CN105155774A - Duplex channel steel and recycled concrete combination beam - Google Patents
Duplex channel steel and recycled concrete combination beam Download PDFInfo
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- CN105155774A CN105155774A CN201510485548.4A CN201510485548A CN105155774A CN 105155774 A CN105155774 A CN 105155774A CN 201510485548 A CN201510485548 A CN 201510485548A CN 105155774 A CN105155774 A CN 105155774A
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- 239000004567 concrete Substances 0.000 title claims abstract description 74
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 54
- 239000010959 steel Substances 0.000 title claims abstract description 54
- 239000002131 composite material Substances 0.000 claims abstract description 16
- 239000002699 waste material Substances 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 239000004568 cement Substances 0.000 claims description 24
- 239000011449 brick Substances 0.000 claims description 23
- 239000004576 sand Substances 0.000 claims description 17
- 238000010521 absorption reaction Methods 0.000 claims description 6
- 238000010276 construction Methods 0.000 abstract description 10
- 238000005452 bending Methods 0.000 abstract description 3
- 238000009415 formwork Methods 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000003638 chemical reducing agent Substances 0.000 description 8
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- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910021487 silica fume Inorganic materials 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
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- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
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- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
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- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011150 reinforced concrete Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Processing Of Solid Wastes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
本发明公开了一种双层槽钢-再生混凝土组合梁,包括第一槽型钢和与所述第一槽型钢铆接的第二槽型钢,所述第一槽型钢的底部设置有抗剪连接件,第一槽型钢内填充有再生骨料混凝土;所述第二槽型钢通过铆钉固定连接,所述第二槽型钢腹板的厚度大于第一槽型钢腹板的厚度,所述再生骨料混凝土中再生骨料的替代率为50%。在本发明中,通过设置下层槽型钢受拉,上层槽型钢内的混凝土受压,能够充分发挥各自的性能,组合梁的抗弯能力较强;在同样的性能下,本发明的重量更轻,有利于提高抗震能力;本发明可以减少施工阶段的支撑和模板,给施工带来极大便利;在下层槽型钢充分发挥抗拉强度的同时,简化了建筑构造,减少了钢筋绑扎,提高了施工效率。
The invention discloses a double-layer channel steel-recycled concrete composite beam, comprising a first channel steel and a second channel steel riveted with the first channel steel, the bottom of the first channel steel is provided with a shear connector , the first channel-shaped steel is filled with recycled aggregate concrete; the second channel-shaped steel is fixedly connected by rivets, the thickness of the second channel-shaped steel web is greater than the thickness of the first channel-shaped steel web, and the recycled aggregate concrete The replacement rate of recycled aggregate is 50%. In the present invention, by arranging the lower channel steel to be tensioned and the concrete in the upper channel steel to be compressed, respective performances can be fully exerted, and the composite beam has stronger bending resistance; under the same performance, the weight of the present invention is lighter , which is conducive to improving the earthquake resistance; the invention can reduce the support and formwork in the construction stage, which brings great convenience to the construction; while the lower channel steel fully exerts the tensile strength, it simplifies the building structure, reduces the binding of steel bars, and improves the construction efficiency. construction efficiency.
Description
技术领域technical field
本发明属于建筑结构领域,尤其是一种组合梁。The invention belongs to the field of building structures, in particular to a composite beam.
背景技术Background technique
随着中国城市化的进展,建筑垃圾(废弃物)的问题逐渐被重视。如采取简单的堆放方式处理,每年新增建筑垃圾处理将占地至少1.5亿平方米。再生混凝土作为一种新材料则能很好地解决这个问题。With the progress of urbanization in China, the problem of construction waste (waste) has gradually been paid attention to. If a simple stacking method is adopted, the annual construction waste disposal will cover an area of at least 150 million square meters. Recycled concrete as a new material can solve this problem well.
随着社会经济和建筑结构的发展,钢-混凝土组合结构的应用越来越多,钢-混凝土组合结构充分发挥了混凝土承受压力而钢材承受拉力的材料力学性能,钢材的应用可以减小混凝土结构的过大截面,减轻自重而有利于抗震性能的提高。With the development of social economy and building structure, more and more steel-concrete composite structures are used. The steel-concrete composite structure fully exerts the material mechanical properties of concrete under pressure and steel under tension. The application of steel can reduce the size of concrete structures. The excessively large cross-section reduces the self-weight and is conducive to the improvement of seismic performance.
