CN105163711B - Emulsifying hair cosmetic composition - Google Patents
Emulsifying hair cosmetic composition Download PDFInfo
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- CN105163711B CN105163711B CN201480025142.1A CN201480025142A CN105163711B CN 105163711 B CN105163711 B CN 105163711B CN 201480025142 A CN201480025142 A CN 201480025142A CN 105163711 B CN105163711 B CN 105163711B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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Abstract
A kind of emulsifying hair cosmetic composition, it contains：(A) cationic surfactant, (B) higher alcohol, (C) L histidines, (D) L arginine and 0.1~0.5 mass % (E) water-soluble high-molecular compound, (C), total combined amount of (D) composition and mass ratio are as follows：(C) 0.01~0.5 mass %, (D) 0.01~0.5 mass %, (C)+(D)=0.05~0.6 mass %, (C)/(D)=0.2~5.
Description
Technical field
The present invention relates to the outstanding emulsifying hair cosmetic composition of a kind of hair internal repair and emulsion stability.
Background technology
It is hair interior void, crude and stick up the problems such as sticking up and become because hair-waving processing, dyeing processing, age increase etc.
Substantially.In the past, it is known to use the emulsifying hair cosmetic composition such as wash type hair conditioner Huo treatment waxes, by the amino for making low molecule amount
Acid is impregnated into inside hair, is provided the technology of moisturizing for hair, is suppressed crude technology (Japanese Patent Laid-Open 2007-8884
Number publication, Japanese Patent Laid-Open 2011-84584 publications, Japanese Patent Laid-Open 2011-195553 publications).
But, in order that amino acid is impregnated into inside hair, it is necessary to increase the combined amount of amino acid, and if amino acid it is mixed
Resultant is excessive, and emulsion stability can be deteriorated.Thus, in the emulsifying hair cosmetic composition containing amino acid simultaneously, it is difficult to realize
Emulsion stability and amino acid are to the impregnability inside hair.
Prior art literature
Patent document
Patent document 1：Japanese Patent Laid-Open 2007-8884 publications
Patent document 2：Japanese Patent Laid-Open 2011-84584 publications
Patent document 3：Japanese Patent Laid-Open 2011-195553 publications
The content of the invention
Problems to be solved by the invention
Based on above-mentioned situation, it can obtain emulsion stability it is an object of the invention to provide one kind and improve amino acid
To the emulsifying hair cosmetic composition for being impregnated with and realizing hair repairing effect inside hair.
The method solved the problems, such as
The present inventor concentrates on studies in order to achieve the above object, as a result finds (E) water-soluble high-molecular compound
Emulsion stability is improved in the emulsification composition containing amino acid, and is found by the way that (C) L-Histidine and (D) is applied in combination
L-arginine, compared with situation about being each used alone, even if the combined amount of amino acid is few, amino acid is to being impregnated with inside hair
Also increase, realize hair repairing effect, this completes the present invention.
Therefore, the present invention provides a kind of emulsifying hair cosmetic composition.
[1] a kind of emulsifying hair cosmetic composition, it contains：(A) cationic surfactant, (B) higher alcohol, (C) L- groups
(E) water-soluble high-molecular compound of propylhomoserin, (D) L-arginine and 0.1~0.5 mass %, (C), the mixing of (D) composition
Amount and mass ratio are as follows：
(C) 0.01~0.5 mass %
(D) 0.01~0.5 mass %
(C)+mass % of (D)=0.05~0.6, (C)/(D)=0.2~5.
[2] the emulsifying hair cosmetic composition as described in [1], wherein, the cosmetics are further containing (F) containing amino acid
Aliphatic acid ester oil.
[3] the emulsifying hair cosmetic composition as described in [1] or [2], wherein, the cosmetics are to make before hair-washing composition
Prewashing hair style cosmetics.
The effect of invention
, can be in good same of emulsion stability in the emulsifying hair cosmetic composition containing amino acid according to the present invention
Shi Tigao amino acid improves hair repairing effect to being impregnated with inside hair.
Embodiment
Hereinafter, the present invention will be described in detail.
