CN105178038B - A kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent - Google Patents
A kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent Download PDFInfo
- Publication number
- CN105178038B CN105178038B CN201510558392.8A CN201510558392A CN105178038B CN 105178038 B CN105178038 B CN 105178038B CN 201510558392 A CN201510558392 A CN 201510558392A CN 105178038 B CN105178038 B CN 105178038B
- Authority
- CN
- China
- Prior art keywords
- nano
- fabric
- cloth
- particle
- essence
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Fats And Perfumes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent, comprised the following steps：S1, the nano-particle for preparing half crosslinking；S2, the nano-particle containing essence preparation；S3, the surface chemical modification by the unmodified nano-particle containing essence in S2；S4, the surface of fabric are modified；S5, the nano-particle containing essence of surface chemical modification are connected on fabric.The present invention is connected in function nano particle on cloth with chemical bond, stable and firm；Cloth is handled by finishing agent, is not simple film forming, but by with modified fabric chemical bonding, do not influence the flexibility of fabric, gas permeability；Oiliness essence is in lightly crosslinked inside nanoparticles, so not fearing washing；The cloth that this method arranges, because oiliness essence is locked in inside nanoparticles, so fragrant continual and steady with dissipating.
Description
Technical field
The present invention relates to clothes arrangement agent technical field, more particularly to a kind of wash resistant, to continue fabric fragrant
The preparation method of finishing agent.
Background technology
As the improvement of people's living standards, pursuit of the people to fabric has been not solely restricted in quality, while
Wish that fabric has multifunctionality.Such as all the more attention of the people to the external image of itself, spray and kindle incense on fabric often
Water, bring others a kind of pure and fresh pleasant impression, enable oneself preferably to exchange with people, got along with people.But the perfume of sprinkling
It is difficult to stablize lasting fragrant, fragrance is dense when just having sprayed perfume, but perfume volatilizees and several quickly later
Complete no any fragrance.
The raising required based on people living standard, the compound expectation to clothing multifunctional.Many scientific research personnel exist
This respect also has a preliminary exploration, but effect does not obtain the popularization of large area nor highly desirable, the present invention is intended to provide
It is a kind of to make the continual and steady fragrant finishing agent of fabric, solve this worries of people.
A kind of fragrant bar has done in some companies, sews in fabric pack edge, or as interlayer center, gives out fabric
Fragrance, but this method makes complicated, and is difficult to accomplish continual and steady fragrant.Ye You companies have done a kind of fatty
The detergent of enzyme and aromatic, making fabric, fragrant physical absorption enables fabric to give out in short term on fabric after washing
Fragrance.But the reservation of this method fragrance is of short duration, and if washing is not worn immediately after drying, the fabric will no longer distribute perfume (or spice)
Taste.Also have by the way that cloth is put into the solution for filling with perfume, many perfume particles are left on cloth after drying, so that cloth
It is fragrant, but the perfume particle that general knowledge is both known about on this cloth will come off afterwards several times in washing, this physical absorption, root
This is insecure.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of wash resistant, fabric can be made persistently to distribute perfume (or spice)
The preparation method of taste finishing agent.
A kind of wash resistant proposed by the present invention, fabric can be made to continue the preparation method of fragrant finishing agent, including it is as follows
Step：
S1, the nano-particle for preparing half crosslinking；
In distilled water solution, a kind of parents' emulsifying agent maleic acid octadecyl alcolol Macrogol 600 that can be waist crosslinked is added
Dibasic acid esters（OBEG）, sodium hexadecyl sulfate and esters of acrylic acid, initiator A IBN, crosslinking agent DVB, reacted at 60-80 DEG C
6-12h, obtain half crosslinking oiliness nano-particle；
S2, the nano-particle containing essence preparation；
By prepared in S1 half crosslinking oiliness nano-particle ultrasound 30 minutes in the solvent containing oiliness essence, make nanometer
Particle is fully swelled, and washs drying, and surface unmodified nano-particle containing essence is made；
S3, the surface chemical modification by the unmodified nano-particle containing essence in S2；
S4, the surface of fabric are modified；
Cloth is immersed in the solution for filling silane coupler, catalyst is added, is warming up to 30-70 DEG C of thermotonus
3-6h, the active cloth that surface is modified is made；
S5, the nano-particle containing essence of surface chemical modification are connected on fabric；
The nano-particle containing essence that S3 is obtained to surface chemical modification is made into slurries, covered with paint, lacquer, colour wash, etc. on cloth, heating is default
Time, the active cloth that nano-particle containing essence and the surface of surface chemical modification are modified chemically react, so that containing perfume
Smart nano-particle is stable and firm to be connected on cloth, is produced containing wash resistant, the cloth that fabric can be made to continue fragrant finishing agent
Material.