现有的型钢混凝土组合梁是将型钢埋设在混凝土内,由于要防止型钢翼缘可能向外屈曲导致翼缘外侧混凝土开裂,所以要有一定厚度的混凝土保护层,造成型钢抗弯作用发挥不完全,受拉区的混凝土没有发挥作用却增加了构件的自重;使用的混凝土多为配筋混凝土,虽然配筋混凝土可以有效地约束型钢与混凝土的共同作用,但是绑扎钢筋大多为人工绑扎,生产效率低下,不利于工厂机械化生产。The existing steel-concrete composite beam is to bury the section steel in the concrete. To prevent the flange of the section steel from buckling outwards and cause the concrete on the outside of the flange to crack, a certain thickness of concrete protective layer is required, which will cause the bending resistance of the section steel to be incomplete. , the concrete in the tension area does not play a role but increases the self-weight of the component; the concrete used is mostly reinforced concrete, although reinforced concrete can effectively restrain the joint action of steel and concrete, but most of the binding steel bars are manually bound, and the production efficiency Low, not conducive to factory mechanized production.
发明内容Contents of the invention
发明目的:提供一种双层槽钢-再生混凝土组合梁,以解决现有技术中存在的上述问题。Purpose of the invention: to provide a double-layer channel steel-regenerated concrete composite beam to solve the above-mentioned problems in the prior art.
技术方案:一种双层槽钢-再生混凝土组合梁,其特征在于,包括第一槽型钢和与所述第一槽型钢铆接的第二槽型钢,所述第一槽型钢的底部设置有抗剪连接件,第一槽型钢内填充有再生骨料混凝土;所述第二槽型钢通过铆钉固定连接,所述第二槽型钢腹板的厚度大于第一槽型钢腹板的厚度,所述再生骨料混凝土中再生骨料的替代率为50%。Technical solution: a double-layer channel steel-recycled concrete composite beam, characterized in that it includes a first channel steel and a second channel steel riveted with the first channel steel, and the bottom of the first channel steel is provided with anti- Shear connectors, the first channel-shaped steel is filled with recycled aggregate concrete; the second channel-shaped steel is fixedly connected by rivets, the thickness of the second channel-shaped steel web is greater than the thickness of the first channel-shaped steel web, and the recycled The replacement rate of recycled aggregate in aggregate concrete is 50%.
进一步的,所述再生骨料混凝土包括如下重量比的各组分,水:水泥:砂:废弃砖块:废弃混凝土块=1:(2~2.5):(2~2.5):(1~1.2):(4.8~5.5)。Further, the recycled aggregate concrete includes components in the following weight ratio, water: cement: sand: waste bricks: waste concrete blocks = 1: (2-2.5): (2-2.5): (1-1.2 ): (4.8~5.5).
进一步的,所述再生骨料混凝土包括如下重量比的各组分,水:水泥:砂:废弃砖块:废弃混凝土块=1:2.27:2.27:1.04:5.21。Further, the recycled aggregate concrete includes components in the following weight ratio, water: cement: sand: waste bricks: waste concrete blocks = 1:2.27:2.27:1.04:5.21.
进一步的,所述再生骨料混凝土还包括废弃混凝土骨料10min吸水率计算的需水量。Further, the recycled aggregate concrete also includes the water demand calculated from the 10-min water absorption rate of the waste concrete aggregate.
有益效果:在本发明中,通过设置下层槽型钢受拉,上层槽型钢内的混凝土受压,能够充分发挥各自的性能,组合梁的抗弯能力较强;在同样的性能下,本发明的重量更轻,有利于提高抗震能力;与现有结构不同,本发明可以减少施工阶段的支撑和模板,给施工带来极大便利;在下层槽型钢充分发挥抗拉强度的同时,大大简化了建筑构造,减少了钢筋绑扎,提高了施工效率;下层槽型钢内侧易于布置各类通讯电子设备,可以增加房屋净高,提高空间利用率。在进一步的实施例中,再生骨料混凝土可以使用回收建筑垃圾,变废为宝,节约资源,保护环境。Beneficial effects: in the present invention, by setting the channel steel in the lower layer under tension and the concrete in the upper channel steel under compression, their respective performances can be fully exerted, and the bending resistance of the composite beam is relatively strong; under the same performance, the present invention The weight is lighter, which is beneficial to improve the anti-seismic ability; different from the existing structure, the present invention can reduce the support and formwork in the construction stage, which brings great convenience to the construction; while the lower channel steel fully exerts the tensile strength, it greatly simplifies The building structure reduces steel bar binding and improves construction efficiency; various communication and electronic equipment can be easily arranged on the inner side of the lower channel steel, which can increase the net height of the house and improve space utilization. In a further embodiment, recycled aggregate concrete can use recycled construction waste to turn waste into treasure, save resources and protect the environment.
