CN105174538B - The minimizing technology of aromatic sulphonic acid type organic in a kind of wastewater from chemical industry - Google Patents
The minimizing technology of aromatic sulphonic acid type organic in a kind of wastewater from chemical industry Download PDFInfo
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- CN105174538B CN105174538B CN201510584728.8A CN201510584728A CN105174538B CN 105174538 B CN105174538 B CN 105174538B CN 201510584728 A CN201510584728 A CN 201510584728A CN 105174538 B CN105174538 B CN 105174538B
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- waste water
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- magnesium
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- 239000002351 wastewater Substances 0.000 title claims abstract description 69
- 239000000126 substance Substances 0.000 title claims abstract description 20
- 125000003118 aryl group Chemical group 0.000 title claims abstract description 13
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000005516 engineering process Methods 0.000 title claims abstract description 9
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 17
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000008394 flocculating agent Substances 0.000 claims abstract description 9
- 239000010802 sludge Substances 0.000 claims abstract description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 12
- 239000003864 humus Substances 0.000 claims description 11
- 239000013049 sediment Substances 0.000 claims description 7
- 125000002091 cationic group Chemical group 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 4
- 230000003111 delayed effect Effects 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 16
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 abstract description 9
- 229940077388 benzenesulfonate Drugs 0.000 abstract description 9
- 239000002253 acid Substances 0.000 abstract description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 7
- 150000001768 cations Chemical class 0.000 abstract description 7
- 239000011777 magnesium Substances 0.000 abstract description 7
- 229910052749 magnesium Inorganic materials 0.000 abstract description 7
- FSTZWKIICVTWLA-UHFFFAOYSA-N benzenesulfonic acid;magnesium Chemical compound [Mg].OS(=O)(=O)C1=CC=CC=C1 FSTZWKIICVTWLA-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 239000000428 dust Substances 0.000 abstract description 3
- 238000005189 flocculation Methods 0.000 abstract description 3
- 230000016615 flocculation Effects 0.000 abstract description 3
- 238000005342 ion exchange Methods 0.000 abstract description 3
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 abstract description 3
- -1 aromatic sulphonic acid class Chemical class 0.000 abstract description 2
- XNEYCQMMVLAXTN-UHFFFAOYSA-N carbonic acid;magnesium Chemical compound [Mg].OC(O)=O XNEYCQMMVLAXTN-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002894 chemical waste Substances 0.000 abstract description 2
- RECVMTHOQWMYFX-UHFFFAOYSA-N oxygen(1+) dihydride Chemical group [OH2+] RECVMTHOQWMYFX-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002244 precipitate Substances 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 238000007654 immersion Methods 0.000 description 4
- 238000000643 oven drying Methods 0.000 description 4
- 238000011010 flushing procedure Methods 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 241001504664 Crossocheilus latius Species 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000009303 advanced oxidation process reaction Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention discloses a kind of minimizing technology of aromatic sulphonic acid type organic in wastewater from chemical industry, belong to technical field of waste water processing.The present invention is to soak the detritus acid in black mud by magnesium nitrate solution, form it into the sour magnesium of detritus, with benzene sulfonic acid sodium salt in waste water ion exchange generation benzene sulfonic acid magnesium occurs for detritus acid magnesium, carbonic acid magnesium precipitate is generated in the presence of sodium carbonate again, benzene sulfonic acid magnesium is separated out simultaneously, under the flocculation of cation PAC flocculants and PAM polyacrylamides, is precipitated together with riverway sludge flying dust, separated from solution, reach the purpose of removal.The beneficial effects of the invention are as follows：This method is good to the removal effect of aromatic sulphonic acid type organic in wastewater from chemical industry, and benzene sulfonate clearance is up to more than 98%, COD clearances up to more than 95%；Simple to operate, selectivity is strong, and operating cost is low, and processing procedure is pollution-free, has good development prospect in aromatic sulphonic acid class organic chemical waste water process field.
Description
Technical field
The present invention relates to a kind of minimizing technology of aromatic sulphonic acid type organic in wastewater from chemical industry, belong to wastewater processing technology neck
Domain.
