CN105175820A - Cable with fluorine-modified polyacrylate sheath layer - Google Patents
Cable with fluorine-modified polyacrylate sheath layer Download PDFInfo
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- CN105175820A CN105175820A CN201510420362.0A CN201510420362A CN105175820A CN 105175820 A CN105175820 A CN 105175820A CN 201510420362 A CN201510420362 A CN 201510420362A CN 105175820 A CN105175820 A CN 105175820A
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Abstract
The invention discloses a cable with a fluorine-modified polyacrylate sheath layer. The cable comprises a cable core and a sheath layer which coats the cable core. Raw materials of the sheath layer comprise, by weight, 32-35 parts of nitrile rubber 2707, 24-27 parts of fluorine-modified polyacrylate, 23-26 parts of ethylene propylene diene monomer, 13-16 parts of para-aramid fibers, 11-14 parts of furnace black, 17-20 parts of mica, 8-11 parts of sepiolite, 3-5 parts of a mono-alkoxy titanate coupling agent, 2.3-3.5 parts of sulphur, 1.5-1.8 parts of an accelerant TT, 2.2-2.5 parts of an accelerant DM, 1.1-1.4 parts of an anti-aging agent SP, 2.3-2.6 parts of an anti-aging agent RD, 0.7-1.1 parts of stearic acid, 7-11 parts of phenyl petroleum sulfonate and 1-3 parts of castor oil. The cable has good waterproofness and oil-proof performance, and has excellent weather fastness and corrosion resistance. The preparation process is simple and easy to operate, and reaction conditions are mild. The cable is convenient for industrial production.
Description
Technical field
The present invention relates to field of cable technology, particularly relate to a kind of cable with fluorine richness polyacrylic ester restrictive coating.
Background technology
Cable usually touches the water surrounding of occurring in nature in use; traditional cable does not often set up sfgd. to cause moisture to invade; destroy the molecular structure of cable outside surface; cable disintegration can be caused time serious; thus badly influencing the safe operating life of cable, the cable be more particularly laid on bottom rivers,lakes and seas more will in the face of this problem.Meanwhile, often containing a large amount of salinities, microorganism and some pollutents in natural water, these also can cause serious corrosion to the cable laid wherein.
Research finds, adds in CABLE MATERIALS, greatly can reduce the surface energy of cable by the material that some surface energy are extremely low, improve waterproof, oil preventing performance, but, how to improve weathering resistance, the erosion resistance of these materials further, there is no research with the performance strengthening cable.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of cable with fluorine richness polyacrylic ester restrictive coating, waterproof of the present invention, grease proofness are good, and possess excellent weathering resistance and corrosion resistance nature, preparation process is simple to operation and reaction conditions gentle, is convenient to suitability for industrialized production.
A kind of cable with fluorine richness polyacrylic ester restrictive coating that the present invention proposes, the restrictive coating comprising cable core and be coated on outside cable core; The raw material of restrictive coating comprises by weight: paracril 270732-35 part, fluorine richness polyacrylic ester 24-27 part, terpolymer EP rubber 23-26 part, para-aramid fiber 13-16 part, furnace treated black 11-14 part, mica powder 17-20 part, sepiolite 8-11 part, monoalkoxy type titanate coupling agent 3-5 part, sulphur 2.3-3.5 part, promotor TT1.5-1.8 part, altax 2.2-2.5 part, antioxidant SP 1.1-1.4 part, anti-aging agent RD 2.3-2.6 part, stearic acid 0.7-1.1 part, phenyl alkylsulfonate 7-11 part, Viscotrol C 1-3 part;
In the preparation process of fluorine richness polyacrylic ester, deionized water, perfluoroalkyl acrylate, silane coupling agent KH570, butyl acrylate, methyl methacrylate, lauryl methacrylate, hydroxyethyl methylacrylate, Potassium Persulphate, ammonium perfluorocaprylate, sodium lauryl sulphate are added in reaction vessel and stirs, raise reaction vessel and contents temperature thereof, carry out supersound process again and obtain material A, after continuing insulation, add potassium persulfate solution to containing in the reaction vessel of material A, insulation obtains fluorine richness polyacrylic ester.
