CN105175840A - Aging-resistant, hot-resistant and oil-resistant cable for oil platform - Google Patents
Aging-resistant, hot-resistant and oil-resistant cable for oil platform Download PDFInfo
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- CN105175840A CN105175840A CN201510607760.3A CN201510607760A CN105175840A CN 105175840 A CN105175840 A CN 105175840A CN 201510607760 A CN201510607760 A CN 201510607760A CN 105175840 A CN105175840 A CN 105175840A
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Abstract
The invention discloses an aging-resistant, hot-resistant and oil-resistant cable for an oil platform. The aging-resistant, hot-resistant and oil-resistant cable comprises a conductor, wherein the conductor is wrapped by an insulation layer, and the insulation layer is wrapped by a sheath layer. The sheath layer is prepared from composite rubber, and the composite rubber is prepared from brominated butyl rubber, nitrile rubber, polysulfide rubber, zinc oxide, magnesium oxide, fatty acid, tetramethyl thiuram disulfide, gypsum, kieselguhr, micro-encapsulation red phosphorous, white carbon black, nanosilicon dioxide, modified kaolin, vinyl triethoxysilane, paraffin, rosin, stearic acid, white factice, dioctyl sebacate, a D-50 anti-aging agent and phosphate ester. The aging-resistant, hot-resistant and oil-resistant cable for the oil platform is extremely good in aging-resistant, hot-resistant and oil-resistant performance.
Description
Technical field
The present invention relates to field of cable technology, particularly relate to a kind of ageing-resistant heat-resisting oil resistant cable used for oil platform.
Background technology
At present, the development and utilization to oceanic resources is all constantly strengthened in countries in the world, particularly to the development and utilization of offshore oil, ageing-resistant heat-resisting oil resistant cable used for oil platform as power transmission and communication has longer applicating history, along with various countries constantly increase energy exploration offshore oil platform, ageing-resistant, the heat-resisting and oil resistance of current people to ageing-resistant heat-resisting oil resistant cable used for oil platform is had higher requirement.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of ageing-resistant heat-resisting oil resistant cable used for oil platform, ageing-resistant, heat-resisting and oil-proofness is fabulous.
The ageing-resistant heat-resisting oil resistant of the one cable used for oil platform that the present invention proposes, comprise conductor, be coated with insulation layer at conductor, insulation layer is coated with restrictive coating; Restrictive coating adopts compounded rubber preparation.
Preferably, the raw material of described compounded rubber comprises by weight: brominated butyl rubber 20-40 part, paracril 5-15 part, thiorubber 15-30 part, zinc oxide 1-2 part, magnesium oxide 1-3 part, lipid acid 1-3 part, tetramethyl-thiuram disulfide 1-3 part, gypsum 20-30 part, diatomite 5-15 part, microencapsulated powder oil 5-15 part, white carbon black 5-15 part, nano silicon 20-30 part, modified kaolin 30-50 part, vinyltriethoxysilane 1-3 part, paraffin 1-2 part, rosin 1-5 part, stearic acid 1-3 part, white factice 1-3 part, dioctyl sebacate 1-3 part, D-50 anti-aging agent 1-2 part, phosphorous acid ester 1-2 part.
Preferably, modified kaolin adopts following technique to prepare: in kaolin, add intercalator cesium acetate stir, and carries out ultrasonic in feeding ultrasonic reactor, filter, pulverize, add p-Nitroaniline and stir, centrifugal, add palmityl trimethyl ammonium chloride, p-Nitroaniline, water stirs, filter, washing, dry, heat up calcining, is cooled to room temperature, pulverizes and obtain modified kaolin.
Preferably, modified kaolin adopts following technique to prepare: in 40-60 part kaolin, add 20-30 part intercalator cesium acetate by weight stir, stirring velocity is 2400-2800r/min, churning time is 25-30min, carry out ultrasonic in feeding ultrasonic reactor, ultrasonic temperature is 80-88 DEG C, ultrasonic time is 5-15min, filter, pulverize, add 30-60 part p-Nitroaniline to stir, stirring velocity is 1500-1800r/min, churning time is 15-35h, centrifugal, add 15-35 part palmityl trimethyl ammonium chloride, 20-40 part p-Nitroaniline, 15-25 part water stirs, churning time is 20-40h, whipping temp is 55-65 DEG C, filter, washing, dry, 320-350 DEG C of calcining 1-2h is warming up to the speed of 0.5-1 DEG C/min from room temperature, 400-430 DEG C of calcining 1-2h is warming up to the speed of 1-2 DEG C/min, 570-600 DEG C of calcining 1-2h is warming up to the speed of 0.5-1.5 DEG C/min, room temperature is cooled to the speed of 1-3 DEG C/min, pulverizing obtains modified kaolin.