Background technology
Aromatic sulphonic acid based compound, as a kind of important fine chemical product, is the indispensable former material of chemical industry
Material, its yield is considerable, be widely used in synthetic catalyst, emulsifying agent, lube oil additive, ion exchange resin and its
The raw material of his a variety of specialty chemicals, be prepare phenolic compound, dyestuff, medicine, leather retanning agent and agrochemical it is important in
Mesosome, but because its is complicated, production procedure length, side reaction be more, water solubility is strong, and a large amount of compositions are easily produced in production process
The organic chemical waste water of the higher aromatic sulphonic acid class of complicated, concentration.This kind of Wastewater Pollutant concentration is high, aromatic azochlorosulfonate acid compound
With hydrophilic sulfonic group, its water solubility is larger, and COD concentration is higher；Acid strong, color and luster is deep, and easily biological-degradable, not biochemical
Property is poor.Because its waste water yield is big, concentration is high, difficult, to the seriously polluted of environment, receive significant attention its processing means.
At present, the processing method of this kind of waste water is concentrated mainly on materializing strategy, including advanced oxidation processes, extraction and resin adsorption method,
But these methods are present, and energy consumption is big, operating cost is high, poor selectivity, treatment effeciency are low, secondary pollution problems.Due to benzene sulfonic acid
Salt is soluble in water, the bioremediation developed in recent years, and small water operational efficiency is high, and large-engineering is using very unstable, because of water quality
Water is difficult to constant, and microorganism is difficult to stable adaptation to the change such as phenyl ring and sulfonic acid group, causes microorganism moment high-volume dead
Die, the organic matter in waste water is difficult to remove.
The content of the invention
The technical problems to be solved by the invention：It is soluble in water for benzene sulfonate, and the presence of phenyl ring and sulfonic acid group
The drawbacks of being difficult to be removed by microorganism again, there is provided a kind of minimizing technology of aromatic sulphonic acid type organic in wastewater from chemical industry, the party
The detritus acid that method is extracted in black mud is soaked by magnesium nitrate solution, is formed it into the sour magnesium of detritus, detritus acid magnesium and waste water
Ion exchange generation benzene sulfonic acid magnesium occurs for benzene sulfonic acid sodium salt, then generates carbonic acid magnesium precipitate in the presence of sodium carbonate, while separating out benzene
Sulfonic acid magnesium, under the flocculation of cation PAC flocculants and PAM polyacrylamides, is precipitated, from molten together with riverway sludge flying dust
Separated in liquid, reach the purpose of removal.
In order to solve the above technical problems, the present invention is using technical scheme as described below：It is fragrant in a kind of wastewater from chemical industry
The minimizing technology of sulfonic acid type organic, its concrete operation step is：
(1) riverway sludge is taken, it is 8~10% to be dried at 90~95 DEG C to mud humidity, then stands and is cooled to room temperature,
And make lower leaf thereon, the thick mud of 3~5cm of upper strata is then removed, lower floor's mud is obtained；
(2) lower floor's mud clear water that processing is obtained is rinsed 1~2 time, removes the impurity of upper strata mud residual, be placed in
3~4h is dried in baking oven, it is 80~90 DEG C to control oven temperature, obtains lower floor's humus mud；
(3) dried lower floor's humus mud is placed in the magnesium nitrate solution that concentration is 0.08mol/L and soaked, immersion
Time is 1~2h, waits after the completion of soaking that exposure 1~2 day under sunshine teds once every 30~50min, treats that it is dried
Afterwards, it is placed in grinding mill and is milled into powder；
(4) wastewater from chemical industry by required processing is introduced into processing pond, surveys its pH value, if pH value of waste water is 6.0~7.0,
Directly handled, it is 6.0~7.0 to be adjusted if not in this range to pH value, and the powder for then obtaining above-mentioned processing is by 1
In~3g/L input waste water, and quickly stir, setting rotating speed is 3000r/min；
(5) sodium carbonate liquor that concentration is 1mol/L is added into waste water while stirring, when there is sediment in it,
Cation PAC flocculants are added, it is 300~500mg to make its every liter waste water cationic PAC flocculant concentration, setting rotating speed is
300r/min, stirs 30~50s；
(6) after the completion of to be mixed, then the addition PAM polyacrylamides into waste water, make PAM polyacrylamides in its every liter waste water
Amine concentration is 30~50mg, under the conditions of rotating speed is 300r/min, after 30~50s of stirring, rotating speed is reduced into 80r/min, entered
Row is slowly stirred, control mixing time 10~15min, it is to be mixed after the completion of, stand 3~5h, filtering, water outlet.