Preferably, in the raw material of restrictive coating, the weight ratio of paracril 2707, fluorine richness polyacrylic ester, terpolymer EP rubber, para-aramid fiber is 33-34:25-26:24-25:14-15.
Preferably, the raw material of restrictive coating comprises by weight: paracril 270733-34 part, fluorine richness polyacrylic ester 25-26 part, terpolymer EP rubber 24-25 part, para-aramid fiber 14-15 part, furnace treated black 12-13 part, mica powder 18-19 part, sepiolite 9-10 part, monoalkoxy type titanate coupling agent 3.5-4 part, sulphur 2.6-3.2 part, promotor TT1.6-1.7 part, altax 2.3-2.4 part, antioxidant SP 1.2-1.3 part, anti-aging agent RD 2.4-2.5 part, stearic acid 0.8-1 part, phenyl alkylsulfonate 8-10 part, Viscotrol C 1.5-2 part.
Preferably, in the preparation process of restrictive coating Fluoride for Raw Material modified polyacrylate, by weight by 20-23 part deionized water, 2-4 part perfluoroalkyl acrylate, 2.5-3.5 part silane coupling agent KH570, 5-7 part butyl acrylate, 2-4 part methyl methacrylate, 2-4 part lauryl methacrylate, 0.5-0.8 part hydroxyethyl methylacrylate, 0.3-0.5 part Potassium Persulphate, 0.3-0.5 part ammonium perfluorocaprylate, 0.2-0.5 part sodium lauryl sulphate adds in reaction vessel and stirs, rising reaction vessel and contents temperature thereof are to 80-85 DEG C, carry out supersound process again and obtain material A, the time of supersound process is 30-35min, the frequency of supersound process is 35-38KHz, the power of supersound process is 1000-1200W, after continuing insulation 1.5-2h, with the speed of 1-2 part/min to being the potassium persulfate solution of 1-3wt% containing adding 10-13 part massfraction in the reaction vessel of material A, insulation 2-3h obtains fluorine richness polyacrylic ester.
Preferably, in the preparation process of restrictive coating Fluoride for Raw Material modified polyacrylate, the weight ratio of perfluoroalkyl acrylate, silane coupling agent KH570 is 2.5-3:2.8-3.2.
Preferably, in the preparation process of restrictive coating Fluoride for Raw Material modified polyacrylate, the weight ratio of butyl acrylate, methyl methacrylate, lauryl methacrylate, hydroxyethyl methylacrylate is 5.5-6:3-3.5:2.5-3:0.6-0.7.
Preferably, in the preparation process of restrictive coating Fluoride for Raw Material modified polyacrylate, by weight by 21-22 part deionized water, 2.5-3 part perfluoroalkyl acrylate, 2.8-3.2 part silane coupling agent KH570, 5.5-6 part butyl acrylate, 3-3.5 part methyl methacrylate, 2.5-3 part lauryl methacrylate, 0.6-0.7 part hydroxyethyl methylacrylate, 0.35-0.45 part Potassium Persulphate, 0.37-0.44 part ammonium perfluorocaprylate, 0.3-0.4 part sodium lauryl sulphate adds in reaction vessel and stirs, rising reaction vessel and contents temperature thereof are to 83-84 DEG C, carry out supersound process again and obtain material A, the time of supersound process is 31-33min, the frequency of supersound process is 36-37KHz, the power of supersound process is 1050-1100W, after continuing insulation 1.6-1.8h, with the speed of 1.5-2 part/min to being the potassium persulfate solution of 1.5-2wt% containing adding 11-12 part massfraction in the reaction vessel of material A, insulation 2.2-2.5h obtains fluorine richness polyacrylic ester.
