CN1051809C - Method for chemically and electrolytically recovering and extracting gold - Google Patents
Method for chemically and electrolytically recovering and extracting gold Download PDFInfo
- Publication number
- CN1051809C CN1051809C CN95110534A CN95110534A CN1051809C CN 1051809 C CN1051809 C CN 1051809C CN 95110534 A CN95110534 A CN 95110534A CN 95110534 A CN95110534 A CN 95110534A CN 1051809 C CN1051809 C CN 1051809C
- Authority
- CN
- China
- Prior art keywords
- gold
- golden liquid
- move back
- back golden
- plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 239000010931 gold Substances 0.000 title claims abstract description 43
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000002699 waste material Substances 0.000 claims abstract description 12
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 6
- 239000010935 stainless steel Substances 0.000 claims abstract description 6
- 238000011084 recovery Methods 0.000 claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 4
- 239000010439 graphite Substances 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 20
- 239000000284 extract Substances 0.000 claims description 5
- 238000010790 dilution Methods 0.000 claims description 4
- 239000012895 dilution Substances 0.000 claims description 4
- 238000005868 electrolysis reaction Methods 0.000 claims description 4
- 238000007747 plating Methods 0.000 claims description 4
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 3
- PPSSQRUPSRPZON-UHFFFAOYSA-N nitrobenzene;sodium Chemical compound [Na].[O-][N+](=O)C1=CC=CC=C1 PPSSQRUPSRPZON-UHFFFAOYSA-N 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 3
- 229940038773 trisodium citrate Drugs 0.000 claims description 3
- 239000001508 potassium citrate Substances 0.000 claims description 2
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 2
- 235000015870 tripotassium citrate Nutrition 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 abstract 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- 238000007865 diluting Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000007790 scraping Methods 0.000 abstract 1
- LJRGBERXYNQPJI-UHFFFAOYSA-M sodium;3-nitrobenzenesulfonate Chemical compound [Na+].[O-][N+](=O)C1=CC=CC(S([O-])(=O)=O)=C1 LJRGBERXYNQPJI-UHFFFAOYSA-M 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000005363 electrowinning Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Electrolytic Production Of Metals (AREA)
Abstract
The invention relates to a method for recovering and extracting gold from waste gold-plated parts through chemical and electrolytic processes, which comprises the steps of preparing a gold-removing solution by taking a proper amount of sodium m-nitrobenzenesulfonate, cyanide and citrate, putting the waste gold-plated parts into the diluted gold-removing solution, and heating to obtain a gold-containing gold-removing solution; diluting the gold-containing gold-withdrawing solution, placing the diluted gold-containing gold-withdrawing solution into a direct current electrolytic tank with a stainless steel plate as a cathode and graphite as an anode, heating, electrifying, controlling the current density to deposit gold on the anode plate, scraping, cleaning and drying to obtain the gold. The method has the advantages of simple process, low cost, raw material saving, no environmental pollution, and high recovery rate and purity.
Description
The present invention relates to a kind ofly from waste and old gold-plated article, reclaim the method that extracts gold from through chemistry and electrolytic process, genus chemical electrolysis technical field.
Gold is the more expensive metal of a kind of price, its social value is well-known, but gold also is a kind of good electric conductor, have be difficult for getting rusty, anti-oxidant, corrosion resistant characteristics, therefore in many semiconducter device especially transistor pin, usually use gold coating so that guarantee quality of semiconductor devices.Because the special value of gold, people also usually use gold as ornament, as golden jewelry, gold-plated wrist-watch etc.In the production and use of gold-plated device and other gold-plated article, waste product is very common, has lost value although these ormolu waste products mainly act on as it, still has very high economic worth in the lip-deep Gold plated Layer of these waste products.At present, the method that reclaims gold from these gold-plated waste products is many, but sum up these methods and all use some strong acid and deleterious pharmaceutical chemicals like this such as sodium cyanide, potassium cyanide, hydrogen peroxide, sulfuric acid, hydrochloric acid, and from its prescription, its consumption has all surpassed specified standards, this just is easy to cause poisons and environmental pollution, and step complexity, cost height, the rate of recovery are low.