Preferably, the weight ratio of gypsum, kaolin, microencapsulated powder oil, white carbon black, nano silicon and modified kaolin is 24-28:8-12:10-13:8-10:22-25:40-46.
Preferably, the weight ratio of zinc oxide, magnesium oxide, lipid acid and tetramethyl-thiuram disulfide is 1.4-1.7:2-2.6:1.5-2.3:1-2.
Preferably, the weight ratio of brominated butyl rubber, paracril and thiorubber is 30-36:8-13:20-25.
Preferably, the raw material of described compounded rubber comprises by weight: brominated butyl rubber 30-36 part, paracril 8-13 part, thiorubber 20-25 part, zinc oxide 1.4-1.7 part, magnesium oxide 2-2.6 part, lipid acid 1.5-2.3 part, tetramethyl-thiuram disulfide 1-2 part, gypsum 24-28 part, diatomite 8-12 part, microencapsulated powder oil 10-13 part, white carbon black 8-10 part, nano silicon 22-25 part, modified kaolin 40-46 part, vinyltriethoxysilane 1.5-2.3 part, paraffin 1.5-1.8 part, rosin 2-3 part, stearic acid 1.6-2.2 part, white factice 1.4-2.4 part, dioctyl sebacate 1.5-2 part, D-50 anti-aging agent 1.2-1.5 part, phosphorous acid ester 1.5-1.8 part.
In the present invention, above-mentioned compounded rubber adopts preparation technology's preparation of ordinary rubber, and namely starting material prepare → plasticate → mixing → shaping → sulfuration → rest and reorganization → inspection.
In the present invention, brominated butyl rubber, paracril and thiorubber synergy, on the basis ensureing primary characteristic, goods are ageing-resistant, oil resistant and resistance toheat are very excellent, brominated butyl rubber, paracril and thiorubber are at paraffin, rosin, under stearic acid effect, comixing compatibility is fabulous, adopts zinc oxide further, magnesium oxide, lipid acid and tetramethyl-thiuram disulfide are as vulcanization system, and cure efficiency is good, sizing material resistance toheat, the gypsum wherein added, kaolin, microencapsulated powder oil, white carbon black, nano silicon, modified kaolin, filling properties is good, and sizing material can be made to have good toughness, and compression set is little, and goods are ageing-resistant and oil resistance is fabulous, acts synergistically with vinyltriethoxysilane, with brominated butyl rubber, the consistency of paracril and thiorubber is fabulous, ageing-resistant and the resistance toheat of goods strengthens further, modified kaolin wherein, from structure-forming process, be curled into modified kaolin by kaolin layer, the feature of Cheng Guanhou, more easily show the constitutional features of pipe to resistance toheat, tube surfaces has hydroxyl layer in addition, with brominated butyl rubber, paracril, thiorubber and other inorganic materials organically combine, and goods are ageing-resistant, oil resistant and thermotolerance are very excellent.
Accompanying drawing explanation
Fig. 1 is the cross section structure schematic diagram of a kind of ageing-resistant heat-resisting oil resistant cable used for oil platform that the present invention proposes.
Embodiment
As shown in Figure 1, Fig. 1 is the cross section structure schematic diagram of a kind of ageing-resistant heat-resisting oil resistant cable used for oil platform that the present invention proposes.
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
With reference to Fig. 1, a kind of ageing-resistant heat-resisting oil resistant cable used for oil platform, comprise conductor 1, be coated with insulation layer 2 at conductor 1, insulation layer 2 is coated with restrictive coating 3; Restrictive coating 3 adopts compounded rubber to prepare.
The raw material of described compounded rubber comprises by weight: brominated butyl rubber 20 parts, paracril 15 parts, thiorubber 15 parts, 2 parts, zinc oxide, 1 part, magnesium oxide, 3 parts, lipid acid, tetramethyl-thiuram disulfide 1 part, 30 parts, gypsum, 5 parts, diatomite, microencapsulated powder oil 15 parts, white carbon black 5 parts, nano silicon 30 parts, modified kaolin 30 parts, vinyltriethoxysilane 3 parts, 1 part, paraffin, rosin 5 parts, stearic acid 1 part, white factice 3 parts, dioctyl sebacate 1 part, 2 parts, D-50 anti-aging agent, phosphorous acid ester 1 part.
Embodiment 2
With reference to Fig. 1, a kind of ageing-resistant heat-resisting oil resistant cable used for oil platform, comprise conductor 1, be coated with insulation layer 2 at conductor 1, insulation layer 2 is coated with restrictive coating 3; Restrictive coating 3 adopts compounded rubber to prepare.