The preparation process of restrictive coating of the present invention is as follows: preheating Banbury mixer, paracril 2707, fluorine richness polyacrylic ester, terpolymer EP rubber, para-aramid fiber are obtained rubber major ingredient in Banbury mixer banburying, triangle bag is played in process, continue to drop into furnace treated black, mica powder, sepiolite and monoalkoxy type titanate coupling agent, banburying obtains mixture A; Stearic acid, phenyl alkylsulfonate, Viscotrol C are added in the Banbury mixer of contain mixtures material A mixing, then add antioxidant SP, anti-aging agent RD is mixing, continue to add sulphur, promotor TT, altax banburying, mixing after, cooling discharge, obtains restrictive coating.
The present invention, using paracril 2707, fluorine richness polyacrylic ester, terpolymer EP rubber as major ingredient, substantially increases waterproof of the present invention, grease proofing, antifouling property, makes the present invention possess excellent weathering resistance, corrosion resistance nature, elasticity and mechanical property simultaneously; In the preparation process of fluorine richness polyacrylic ester, generate polypropylene ester with butyl acrylate, methyl methacrylate, lauryl methacrylate, hydroxyethyl methylacrylate polymerization, have that cementability is strong, the good feature of waterproof and oilproof performance; And the emulsification system that perfluoroalkyl acrylate, silane coupling agent KH570 can be formed at sodium lauryl sulphate, ammonium perfluorocaprylate and initiator potassium persulfate effect issue lactogenesis liquid copolyreaction generation perfluoroalkyl polyacrylate dispersion; Wherein, the surface energy of perfluoroalkyl acrylate is extremely low, among the loose webs structure being filled in polypropylene ester, greatly reduces the surface energy of cable, improve waterproof of the present invention, grease proofing and anti-pollution function,, meanwhile, due to, bond energy great C-F key short containing bond length, fluorine atom surrounds C-C major key thick and fast, form a spirane structure, protection carbon bond is not impacted, is destroyed, and makes the present invention possess excellent weathering resistance, chemical resistance, snappiness, anti-oxidant and good mechanical property; Silane coupling agent KH570 is also known as γ methyl allyl acyloxypropyl trimethoxysilane, to be evenly distributed among the present invention and the polymerizable acrylic monomer added with institute the present invention, what it contained enrich siloxane bond, silicon-carbon bonds is aggregated on the side chain of polypropylene ester, substantially increases toughness of the present invention, weathering resistance, wear resisting property; In emulsification system, ammonium perfluorocaprylate has and monomer and the similar fluoroalkyl of polymer phase, can greatly strengthen emulsifying effectiveness of the present invention; And sodium lauryl sulphate by chemical bonding on latex particle surface, can substantially increase stability of the present invention; The collision of ultrasonic disperse then further between promotion monomer molecule of the present invention, polymerization, optimize structure of the present invention, substantially increase waterproof of the present invention, grease proofness and weathering resistance, corrosion resistance nature; And the interpolation of para-aramid fiber, improve crosslinking degree of the present invention, enhance elasticity of the present invention, wear resisting property and mechanical property; The vulcanization system that sulphur, promotor TT, altax are formed has the advantages that sulfurate activity is high, curing time is short, and then improves cross-linking density of the present invention and crosslinking degree, enhances weathering resistance of the present invention, waterproof, grease proofing and corrosion resistance nature; The interpolation of furnace treated black, mica powder, sepiolite, add volume of the present invention on the one hand, reduce cost, on the other hand can under the effect of monoalkoxy type titanate coupling agent and lubricant phenyl alkylsulfonate, be dispersed in rubber major ingredient, greatly strengthen intensity of the present invention, weathering resistance and corrosion resistance nature; And phenyl alkylsulfonate can coordinate with stearic acid, make any surface finish of the present invention, be easy to depart from from mould, be beneficial to further processing treatment, can also with antioxidant SP, anti-aging agent RD with the use of, improve ageing-resistant and oxidation resistent susceptibility of the present invention; Viscotrol C uses as tenderizer, can improve the present invention plastic while, reduce material viscosity and mixing time temperature, improve intensity of the present invention, elongation and elasticity.