The objective of the invention is to overcome existing big, the shortcomings such as cost is high, contaminate environment of toxicity that exist in the method that extracts gold from that reclaim, seek a kind of elder generation the metallizing on the waste product spare is stripped in solution, make the novel method of the higher gold of purity again by electrowinning under the certain condition.
In order to realize the foregoing invention purpose, earlier the pharmaceutical chemicals of choosing is mixed with in proportion and moves back golden liquid, gold-plated waste product spare is put into the golden liquid that moves back after the dilution, move back gold at a certain temperature to saturated; get saturated moving back golden liquid dilution and heat and be placed in the dc electrolysis groove; connect the current density on direct supply and the control cathode plate; making through electrolysis has the gold deposition on the negative plate; take out stainless steel cathode plate then; scrape and get its surface and go up sedimentary sheet gold, again with sheet gold through acid solution clean and drying treatment after just pure gold.
The inventive method has compared with prior art that technology is easy, conservation and time, gold rate of recovery height, advantage that purity is good, free from environmental pollution; If plating piece adopts this method can also keep former plating piece any surface finish, so that use again.
When the inventive method is implemented, it moves back being formulated as of golden liquid: add m-nitrobenzene sodium sulfonate 10～20 grams in every premium on currency, potassium cyanide or sodium cyanide 10～50 grams, Tripotassium Citrate or Trisodium Citrate 10～50 grams are made into and move back golden liquid, to move back golden liquid thin up again is placed in the container for 5～10 times, put into gold-plated waste product spare post-heating to 90～100 ℃, it is extremely saturated in moving back golden liquid that gold coating is backed off from the plating piece surface, must contain gold and move back golden liquid.To contain gold moves back to fall in glass or plastic electrobath after golden liquid dilutes 5～10 times, make negative electrode with stainless steel plate, at the negative electrode both sides certain distance graphite anode plate that to put two thickness of same area be 0.5～1cm, feeding voltage is 6 volts direct supply, heat electrolyzer temperature simultaneously after between 40～60 ℃, constant temperature 4～8 hours takes out negative plate, scrapes and gets sheet gold sheet.During energising, the current density on the control cathode plate is 0.3～0.5A/dm
2
With the sheet gold sheet collected heated and boiled 0.5 hour in 1: 1 aqueous hydrochloric acid, take out the aqueous nitric acid heated and boiled 0.5 hour of using 1: 1 after cleaning again, take out clean after, drying is handled and is promptly got pure gold.
Embodiment: get gold-plated useless package 10kg, totally stand-by with flushing with clean water; Get potassium cyanide 50 grams, trisodium citrate 50 grams, m-nitrobenzene sodium sulfonate 20 grams, adding water is made into for 1 liter and moves back golden liquid, thin up becomes 2 liters to move back golden liquid and pour in the Glass Containers, contain gold-plated useless part with plastic crate and put into ebullient and move back golden liquid, through 3～5 seconds time move back clean after, take out plastic crate and useless part is clean with flushing with clean water.Get the above-mentioned water that moves back golden liquid and clean plastic crate, to make total amount be 10 liters to adding distil water again, pours in the electrolyzer, makes electrolyzer have 2/3～3/4 volume to be full of.The stainless steel plate area is 2.0dm
2, make it that 1.5dm be arranged
2Immerse in the solution, promptly two-sided area can reach 3.0dm
2, the graphite anode plate with homalographic is put on the negative plate both sides.Make 55 ℃ of electrolyzer constant temperature, switched on 8 hours, collect deposition gold 12～13.5 grams on the stainless steel plate negative electrode, surveying its purity is about 99%.Continue energising 20 hours, can collect purity and be about 50% the golden material that contains, after purification processes, can get purity and be 99% gold 1 gram.The gold amount that it is recovered to is 13～14g, accounts for useless more than 99.5% of shell Gold Content.