The principle of the present invention：Detritus acid in black mud is soaked by magnesium nitrate solution, forms it into the sour magnesium of detritus, rotten
Matter acid magnesium and benzene sulfonic acid sodium salt generation ion exchange generation benzene sulfonic acid magnesium in waste water, then generation magnesium carbonate sinks in the presence of sodium carbonate
Form sediment, while benzene sulfonic acid magnesium is separated out, under the flocculation of cation PAC flocculants and PAM polyacrylamides, together with riverway sludge
Flying dust is precipitated, and is separated from solution, is reached the purpose of removal.
The present invention is compared with other method, and advantageous effects are：
(1) this method is good to the removal effect of aromatic sulphonic acid type organic in wastewater from chemical industry, and benzene sulfonate clearance reaches
More than 98%, COD clearance are up to more than 95%；
(2) simple to operate, selectivity is strong, and operating cost is low, and processing procedure is pollution-free.
Embodiment
Riverway sludge is taken first, and it is 8~10% to be dried at 90~95 DEG C to mud humidity, then stands and is cooled to room
Temperature, and make lower leaf thereon, the thick mud of 3~5cm of upper strata is then removed, lower floor's mud is obtained；Obtained lower floor's mud will be handled
Rinsed 1~2 time with clear water, remove the impurity of upper strata mud residual, be placed in baking oven drying 3~4h, control the oven temperature to be
80~90 DEG C, obtain lower floor's humus mud；Then dried lower floor's humus mud is placed in the nitre that concentration is 0.08mol/L
Soaked in sour magnesium solution, soak time is 1~2h, is waited after the completion of soaking, exposure 1~2 day under sunshine, every 30~
50min is tedded once, after it is dried, and is placed in grinding mill and is milled into powder；Again by the wastewater from chemical industry introducing of required processing
Manage in pond, survey its pH value, if pH value of waste water is 6.0~7.0, is directly handled, adjusted if not in this range to pH
It is worth for 6.0~7.0, the powder for then obtaining above-mentioned processing is put into waste water by 1~3g/L, and is quickly stirred, rotating speed is set
For 3000r/min；The sodium carbonate liquor that concentration is 1mol/L is added into waste water while stirring, treats that it sediment occurs
When, cation PAC flocculants are added, it is 300~500mg to make its every liter waste water cationic PAC flocculant concentration, sets rotating speed
For 300r/min, 30~50s is stirred；After the completion of finally to be mixed, then the addition PAM polyacrylamides into waste water, make its every liter
PAM concentration of polyacrylamide is 30~50mg in waste water, under the conditions of rotating speed is 300r/min, after 30~50s of stirring, by rotating speed
Be reduced to 80r/min, be slowly stirred, control mixing time 10~15min, it is to be mixed after the completion of, stand 3~5h, filtering,
Water outlet.
Example 1
Riverway sludge is taken first, and it is 8% to be dried at 90 DEG C to mud humidity, then stands and is cooled to room temperature, and makes it
Upper lower leaf, then removes the thick mud of upper strata 3cm, obtains lower floor's mud；Obtained lower floor's mud clear water flushing 1 will be handled
It is secondary, the impurity of upper strata mud residual is removed, is placed in baking oven drying 3h, it is 80 DEG C to control oven temperature, obtains lower floor's humus
Mud；Then dried lower floor's humus mud is placed in the magnesium nitrate solution that concentration is 0.08mol/L and soaked, during immersion
Between be 1h, wait after the completion of soaking that exposure 1 day under sunshine teds once every 30min, after it is dried, is placed in grinding mill
In be milled into powder；The wastewater from chemical industry by required processing is introduced into processing pond again, surveys its pH value, if pH value of waste water is 6.0, is entered
Row is directly handled, and it is 6.0 to be adjusted if not in this range to pH value, and the powder for then obtaining above-mentioned processing is put into by 1g/L
In waste water, and quickly stir, setting rotating speed is 3000r/min；It is 1mol/L's to add concentration into waste water while stirring
Sodium carbonate liquor, when it sediment occurs, adds cation PAC flocculants, makes its every liter waste water cationic PAC flocculant
Concentration is 300mg, and setting rotating speed is 300r/min, stirs 30s；After the completion of finally to be mixed, then the addition PAM poly- third into waste water
Acrylamide, it is 30mg to make PAM concentration of polyacrylamide in its every liter waste water, under the conditions of rotating speed is 300r/min, stirs 30s
Afterwards, rotating speed is reduced to 80r/min, is slowly stirred, control mixing time 10min, it is to be mixed after the completion of, stand 3h, mistake
Filter, water outlet.