Accompanying drawing explanation
Fig. 1 is a kind of structural representation with the cable of fluorine richness polyacrylic ester restrictive coating that the present invention proposes.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
As shown in Figure 1, Fig. 1 is a kind of structural representation with the cable of fluorine richness polyacrylic ester restrictive coating that the present invention proposes.
With reference to Fig. 1, a kind of cable with fluorine richness polyacrylic ester restrictive coating that the present invention proposes, the restrictive coating 2 comprising cable core 1 and be coated on outside cable core;
The raw material of restrictive coating 2 comprises by weight: paracril 270735 parts, fluorine richness polyacrylic ester 24 parts, terpolymer EP rubber 26 parts, para-aramid fiber 13 parts, furnace treated black 14 parts, mica powder 17 parts, sepiolite 11 parts, monoalkoxy type titanate coupling agent 3 parts, 3.5 parts, sulphur, promotor TT1.5 part, altax 2.5 parts, antioxidant SP 1.1 parts, anti-aging agent RD 2.6 parts, stearic acid 0.7 part, phenyl alkylsulfonate 11 parts, Viscotrol C 1 part;
In the preparation process of fluorine richness polyacrylic ester, by weight by 23 parts of deionized waters, 2 parts of perfluoroalkyl acrylates, 3.5 parts of silane coupling agent KH570, 5 parts of butyl acrylates, 4 parts of methyl methacrylates, 2 parts of lauryl methacrylates, 0.8 part of hydroxyethyl methylacrylate, 0.3 part of Potassium Persulphate, 0.5 part of ammonium perfluorocaprylate, 0.2 part of sodium lauryl sulphate adds in reaction vessel and stirs, raise reaction vessel and contents temperature to 85 DEG C thereof, carry out supersound process again and obtain material A, the time of supersound process is 30min, the frequency of supersound process is 38KHz, the power of supersound process is 1000W, after continuing insulation 2h, with the speed of 1 part/min to being the potassium persulfate solution of 1wt% containing adding 13 parts of massfractions in the reaction vessel of material A, insulation 3h obtains fluorine richness polyacrylic ester.
Embodiment 2
A kind of cable with fluorine richness polyacrylic ester restrictive coating that the present invention proposes, the restrictive coating 2 comprising cable core 1 and be coated on outside cable core; The raw material of restrictive coating 2 comprises by weight: paracril 270732 parts, fluorine richness polyacrylic ester 27 parts, terpolymer EP rubber 23 parts, para-aramid fiber 16 parts, furnace treated black 11 parts, mica powder 20 parts, sepiolite 8 parts, monoalkoxy type titanate coupling agent 5 parts, 2.3 parts, sulphur, promotor TT1.8 part, altax 2.2 parts, antioxidant SP 1.4 parts, anti-aging agent RD 2.3 parts, stearic acid 1.1 parts, phenyl alkylsulfonate 7 parts, Viscotrol C 3 parts;
In the preparation process of fluorine richness polyacrylic ester, by weight by 20 parts of deionized waters, 4 parts of perfluoroalkyl acrylates, 2.5 parts of silane coupling agent KH570, 7 parts of butyl acrylates, 2 parts of methyl methacrylates, 4 parts of lauryl methacrylates, 0.5 part of hydroxyethyl methylacrylate, 0.5 part of Potassium Persulphate, 0.3 part of ammonium perfluorocaprylate, 0.5 part of sodium lauryl sulphate adds in reaction vessel and stirs, raise reaction vessel and contents temperature to 80 DEG C thereof, carry out supersound process again and obtain material A, the time of supersound process is 35min, the frequency of supersound process is 35KHz, the power of supersound process is 1200W, after continuing insulation 1.5h, with the speed of 2 parts/min to being the potassium persulfate solution of 3wt% containing adding 10 parts of massfractions in the reaction vessel of material A, insulation 2h obtains fluorine richness polyacrylic ester.
