CN105154797A - Glass fiber reinforcement aluminum matrix composite material and preparation method thereof - Google Patents
Glass fiber reinforcement aluminum matrix composite material and preparation method thereof Download PDFInfo
- Publication number
- CN105154797A CN105154797A CN201510546139.0A CN201510546139A CN105154797A CN 105154797 A CN105154797 A CN 105154797A CN 201510546139 A CN201510546139 A CN 201510546139A CN 105154797 A CN105154797 A CN 105154797A
- Authority
- CN
- China
- Prior art keywords
- oxide
- matrix composite
- fiber reinforcement
- aluminum matrix
- glass fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Glass Compositions (AREA)
Abstract
The invention provides a glass fiber reinforcement aluminum matrix composite material and a preparation method thereof. The composite material comprises the following components of glass fibers, boric oxide, sodium oxide, cobalt oxide, zinc oxide, molybdenum sulfide, titanium powder with granularity being smaller than or equal to 30 micrometers, sulphur, stearic acid, and the balance aluminum powder with granularity being smaller than or equal to 60 micrometers. The preparation method comprises the steps that (1) raw materials are mixed evenly, ball-milled and mixed; (2) a mixture is put into a mould to be pressed and formed; (3) a pressed blank is heated to be a primary product under the condition of inert gas shielding; and (4) the primary product is heated under the vacuum condition, the temperature is preserved, and the primary product is cooled to be at the room temperature to obtain the composite material. The apparent hardness of the composite material prepared through compounding, compaction and sintering of the glass fibers and other powder metallic materials is improved remarkably.
Description
Technical field
The invention belongs to metallurgical field of compound material, be specifically related to a kind of glass fiber reinforcement aluminum matrix composite and preparation method thereof.
Background technology
Aluminum matrix composite, because of advantages such as its density are little, price is low, corrosion-resistant, causes the great interest of people, has been applied to the various industries such as automobile, household electrical appliances, agricultural machine, precision optical machinery.Aluminium has many features on making matrix material, and as light in quality, density is little, plasticity-good, aluminum-base composite technology is easily grasped, and is easy to processing etc.In addition, aluminum matrix composite specific tenacity and specific rigidity high, high-temperature behavior is good, more antifatigue and more wear-resisting, and damping capacity is good, and thermal expansivity is low.The same with other matrix materials, it can combine specific mechanics and physicals, to meet the needs of product.Therefore, aluminum matrix composite become the most frequently used in metal-base composites, one of most important material.But the quality of alumina-base material is partially soft, poor rigidity, yielding in process of production.In order to improve the characteristic of matrix material, usually add strongthener to improve the performance of matrix material.
Summary of the invention
goal of the invention:the object of the present invention is to provide a kind of glass fiber reinforcement aluminum matrix composite and preparation method thereof, obtained composite hardness is high, not yielding in production process.
technical scheme of the present invention:
Glass fiber reinforcement aluminum matrix composite, the component containing following mass percentage: glass fibre 14 ~ 18%, boron oxide 1 ~ 10%, sodium oxide 4 ~ 9%, cobalt oxide 5 ~ 6%, zinc oxide 7 ~ 9%, moly-sulfide 2 ~ 6%, titanium valve 1 ~ 5%, sulphur 4 ~ 20%, stearic acid 5 ~ 15%, all the other are aluminium powder.
Preferably, the component containing following mass percentage: glass fibre 15 ~ 17%, boron oxide 6 ~ 8%, sodium oxide 6 ~ 7%, cobalt oxide 6%, zinc oxide 8%, moly-sulfide 3 ~ 4%, titanium valve 2 ~ 3%, sulphur 5 ~ 8%, stearic acid 7 ~ 9%, all the other are aluminium powder.
Preferred, the component containing following mass percentage: glass fibre 16%, boron oxide 7%, sodium oxide 6%, cobalt oxide 6%, zinc oxide 8%, moly-sulfide 3%, titanium valve 2%, sulphur 6%, stearic acid 8%, all the other are aluminium powder.
Described glass fibre is resurrection glass fibre.