Preferably, esters of acrylic acid is different pungent including butyl acrylate, ethyl acrylate, methyl acrylate, acrylic acid in S1
One or more combinations in ester, methyl methacrylate.
Preferably, the medium oil essence of S2 is rose scent oiliness essence, lavender flavor type oiliness essence.
Preferably, silane coupler is in S4：3-（Phenyl amino）Propyl trimethoxy silicane, [3-（Triethoxysilicane
Base）Propyl group] one or more combinations in urethanes.
A kind of wash resistant proposed by the present invention, fabric can be made to continue the preparation method of fragrant finishing agent, pass through preparation
Can pin the active nanoparticles that the surface of oiliness essence molecule is modified, and can be continual and steady scattered fragrance, by by this table
The active fabrics that the active nanoparticles that face is modified are modified with surface chemically react, firm with the form stable of chemical bond
Function nano particle is keyed on fabric, makes continual and steady fragrant of fabric；Due to not being the film forming on fabric, so
The pliability of fabric, gas permeability are not influenceed.The fabric of functional finishing agent processing of the present invention does not fear washing, because in nano-particle
The hydrophobic cross-linked structure in portion, thus the medium oil functional molecular of washing process can be tightly be gathered in hydrophobic nano-particles
Portion, it will not be overflowed during washing.Finishing agent of the present invention have can make the continual and steady sending-forth function molecule of fabric；No
Influence the pliability of fabric, gas permeability；Washing is not feared.
The present invention is connected in function nano particle on cloth with chemical bond, stable and firm；Cloth is handled by finishing agent, no
Simple film forming, but by with modified fabric chemical bonding, do not influence the flexibility of fabric, gas permeability；Oiliness essence exists
Lightly crosslinked inside nanoparticles, so not fearing washing；The cloth that this method arranges, because oiliness essence is locked in nanoparticle
It is sub internal, so fragrant continual and steady with dissipating.
Embodiment
The present invention is made with reference to specific embodiment further to explain.
Embodiment one
A kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent, comprised the following steps：
S1, the nano-particle for preparing half crosslinking；
In distilled water solution, a kind of parents' emulsifying agent maleic acid octadecyl alcolol Macrogol 600 that can be waist crosslinked is added
Dibasic acid esters（OBEG）, sodium hexadecyl sulfate and esters of acrylic acid, initiator A IBN, crosslinking agent DVB, the anti-12h at 60 DEG C,
Obtain half crosslinking oiliness nano-particle；
S2, the nano-particle containing essence preparation；
By prepared in S1 half crosslinking oiliness nano-particle ultrasound 30 minutes in the solvent containing oiliness essence, make nanometer
Particle is fully swelled, and washs drying, and surface unmodified nano-particle containing essence is made；
S3, the surface chemical modification by the unmodified nano-particle containing essence in S2；
S4, the surface of fabric are modified；
Cloth is immersed in the solution for filling silane coupler, catalyst is added, is warming up to 40 DEG C of thermotonus 6h,
The active cloth that surface is modified is made；
S5, the nano-particle containing essence of surface chemical modification are connected on fabric；
The nano-particle containing essence that S3 is obtained to surface chemical modification is made into slurries, covered with paint, lacquer, colour wash, etc. on cloth, heating is default
Time, the active cloth that nano-particle containing essence and the surface of surface chemical modification are modified chemically react, so that containing perfume
Smart nano-particle is stable and firm to be connected on cloth, is produced containing wash resistant, the cloth that fabric can be made to continue fragrant finishing agent
Material.