The raw material of described compounded rubber comprises by weight: brominated butyl rubber 40 parts, paracril 5 parts, thiorubber 30 parts, 1 part, zinc oxide, 3 parts, magnesium oxide, 1 part, lipid acid, tetramethyl-thiuram disulfide 3 parts, 20 parts, gypsum, 15 parts, diatomite, microencapsulated powder oil 5 parts, white carbon black 15 parts, nano silicon 20 parts, modified kaolin 50 parts, vinyltriethoxysilane 1 part, 2 parts, paraffin, rosin 1 part, stearic acid 3 parts, white factice 1 part, dioctyl sebacate 3 parts, 1 part, D-50 anti-aging agent, phosphorous acid ester 2 parts.
Embodiment 3
With reference to Fig. 1, a kind of ageing-resistant heat-resisting oil resistant cable used for oil platform, comprise conductor 1, be coated with insulation layer 2 at conductor 1, insulation layer 2 is coated with restrictive coating 3; Restrictive coating 3 adopts compounded rubber to prepare.
The raw material of described compounded rubber comprises by weight: brominated butyl rubber 30 parts, paracril 13 parts, thiorubber 20 parts, 1.7 parts, zinc oxide, 2 parts, magnesium oxide, 2.3 parts, lipid acid, tetramethyl-thiuram disulfide 1 part, 28 parts, gypsum, 8 parts, diatomite, microencapsulated powder oil 13 parts, white carbon black 8 parts, nano silicon 25 parts, modified kaolin 40 parts, vinyltriethoxysilane 2.3 parts, 1.5 parts, paraffin, rosin 3 parts, stearic acid 1.6 parts, white factice 2.4 parts, dioctyl sebacate 1.5 parts, 1.5 parts, D-50 anti-aging agent, phosphorous acid ester 1.5 parts.
Modified kaolin adopts following technique to prepare: in 60 parts of kaolin, add 20 parts of intercalator cesium acetates by weight and stir, stirring velocity is 2800r/min, churning time is 25min, carry out ultrasonic in feeding ultrasonic reactor, ultrasonic temperature is 88 DEG C, ultrasonic time is 5min, filter, pulverize, add 60 parts of p-Nitroaniline to stir, stirring velocity is 1500r/min, churning time is 35h, centrifugal, add 15 parts of palmityl trimethyl ammonium chlorides, 40 parts of p-Nitroaniline, 15 parts of water stir, churning time is 40h, whipping temp is 55 DEG C, filter, washing, dry, 320 DEG C of calcining 2h are warming up to the speed of 1 DEG C/min from room temperature, 430 DEG C of calcining 1h are warming up to the speed of 1 DEG C/min, 570 DEG C of calcining 2h are warming up to the speed of 1.5 DEG C/min, room temperature is cooled to the speed of 1 DEG C/min, pulverizing obtains modified kaolin.
Embodiment 4
With reference to Fig. 1, a kind of ageing-resistant heat-resisting oil resistant cable used for oil platform, comprise conductor 1, be coated with insulation layer 2 at conductor 1, insulation layer 2 is coated with restrictive coating 3; Restrictive coating 3 adopts compounded rubber to prepare.
The raw material of described compounded rubber comprises by weight: brominated butyl rubber 36 parts, paracril 8 parts, thiorubber 25 parts, 1.4 parts, zinc oxide, 2.6 parts, magnesium oxide, 1.5 parts, lipid acid, tetramethyl-thiuram disulfide 2 parts, 24 parts, gypsum, 12 parts, diatomite, microencapsulated powder oil 10 parts, white carbon black 10 parts, nano silicon 22 parts, modified kaolin 46 parts, vinyltriethoxysilane 1.5 parts, 1.8 parts, paraffin, rosin 2 parts, stearic acid 2.2 parts, white factice 1.4 parts, dioctyl sebacate 2 parts, 1.2 parts, D-50 anti-aging agent, phosphorous acid ester 1.8 parts.
Modified kaolin adopts following technique to prepare: in 40 parts of kaolin, add 30 parts of intercalator cesium acetates by weight and stir, stirring velocity is 2400r/min, churning time is 30min, carry out ultrasonic in feeding ultrasonic reactor, ultrasonic temperature is 80 DEG C, ultrasonic time is 15min, filter, pulverize, add 30 parts of p-Nitroaniline to stir, stirring velocity is 1800r/min, churning time is 15h, centrifugal, add 35 parts of palmityl trimethyl ammonium chlorides, 20 parts of p-Nitroaniline, 25 parts of water stir, churning time is 20h, whipping temp is 65 DEG C, filter, washing, dry, 350 DEG C of calcining 1h are warming up to the speed of 0.5 DEG C/min from room temperature, 400 DEG C of calcining 2h are warming up to the speed of 2 DEG C/min, 600 DEG C of calcining 1h are warming up to the speed of 0.5 DEG C/min, room temperature is cooled to the speed of 3 DEG C/min, pulverizing obtains modified kaolin.