附图说明Description of drawings
图1是本发明实施例双层槽钢-再生混凝土组合梁的截面示意图。Fig. 1 is a schematic cross-sectional view of a double-layer channel steel-recycled concrete composite beam according to an embodiment of the present invention.
图2是本发明实施例双层槽钢-再生混凝土组合梁的主视图。Fig. 2 is a front view of a double-layer channel steel-regenerated concrete composite beam according to an embodiment of the present invention.
具体实施方式Detailed ways
如图1所示,一种双层槽钢-再生混凝土组合梁,包括第一槽型钢1(从方位上看为上层槽型钢)和与第一槽型钢1铆接的第二槽型钢2(从方位上看为下层槽型钢)。第一槽型钢的底部设置有抗剪连接件5,第一槽型钢内填充有再生骨料混凝土3.As shown in Figure 1, a double-layer channel steel-recycled concrete composite beam includes a first channel steel 1 (viewed from the azimuth as the upper channel steel) and a second channel steel 2 riveted with the first channel steel 1 (from the From the perspective of orientation, it is the lower channel steel). The bottom of the first channel-shaped steel is provided with a shear connector 5, and the first channel-shaped steel is filled with recycled aggregate concrete 3.
如图1和图2所示,第二槽型钢通过铆钉4固定连接,第二槽型钢腹板的厚度大于第一槽型钢腹板的厚度,以防止第二槽型钢的钢腹板受到铆钉传下来的荷载而屈曲。As shown in Figures 1 and 2, the second channel-shaped steel is fixedly connected by rivets 4, and the thickness of the second channel-shaped steel web is greater than the thickness of the first channel-shaped steel web, so as to prevent the steel web of the second channel-shaped steel from being transmitted by the rivets. buckling under load.
所述再生骨料混凝土中再生骨料的替代率为50%。进一步的,所述再生骨料混凝土包括如下重量比的各组分,水:水泥:砂:废弃砖块:废弃混凝土块=1:(2~2.5):(2~2.5):(1~1.2):(4.8~5.5)。The replacement rate of recycled aggregate in the recycled aggregate concrete is 50%. Further, the recycled aggregate concrete includes components in the following weight ratio, water: cement: sand: waste bricks: waste concrete blocks = 1: (2-2.5): (2-2.5): (1-1.2 ): (4.8~5.5).
进一步的实施例中,申请人对再生骨料混凝土的配比进行了优化,较为优选的配比范围是水:水泥:砂:废弃砖块:废弃混凝土块=1:(2~2.5):(2~2.5):(1~1.2):(4.8~5.5)。In a further embodiment, the applicant has optimized the ratio of recycled aggregate concrete, and the more preferred ratio range is water: cement: sand: waste bricks: waste concrete blocks = 1: (2 ~ 2.5): ( 2~2.5):(1~1.2):(4.8~5.5).
以强度等级为C35的混凝土为例:Take concrete with strength grade C35 as an example:
实施例1各组分的重量比为,水:水泥:砂:废弃砖块:废弃混凝土块=1:2.27:2.27:1.04:5.21。采用标准方法进行检测,实验数据如下:塌落度180,和易性优异,7天抗压强度28.5MPa,28天抗压强度43.5MPa。The weight ratio of each component in Example 1 is water: cement: sand: waste bricks: waste concrete blocks = 1:2.27:2.27:1.04:5.21. The standard method is used for detection, and the experimental data are as follows: the slump is 180, the workability is excellent, the 7-day compressive strength is 28.5MPa, and the 28-day compressive strength is 43.5MPa.