Embodiment two
A kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent, comprised the following steps：
S1, the nano-particle for preparing half crosslinking；
In distilled water solution, a kind of parents' emulsifying agent maleic acid octadecyl alcolol Macrogol 600 that can be waist crosslinked is added
Dibasic acid esters（OBEG）, sodium hexadecyl sulfate and esters of acrylic acid, initiator A IBN, crosslinking agent DVB, react 9h at 70 DEG C,
Obtain half crosslinking oiliness nano-particle；
S2, the nano-particle containing essence preparation；
By prepared in S1 half crosslinking oiliness nano-particle ultrasound 30 minutes in the solvent containing oiliness essence, make nanometer
Particle is fully swelled, and washs drying, and surface unmodified nano-particle containing essence is made；
S3, the surface chemical modification by the unmodified nano-particle containing essence in S2；
S4, the surface of fabric are modified；
Cloth is immersed in the solution for filling silane coupler, catalyst is added, is warming up to 55 DEG C of thermotonuses
4.5h, the active cloth that surface is modified is made；
S5, the nano-particle containing essence of surface chemical modification are connected on fabric；
The nano-particle containing essence that S3 is obtained to surface chemical modification is made into slurries, covered with paint, lacquer, colour wash, etc. on cloth, heating is default
Time, the active cloth that nano-particle containing essence and the surface of surface chemical modification are modified chemically react, so that containing perfume
Smart nano-particle is stable and firm to be connected on cloth, is produced containing wash resistant, the cloth that fabric can be made to continue fragrant finishing agent
Material.
Embodiment three
A kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent, comprised the following steps：
S1, the nano-particle for preparing half crosslinking；
In distilled water solution, a kind of parents' emulsifying agent maleic acid octadecyl alcolol Macrogol 600 that can be waist crosslinked is added
Dibasic acid esters（OBEG）, sodium hexadecyl sulfate and esters of acrylic acid, initiator A IBN, crosslinking agent DVB, react 6h at 80 DEG C,
Obtain half crosslinking oiliness nano-particle；
S2, the nano-particle containing essence preparation；
By prepared in S1 half crosslinking oiliness nano-particle ultrasound 30 minutes in the solvent containing oiliness essence, make nanometer
Particle is fully swelled, and washs drying, and surface unmodified nano-particle containing essence is made；
S3, the surface chemical modification by the unmodified nano-particle containing essence in S2；
S4, the surface of fabric are modified；
Cloth is immersed in the solution for filling silane coupler, catalyst is added, is warming up to 70 DEG C of thermotonus 3h,
The active cloth that surface is modified is made；
S5, the nano-particle containing essence of surface chemical modification are connected on fabric；
The nano-particle containing essence that S3 is obtained to surface chemical modification is made into slurries, covered with paint, lacquer, colour wash, etc. on cloth, heating is default
Time, the active cloth that nano-particle containing essence and the surface of surface chemical modification are modified chemically react, so that containing perfume
Smart nano-particle is stable and firm to be connected on cloth, is produced containing wash resistant, the cloth that fabric can be made to continue fragrant finishing agent
Material.
The present invention can pin oiliness essence molecule by preparing, the table that control oiliness essence functional molecular continually and steadily discharges
Face modification activities nano-particle, it is anti-by the way that this surface modified active nano-particle and surface modified active fabric into chemistry occur
Should, form stable is obtained with chemical bond firmly function nano particle is keyed on fabric, make fabric it is continual and steady distribute perfume (or spice)
Taste, and the pliability of fabric, gas permeability are not influenceed.With easy to use, the characteristics of stable and durable effect.Inventive can refer to
Mark is as follows：40 degrees Celsius remain to smell fragrance for lower 1 month, wash 30 times and remain to smell fragrance.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (4)
1. a kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent cloth, it is characterised in that including as follows
Step：
S1, the nano-particle for preparing half crosslinking；
In distilled water solution, a kind of parents' emulsifying agent maleic acid octadecyl alcolol Macrogol 600 dibasic acid esters that can be waist crosslinked of addition,
Sodium hexadecyl sulfate and esters of acrylic acid, initiator A IBN, crosslinking agent DVB, react 6-12h at 60-80 DEG C, obtain
Half crosslinking oiliness nano-particle；
S2, the nano-particle containing essence preparation；
By prepared in S1 half crosslinking oiliness nano-particle ultrasound 30 minutes in the solvent containing oiliness essence, make nano-particle
Fully swelling, drying is washed, surface unmodified nano-particle containing essence is made；
S3, the surface chemical modification by the unmodified nano-particle containing essence in S2；
S4, the surface of fabric are modified；
Cloth is immersed in the solution for filling silane coupler, catalyst is added, is warming up to 30-70 DEG C of thermotonus 3-6h,
The active cloth that surface is modified is made；
S5, the nano-particle containing essence of surface chemical modification are connected on fabric；
The nano-particle containing essence that S3 is obtained to surface chemical modification is made into slurries, covered with paint, lacquer, colour wash, etc. on cloth, heats preset time,
The nano-particle containing essence of surface chemical modification chemically reacts with the active cloth that surface is modified, so that nanometer containing essence
It is particle-stabilised to be securely attached on cloth, produce containing wash resistant, the cloth that fabric can be made to continue fragrant finishing agent.