The emulsifying hair cosmetic composition of the present invention contains：(A) cationic surfactant, (B) higher alcohol, (C) L- group ammonia
(E) water-soluble high-molecular compound of acid, (D) L-arginine and 0.1~0.5 mass %, (C), the combined amount of (D) composition
And mass ratio is as follows：(C) 0.01~0.5 mass %, (D) 0.01~0.5 mass %, (C)+(D)=0.05~0.6 matter
% is measured, (C)/(D) mixing quality ratio is 0.2~5.
(A) cationic surfactant
As long as cationic surfactant can be mixed into the cationic surfactant in hair cosmetic composition, do not have
Especially limit, can be used alone one kind or be combined as two or more use.It is used as cationic surfactant, example
Alkyl trimethyl ammonium salt, dialkyl dimethyl ammonium salt, alkylammonium salt, benzene can such as be enumerated and prick ammonium salt, benzyl rope ammonium salt, pyridiniujm,
Imidazoline salt, fatty acid amide etc..As the counter ion counterionsl gegenions of these cationic surfactants, halide ion, first can be enumerated
Base sulfate ion (CH3OSO3 -), ethyl sulfuric acid radical ion (CH3CH2OSO3 -) etc..Wherein, from emulsion stability, preferably
INCROQUAT TMC-80, dimethylaminopropyl stearic amide.
From to crude inhibition aspect, relative to the total amount of emulsifying hair cosmetic composition, cationic surface is lived
The combined amount of property agent is usually 1~4 mass %, preferably 1.2~3 mass %.
(B) higher alcohol
As long as higher alcohol can be mixed into the higher alcohol in hair cosmetic composition, it is not particularly limited, can be independent
Using a kind of or be combined as two or more use.As higher alcohol, preferably carbon number is 12~22 higher alcohol, more
It is preferred that carbon number is 18~22 higher alcohol.Laruyl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl can for example be enumerated
Alcohol, hexadecanol, oleyl alcohol, isooctadecanol, hexyl dodecanol, octyldodecanol, cetostearyl alcohol etc..Wherein, it is steady from emulsification
Qualitative aspect is set out, preferably stearyl alcohol, docosyl alcohol.
From to crude inhibition aspect, relative to the total amount of emulsifying hair cosmetic composition, the mixing of higher alcohol
Amount is usually 2~10 mass %, preferably 3~8 mass %.
In the present invention, by the way that (C) L-Histidine and (D) L-arginine is applied in combination with specified quantitative, special ratios, in scheme
While seeking emulsion stability, the amino acid that can not be obtained when can obtain exclusive use is to the notable effect being impregnated with inside hair
Really, hair repairing effect is significantly played.
Effect is impregnated with from amino acid to inside hair, to crude inhibition, emulsion stability angle, relatively
In the total amount of emulsifying hair cosmetic composition, the combined amount of (C) L-Histidine is 0.01~0.5 mass %, preferably 0.02~0.3
Quality %.If less than 0.01 mass %, amino acid is impregnated with effect and not enough to crude inhibition to inside hair,
If more than 0.5 mass %, emulsion stability is poor, causes water to separate.
Effect is impregnated with from amino acid to inside hair, to crude inhibition, emulsion stability angle, relatively
In the total amount of emulsifying hair cosmetic composition, (C)+(D) total combined amount is 0.05~0.6 mass %, preferably 0.1~0.4 matter
Measure %, more preferably 0.3~0.4 mass %.If total combined amount is less than 0.05 mass %, amino acid is to being impregnated with inside hair
Effect and not enough to crude inhibition, if more than 0.6 mass %, emulsion stability is poor, causes water to separate.
Effect is impregnated with from amino acid to inside hair, to crude inhibition angle, (C)/(D) mixing matter
Amount is than being 0.2~5, preferably 0.5~2.If outside 0.2~5 scope, amino acid to inside hair be impregnated with effect and
It is not enough to crude inhibition.
(E) water-soluble high-molecular compound
It is used as water-soluble high-molecular compound, preferably methylcellulose, ethyl cellulose, methylhydroxypropylcellulose, hydroxyl
The cellulose family macromolecule compounds such as ethyl cellulose, the salt of hydroxypropyl cellulose and these materials, sodium carboxymethylcellulose.
Wherein, from emulsion stability, preferably hydroxyethyl cellulose, hydroxypropyl cellulose.
From the angle of emulsion stability, relative to the total amount of emulsifying hair cosmetic composition, water soluble polymer chemical combination
The combined amount of thing is 0.1~0.5 mass %, preferably 0.2~0.4 mass %.