1、确定配制强度fcu,0 1. Determine the preparation strength f cu,0
fcu.0=fcu,k+1.645σf cu.0 =f cu,k +1.645σ
当混凝土的强度等级为C35时,σ=5.0MPa,则When the strength grade of concrete is C35, σ=5.0MPa, then
fcu,0=48.2MPaf cu,0 =48.2MPa
2、初步确定水灰比W:C2. Preliminary determination of the water-cement ratio W:C
因该实验所用的水泥28d实测强度fce未知,现预期水泥28d实测强度可达到48.0MPa。粗骨料为碎石,A=0.46,B=0.07Since the 28d measured strength f ce of the cement used in this experiment is unknown, it is expected that the measured 28d strength of the cement can reach 48.0MPa. Coarse aggregate is gravel, A=0.46, B=0.07
3、初步估计单位用水量3. Preliminary estimate of unit water consumption
最大粒径为40mm。由于废弃混凝土块体在破碎过程中受到较大外力作用,且废弃混凝土块体在烧制过程中会产生大量裂缝,使得再生集料的吸水率与吸水速率都远高于天然集料。一般认为,再生粗集料吸水率超过天然集料的5%左右。因此,需要在初步设定的用水量基础上加以调整。The maximum particle size is 40mm. Because the waste concrete block is subjected to a large external force during the crushing process, and the waste concrete block will produce a large number of cracks during the firing process, the water absorption rate and water absorption rate of the recycled aggregate are much higher than that of the natural aggregate. It is generally believed that the water absorption rate of recycled coarse aggregate is about 5% higher than that of natural aggregate. Therefore, it needs to be adjusted on the basis of the initially set water consumption.
当最大粒径为40mm时,mW0=175kg/m3,经调整,mW=184kg/m3 When the maximum particle size is 40mm, m W0 = 175kg/m 3 , after adjustment, m W = 184kg/m 3
4、计算水泥用量4. Calculate the amount of cement
(1)
(2)
5、初步选取砂率βS 5. Preliminary selection of sand rate β S
(1)混凝土所用碎石的最大粒径30mm,水灰比为0.44,线性查表βS=33.2%(1) The maximum particle size of crushed stone used in concrete is 30mm, the water-cement ratio is 0.44, and the linear look-up table β S =33.2%
(2)混凝土所用碎石的最大粒径40mm,水灰比为0.44,线性查表βS=30.7%(2) The maximum particle size of crushed stone used in concrete is 40mm, the water-cement ratio is 0.44, and the linear look-up table β S =30.7%
6、计算砂、等效石子用量mS、mG 6. Calculate the amount of sand and equivalent stone m S , m G
联立上述两公式,求解出所需的mS、mG Simultaneously combine the above two formulas to solve the required m S , m G
7、求出所需替代的废弃砖块和废弃混凝土块体的量;7. Calculate the amount of waste bricks and waste concrete blocks that need to be replaced;
此实验指体积替代率(预期的替代率废弃粘土砖20%,废弃混凝土块体80%),用排液置换法求出废弃砖体块的密度ρRB和废弃混凝土块体的密度ρRC,求出所需的废弃砖块体和废弃混凝土块体块的质量::
根据上述计算求得混凝土配合比为:mW:mC:mS:mRB:mRC=1:2.27:2.77:1.04:5.21。According to the above calculation, the concrete mix ratio is: m W : m C : m S : m RB : m RC = 1:2.27:2.77:1.04:5.21.
实施例2~5,相关过程参考实施例1,调整相关参数,获得配比如下:Embodiments 2 to 5, the relevant process refers to Embodiment 1, adjusts relevant parameters, and obtains the ratio as follows:
实施例2各组分的重量比为,水:水泥:砂:废弃砖块:废弃混凝土块=1:2.11::2.48:1.15:5.25。采用标准方法进行检测,实验数据如下:塌落度160,和易性优异,7天抗压强度22.5MPa,28天抗压强度45MPa。The weight ratio of the components in Example 2 is water: cement: sand: waste bricks: waste concrete blocks = 1:2.11::2.48:1.15:5.25. The standard method is used for detection, and the experimental data are as follows: slump is 160, excellent workability, 7-day compressive strength is 22.5MPa, and 28-day compressive strength is 45MPa.
实施例3各组分的重量比为,水:水泥:砂:废弃砖块:废弃混凝土块=1:2.45:2.18:1.18:1.89。采用标准方法进行检测,实验数据如下:塌落度175,和易性良好,7天抗压强度24.5MPa,28天抗压强度47.5MPa。The weight ratio of the components in Example 3 is water: cement: sand: waste bricks: waste concrete blocks = 1:2.45:2.18:1.18:1.89. The standard method is used for detection, and the experimental data are as follows: the slump is 175, the workability is good, the 7-day compressive strength is 24.5MPa, and the 28-day compressive strength is 47.5MPa.
实施例4各组分的重量比为,水:水泥:砂:废弃砖块:废弃混凝土块=1:2.36:2.39:1.09:5.05。采用标准方法进行检测,实验数据如下:塌落度155,和易性优异,7天抗压强度20.5MPa,28天抗压强度48.5MPa。The weight ratio of the components in Example 4 is water: cement: sand: waste bricks: waste concrete blocks = 1:2.36:2.39:1.09:5.05. The standard method is used to test, the experimental data is as follows: slump 155, excellent workability, 7-day compressive strength 20.5MPa, 28-day compressive strength 48.5MPa.