The preparation method of glass fiber reinforcement aluminum matrix composite, comprises the steps:
(1) glass fibre, boron oxide, sodium oxide, cobalt oxide, zinc oxide, moly-sulfide, titanium valve, sulphur, stearic acid, aluminium powder are mixed, put into ball mill and carry out ground and mixed, evenly to be mixed, drop in mixing roll, be then dry mixed 1 ~ 2h;
(2) mixture of step (1) is put into mould, be under the condition of 0.01 ~ 0.05MPa in vacuum tightness, compression moulding at being heated to 160 ~ 180 DEG C, obtains pressed compact;
(3) pressed compact of step (2) is heated to 350 ~ 380 DEG C under the condition of protection of inert gas, keeps 40 ~ 60 minutes, obtain first product;
(4) by the first product of step (3) in vacuum tightness be 0.001 ~ 0.004MPa condition under be heated to 1150 ~ 1200 DEG C, be incubated 200 ~ 250 minutes, be then down to room temperature, obtain glass fiber reinforcement aluminum matrix composite.
beneficial effect:
The present invention is by blended, pressed compact, the sintering by glass fibre and other each mmaterials, and the apparent hardness of the matrix material of preparation obtains obvious lifting.
Embodiment
Below the specific embodiment of the present invention is described in detail.
embodiment 1
Glass fiber reinforcement aluminum matrix composite, the component containing following mass percentage: resurrection glass fibre 14%, boron oxide 1%, sodium oxide 4%, cobalt oxide 5%, zinc oxide 7%, moly-sulfide 2%, titanium valve 1%, sulphur 4%, stearic acid 5%, all the other are aluminium powder.
Preparation method, comprises the steps:
(1) resurrection glass fibre, boron oxide, sodium oxide, cobalt oxide, zinc oxide, moly-sulfide, titanium valve, sulphur, stearic acid, aluminium powder are mixed, put into ball mill and carry out ground and mixed, evenly to be mixed, drop in mixing roll, be then dry mixed 1h;
(2) mixture of step (1) is put into mould, be under the condition of 0.01MPa in vacuum tightness, compression moulding at being heated to 180 DEG C, obtains pressed compact;
(3) pressed compact of step (2) is heated to 350 DEG C under the condition of nitrogen protection, keeps 40 minutes, obtain first product;
(4) by the first product of step (3) in vacuum tightness be 0.001MPa condition under be heated to 1200 DEG C, be incubated 200 minutes, be then down to room temperature, obtain glass fiber reinforcement aluminum matrix composite.
embodiment 2
Glass fiber reinforcement aluminum matrix composite, the component containing following mass percentage: resurrection glass fibre 15%, boron oxide 6%, sodium oxide 6%, cobalt oxide 6%, zinc oxide 8%, moly-sulfide 3%, titanium valve 2%, sulphur 5%, stearic acid 7%, all the other are aluminium powder.
Preparation method, comprises the steps:
(1) resurrection glass fibre, boron oxide, sodium oxide, cobalt oxide, zinc oxide, moly-sulfide, titanium valve, sulphur, stearic acid, aluminium powder are mixed, put into ball mill and carry out ground and mixed, evenly to be mixed, drop in mixing roll, be then dry mixed 1.2h;
(2) mixture of step (1) is put into mould, be under the condition of 0.02MPa in vacuum tightness, compression moulding at being heated to 175 DEG C, obtains pressed compact;
(3) pressed compact of step (2) is heated to 360 DEG C under the condition of nitrogen protection, keeps 45 minutes, obtain first product;
(4) by the first product of step (3) in vacuum tightness be 0.002MPa condition under be heated to 1190 DEG C, be incubated 220 minutes, be then down to room temperature, obtain glass fiber reinforcement aluminum matrix composite.
embodiment 3
Glass fiber reinforcement aluminum matrix composite, the component containing following mass percentage: resurrection glass fibre 16%, boron oxide 7%, sodium oxide 6%, cobalt oxide 6%, zinc oxide 8%, moly-sulfide 3%, titanium valve 2%, sulphur 6%, stearic acid 8%, all the other are aluminium powder.
Preparation method, comprises the steps:
(1) resurrection glass fibre, boron oxide, sodium oxide, cobalt oxide, zinc oxide, moly-sulfide, titanium valve, sulphur, stearic acid, aluminium powder are mixed, put into ball mill and carry out ground and mixed, evenly to be mixed, drop in mixing roll, be then dry mixed 1.5h;
(2) mixture of step (1) is put into mould, be under the condition of 0.03MPa in vacuum tightness, compression moulding at being heated to 170 DEG C, obtains pressed compact;
(3) pressed compact of step (2) is heated to 365 DEG C under the condition of argon shield, keeps 50 minutes, obtain first product;
(4) by the first product of step (3) in vacuum tightness be 0.003MPa condition under be heated to 1180 DEG C, be incubated 230 minutes, be then down to room temperature, obtain glass fiber reinforcement aluminum matrix composite.
embodiment 4
Glass fiber reinforcement aluminum matrix composite, the component containing following mass percentage: resurrection glass fibre 17%, boron oxide 8%, sodium oxide 7%, cobalt oxide 6%, zinc oxide 8%, moly-sulfide 4%, titanium valve 3%, sulphur 8%, stearic acid 9%, all the other are aluminium powder.