(F) aliphatic acid ester oil containing amino acid
The present invention emulsifying hair cosmetic composition in, from amino acid to hair inside be impregnated with effect, to crude suppression
Effect processed, the angle of emulsion stability are set out, and preferably individually mixing is a kind of or is combined as mixing two or more (F) containing ammonia
The aliphatic acid ester oil of base acid.From increase angle of the amino acid to the amounts of saturation inside hair, the fat containing amino acid is used as
Acid esters oil, preferred amino acid derivative can for example enumerate N- lauroyl-Pidolidone two (phytosterol/2- octyldodecyls
Base alcohol) ester, N- lauroyl-Pidolidone two (cholesterine/docosyl alcohol/octyldodecyl alcohol) ester, N- lauroyl-Pidolidone
Two (cholesterine/octyldodecyl alcohol) esters, N- lauroyl-Pidolidone two (phytosterol/behenyl alcohols/2- octyldodecyls
Base alcohol) ester, N- Hamposyl Ls isopropyl ester, N- lauroyl-Pidolidone dioctyldodecyl base ester etc..Wherein, from raising
Amino acid sets out to the be impregnated with effect, raising inside hair to crude inhibition angle, preferably N- lauroyl-Pidolidone
Two (phytosterol/2- octyldodecyls alcohol) esters, N- lauroyl-Pidolidone two (phytosterol/behenyl alcohols/2- octyl groups ten
Dialkyl group alcohol) ester.
Effect is impregnated with from amino acid to inside hair, to crude inhibition, emulsion stability angle, relatively
In the total amount of emulsifying hair cosmetic composition, the combined amount of the aliphatic acid ester oil containing amino acid is preferably 0.1~1 mass %, more excellent
Elect 0.2~0.8 mass % as.If in more than 0.1 mass %, can further play aliphatic acid ester oil of the mixing containing amino acid
Effect, i.e. amino acid are impregnated with effect, to crude inhibition, emulsion stability effect to inside hair, if more than 1 matter
% is measured, emulsion stability may be influenceed.
In addition, in order to utilize (F) composition to promote amino acid to be impregnated with effect to inside hair, relative to emulsifying hair
The total amount of cosmetic, (C)+(D) total combined amount is 0.05~0.6 mass %, preferably 0.1~0.4 mass %.
Emulsifying hair cosmetic composition can be prepared conventionally, in the range of the effect of the present invention is not destroyed, be removed
Outside mentioned component, it can be used alone or be combined as in appropriate amount to take care of hair using the two or more wash types that are generally used for
The composition of element, hair conditioner, treatment waxes.Hydrocarbon ils, ester oil, wax class, silicone oil can for example be enumerated (for example, relative to emulsifying hair
Cosmetics total amount, content is 0.1~30 mass %), amphoteric surfactant, non-ionic surface active is (for example, relative to emulsification
Type hair cosmetic composition total amount, content be 0.05~2 mass %), amphoteric surfactant, Semi-polar surfactants, polyalcohol
It is (for example, relative to emulsifying hair cosmetic composition total amount, content is 3~20 mass %), ultra-violet absorber, tackifier, organic
The water compositions such as salt, carbohydrate, lower alcohol, water are (for example, relative to emulsifying hair cosmetic composition total amount, content is 40~96 matter
Measure %), the antiinflammatory such as the anti-dandruff agent such as piroctone olamine salt, ZPT, dipotassium glycyrrhizinate, p-hydroxybenzoate,
The pearling agents such as the preservatives such as KF88 CG, pH adjusting agent, di-fatty acid esters, opacifiers, freshener, vitamin, plant carry
Take hydrotropic agent outside the Cosmetic Ingredients such as thing and plant essence, spices, powder, polyalcohol etc.., can be with pH adjusting agent
Phosphoric acid, citric acid, malic acid, lactic acid, amino acid, trisodium citrate, ammonium lactate is suitably used to adjust to 3~5 (25 DEG C).This
Outside, pH is the value determined with pH meter HM-30G (DKK Toa Corp.).
Emulsifying in the emulsifying hair cosmetic composition of the present invention refers to one in immiscible liquid phase with small
Formulation of the droplet distribution in another phase, refers in particular to the O/W breasts that dispersed phase is oil phase, continuous phase is aqueous phase in the present invention
Liquid.