Embodiment 5
With reference to Fig. 1, a kind of ageing-resistant heat-resisting oil resistant cable used for oil platform, comprise conductor 1, be coated with insulation layer 2 at conductor 1, insulation layer 2 is coated with restrictive coating 3; Restrictive coating 3 adopts compounded rubber to prepare.
The raw material of described compounded rubber comprises by weight: brominated butyl rubber 32 parts, paracril 12 parts, thiorubber 22 parts, 1.6 parts, zinc oxide, 2.4 parts, magnesium oxide, 2.2 parts, lipid acid, tetramethyl-thiuram disulfide 1.5 parts, 26 parts, gypsum, 11 parts, diatomite, microencapsulated powder oil 12 parts, white carbon black 9 parts, nano silicon 24 parts, modified kaolin 42 parts, vinyltriethoxysilane 2.2 parts, 1.7 parts, paraffin, rosin 2.6 parts, stearic acid 2.1 parts, white factice 2.1 parts, dioctyl sebacate 1.8 parts, 1.4 parts, D-50 anti-aging agent, phosphorous acid ester 1.7 parts.
Modified kaolin adopts following technique to prepare: in 55 parts of kaolin, add 26 parts of intercalator cesium acetates by weight and stir, stirring velocity is 2700r/min, churning time is 28min, carry out ultrasonic in feeding ultrasonic reactor, ultrasonic temperature is 84 DEG C, ultrasonic time is 12min, filter, pulverize, add 45 parts of p-Nitroaniline to stir, stirring velocity is 1750r/min, churning time is 32h, centrifugal, add 24 parts of palmityl trimethyl ammonium chlorides, 36 parts of p-Nitroaniline, 22 parts of water stir, churning time is 36h, whipping temp is 62 DEG C, filter, washing, dry, 340 DEG C of calcining 1.5h are warming up to the speed of 0.6 DEG C/min from room temperature, 420 DEG C of calcining 1.5h are warming up to the speed of 1.5 DEG C/min, 580 DEG C of calcining 1.5h are warming up to the speed of 1.2 DEG C/min, room temperature is cooled to the speed of 1.6 DEG C/min, pulverizing obtains modified kaolin.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. an ageing-resistant heat-resisting oil resistant cable used for oil platform, is characterized in that, comprises conductor (1), is coated with insulation layer (2) at conductor (1), and insulation layer (2) is coated with restrictive coating (3); Restrictive coating (3) adopts compounded rubber preparation.
2. to remove the ageing-resistant heat-resisting oil resistant cable used for oil platform described in 1 according to right, it is characterized in that, the raw material of described compounded rubber comprises by weight: brominated butyl rubber 20-40 part, paracril 5-15 part, thiorubber 15-30 part, zinc oxide 1-2 part, magnesium oxide 1-3 part, lipid acid 1-3 part, tetramethyl-thiuram disulfide 1-3 part, gypsum 20-30 part, diatomite 5-15 part, microencapsulated powder oil 5-15 part, white carbon black 5-15 part, nano silicon 20-30 part, modified kaolin 30-50 part, vinyltriethoxysilane 1-3 part, paraffin 1-2 part, rosin 1-5 part, stearic acid 1-3 part, white factice 1-3 part, dioctyl sebacate 1-3 part, D-50 anti-aging agent 1-2 part, phosphorous acid ester 1-2 part.
3. will remove the ageing-resistant heat-resisting oil resistant cable used for oil platform described in 2 according to right, it is characterized in that, modified kaolin adopts following technique to prepare: in kaolin, add intercalator cesium acetate stir, carry out ultrasonic in feeding ultrasonic reactor, filter, pulverize, add p-Nitroaniline to stir, centrifugal, add palmityl trimethyl ammonium chloride, p-Nitroaniline, water stirs, filter, washing, dry, heat up calcining, be cooled to room temperature, pulverize and obtain modified kaolin.