Embodiment 3
A kind of cable with fluorine richness polyacrylic ester restrictive coating that the present invention proposes, the restrictive coating 2 comprising cable core 1 and be coated on outside cable core; The raw material of restrictive coating 2 comprises by weight: paracril 270734 parts, fluorine richness polyacrylic ester 25 parts, terpolymer EP rubber 25 parts, para-aramid fiber 14 parts, furnace treated black 13 parts, mica powder 18 parts, sepiolite 10 parts, monoalkoxy type titanate coupling agent 3.5 parts, 3.2 parts, sulphur, promotor TT1.6 part, altax 2.4 parts, antioxidant SP 1.2 parts, anti-aging agent RD 2.5 parts, stearic acid 0.8 part, phenyl alkylsulfonate 10 parts, Viscotrol C 1.5 parts;
In the preparation process of fluorine richness polyacrylic ester, by weight by 22 parts of deionized waters, 2.5 parts of perfluoroalkyl acrylates, 3.2 parts of silane coupling agent KH570, 5.5 parts of butyl acrylates, 3.5 parts of methyl methacrylates, 2.5 parts of lauryl methacrylates, 0.7 part of hydroxyethyl methylacrylate, 0.35 part of Potassium Persulphate, 0.44 part of ammonium perfluorocaprylate, 0.3 part of sodium lauryl sulphate adds in reaction vessel and stirs, raise reaction vessel and contents temperature to 84 DEG C thereof, carry out supersound process again and obtain material A, the time of supersound process is 31min, the frequency of supersound process is 37KHz, the power of supersound process is 1050W, after continuing insulation 1.8h, with the speed of 1.5 parts/min to being the potassium persulfate solution of 1.5wt% containing adding 12 parts of massfractions in the reaction vessel of material A, insulation 2.5h obtains fluorine richness polyacrylic ester.
Embodiment 4
A kind of cable with fluorine richness polyacrylic ester restrictive coating that the present invention proposes, the restrictive coating 2 comprising cable core 1 and be coated on outside cable core; The raw material of restrictive coating 2 comprises by weight: paracril 270733 parts, fluorine richness polyacrylic ester 26 parts, terpolymer EP rubber 24 parts, para-aramid fiber 15 parts, furnace treated black 12 parts, mica powder 19 parts, sepiolite 9 parts, monoalkoxy type titanate coupling agent 4 parts, 2.6 parts, sulphur, promotor TT1.7 part, altax 2.3 parts, antioxidant SP 1.3 parts, anti-aging agent RD 2.4 parts, stearic acid 1 part, phenyl alkylsulfonate 8 parts, Viscotrol C 2 parts;
In the preparation process of fluorine richness polyacrylic ester, by weight by 21 parts of deionized waters, 3 parts of perfluoroalkyl acrylates, 2.8 parts of silane coupling agent KH570, 6 parts of butyl acrylates, 3 parts of methyl methacrylates, 3 parts of lauryl methacrylates, 0.6 part of hydroxyethyl methylacrylate, 0.45 part of Potassium Persulphate, 0.37 part of ammonium perfluorocaprylate, 0.4 part of sodium lauryl sulphate adds in reaction vessel and stirs, raise reaction vessel and contents temperature to 83 DEG C thereof, carry out supersound process again and obtain material A, the time of supersound process is 33min, the frequency of supersound process is 36KHz, the power of supersound process is 1100W, after continuing insulation 1.6h, with the speed of 2 parts/min to being the potassium persulfate solution of 2wt% containing adding 11 parts of massfractions in the reaction vessel of material A, insulation 2.2h obtains fluorine richness polyacrylic ester.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (7)
1. there is a cable for fluorine richness polyacrylic ester restrictive coating, it is characterized in that, comprise cable core (1) and be coated on the restrictive coating (2) outside cable core;
The raw material of restrictive coating (2) comprises by weight: paracril 270732-35 part, fluorine richness polyacrylic ester 24-27 part, terpolymer EP rubber 23-26 part, para-aramid fiber 13-16 part, furnace treated black 11-14 part, mica powder 17-20 part, sepiolite 8-11 part, monoalkoxy type titanate coupling agent 3-5 part, sulphur 2.3-3.5 part, promotor TT1.5-1.8 part, altax 2.2-2.5 part, antioxidant SP 1.1-1.4 part, anti-aging agent RD 2.3-2.6 part, stearic acid 0.7-1.1 part, phenyl alkylsulfonate 7-11 part, Viscotrol C 1-3 part;
In the preparation process of fluorine richness polyacrylic ester, deionized water, perfluoroalkyl acrylate, silane coupling agent KH570, butyl acrylate, methyl methacrylate, lauryl methacrylate, hydroxyethyl methylacrylate, Potassium Persulphate, ammonium perfluorocaprylate, sodium lauryl sulphate are added in reaction vessel and stirs, raise reaction vessel and contents temperature thereof, carry out supersound process again and obtain material A, after continuing insulation, add potassium persulfate solution to containing in the reaction vessel of material A, insulation obtains fluorine richness polyacrylic ester.