This method is good to the removal effect of aromatic sulphonic acid type organic in wastewater from chemical industry, can make benzene sulfonate concentration in waste water
34mg/L is reduced to from 2000mg/L, benzene sulfonate clearance is 98.3%；Organic concentration in waste water is set to be dropped from 3000mg/L
Low to arrive 44mg/L, COD clearances are 95.2%；Simple to operate, selectivity is strong, and operating cost is low, and processing procedure is pollution-free.
Example 2
Riverway sludge is taken first, and it is 9% to be dried at 92 DEG C to mud humidity, then stands and is cooled to room temperature, and makes it
Upper lower leaf, then removes the thick mud of upper strata 4cm, obtains lower floor's mud；Obtained lower floor's mud clear water flushing 2 will be handled
It is secondary, the impurity of upper strata mud residual is removed, is placed in baking oven drying 3.5h, it is 85 DEG C to control oven temperature, obtains lower floor's humic
Matter mud；Then dried lower floor's humus mud is placed in the magnesium nitrate solution that concentration is 0.08mol/L and soaked, immersion
Time is 1.5h, is waited after the completion of soaking, exposure 2 days under sunshine, is tedded once every 40min, after it is dried, is placed in stone roller
Powder is milled into grinding machine；The wastewater from chemical industry by required processing is introduced into processing pond again, surveys its pH value, if pH value of waste water is 6.5,
Then directly handled, it is 6.5 to be adjusted if not in this range to pH value, and the powder for then obtaining above-mentioned processing is by 2g/L
Put into waste water, and quickly stir, setting rotating speed is 3000r/min；It is 1mol/ to add concentration into waste water while stirring
L sodium carbonate liquor, when it sediment occurs, adds cation PAC flocculants, makes its every liter waste water cationic PAC wadding
Solidifying agent concentration is 400mg, and setting rotating speed is 300r/min, stirs 40s；It is last it is to be mixed after the completion of, then add into waste water PAM
Polyacrylamide, it is 40mg to make PAM concentration of polyacrylamide in its every liter waste water, under the conditions of rotating speed is 300r/min, stirring
After 40s, rotating speed is reduced to 80r/min, is slowly stirred, control mixing time 13min, it is to be mixed after the completion of, stand 4h,
Filtering, water outlet.
This method is good to the removal effect of aromatic sulphonic acid type organic in wastewater from chemical industry, can make benzene sulfonate concentration in waste water
45.5mg/L is reduced to from 3500mg/L, benzene sulfonate clearance is 98.7%；Make in waste water organic concentration from 4000mg/L
60mg/L is reduced to, COD clearances are 96%；Simple to operate, selectivity is strong, and operating cost is low, and processing procedure is pollution-free.
Example 3
Riverway sludge is taken first, and it is 10% to be dried at 95 DEG C to mud humidity, then stands and is cooled to room temperature, and makes it
Upper lower leaf, then removes the thick mud of upper strata 5cm, obtains lower floor's mud；Obtained lower floor's mud clear water flushing 2 will be handled
It is secondary, the impurity of upper strata mud residual is removed, is placed in baking oven drying 4h, it is 90 DEG C to control oven temperature, obtains lower floor's humus
Mud；Then dried lower floor's humus mud is placed in the magnesium nitrate solution that concentration is 0.08mol/L and soaked, during immersion
Between be 2h, wait after the completion of soaking that exposure 2 days under sunshine ted once every 50min, after it is dried, are placed in grinding mill
In be milled into powder；The wastewater from chemical industry by required processing is introduced into processing pond again, surveys its pH value, if pH value of waste water is 7.0, is entered
Row is directly handled, and it is 7.0 to be adjusted if not in this range to pH value, and the powder for then obtaining above-mentioned processing is put into by 3g/L
In waste water, and quickly stir, setting rotating speed is 3000r/min；It is 1mol/L's to add concentration into waste water while stirring
Sodium carbonate liquor, when it sediment occurs, adds cation PAC flocculants, makes its every liter waste water cationic PAC flocculant
Concentration is 500mg, and setting rotating speed is 300r/min, stirs 50s；After the completion of finally to be mixed, then the addition PAM poly- third into waste water
Acrylamide, it is 50mg to make PAM concentration of polyacrylamide in its every liter waste water, under the conditions of rotating speed is 300r/min, stirs 50s
Afterwards, rotating speed is reduced to 80r/min, is slowly stirred, control mixing time 15min, it is to be mixed after the completion of, stand 5h, mistake
Filter, water outlet.