实施例5各组分的重量比为,水:水泥:砂:废弃砖块:废弃混凝土块=1:2.40:2.06:1.12:5.15。采用标准方法进行检测,实验数据如下:塌落度185,和易性良好,7天抗压强度21.5MPa,28天抗压强度46.5MPa。The weight ratio of each component in Example 5 is water: cement: sand: waste bricks: waste concrete blocks = 1:2.40:2.06:1.12:5.15. The standard method is used for detection, and the experimental data are as follows: the slump is 185, the workability is good, the 7-day compressive strength is 21.5MPa, and the 28-day compressive strength is 46.5MPa.
所述再生骨料混凝土还包括废弃混凝土骨料10min吸水率计算的需水量。The recycled aggregate concrete also includes the water demand calculated by the 10-min water absorption rate of the waste concrete aggregate.
对照组的替代率为0,28d强度约为48MPa,本实施的强度与其基本持平,性能优于现有的再生骨料混凝土配方。The replacement rate of the control group is 0, and the 28d strength is about 48MPa. The strength of this implementation is basically the same, and the performance is better than the existing recycled aggregate concrete formula.
实施例6-8Example 6-8
其他过程参考实施例1,在该组实施例中,Other processes refer to embodiment 1, in this group of embodiments,
废弃砖块的处理过程进一步为:The processing process of waste bricks is further as follows:
除去再生骨料(废弃砖块和废弃混凝土块)中的玻璃、塑料和钢筋等杂质,用颚式破碎机破碎;采用50mm孔径筛分,对筛中剩余物继续进行破碎,对筛底剩余物进行20mm孔径筛分,保留筛中剩余物,筛底剩余物丢弃;用水冲洗再生骨料,晾干。Remove impurities such as glass, plastic and steel bars in recycled aggregates (waste bricks and waste concrete blocks), and crush them with a jaw crusher; use 50mm aperture to sieve, and continue to crush the residue in the sieve, and the residue at the bottom of the sieve Sieve with a 20mm aperture, keep the residue in the sieve, and discard the residue at the bottom of the sieve; rinse the recycled aggregate with water and dry it in the air.
在计算出水、水泥、沙、碎石和废弃砖块的配比后,加入再生骨料改性材料。After calculating the ratio of water, cement, sand, gravel and discarded bricks, add recycled aggregate modified materials.
再生骨料改性材料包括:减水剂、补强剂和膨胀剂。减水剂的用量为配料总量的0.1-0.5wt%,补强剂的用量为配料总量的3-5wt%,膨胀剂为配料总量的1-3wt%。Recycled aggregate modified materials include: water reducing agent, reinforcing agent and expansion agent. The dosage of the water reducing agent is 0.1-0.5wt% of the total batching, the dosage of the reinforcing agent is 3-5wt% of the total batching, and the expansion agent is 1-3wt% of the total batching.
所述减水剂的结构式如下:The structural formula of the water reducer is as follows:
其中,R1、R2、R3、R4和R5均选自H或CH3,n为35~55,m为25~45,a、b、c和d为正整数,M为一价阳离子。Among them, R 1 , R 2 , R 3 , R 4 and R 5 are all selected from H or CH 3 , n is 35-55, m is 25-45, a, b, c and d are positive integers, M is one Valence cations.
所述补强剂为硅灰,膨胀剂为硫铝酸盐。The reinforcing agent is silica fume, and the expansion agent is sulphoaluminate.
上述新型聚羧酸减水剂的制备方法,步骤如下:The preparation method of above-mentioned novel polycarboxylate water reducer, the steps are as follows:
步骤1:制备或购买大分子单体,按照预定的配比称取原料;Step 1: Prepare or purchase the macromer, and weigh the raw materials according to the predetermined ratio;
步骤2:将烷基聚醚、丙烯酸单体、阻聚剂、催化剂和协水剂加入到反应釜中升温至160℃,回流状态进行酯化反应5小时,得到中间产物;催化剂选自硫酸、甲苯磺酸、固体酸ZrO2的一种或几种,所说阻聚剂选自羟基苯甲醚、苯二酚、硫化二苯胺中的一种的或几种,所述协水剂选自乙酸乙酯、异戊醇中的一种或两种。Step 2: Add alkyl polyether, acrylic acid monomer, polymerization inhibitor, catalyst and water coordinating agent to the reaction kettle and raise the temperature to 160°C, carry out esterification reaction for 5 hours under reflux, and obtain an intermediate product; the catalyst is selected from sulfuric acid, One or more of toluenesulfonic acid, solid acid ZrO 2 , said polymerization inhibitor is selected from one or more of hydroxyanisole, hydroquinone, sulfurized diphenylamine, and said water coordinating agent is selected from One or both of ethyl acetate and isoamyl alcohol.