2. there is the cable of fluorine richness polyacrylic ester restrictive coating according to claim 1, it is characterized in that, in the raw material of restrictive coating (2), the weight ratio of paracril 2707, fluorine richness polyacrylic ester, terpolymer EP rubber, para-aramid fiber is 33-34:25-26:24-25:14-15.
3. there is the cable of fluorine richness polyacrylic ester restrictive coating according to claim 1 or 2, it is characterized in that, the raw material of restrictive coating (2) comprises by weight: paracril 270733-34 part, fluorine richness polyacrylic ester 25-26 part, terpolymer EP rubber 24-25 part, para-aramid fiber 14-15 part, furnace treated black 12-13 part, mica powder 18-19 part, sepiolite 9-10 part, monoalkoxy type titanate coupling agent 3.5-4 part, sulphur 2.6-3.2 part, promotor TT1.6-1.7 part, altax 2.3-2.4 part, antioxidant SP 1.2-1.3 part, anti-aging agent RD 2.4-2.5 part, stearic acid 0.8-1 part, phenyl alkylsulfonate 8-10 part, Viscotrol C 1.5-2 part.
4. there is the cable of fluorine richness polyacrylic ester restrictive coating according to any one of claim 1-3, it is characterized in that, in the preparation process of restrictive coating (2) Fluoride for Raw Material modified polyacrylate, by weight by 20-23 part deionized water, 2-4 part perfluoroalkyl acrylate, 2.5-3.5 part silane coupling agent KH570, 5-7 part butyl acrylate, 2-4 part methyl methacrylate, 2-4 part lauryl methacrylate, 0.5-0.8 part hydroxyethyl methylacrylate, 0.3-0.5 part Potassium Persulphate, 0.3-0.5 part ammonium perfluorocaprylate, 0.2-0.5 part sodium lauryl sulphate adds in reaction vessel and stirs, rising reaction vessel and contents temperature thereof are to 80-85 DEG C, carry out supersound process again and obtain material A, the time of supersound process is 30-35min, the frequency of supersound process is 35-38KHz, the power of supersound process is 1000-1200W, after continuing insulation 1.5-2h, with the speed of 1-2 part/min to being the potassium persulfate solution of 1-3wt% containing adding 10-13 part massfraction in the reaction vessel of material A, insulation 2-3h obtains fluorine richness polyacrylic ester.
5. there is the cable of fluorine richness polyacrylic ester restrictive coating according to any one of claim 1-4, it is characterized in that, in the preparation process of restrictive coating (2) Fluoride for Raw Material modified polyacrylate, the weight ratio of perfluoroalkyl acrylate, silane coupling agent KH570 is 2.5-3:2.8-3.2.