The emulsifying hair cosmetic composition of the present invention contains (A) cationic surfactant, (B) higher alcohol, therefore is to remove to wash
Send out the smearing inorganic agent outside composition and hair dye.As the classification for smearing inorganic agent, wash type hair conditioner, shield can be enumerated
Send out Su, treatment waxes etc..
The present invention emulsifying hair cosmetic composition for being handled by hair-waving, hair dyeing processing, the age increase etc. caused by be damaged
Hair can obtain more significant effect, therefore be preferably applied to damaged hair.
The present invention emulsifying hair cosmetic composition can be applied to hair after being had one's hair wash with hair-washing composition, can also with
Use, i.e., used as prewashing hair style emulsifying hair cosmetic composition before hair-washing composition hair washing.At emulsifying hair cosmetic composition
Manage after hair, water or hot water injection can be used, can not also be rinsed, but preferably use hot water injection.When as prewashing hair style breast
During change type hair cosmetic composition, in the good scope of emulsion stability, amino acid is improved to being impregnated with inside hair obtaining
While improving hair repairing effect such effect, these effects can not be destroyed, further obtains and assigns the fluffy sense of overhead
Effect.Alternatively, it is also possible to using prewashing hair style emulsifying hair cosmetic composition and hair-washing composition as a set of.
As long as hair-washing composition can have one's hair wash, it is not particularly limited, preferably comprises (a) anion surface active
Agent.
(a) anion surfactant
As long as cleaning of the anion surfactant used in the present invention available for scalp and hair, without special
Ground is limited, and be can be used alone a kind of or is suitably used in combination of two or more.It is used as anion surfactant, Ke Yiju
Go out alkylsulfonate, alkyl sulfate, acylated amino hydrochlorate, polyoxyethylene alkyl ether sulfate salt, alkylbenzenesulfonate, N- acyls
Base-N methyl taurine salt, alpha-alkene sulfonate, higher fatty acids sulfonated ester, alkyl ether acetates, polyoxyethylene alkyl ether
Acetate, fatty acid soaps, alkyl phosphate salt, N- lauroyl glutamates, N- palmityls glutamate, N- lauroyls-N-
Ethyl glycine salt, N- Hamposyl Ls salt, N- myristoyls-Beta-alanine salt.Wherein, preferred polyoxyethylene alkyl ether
Sulfate (AES).As salt, alkali metal, alkaline-earth metal, ammonium salt, alkanol amine salt or alkaline amino acid salt can be enumerated, from bubble
Foam amount, low-temperature stability angle are set out, preferably the alkali metal such as sodium, calcium, especially more preferably sodium.Never stick greasy, overhead fluffy
Sense angle is set out, and preferably the average addition molal quantity of polyoxyethylene (E.O.) is 1~5, more preferably 1~3 polyoxyethylene alkane
Base ether sulfate.Specifically, preferably polyoxyethylene laurel ether sodium sulphate (2E.O.), polyoxyethylene laurel ether sodium sulphate
(3E.O.)。
From the cleaning force and the fluffy sense angle of overhead of hair washing, relative to hair-washing composition total amount, cation form
The combined amount of face activating agent is preferably 3~20 mass %, more preferably 12~20 mass %.
Hair-washing composition can be prepared conventionally, do not destroy the present invention effect in the range of, except it is above-mentioned must
Outside palpus composition, it can in appropriate amount be used alone a kind of or be combined as using two or more in common hair-washing composition
The composition used.For example, as solubilizer, can enumerate the polyalcohols such as the lower alcohols such as ethanol, isopropanol, propane diols, sorbierite,
Cationic surfactant, polyoxyethylene (24E.O.) polyoxypropylene (24E.O.) glycerin ether, polyglyceryl laurate etc. it is non-from
It is the chelating agents such as the thickeners such as sub- surfactant, oil, carboxymethyl cellulose, hydroxyethyl cellulose, citric acid, EDTA, two different
The milky white agent such as glycol stearate or fish scale, mica sheet, pigment, anti-corrosion/mould inhibitor, freshener, plant extracts, perfume (or spice)
Material/flavor compositions etc..On pH adjusting agent, phosphoric acid, citric acid, malic acid, lactic acid, amino acid, lemon can be suitably used
Lemon acid trisodium, ammonium lactate etc. are adjusted to 4.5~9 (25 DEG C).In addition, pH is surveyed with pH meter HM-30G (DKK Toa Corp.)