This method is good to the removal effect of aromatic sulphonic acid type organic in wastewater from chemical industry, can make benzene sulfonate concentration in waste water
35mg/L is reduced to from 5000mg/L, benzene sulfonate clearance is 99.3%；Organic concentration in waste water is set to be dropped from 5000mg/L
Low to arrive 60mg/L, COD clearances are 96.8%；Simple to operate, selectivity is strong, and operating cost is low, and processing procedure is pollution-free.
Claims (1)
1. the minimizing technology of aromatic sulphonic acid type organic in a kind of wastewater from chemical industry, it is characterised in that concrete operation step is：
(1) riverway sludge is taken, it is 8~10% to be dried at 90~95 DEG C to mud humidity, then stands and is cooled to room temperature, and makes
Lower leaf thereon, then removes the thick mud of 3~5cm of upper strata, obtains lower floor's mud；
(2) lower floor's mud clear water that processing is obtained is rinsed 1~2 time, removes the impurity of upper strata mud residual, be placed in baking oven
Middle 3~4h of drying, it is 80~90 DEG C to control oven temperature, obtains lower floor's humus mud；
(3) dried lower floor's humus mud is placed in the magnesium nitrate solution that concentration is 0.08mol/L and soaked, soak time
For 1~2h, wait after the completion of soaking that exposure 1~2 day under sunshine teds once every 30~50min, after it is dried, put
Powder is milled into grinding mill；
(4) wastewater from chemical industry by required processing is introduced into processing pond, surveys its pH value, if pH value of waste water is 6.0~7.0, is carried out
Directly handle, it is 6.0~7.0 to be adjusted if not in this range to pH value, the powder for then obtaining above-mentioned processing by 1~
In 3g/L input waste water, and quickly stir, setting rotating speed is 3000r/min；
(5) sodium carbonate liquor that concentration is 1mol/L is added into waste water while stirring, when it sediment occurs, is added
Cation PAC flocculants, it is 300~500mg to make its every liter waste water cationic PAC flocculant concentration, and setting rotating speed is 300r/
Min, stirs 30~50s；
(6) after the completion of to be mixed, then the addition PAM polyacrylamides into waste water, make PAM polyacrylamides in its every liter waste water dense
Spend for 30~50mg, under the conditions of rotating speed is 300r/min, after 30~50s of stirring, rotating speed is reduced to 80r/min, delayed
Slow stirring, control mixing time 10~15min, it is to be mixed after the completion of, stand 3~5h, filtering, water outlet.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1500422A1 (en) * | 2003-07-25 | 2005-01-26 | Georg Dipl. Ing. Dr. Husz | Filter body for cleaning contaminated surface water in the form of a ground profile acting as a filter |
| CN101037287A (en) * | 2007-03-05 | 2007-09-19 | 清华大学 | Method of resource protection, decrement treatment of town sewage and sludge |
| CN101041599A (en) * | 2007-03-08 | 2007-09-26 | 上海交通大学 | Method for treating sulfur-heavy metal containing waste gas with by-product of compound fertilizer by humic acid |
| CN101905994A (en) * | 2010-06-22 | 2010-12-08 | 山东省科学院新材料研究所 | Method for extracting humic acid liquid fertilizer with rich trace elements from sludge |
Family Cites Families (1)
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|---|---|---|---|---|
| KR20070018192A (en) * | 2005-08-09 | 2007-02-14 | 주식회사 파이닉스알엔디 | Processing method of high thickness organic sewage by sequencing and Batch type AB SAcksang-Busick-System |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1500422A1 (en) * | 2003-07-25 | 2005-01-26 | Georg Dipl. Ing. Dr. Husz | Filter body for cleaning contaminated surface water in the form of a ground profile acting as a filter |
| CN101037287A (en) * | 2007-03-05 | 2007-09-19 | 清华大学 | Method of resource protection, decrement treatment of town sewage and sludge |
| CN101041599A (en) * | 2007-03-08 | 2007-09-26 | 上海交通大学 | Method for treating sulfur-heavy metal containing waste gas with by-product of compound fertilizer by humic acid |
| CN101905994A (en) * | 2010-06-22 | 2010-12-08 | 山东省科学院新材料研究所 | Method for extracting humic acid liquid fertilizer with rich trace elements from sludge |
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