6. there is the cable of fluorine richness polyacrylic ester restrictive coating according to any one of claim 1-5, it is characterized in that, in the preparation process of restrictive coating (2) Fluoride for Raw Material modified polyacrylate, the weight ratio of butyl acrylate, methyl methacrylate, lauryl methacrylate, hydroxyethyl methylacrylate is 5.5-6:3-3.5:2.5-3:0.6-0.7.
7. there is the cable of fluorine richness polyacrylic ester restrictive coating according to any one of claim 1-6, it is characterized in that, in the preparation process of restrictive coating (2) Fluoride for Raw Material modified polyacrylate, by weight by 21-22 part deionized water, 2.5-3 part perfluoroalkyl acrylate, 2.8-3.2 part silane coupling agent KH570, 5.5-6 part butyl acrylate, 3-3.5 part methyl methacrylate, 2.5-3 part lauryl methacrylate, 0.6-0.7 part hydroxyethyl methylacrylate, 0.35-0.45 part Potassium Persulphate, 0.37-0.44 part ammonium perfluorocaprylate, 0.3-0.4 part sodium lauryl sulphate adds in reaction vessel and stirs, rising reaction vessel and contents temperature thereof are to 83-84 DEG C, carry out supersound process again and obtain material A, the time of supersound process is 31-33min, the frequency of supersound process is 36-37KHz, the power of supersound process is 1050-1100W, after continuing insulation 1.6-1.8h, with the speed of 1.5-2 part/min to being the potassium persulfate solution of 1.5-2wt% containing adding 11-12 part massfraction in the reaction vessel of material A, insulation 2.2-2.5h obtains fluorine richness polyacrylic ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510420362.0A CN105175820A (en) | 2015-07-15 | 2015-07-15 | Cable with fluorine-modified polyacrylate sheath layer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510420362.0A CN105175820A (en) | 2015-07-15 | 2015-07-15 | Cable with fluorine-modified polyacrylate sheath layer |
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| CN105175820A true CN105175820A (en) | 2015-12-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510420362.0A Pending CN105175820A (en) | 2015-07-15 | 2015-07-15 | Cable with fluorine-modified polyacrylate sheath layer |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440362A (en) * | 2015-12-30 | 2016-03-30 | 合肥星辰电线电缆股份有限公司 | Insulating material for railway vehicle cables |
| CN107629376A (en) * | 2017-06-08 | 2018-01-26 | 合肥华盖光伏科技有限公司 | A kind of photovoltaic generation water-proof cable and preparation method |
| WO2019127315A1 (en) * | 2017-12-28 | 2019-07-04 | 珠海市盛西源机电设备有限公司 | Highly stain-resistant acrylic solid surface material and preparation method therefor |
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| CN100545371C (en) * | 2006-12-07 | 2009-09-30 | 黄金伦 | Innovation hollow curtain wall |
| CN102041681A (en) * | 2009-10-14 | 2011-05-04 | 江南大学 | Method for preparing short-chain branch water and oil repellent finishing agent containing modified nano-oxide and fluorine |
| CN103524843A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Sheath material for signal controlling cable and preparation method thereof |
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- 2015-07-15 CN CN201510420362.0A patent/CN105175820A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100545371C (en) * | 2006-12-07 | 2009-09-30 | 黄金伦 | Innovation hollow curtain wall |
| CN102041681A (en) * | 2009-10-14 | 2011-05-04 | 江南大学 | Method for preparing short-chain branch water and oil repellent finishing agent containing modified nano-oxide and fluorine |
| CN103524843A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Sheath material for signal controlling cable and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440362A (en) * | 2015-12-30 | 2016-03-30 | 合肥星辰电线电缆股份有限公司 | Insulating material for railway vehicle cables |
| CN107629376A (en) * | 2017-06-08 | 2018-01-26 | 合肥华盖光伏科技有限公司 | A kind of photovoltaic generation water-proof cable and preparation method |
| WO2019127315A1 (en) * | 2017-12-28 | 2019-07-04 | 珠海市盛西源机电设备有限公司 | Highly stain-resistant acrylic solid surface material and preparation method therefor |
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Application publication date: 20151223 |