Claims (2)
1, a kind ofly from waste and old gold-plated article, reclaims the method that extracts gold from through chemistry and electrolytic process, it is characterized in that its compound method of moving back golden liquid is: add m-nitrobenzene sodium sulfonate 10-20 gram in every premium on currency, potassium cyanide or sodium cyanide 10-50 gram, Tripotassium Citrate or Trisodium Citrate 10-50 gram are made into and move back golden liquid, to move back golden liquid thin up 5-10 more doubly is placed in the container, add gold-plated waste product spare post-heating to 90-100 ℃, it is extremely saturated in moving back golden liquid that gold coating is backed off from the plating piece surface, must contain gold and move back golden liquid; To contain gold and move back golden liquid dilution 5-10 and doubly be placed in the dc electrolysis groove and heat, the current density on the control cathode plate, making has the gold deposition on the negative plate, scrape get sheet gold treated pure gold.
2, the method that extracts gold from through chemistry and electrolytic recovery according to claim 1, it is characterized in that to contain gold and move back golden liquid dilution back in electrolyzer, make negative electrode with stainless steel plate, at the negative electrode both sides certain distance graphite anode plate that to put two thickness of same area be 0.5-1cm, feeding voltage is 6 volts direct supply, heat electrolyzer temperature simultaneously after between 40-60 ℃, constant temperature 4-8 hour, the current density on the control cathode plate was 0.3-0.5A/dm
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95110534A CN1051809C (en) | 1995-07-06 | 1995-07-06 | Method for chemically and electrolytically recovering and extracting gold |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95110534A CN1051809C (en) | 1995-07-06 | 1995-07-06 | Method for chemically and electrolytically recovering and extracting gold |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1121541A CN1121541A (en) | 1996-05-01 |
| CN1051809C true CN1051809C (en) | 2000-04-26 |
Family
ID=5077908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95110534A Expired - Fee Related CN1051809C (en) | 1995-07-06 | 1995-07-06 | Method for chemically and electrolytically recovering and extracting gold |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1051809C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103397351B (en) * | 2013-07-24 | 2016-04-06 | 励福(江门)环保科技股份有限公司 | The degold water of automatic degold production equipment, method and use |
| CN108277347B (en) * | 2017-06-26 | 2019-11-26 | 洪福安 | A kind of electroplating gold recovered liquid and its preparation method and application |
| CN109518055B (en) * | 2018-11-02 | 2021-07-16 | 上海交通大学 | Mineral gold extraction method based on mercury-free liquid alloy |
| CN110344080A (en) * | 2019-07-04 | 2019-10-18 | 苏州鑫达资源再生利用有限公司 | A method of extracting gold from waste of gold plating procedure |
| CN110656245A (en) * | 2019-09-23 | 2020-01-07 | 励福(江门)环保科技股份有限公司 | Method for gold removing treatment of stainless steel surface |
| CN111485116A (en) * | 2020-05-12 | 2020-08-04 | 深圳金贝得科技发展有限公司 | Efficient environment-friendly gold removing powder and gold recovery process |
| CN113005295A (en) * | 2021-03-05 | 2021-06-22 | 苏州鑫达资源再生利用有限公司 | Method for recovering gold from waste gold-containing circuit board |
| CN113584539A (en) * | 2021-06-26 | 2021-11-02 | 东莞市弘裕表面处理技术有限公司 | Method for preparing gold salt solution and recovering gold and cyanide-free gold electroplating solution |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1058996A (en) * | 1990-08-09 | 1992-02-26 | 浙江省诸暨黄金公司 | Noble liquid cyanide is with the direct electrolysis gold extraction technology of steel wool |
| CN1096057A (en) * | 1994-03-25 | 1994-12-07 | 长春黄金研究所 | Quick-cyaniding gold-extracting method in autoclave |
| CN1104266A (en) * | 1993-12-24 | 1995-06-28 | 中国科学院金属研究所 | Technology for extracting gold by directly electrolysing noble liquid cyanide |
-
1995
- 1995-07-06 CN CN95110534A patent/CN1051809C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1058996A (en) * | 1990-08-09 | 1992-02-26 | 浙江省诸暨黄金公司 | Noble liquid cyanide is with the direct electrolysis gold extraction technology of steel wool |
| CN1104266A (en) * | 1993-12-24 | 1995-06-28 | 中国科学院金属研究所 | Technology for extracting gold by directly electrolysing noble liquid cyanide |
| CN1096057A (en) * | 1994-03-25 | 1994-12-07 | 长春黄金研究所 | Quick-cyaniding gold-extracting method in autoclave |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1121541A (en) | 1996-05-01 |
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