Preparation method, comprises the steps:
(1) resurrection glass fibre, boron oxide, sodium oxide, cobalt oxide, zinc oxide, moly-sulfide, titanium valve, sulphur, stearic acid, aluminium powder are mixed, put into ball mill and carry out ground and mixed, evenly to be mixed, drop in mixing roll, be then dry mixed 1.7h;
(2) mixture of step (1) is put into mould, be under the condition of 0.04MPa in vacuum tightness, compression moulding at being heated to 165 DEG C, obtains pressed compact;
(3) pressed compact of step (2) is heated to 370 DEG C under the condition of argon shield, keeps 55 minutes, obtain first product;
(4) by the first product of step (3) in vacuum tightness be 0.004MPa condition under be heated to 1160 DEG C, be incubated 240 minutes, be then down to room temperature, obtain glass fiber reinforcement aluminum matrix composite.
embodiment 5
Glass fiber reinforcement aluminum matrix composite, the component containing following mass percentage: resurrection glass fibre 18%, boron oxide 10%, sodium oxide 9%, cobalt oxide 6%, zinc oxide 9%, moly-sulfide 6%, titanium valve 5%, sulphur 20%, stearic acid 15%, all the other are aluminium powder.
Preparation method, comprises the steps:
(1) resurrection glass fibre, boron oxide, sodium oxide, cobalt oxide, zinc oxide, moly-sulfide, titanium valve, sulphur, stearic acid, aluminium powder are mixed, put into ball mill and carry out ground and mixed, evenly to be mixed, drop in mixing roll, be then dry mixed 2h;
(2) mixture of step (1) is put into mould, be under the condition of 0.05MPa in vacuum tightness, compression moulding at being heated to 160 DEG C, obtains pressed compact;
(3) pressed compact of step (2) is heated to 380 DEG C under the condition of argon shield, keeps 40 minutes, obtain first product;
(4) by the first product of step (3) in vacuum tightness be 0.004MPa condition under be heated to 1150 DEG C, be incubated 250 minutes, be then down to room temperature, obtain glass fiber reinforcement aluminum matrix composite.
comparative example 1
Be with the difference of embodiment 3: do not add resurrection glass fibre.
performance test
The matrix material that embodiment 1 ~ 5 and comparative example 1 obtain is carried out the test of density, apparent hardness, the results are shown in Table 1.
Table 1
。
As can be seen from Table 1, the apparent hardness of matrix material of the present invention is significantly higher than the apparent hardness of comparative example, and simultaneously in embodiments of the invention, the technique of embodiment 3 and moiety are best, and the apparent hardness of the matrix material of preparation is also the highest.
Although embodiment of the present invention are open as above, but it is not restricted to listed in specification sheets and embodiment utilization, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details.
Claims (5)
1. glass fiber reinforcement aluminum matrix composite, it is characterized in that, the component containing following mass percentage: glass fibre 14 ~ 18%, boron oxide 1 ~ 10%, sodium oxide 4 ~ 9%, cobalt oxide 5 ~ 6%, zinc oxide 7 ~ 9%, moly-sulfide 2 ~ 6%, titanium valve 1 ~ 5%, sulphur 4 ~ 20%, stearic acid 5 ~ 15%, all the other are aluminium powder.
2. glass fiber reinforcement aluminum matrix composite according to claim 1, it is characterized in that, the component containing following mass percentage: glass fibre 15 ~ 17%, boron oxide 6 ~ 8%, sodium oxide 6 ~ 7%, cobalt oxide 6%, zinc oxide 8%, moly-sulfide 3 ~ 4%, titanium valve 2 ~ 3%, sulphur 5 ~ 8%, stearic acid 7 ~ 9%, all the other are aluminium powder.
3. glass fiber reinforcement aluminum matrix composite according to claim 1, it is characterized in that, the component containing following mass percentage: glass fibre 16%, boron oxide 7%, sodium oxide 6%, cobalt oxide 6%, zinc oxide 8%, moly-sulfide 3%, titanium valve 2%, sulphur 6%, stearic acid 8%, all the other are aluminium powder.