2. wash resistant according to claim 1, fabric can be made to continue the preparation method of fragrant finishing agent cloth, it is special
Sign is that esters of acrylic acid includes butyl acrylate, ethyl acrylate, methyl acrylate, Isooctyl acrylate monomer, methyl-prop in S1
One or more combinations in e pioic acid methyl ester.
3. wash resistant according to claim 1, fabric can be made to continue the preparation method of fragrant finishing agent cloth, it is special
Sign is that the medium oil essence of S2 is rose scent oiliness essence, lavender flavor type oiliness essence.
4. wash resistant according to claim 1, fabric can be made to continue the preparation method of fragrant finishing agent cloth, it is special
Sign is that silane coupler is in S4：3-（Phenyl amino）Propyl trimethoxy silicane, [3-（Triethoxy silicon substrate）Propyl group] ammonia
One or more combinations in base Ethyl formate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510558392.8A CN105178038B (en) | 2015-09-06 | 2015-09-06 | A kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510558392.8A CN105178038B (en) | 2015-09-06 | 2015-09-06 | A kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105178038A CN105178038A (en) | 2015-12-23 |
| CN105178038B true CN105178038B (en) | 2018-02-13 |
Family
ID=54900433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510558392.8A Active CN105178038B (en) | 2015-09-06 | 2015-09-06 | A kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105178038B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1412382A (en) * | 2001-10-08 | 2003-04-23 | 欧光宜 | Production method of textile or paper product capable of continuously-releasing perfume |
| CN1742024A (en) * | 2003-01-29 | 2006-03-01 | 弗门尼舍有限公司 | Polymeric particles and fragrance delivery systems |
| CN1966847A (en) * | 2006-11-24 | 2007-05-23 | 华明浩 | Method for preparing inorganic clad nano silver-supported antibacterial composite polyurethane microcapsule aromatic fabrics |
| CN101838933A (en) * | 2009-03-20 | 2010-09-22 | 李江陵 | Sleeping-aided fabric and manufacturing method thereof |
| CN102444027A (en) * | 2011-08-24 | 2012-05-09 | 翔瑞（泉州）纳米科技有限公司 | Antimicrobial fabric supported with nano silver core-shell polymer microsphere and preparation method thereof |
| CN104120607A (en) * | 2014-07-16 | 2014-10-29 | 陕西科技大学 | Preparation method of grafting modified beta-cyclodextrin aromatic finishing agent |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5961872B2 (en) * | 2013-03-22 | 2016-08-02 | ライオン株式会社 | Liquid softener composition |
-
2015
- 2015-09-06 CN CN201510558392.8A patent/CN105178038B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1412382A (en) * | 2001-10-08 | 2003-04-23 | 欧光宜 | Production method of textile or paper product capable of continuously-releasing perfume |
| CN1742024A (en) * | 2003-01-29 | 2006-03-01 | 弗门尼舍有限公司 | Polymeric particles and fragrance delivery systems |
| CN1966847A (en) * | 2006-11-24 | 2007-05-23 | 华明浩 | Method for preparing inorganic clad nano silver-supported antibacterial composite polyurethane microcapsule aromatic fabrics |
| CN101838933A (en) * | 2009-03-20 | 2010-09-22 | 李江陵 | Sleeping-aided fabric and manufacturing method thereof |
| CN102444027A (en) * | 2011-08-24 | 2012-05-09 | 翔瑞（泉州）纳米科技有限公司 | Antimicrobial fabric supported with nano silver core-shell polymer microsphere and preparation method thereof |
| CN104120607A (en) * | 2014-07-16 | 2014-10-29 | 陕西科技大学 | Preparation method of grafting modified beta-cyclodextrin aromatic finishing agent |
Non-Patent Citations (1)
| Title |
|---|
| Waist cross-linked micelles synthesized via self-assembly guiding radical polymerization;Conghui Yuan et al.;《Soft Matter》;20091231(第5期);第4642–4646页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105178038A (en) | 2015-12-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102014851B (en) | Deposition of lipophilic active material in surfactant containing compositions | |
