti-aging corrosion proof cable peculiar to vessel according to claim 1, it is characterized in that, the raw material of modified butadiene acrylonitrile rubber comprises by weight: acrylonitrile-butadiene rubber 20-40 part, neoprene 30-40 part, ethylene propylene diene rubber 5-15 part, fluorosioloxane rubber 5-10 part, vulcanizing agent PDM0.5-1.5 part, vulcanizing agent HTDM1-2 part, accelerator M 0.5-0.8 part, accelerator D 0.5-1.2 part, antioxidant A W1-2 part, anti-aging agent RD 1-4 part, antioxidant BLE 1-2 part, tall oil 1-2 part, pine tar 1-2 part, white oil 1-2 part, carbon black 40-60 part, mica powder 15-30 part, zeolite powder 5-15 part, composite ceramics glass microsphere 30-40 part, adhesive A 5-8 part, sodium carboxymethylcellulose 1-5 part.
3. anti-aging corrosion proof cable peculiar to vessel according to claim 2, it is characterized in that, composite ceramics glass microsphere adopts following technique to prepare: glass microsphere, ceramic particle are put into sodium carbonate liquor and stirred, and filters, washing is to neutral, send in hydrochloric acid and stir, filter, washing is to neutral, dry, send in Muffle furnace and calcine, cooling, obtains preliminary treatment material; Hydroxyl endblocked polydimethylsiloxane ethanol is diluted, adds dimethyl silicone polymer, beta-schardinger dextrin-, preliminary treatment material, trifluoroacetic acid stirring, filter, dry, obtain composite ceramics glass microsphere.
4. the peculiar to vessel anti-aging corrosion proof cable according to Claims 2 or 3, it is characterized in that, composite ceramics glass microsphere adopts following technique to prepare: take 20-40 part glass microsphere by weight, it is that the sodium carbonate liquor of 0.2-0.5mol/L stirs 20-40min that 10-25 part ceramic particle puts into 50-70 part concentration, whipping temp is 40-50 DEG C, filter, washing is to neutral, send into the hydrochloric acid stirring 15-30min that 60-70 part concentration is 1-2mol/L, whipping temp is 30-37 DEG C, filter, washing is to neutral, dry, send in Muffle furnace and calcine, calcination time is 2-3h, calcining heat is 500-550 DEG C, cooling, obtain preliminary treatment material, by weight 15-30 part hydroxyl endblocked polydimethylsiloxane 50-60 part ethanol is diluted, add 1-3 part dimethyl silicone polymer, 10-15 part beta-schardinger dextrin-, 40-80 part preliminary treatment material, 0.5-3 part trifluoroacetic acid stirring 40-60min, whipping temp is 70-90 DEG C, filter, dry, obtain composite ceramics glass microsphere.
5. the peculiar to vessel anti-aging corrosion proof cable according to any one of claim 2-4, is characterized in that, the weight ratio of acrylonitrile-butadiene rubber, neoprene, ethylene propylene diene rubber and fluorosioloxane rubber is 30-34:32-35:10-12:6-8.
6. the peculiar to vessel anti-aging corrosion proof cable according to any one of claim 2-5, is characterized in that, the weight ratio of vulcanizing agent PDM, vulcanizing agent HTDM, accelerator M and accelerator D is 1-1.2:1.4-1.8:0.6-0.64:0.8-1.
7. the peculiar to vessel anti-aging corrosion proof cable according to any one of claim 2-6, is characterized in that, the weight ratio of carbon black, mica powder, zeolite powder and composite ceramics glass microsphere is 50-54:20-25:8-12:34-37.
8. the peculiar to vessel anti-aging corrosion proof cable according to any one of claim 2-7, it is characterized in that, the raw material of modified butadiene acrylonitrile rubber comprises by weight: acrylonitrile-butadiene rubber 30-34 part, neoprene 32-35 part, ethylene propylene diene rubber 10-12 part, fluorosioloxane rubber 6-8 part, vulcanizing agent PDM1-1.2 part, vulcanizing agent HTDM1.4-1.8 part, accelerator M 0.6-0.64 part, accelerator D 0.8-1 part, antioxidant A W1.4-1.6 part, anti-aging agent RD 2-3.4 part, antioxidant BLE 1.2-1.5 part, tall oil 1.6-1.9 part, pine tar 1.5-1.7 part, white oil 1.4-1.6 part, carbon black 50-54 part, mica powder 20-25 part, zeolite powder 8-12 part, composite ceramics glass microsphere 34-37 part, adhesive A 6-7 part, sodium carboxymethylcellulose 2-4 part.