4. to remove the ageing-resistant heat-resisting oil resistant cable used for oil platform described in 2 or 3 according to right, it is characterized in that, modified kaolin adopts following technique to prepare: in 40-60 part kaolin, add 20-30 part intercalator cesium acetate by weight stir, stirring velocity is 2400-2800r/min, churning time is 25-30min, carry out ultrasonic in feeding ultrasonic reactor, ultrasonic temperature is 80-88 DEG C, ultrasonic time is 5-15min, filter, pulverize, add 30-60 part p-Nitroaniline to stir, stirring velocity is 1500-1800r/min, churning time is 15-35h, centrifugal, add 15-35 part palmityl trimethyl ammonium chloride, 20-40 part p-Nitroaniline, 15-25 part water stirs, churning time is 20-40h, whipping temp is 55-65 DEG C, filter, washing, dry, 320-350 DEG C of calcining 1-2h is warming up to the speed of 0.5-1 DEG C/min from room temperature, 400-430 DEG C of calcining 1-2h is warming up to the speed of 1-2 DEG C/min, 570-600 DEG C of calcining 1-2h is warming up to the speed of 0.5-1.5 DEG C/min, room temperature is cooled to the speed of 1-3 DEG C/min, pulverizing obtains modified kaolin.
5. to remove the ageing-resistant heat-resisting oil resistant cable used for oil platform described in any one of 2-4 according to right, it is characterized in that, the weight ratio of gypsum, kaolin, microencapsulated powder oil, white carbon black, nano silicon and modified kaolin is 24-28:8-12:10-13:8-10:22-25:40-46.
6. will remove the ageing-resistant heat-resisting oil resistant cable used for oil platform described in any one of 2-5 according to right, it is characterized in that, the weight ratio of zinc oxide, magnesium oxide, lipid acid and tetramethyl-thiuram disulfide is 1.4-1.7:2-2.6:1.5-2.3:1-2.
7. will remove the ageing-resistant heat-resisting oil resistant cable used for oil platform described in any one of 2-6 according to right, it is characterized in that, the weight ratio of brominated butyl rubber, paracril and thiorubber is 30-36:8-13:20-25.
8. to remove the ageing-resistant heat-resisting oil resistant cable used for oil platform described in any one of 2-7 according to right, it is characterized in that, the raw material of described compounded rubber comprises by weight: brominated butyl rubber 30-36 part, paracril 8-13 part, thiorubber 20-25 part, zinc oxide 1.4-1.7 part, magnesium oxide 2-2.6 part, lipid acid 1.5-2.3 part, tetramethyl-thiuram disulfide 1-2 part, gypsum 24-28 part, diatomite 8-12 part, microencapsulated powder oil 10-13 part, white carbon black 8-10 part, nano silicon 22-25 part, modified kaolin 40-46 part, vinyltriethoxysilane 1.5-2.3 part, paraffin 1.5-1.8 part, rosin 2-3 part, stearic acid 1.6-2.2 part, white factice 1.4-2.4 part, dioctyl sebacate 1.5-2 part, D-50 anti-aging agent 1.2-1.5 part, phosphorous acid ester 1.5-1.8 part.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105694456A (en) * | 2016-03-17 | 2016-06-22 | 苏州科茂电子材料科技有限公司 | Corrosion-resistant cable sheath material and preparation method thereof |
CN106751837A (en) * | 2016-12-28 | 2017-05-31 | 德轮橡胶股份有限公司 | A kind of tire is with ageing-resistant abrasive rubber material |
CN107739474A (en) * | 2017-09-15 | 2018-02-27 | 安徽伙伴电气有限公司 | A kind of solar power generation special anti-aging cable |
CN114678167A (en) * | 2022-04-13 | 2022-06-28 | 天环线缆集团有限公司 | Waterproof aluminum alloy cable and preparation method thereof |
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CN1559974A (en) * | 2004-03-10 | 2005-01-05 | 中国科学院广州化学研究所 | Preparation process of modified china-clay for inserted layer |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105694456A (en) * | 2016-03-17 | 2016-06-22 | 苏州科茂电子材料科技有限公司 | Corrosion-resistant cable sheath material and preparation method thereof |
CN106751837A (en) * | 2016-12-28 | 2017-05-31 | 德轮橡胶股份有限公司 | A kind of tire is with ageing-resistant abrasive rubber material |
CN107739474A (en) * | 2017-09-15 | 2018-02-27 | 安徽伙伴电气有限公司 | A kind of solar power generation special anti-aging cable |
CN114678167A (en) * | 2022-04-13 | 2022-06-28 | 天环线缆集团有限公司 | Waterproof aluminum alloy cable and preparation method thereof |
CN114678167B (en) * | 2022-04-13 | 2023-10-27 | 天环线缆集团有限公司 | Waterproof aluminum alloy cable and preparation method thereof |
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Application publication date: 20151223 |