4. the glass fiber reinforcement aluminum matrix composite according to any one of claim 1 ~ 3, is characterized in that, described glass fibre is resurrection glass fibre.
5. the preparation method of the glass fiber reinforcement aluminum matrix composite according to any one of claim 1 ~ 3, is characterized in that, comprise the steps:
(1) glass fibre, boron oxide, sodium oxide, cobalt oxide, zinc oxide, moly-sulfide, titanium valve, sulphur, stearic acid, aluminium powder are mixed, put into ball mill and carry out ground and mixed, evenly to be mixed, drop in mixing roll, be then dry mixed 1 ~ 2h;
(2) mixture of step (1) is put into mould, be under the condition of 0.01 ~ 0.05MPa in vacuum tightness, compression moulding at being heated to 160 ~ 180 DEG C, obtains pressed compact;
(3) pressed compact of step (2) is heated to 350 ~ 380 DEG C under the condition of protection of inert gas, keeps 40 ~ 60 minutes, obtain first product;
(4) by the first product of step (3) in vacuum tightness be 0.001 ~ 0.004MPa condition under be heated to 1150 ~ 1200 DEG C, be incubated 200 ~ 250 minutes, be then down to room temperature, obtain glass fiber reinforcement aluminum matrix composite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510546139.0A CN105154797A (en) | 2015-08-31 | 2015-08-31 | Glass fiber reinforcement aluminum matrix composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510546139.0A CN105154797A (en) | 2015-08-31 | 2015-08-31 | Glass fiber reinforcement aluminum matrix composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105154797A true CN105154797A (en) | 2015-12-16 |
Family
ID=54795834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510546139.0A Pending CN105154797A (en) | 2015-08-31 | 2015-08-31 | Glass fiber reinforcement aluminum matrix composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105154797A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105624478A (en) * | 2016-02-29 | 2016-06-01 | 苏州莱特复合材料有限公司 | Magnesium stearate reinforced aluminum matrix composite and preparation method thereof |
| CN105670115A (en) * | 2016-02-29 | 2016-06-15 | 苏州莱特复合材料有限公司 | Polypropylene resin modified aluminum matrix composite material and preparation method thereof |
| CN105779914A (en) * | 2016-03-01 | 2016-07-20 | 苏州莱特复合材料有限公司 | Aluminum matrix composite for automobile brake calipers and preparation method of such composite |
| CN106893922A (en) * | 2015-12-18 | 2017-06-27 | 赵凤宇 | A kind of low crystallization point devitrified glass and metal aluminium composite material and preparation method thereof |
| CN107099759A (en) * | 2017-03-18 | 2017-08-29 | 华南理工大学 | A kind of silicon dioxide fibre reinforced aluminum matrix composites and preparation method thereof |
| CN114635097A (en) * | 2022-03-14 | 2022-06-17 | 上海兰钧新能源科技有限公司 | Aluminum foil for lithium battery and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2333714Y (en) * | 1998-06-17 | 1999-08-18 | 苏雷虹 | Fiber glass containing aluminum base alloy section |
| WO2005054536A2 (en) * | 2003-12-01 | 2005-06-16 | Touchstone Research Laboratory, Ltd. | Glass fiber metal matrix composites |
| CN103233189A (en) * | 2013-04-18 | 2013-08-07 | 邱献腾 | Aluminum matrix composite material and processing technology thereof |
| CN103556087A (en) * | 2013-11-04 | 2014-02-05 | 倪生标 | Aluminum alloy panel |
| CN104384499A (en) * | 2014-10-28 | 2015-03-04 | 苏州莱特复合材料有限公司 | Powder metallurgy composite material and preparation method thereof |
| CN104388759A (en) * | 2014-10-24 | 2015-03-04 | 苏州莱特复合材料有限公司 | Aluminum matrix composite material and method for preparing powder alloy of aluminum matrix composite material |
| CN104762569A (en) * | 2015-03-23 | 2015-07-08 | 蚌埠南自仪表有限公司 | Fly ash aluminium-based composite material with high fatigue strength and preparation method thereof |
-
2015
- 2015-08-31 CN CN201510546139.0A patent/CN105154797A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2333714Y (en) * | 1998-06-17 | 1999-08-18 | 苏雷虹 | Fiber glass containing aluminum base alloy section |
| WO2005054536A2 (en) * | 2003-12-01 | 2005-06-16 | Touchstone Research Laboratory, Ltd. | Glass fiber metal matrix composites |