Fixed value.
The container of each composition is not particularly limited, except aluminium lamination pressure pipe, EVAL pipes, aluminum pipe, glass evaporation plastic tube
Outside pipe, can also enumerate make use of machinery or pressure difference distribution container and extruding container, lamination film container, injection type container,
Rod-like container, flask etc..The laminated film of aluminium lamination pressure pipe generally has more than 2 layers of a multilayer, its material preferably by polyethylene,
Polyethylene terephthalate, polyester, Biaxially oriented polypropylene, tensionless winkler foundation polypropylene, polyacrylonitrile, ethane-acetic acid ethyenyl
The synthetic resin such as ester copolymer, paper, aluminium-vapour deposition plastics etc. are constituted.In view of intensity, flexibility, weatherability etc., typically using 2~
5 layers of laminated film.As the material of flask, it can be used with individual layer or 2 layers of combination of the above use polyethylene, polypropylene, gathered
Ethylene glycol terephthalate, polystyrene, polyvinyl chloride, ethylene-vinyl alcohol resin, acrylonitrile-styrene resin, ABS trees
Fat, polyamide and glass etc..
Embodiment
Embodiment is given below and comparative example illustrates the present invention, but the present invention is not limited to following embodiments.This
Outside, when in following examples without special instruction, " % " in composition represents quality %, and ratio represents mass ratio.Embodiment and ratio
Compared with each composition in example in addition to plant extracts, hydrolysis extract amount for pure composition conversion amount (in addition, siloxanes miscella
The amount of dimethyl polysiloxane is represented, amodimethicone represents aminoethylaminopropyl siloxanes-dimethyl-silicon
The amount of siloxane copolymers), plant extracts, hydrolysis extract represent the combined amount of former state.
[embodiment 1~65, comparative example 1~23]
Conventionally prepare constituted shown in following table emulsifying hair cosmetic composition (the Wei treatment waxes of embodiment 4~5,
Other embodiments and comparative example are hair conditioner) (pH3.8), hair-washing composition (pH4.5~9), carry out following evaluate.Except implementation
The use of order is hair-washing composition → emulsifying hair cosmetic composition outside example 57~65；Embodiment 57~65 using order be
Emulsifying hair cosmetic composition → hair-washing composition.
[amino acid is to the amounts of saturation inside hair：Evaluation method and standard]
<Method>
(1) it is damaged the preparation method of topknot
Once hair-waving processing, 2 bleachings are carried out to individual human hair (10g, 15cm), impaired topknot is used as.
(i) hair-waving is handled：1 dose of 10g agent for permanent hair waving is smeared on individual human hair (10g, 15cm), 15 points are placed at room temperature
Clock.It is washed with water after topknot, smears 2 doses of 10g agent for permanent hair waving, places 10 minutes at room temperature.Finally, with 1g 27% polyoxyethylene
Bay ether sodium sulfate (2E.O.) is cleaned, and is air-dried at room temperature after washing.
(ii) bleaching：1 dose of 2.5g bleaching agents are smeared on hair (10g, 15cm) after hair-waving processing and 7.5g floats
The mixed liquor of white 2 doses of agent, is placed 15 minutes at room temperature.Then, with 1g 27% polyoxyethylene laurel ether sodium sulphate
(2E.O.) is cleaned, and after being air-dried at room temperature after washing, bleaching is carried out again.
The hair treating agent used is as follows.
I. (IRIYA COSMETICS manufactures) is bleached
1 dose：The bright-coloured high fine and smooth powder of bleaching of stirring foaming
2 doses：The bright-coloured high bleaching note oxygen cream of stirring foaming
Ii hair-wavings (Japanese Co., Ltd. of L'Oreal manufacture)
1 dose：Dulcia Tonica AHA hair-waving superfine are particular for reluctant hair
2 doses：Dulcia Tonica AHA hair-waving superfine are particular for reluctant hair
Iii shampoos (lion king manufacture)
Plant story shampoo：Salubrious fluffy Europe fusion (anion surfactant：Polyoxyethylene laurel ether sulfuric acid
The mass % of sodium (2E.O.) 15.0)
(2) it is damaged the processing method of topknot
I. the situation used according to the order of hair-washing composition → emulsifying hair cosmetic composition
By impaired topknot (15cm) with warm water soak 30 seconds after, to 10g hairs on equably smear 1g shampoos, with 1 time/
The speed of second is combed 60 times, is rinsed 25 times with the speed of 1 time/2 seconds when combing.Then, 1g emulsifying hairs are equably smeared
Cosmetics, after being combed 60 times with the speed of 1 time/second, stand 1 minute.After standing, rushed with the speed of 1 time/2 seconds when combing
Wash 20 times, then dry.The topknot after 7 operations be would be repeated for as hair sample.