| WO2020113903A1 (en) | Skincare and antibacterial microcapsule finishing agent, and preparation method therefor and application thereof | |
| CN109957972A (en) | The method of microcapsules and its arrangement into textile fabric based on plants essential oil | |
| CN103343455B (en) | A kind of production method of aromatic fabrics | |
| CN105567426B (en) | A kind of sweet osmanthus sustained release essence and preparation method thereof | |
| KR20090025095A (en) | Fabric having aromatic microcapsule, mixure and method of manufacturing thereof | |
| CN104997203A (en) | Method for manufacturing composite non-woven fabric collar interlining | |
| CN105178038B (en) | A kind of wash resistant, fabric can be made to continue the preparation method of fragrant finishing agent | |
| CN103725252A (en) | Formaldehyde-free adhesive as well as preparation method and application thereof | |
| JP4647455B2 (en) | Textile treatment agent and treatment method thereof | |
| CN107189532A (en) | A kind of graphene formaldehyde-removing wallpaper, wall paper and preparation method | |
| CN103806284A (en) | Method for manufacturing cool non-woven cloth for diversion layer of sanitary napkin | |
| CN105862447A (en) | Preparation method of self-cleaned polyurethane synthetic leather | |
| CN103205901B (en) | Burnt discoloration synthetic leather and preparation method thereof | |
| CN109303879A (en) | A kind of traditional Chinese medicine plaster and preparation method thereof for treating eczema | |
| CN108146027A (en) | A kind of degradable ecological non-woven fabrics and preparation method thereof | |
| JP6091221B2 (en) | Method for producing deodorant antibacterial fiber and deodorant antibacterial agent for fiber | |
| JP3932291B2 (en) | Modification method for textile products to prevent pollen adhesion | |
| CN103174034A (en) | Fragrant finishing process of woolen sweater and wool blend ready-made clothes | |
| JP2008517076A5 (en) | ||
| CN108797105B (en) | Preparation method and finishing method of finishing agent for endowing fabric with multiple functions | |
| CN107012700B (en) | A kind of production technology of fish scale-shaped gold stampped shell fabric | |
| CN105002655B (en) | A kind of preparation technology of collar support non-woven fabrics | |
| CN104109973A (en) | Textile finishing liquid adopting stamping method, and finishing technology thereof | |
| JP6912647B1 (en) | Method for manufacturing paste composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 362000 Fujian province Quanzhou detai economic and Technological Development Zone, Road No. 51 Building No. 2 business building A area four Patentee after: Fujian Pincheng Environmental Protection Technology Co., Ltd Address before: 362000 Fujian province Quanzhou detai economic and Technological Development Zone, Road No. 51 Building No. 2 business building A area four Patentee before: QUANZHOU PINCHENG ELECTRONIC TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200805 Address after: 215500 No.13, Caotang Road, Changshu, Suzhou, Jiangsu Province Patentee after: Changshu intellectual property operation center Co.,Ltd. Address before: 362000 Fujian province Quanzhou detai economic and Technological Development Zone, Road No. 51 Building No. 2 business building A area four Patentee before: Fujian Pincheng Environmental Protection Technology Co., Ltd |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201130 Address after: 215500, Jiangsu, Suzhou province Changshou City Tong Town, Ren Yang Ren Village Patentee after: CHANGSHU YISHENG COMMODITY Co.,Ltd. Address before: 215500 No.13, Caotang Road, Changshu, Suzhou, Jiangsu Province Patentee before: Changshu intellectual property operation center Co.,Ltd. |