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| CN201510607808.0A CN105185451B (en) | 2015-09-22 | 2015-09-22 | Marine anti-aging and corrosion resistant cable |
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| CN201510607808.0A CN105185451B (en) | 2015-09-22 | 2015-09-22 | Marine anti-aging and corrosion resistant cable |
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| CN105185451B CN105185451B (en) | 2017-04-12 |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105609184A (en) * | 2016-02-01 | 2016-05-25 | 安徽华峰电缆集团有限公司 | High-temperature resistant waterproof cable |
| CN105623035A (en) * | 2016-03-01 | 2016-06-01 | 苏州科茂电子材料科技有限公司 | Marine cable material and preparing method thereof |
| CN105801934A (en) * | 2016-04-29 | 2016-07-27 | 安徽华宇电缆集团有限公司 | Special oil-resistant and flame-proof cable for oil platform |
| CN105869712A (en) * | 2016-05-19 | 2016-08-17 | 安徽华源电缆集团有限公司 | Cold-proof, anti-freezing and anti-drag power cable |
| CN106118069A (en) * | 2016-06-23 | 2016-11-16 | 山东永泰集团有限公司 | A kind of anti-aging rubber |
| CN106118072A (en) * | 2016-08-08 | 2016-11-16 | 安徽埃克森科技集团有限公司 | A kind of instrument and meter spiral cable external jacket |
| CN106700288A (en) * | 2016-12-20 | 2017-05-24 | 安徽新立电缆材料有限公司 | Anti-ageing ship cable material |
| CN106750679A (en) * | 2016-11-25 | 2017-05-31 | 广东中德电缆有限公司 | A kind of low temperature resistant optoelectrical cable |
| CN107033603A (en) * | 2017-04-06 | 2017-08-11 | 安徽三鑫电缆材料有限公司 | A kind of high-temperature-rescontrol control cable material |
| CN108485010A (en) * | 2018-04-26 | 2018-09-04 | 常熟共益信息科技有限公司 | A kind of cable material and preparation method thereof that high-low temperature resistant is sun-proof |
| CN109131748A (en) * | 2018-09-30 | 2019-01-04 | 镇江宝海船舶五金有限公司 | A kind of corrosion-resistant marine anchor chain |
| CN110872402A (en) * | 2019-12-07 | 2020-03-10 | 界首市鑫豪塑胶有限公司 | Method for enhancing temperature resistance of nitrile rubber by using nano zeolite powder |
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| CN104751943A (en) * | 2013-12-31 | 2015-07-01 | 深圳市联嘉祥科技股份有限公司 | Cable and preparation method thereof |
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| JP2010114019A (en) * | 2008-11-10 | 2010-05-20 | Hitachi Cable Ltd | Cable |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105609184A (en) * | 2016-02-01 | 2016-05-25 | 安徽华峰电缆集团有限公司 | High-temperature resistant waterproof cable |
| CN105623035A (en) * | 2016-03-01 | 2016-06-01 | 苏州科茂电子材料科技有限公司 | Marine cable material and preparing method thereof |
| CN105801934A (en) * | 2016-04-29 | 2016-07-27 | 安徽华宇电缆集团有限公司 | Special oil-resistant and flame-proof cable for oil platform |
| CN105869712A (en) * | 2016-05-19 | 2016-08-17 | 安徽华源电缆集团有限公司 | Cold-proof, anti-freezing and anti-drag power cable |
| CN106118069A (en) * | 2016-06-23 | 2016-11-16 | 山东永泰集团有限公司 | A kind of anti-aging rubber |
| CN106118072A (en) * | 2016-08-08 | 2016-11-16 | 安徽埃克森科技集团有限公司 | A kind of instrument and meter spiral cable external jacket |
| CN106750679A (en) * | 2016-11-25 | 2017-05-31 | 广东中德电缆有限公司 | A kind of low temperature resistant optoelectrical cable |
| CN106700288A (en) * | 2016-12-20 | 2017-05-24 | 安徽新立电缆材料有限公司 | Anti-ageing ship cable material |
| CN107033603A (en) * | 2017-04-06 | 2017-08-11 | 安徽三鑫电缆材料有限公司 | A kind of high-temperature-rescontrol control cable material |
| CN108485010A (en) * | 2018-04-26 | 2018-09-04 | 常熟共益信息科技有限公司 | A kind of cable material and preparation method thereof that high-low temperature resistant is sun-proof |
| CN109131748A (en) * | 2018-09-30 | 2019-01-04 | 镇江宝海船舶五金有限公司 | A kind of corrosion-resistant marine anchor chain |
| CN110872402A (en) * | 2019-12-07 | 2020-03-10 | 界首市鑫豪塑胶有限公司 | Method for enhancing temperature resistance of nitrile rubber by using nano zeolite powder |
| CN110872402B (en) * | 2019-12-07 | 2023-04-07 | 界首市鑫豪塑胶有限公司 | Method for enhancing temperature resistance of nitrile rubber by using nano zeolite powder |
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