Ii. the situation handled according to the order of emulsifying hair cosmetic composition → hair-washing composition
By impaired topknot (15cm) with warm water soak 30 seconds, to 10g hairs on equably smear 1g emulsifyings hair cosmetic
Product, are combed 60 times with the speed of 1 time/second, stand 1 minute, are rinsed 20 times with the speed of 1 time/2 seconds when combing.Then, uniformly
1g shampoos are smeared on ground, are combed 60 times with the speed of 1 time/second, are rinsed 25 times, dried when combing with the speed of 1 time/2 seconds.Will
Repeat the topknot after 7 operations as hair sample.
(3) quantitative approach for the amino acid being impregnated into inside hair
I. weigh after hair sample, crushed to 2mL vibrations and hair sample and zirconium oxide bead (diameter 5mm × 2 are added in pipe
Individual, diameter 3mm × 3), add 500 μ L methanol, carry out vibration crushing (1,500rpm, 5 minutes, Shake Master neo；
Bms companies).After crushing, 200 μ L water and 500 μ L chloroforms are added, is stirred 30 seconds, is centrifuged with desk centrifuge with eddy mixer
Separate 1 minute (liquid-liquid extraction operation).After upper strata (water/methanol layer) is recovered in 1.5mL microcentrifugal tubes, to remaining
200 μ L water are added in lower floor's (chloroform layer), above-mentioned liquid-liquid extraction operation is repeated 2 times.400 μ L are added into the water layer of recovery
Methanol, vacuum distillation removes solvent at 45 DEG C.Residue is re-dissolved in 100 μ L water, filter is filtered into (the μ L of φ 0.45, water
System) after solution be used as sample solution.
Ii.LC conditions
Device：SHIMADZU Prominence system
Pillar：Discovery HS F5 (4.6 × 250mm, 5 μ L, lot 071012BOP)
Mobile phase：A：0.1 volume % aqueous formic acid；B：Acetonitrile
Gradient：
More than 0 minute discontented 15 minutes：Mobile phase A：100 volume %；Mobile phase B：0 volume %
More than 15 minutes discontented 20 minutes：Mobile phase A：Reduced by 100 volume % to 0 volume %；Mobile phase B：By 0 body
Product % increases to 100 volume %
More than 20 minutes discontented 30 minutes：Mobile phase A：0 volume %；Mobile phase B：100 volume %
More than 30 minutes discontented 50 minutes：Mobile phase A：100 volume %；Mobile phase B：0 volume %
Flow：0.4mL/min
Oven temperature：40℃
Reservoir quantity：10μL
Iii.MS conditions
Equipment：SHIMADZU LCMS2020
Ionization：ESI positive
Detector voltage：1.2KV
Desolventizing temperature：250℃
Atomizing gas velocities：1.5L/min
Heating module (Heat Block) temperature：450℃
Dry gas speed：15L/min
Detection：SIM (L-Histidines：m/z：156.1；L-arginine：m/z：175.1)
<Evaluation criterion>
It is each in aforementioned manners to carry out quantifying for 3 samples, calculate average value.Evaluated with average value.
5：It is per more than mg hairs 45ng to be impregnated into the L-Histidine of inside, the total amount of L-arginine
4：The L-Histidine of inside, the total amount of L-arginine is impregnated into be per more than mg hairs 20ng, be discontented with 45ng
3：The L-Histidine of inside, the total amount of L-arginine is impregnated into be per more than mg hairs 10ng, be discontented with 20ng
2：The L-Histidine of inside, the total amount of L-arginine is impregnated into be per more than mg hairs 5ng, be discontented with 10ng
1：It is to be discontented with 5ng per mg hairs to be impregnated into the L-Histidine of inside, the total amount of L-arginine
[to the evaluation method and standard of not crude, overhead fluffy sense]
<Method>
30 female volunteers of 40~60 years old are carried out with Shi Jishiyong evaluation.Evaluate as follows：After prerinse, using
After shampoo hair washing or before hair washing, smear and made up usually using the embodiment of amount and the emulsifying hair of comparative example on hair
Product, are rinsed, and hair washing activity is carried out according to usual method.After using each embodiment/comparative example 3 days, to the not crude, crown
The fluffy sense in portion, is evaluated according to following evaluation criterion.