| CN103233189A (en) * | 2013-04-18 | 2013-08-07 | 邱献腾 | Aluminum matrix composite material and processing technology thereof |
| CN103556087A (en) * | 2013-11-04 | 2014-02-05 | 倪生标 | Aluminum alloy panel |
| CN104388759A (en) * | 2014-10-24 | 2015-03-04 | 苏州莱特复合材料有限公司 | Aluminum matrix composite material and method for preparing powder alloy of aluminum matrix composite material |
| CN104384499A (en) * | 2014-10-28 | 2015-03-04 | 苏州莱特复合材料有限公司 | Powder metallurgy composite material and preparation method thereof |
| CN104762569A (en) * | 2015-03-23 | 2015-07-08 | 蚌埠南自仪表有限公司 | Fly ash aluminium-based composite material with high fatigue strength and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106893922A (en) * | 2015-12-18 | 2017-06-27 | 赵凤宇 | A kind of low crystallization point devitrified glass and metal aluminium composite material and preparation method thereof |
| CN105624478A (en) * | 2016-02-29 | 2016-06-01 | 苏州莱特复合材料有限公司 | Magnesium stearate reinforced aluminum matrix composite and preparation method thereof |
| CN105670115A (en) * | 2016-02-29 | 2016-06-15 | 苏州莱特复合材料有限公司 | Polypropylene resin modified aluminum matrix composite material and preparation method thereof |
| CN105779914A (en) * | 2016-03-01 | 2016-07-20 | 苏州莱特复合材料有限公司 | Aluminum matrix composite for automobile brake calipers and preparation method of such composite |
| CN107099759A (en) * | 2017-03-18 | 2017-08-29 | 华南理工大学 | A kind of silicon dioxide fibre reinforced aluminum matrix composites and preparation method thereof |
| CN114635097A (en) * | 2022-03-14 | 2022-06-17 | 上海兰钧新能源科技有限公司 | Aluminum foil for lithium battery and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105154797A (en) | Glass fiber reinforcement aluminum matrix composite material and preparation method thereof | |
| CN103600065B (en) | A kind of powder metallurgical gear and preparation method thereof | |
| CN103601498B (en) | Preparation method of Ti3AlC2 ceramic powder | |
| CN107245621A (en) | A kind of wear-and corrosion-resistant molybdenum alloy and preparation method thereof | |
| CN103537664A (en) | Powder metallurgy composite material and manufacturing method thereof | |
| CN102211925A (en) | Method for preparing micro and nano composite ceramic material | |
| CN103864426B (en) | A kind of intermediate sintering temperature temperature-stabilized microwave medium ceramic material | |
| CN105271207A (en) | Preparation process of isostatic pressing isotropic graphite | |
| CN108083806A (en) | A kind of hyperfine structure isotropic graphite and preparation method thereof | |
| CN103600060A (en) | Powder metallurgy metal bearing material and manufacturing method thereof | |
| CN105440642A (en) | Modified polycarbonate engineering plastic and preparation method of modified polycarbonate engineering plastic | |
| CN108218432A (en) | A kind of processing technology of radiation shielded components boron carbide agglomerate | |
| CN101717253A (en) | Al2O3/Ti2AlC ceramic composite material and preparation method thereof | |
| CN104961445A (en) | Composite ceramic material used for crucible and preparation method thereof | |
| CN105154770A (en) | Phenolic resin reinforcement iron-based composite material and preparation method thereof | |
| CN105624478A (en) | Magnesium stearate reinforced aluminum matrix composite and preparation method thereof | |
| CN107500776A (en) | A kind of polycrystalline CBN cutting tool material and preparation method thereof | |
| CN102990054B (en) | Rare earth molybdenum crucible blank and utilize this blank to manufacture the method for rare earth molybdenum crucible | |
| CN107935556B (en) | Preparation method of nano ceramic binder | |
| CN103409691A (en) | Powder metallurgy tool steel and preparation method thereof | |
| CN104818555A (en) | Composite glass fiber production process | |
| CN109336605A (en) | A kind of special charcoal product preparation method for adding graphite cathode material | |
| CN101734921A (en) | Ti2AlN machinable material and preparation method thereof | |
| CN105622108A (en) | Method for in-situ synthesis of Si3N4-Si2N2O-TiN ternary compound powder | |
| CN105733257A (en) | Glass fiber-modified wear-resistant polyimide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151216 |