步骤3:分离出中间产物并加热至90℃进行溶解,同时滴加其他单体和引发剂溶液,滴加时间为1.2小时,滴加完毕后保温6小时,反应完成后,冷却至40℃,用氢氧化钠溶液调节pH为7,即获得目标产物。Step 3: Separate the intermediate product and heat it to 90°C for dissolution, and add other monomers and initiator solutions dropwise at the same time. The dropping time is 1.2 hours. After the dropwise addition, keep warm for 6 hours. After the reaction is completed, cool to 40°C Adjust the pH to 7 with sodium hydroxide solution to obtain the target product.
实施例6中,水、水泥、沙、碎石和废弃砖块的配比与实施例1相同,加入0.26wt%的减水剂,4.1wt%的补强剂和1.9wt%的膨胀剂。In embodiment 6, the proportion of water, cement, sand, gravel and waste bricks is the same as that of embodiment 1, adding 0.26wt% water reducer, 4.1wt% reinforcing agent and 1.9wt% expansion agent.
实施例7中,水、水泥、沙、碎石和废弃砖块的配比与实施例2相同,加入0.11wt%的减水剂,3.2wt%的补强剂,以及2.7wt%的膨胀剂。In embodiment 7, the proportion of water, cement, sand, gravel and waste bricks is the same as that of embodiment 2, adding 0.11wt% water reducer, 3.2wt% reinforcing agent, and 2.7wt% expansion agent .
实施例8中,水泥、沙、碎石和废弃砖块的配比与实施例3相同,加入0.45wt%的减水剂,4.9wt%的补强剂,以及1.2wt%的膨胀剂。In Example 8, the ratio of cement, sand, gravel and waste bricks is the same as that of Example 3, and 0.45wt% of water reducer, 4.9wt% of reinforcing agent, and 1.2wt% of expansion agent are added.
采用相同的测试方法,得到的28d强度的数据如下:48.8、53.4和55.5。Using the same test method, the obtained 28d strength data are as follows: 48.8, 53.4 and 55.5.
在该组实施例中,清洗再生骨料,可除去其上附着的粉尘,同时硅灰能够少混凝土内部的空隙率和空隙尺寸,改善骨料界面上的水泥浆体结构,硅灰的火山灰效应和微粒填充效应,浆体与骨料的粘结性好。高效减水剂,不仅能降低水灰比,更为重要的是使拌合料中的水泥更加分散,使硬化后的空隙率及孔隙分布情况得到进一步的改善。膨胀剂能够抵消再生骨料产生的收缩,解决了现有技术再生骨料混凝土收缩率大的问题。In this group of embodiments, cleaning the recycled aggregate can remove the dust attached to it, and at the same time, silica fume can reduce the void ratio and void size inside the concrete, improve the cement paste structure on the aggregate interface, and the pozzolanic effect of silica fume And particle filling effect, good adhesion between slurry and aggregate. High-efficiency water reducer can not only reduce the water-cement ratio, but more importantly, make the cement in the mixture more dispersed, so that the porosity and pore distribution after hardening can be further improved. The expansion agent can counteract the shrinkage produced by the recycled aggregate, and solve the problem of large shrinkage of the recycled aggregate concrete in the prior art.
以上详细描述了本发明的优选实施方式,但是,本发明并不限于上述实施方式中的具体细节,在本发明的技术构思范围内,可以对本发明的技术方案进行多种等同变换,这些等同变换均属于本发明的保护范围。另外需要说明的是,在上述具体实施方式中所描述的各个具体技术特征,在不矛盾的情况下,可以通过任何合适的方式进行组合。The preferred embodiments of the present invention have been described in detail above, but the present invention is not limited to the specific details in the above embodiments. Within the scope of the technical concept of the present invention, various equivalent transformations can be carried out to the technical solutions of the present invention. These equivalent transformations All belong to the protection scope of the present invention. In addition, it should be noted that the various specific technical features described in the above specific implementation manners may be combined in any suitable manner if there is no contradiction.
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