<Evaluation criterion>
5：Answer good less than 30 more than 25 in 30
4：Answer good less than 24 more than 19 in 30
3：Answer good less than 18 more than 10 in 30
2：Answer good less than 9 more than 1 in 30
1：What answer was good in 30 has 0 people
[evaluation method and standard of emulsion stability]
(1) emulsion stability (actual use)
<Method>
It is filling 200g samples in 200g oval upright and handstand container (interior bore 6mm) to capacity.To upright and
Handstand container carries out the actual use evaluation of 1 month, is evaluated according to following evaluation criterion.In addition, upright container refers to
The container of preparation type is taken care of and taken out discharging opening downwards when being used with the upward state of discharging opening.Handstand container refer to
Discharging opening downward state takes out downwards discharging opening when being taken care of and being used in the container of preparation type.For handstand container,
Air is easily mixed into the formulation during extruding container, and compared with upright container, its emulsifying composition is sometimes unstable.
<Evaluation criterion>
◎：Moisture is not separated in bottle that is upright or standing upside down
○：Moisture is not separated in upright bottle
×：There is moisture separation in each bottle
(2) emulsion stability (freezing recovers)
<Method>
It is filling 40mL samples in 50mL vial to capacity.Preserved respectively at -20 DEG C and at room temperature, every other day
It is repeated once, is evaluated according to following.
<Evaluation criterion>
◎：Moisture is repeated 5 times not separate
○：3~4 moisture are repeated not separate
×：It is repeated 2 times following moisture separation
[table 1]
Hair-washing composition → emulsifying hair cosmetic composition
[table 2]
Hair-washing composition → emulsifying hair cosmetic composition
[table 3]
Hair-washing composition → emulsifying hair cosmetic composition
[table 4]
Hair-washing composition → emulsifying hair cosmetic composition
[table 5]
Hair-washing composition → emulsifying hair cosmetic composition
[table 6]
Hair-washing composition → emulsifying hair cosmetic composition
[table 7]
Hair-washing composition → emulsifying hair cosmetic composition
[table 8]
Hair-washing composition → emulsifying hair cosmetic composition
[table 9]
Emulsifying hair cosmetic composition → hair-washing composition
[table 10]
Hair-washing composition → emulsifying hair cosmetic composition
[table 11]
Hair-washing composition → emulsifying hair cosmetic composition
[table 12]
Hair-washing composition → emulsifying hair cosmetic composition
The raw material used in above-mentioned example is as shown in the table.
[table 13]
Claims (9)
1. a kind of emulsifying hair cosmetic composition, it contains：
(A) cationic surfactant, (B) higher alcohol, (C) L-Histidine, (D) L-arginine and 0.1~0.5 mass %
(E) water-soluble high-molecular compound selected from hydroxyethyl cellulose and hydroxypropyl cellulose, (C), the mixing of (D) composition
Amount and mass ratio are as follows：
(C) 0.01~0.5 mass %
(D) 0.01~0.5 mass %
(C)+mass % of (D)=0.05~0.6, (C)/(D)=0.2~5.
2. emulsifying hair cosmetic composition as claimed in claim 1, wherein, the cosmetics further contain amino acid containing (F)
Aliphatic acid ester oil.
3. emulsifying hair cosmetic composition as claimed in claim 1 or 2, it is characterised in that (A) composition is to be selected from docosyl
More than a kind of trimethyl ammonium chloride, dimethylaminopropyl stearic amide.
4. emulsifying hair cosmetic composition as claimed in claim 1 or 2, it is characterised in that (B) composition is to be selected from stearyl alcohol, mountain
More than a kind of Yu alcohol.
5. emulsifying hair cosmetic composition as claimed in claim 1 or 2, it is characterised in that the combined amount of (A) composition is 1.2~3
Quality %, the combined amount of (B) composition is 3~8 mass %.
6. emulsifying hair cosmetic composition as claimed in claim 2, it is characterised in that (F) composition is to be selected from N- lauroyl-L- paddy
Propylhomoserin two (phytosterol/2- octyldodecyls alcohol) ester, (phytosterol/behenyl alcohols/2- is pungent for N- lauroyl-Pidolidone two
Base dodecyl alcohol) more than a kind of ester, and
(F) combined amount of composition is 0.1~1 mass %.
7. emulsifying hair cosmetic composition as claimed in claim 1 or 2, wherein, the cosmetics are hair conditioner, treatment waxes.
8. emulsifying hair cosmetic composition as claimed in claim 7, wherein, the hair conditioner is wash type hair conditioner.
9. emulsifying hair cosmetic composition as claimed in claim 1 or 2, wherein, the cosmetics are made before hair-washing composition
Prewashing hair style cosmetics.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013103101 | 2013-05-15 | ||
| JP2013-103101 | 2013-05-15 | ||
| PCT/JP2014/062872 WO2014185464A1 (en) | 2013-05-15 | 2014-05-14 | Emulsion based hair cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105163711A CN105163711A (en) | 2015-12-16 |
| CN105163711B true CN105163711B (en) | 2017-10-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480025142.1A Active CN105163711B (en) | 2013-05-15 | 2014-05-14 | Emulsifying hair cosmetic composition |
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| Country | Link |
|---|---|
| JP (1) | JP6172270B2 (en) |
| KR (1) | KR102164148B1 (en) |
| CN (1) | CN105163711B (en) |
| WO (1) | WO2014185464A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110891546A (en) * | 2017-07-19 | 2020-03-17 | 日商桑妮布雷斯股份有限公司 | Hair cosmetic composition, hair dye composition and hair dyeing method |
| CN110354021B (en) * | 2018-03-26 | 2024-01-05 | 赫尔克里士有限公司 | Use of cationic polymers in pre-shampoo conditioning compositions |
| CN109512703B (en) * | 2018-12-29 | 2021-10-15 | 拉芳家化股份有限公司 | Hair is fostered earlier and is washed product system afterwards |
| KR20220075182A (en) | 2020-11-26 | 2022-06-07 | 피에스비바이오 주식회사 | The hair cosmetic composition and its manufacturing method including Rhodobacter sphaeroides |
| CN115590778B (en) * | 2021-06-28 | 2024-06-11 | 南京华狮新材料有限公司 | Amino acid scalp hair care composition, scalp hair care product containing composition and preparation method |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3205425B2 (en) * | 1993-04-02 | 2001-09-04 | 一丸ファルコス株式会社 | Hair cosmetics |
| TW550084B (en) * | 1996-08-30 | 2003-09-01 | Ajinomoto Kk | Hair care products |
| JP4046570B2 (en) | 2002-07-31 | 2008-02-13 | ポーラ化成工業株式会社 | Hair cosmetics |
| JP4120811B2 (en) | 2003-04-22 | 2008-07-16 | ライオン株式会社 | Hair cosmetics |
| JP4964428B2 (en) * | 2005-04-11 | 2012-06-27 | 花王株式会社 | Hair cosmetics |
| JP4719575B2 (en) * | 2006-01-13 | 2011-07-06 | 花王株式会社 | Hair cosmetic and method for producing the same |
| WO2008006721A1 (en) * | 2006-07-14 | 2008-01-17 | Unilever Plc | Hair care composition |
| JP5502408B2 (en) * | 2009-09-17 | 2014-05-28 | ライオン株式会社 | Shampoo composition |
-
2014
- 2014-05-14 CN CN201480025142.1A patent/CN105163711B/en active Active
- 2014-05-14 KR KR1020157028854A patent/KR102164148B1/en active IP Right Grant
- 2014-05-14 JP JP2015517117A patent/JP6172270B2/en active Active
- 2014-05-14 WO PCT/JP2014/062872 patent/WO2014185464A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| KR20160007497A (en) | 2016-01-20 |
| JPWO2014185464A1 (en) | 2017-02-23 |
| JP6172270B2 (en) | 2017-08-02 |
| KR102164148B1 (en) | 2020-10-12 |
| WO2014185464A1 (en) | 2014-11-20 |
| CN105163711A (en) | 2015-12-16 |
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