CN105153636A - Heat-resistant refractory wallboard with excellent mechanical properties - Google Patents
Heat-resistant refractory wallboard with excellent mechanical properties Download PDFInfo
- Publication number
- CN105153636A CN105153636A CN201510435590.5A CN201510435590A CN105153636A CN 105153636 A CN105153636 A CN 105153636A CN 201510435590 A CN201510435590 A CN 201510435590A CN 105153636 A CN105153636 A CN 105153636A
- Authority
- CN
- China
- Prior art keywords
- parts
- heat
- wallboard
- mechanical performance
- nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a heat-resistant refractory wallboard with excellent mechanical properties. The heat-resistant refractory wallboard comprises a base layer, a bonding layer, a fireproof layer, a decorative coating and a wear-resistant layer, wherein the fireproof layer is made from a refractory material. The refractory material is prepared from the raw materials in parts by weight: 20-30 parts of urea-formaldehyde resin, 10-20 parts of polyvinyl acetate emulsion, 10-15 parts of fatty-alcohol polyethylene oxide ether, 20-30 parts of composite nano-material, 10-20 parts of aluminum hydroxide, 5-20 parts of bauxite, 10-20 parts of magnesite, 5-10 parts of waste/used alumina bricks, 10-16 parts of glass micro-beads, 15-30 parts of kaolin, 3-5 parts of ammonium polyphosphate, 1-3 parts of ammonium borate, 5-10 parts of polypropylene staple fibers, 10-12 parts of staple fibers, 5-10 parts of carboxymethyl cellulose and 1-2 parts of surfactant. The heat-resistant refractory wallboard is excellent in refractability, good in mechanical properties and long in service life.
Description
Technical field
The present invention relates to wallboard technical field, particularly relate to a kind of wallboard of heat and flame excellent in mechanical performance.
Background technology
In the fp measure of panel structure, consider from the accessibility of cost performance and construction, wallboard frie retardant coating is the optimal selection of wallboard flameproof protection, frie retardant coating is coated in substrate surface by tack coat, although constantly there is all kinds of frie retardant coating in wallboard industry, though fire prevention can be realized, but product also exists heat and flame and does not reach demand, poor mechanical property causes long-time coating easily to come off, the shortcomings such as work-ing life is short, though produced multiple fire-resistant wallboard but still can not meet current needs at present, how to prepare a kind of heat and flame excellent performance, mechanical property is good, the wallboard of long service life becomes the current technical issues that need to address.
Summary of the invention
The present invention proposes a kind of wallboard of heat and flame excellent in mechanical performance, high temperature resistant excellent fire retarding performance, mechanical property is good, long service life.
A kind of wallboard of heat and flame excellent in mechanical performance that the present invention proposes, comprise set gradually from the inside to the outside basic unit, tack coat, fireproofing, decorative coveringn and wearing layer, wherein fireproofing adopts refractory materials preparation;
The raw material of described refractory materials comprises by weight: urea-formaldehyde resin 20-30 part, aqueous polyvinyl acetate emulsion 10-20 part, poly alkyl alcohol ethylene oxide ether 10-15 part, composite nano materials 20-30 part, aluminium hydroxide 10-20 part, bauxitic clay 5-20 part, magnesia 10-20 part, waste and old high alumina brick 5-10 part, glass microballon 10-16 part, kaolin 15-30 part, ammonium polyphosphate 3-5 part, ammonium borate 1-3 part, polypropene staple 5-10 part, staple fibre 10-12 part, carboxymethyl cellulose 5-10 part, tensio-active agent 1-2 part.
Preferably, the weight ratio of urea-formaldehyde resin, aqueous polyvinyl acetate emulsion and poly alkyl alcohol ethylene oxide ether is 24-26:12-14:12-14.
Preferably, composite nano materials, aluminium hydroxide, bauxitic clay, magnesia, waste and old high alumina brick, glass microballon and kaolinic weight ratio are 24-26:16-18:10-14:12-16:6-8:12-14:20-24.
Preferably, the weight ratio of ammonium polyphosphate and ammonium borate is 3.5-4:2-2.6.
Preferably, the raw material of described refractory materials comprises by weight: urea-formaldehyde resin 24-26 part, aqueous polyvinyl acetate emulsion 12-14 part, poly alkyl alcohol ethylene oxide ether 12-14 part, composite nano materials 24-26 part, aluminium hydroxide 16-18 part, bauxitic clay 10-14 part, magnesia 12-16 part, waste and old high alumina brick 6-8 part, glass microballon 12-14 part, kaolin 20-24 part, ammonium polyphosphate 3.5-4 part, ammonium borate 2-2.6 part, polypropene staple 6-8 part, staple fibre 10.4-11 part, carboxymethyl cellulose 6-8 part, tensio-active agent 1.2-1.6 part.
Preferably, composite nano materials adopts following technique to prepare: take 10-30 part corundum brick by weight, 5-20 part magnesia chrome brick mixes, add 5-10 part nano aluminium oxide, 1-6 part nano silicon oxide and 2-8 part nano-sized iron oxide material mixing wherein even, then send in runner milling and mill, 1-4 part tetra-sodium type monoalkoxy class titanic acid ester is added in mill processes, the speed that adds of tetra-sodium type monoalkoxy class titanic acid ester is 0.1-0.5 part/h, add completely and continue the 1-2h that mills, obtain composite nano materials.
Preferably, the weight ratio of corundum brick and magnesia chrome brick is 20-24:10-16.
Preferably, the weight ratio of nano aluminium oxide, nano silicon oxide and nano oxidized iron material is 6-8:2-4:4-6.
Preferably, composite nano materials adopts following technique to prepare: take 20-24 part corundum brick by weight, 10-16 part magnesia chrome brick mixes, add 6-8 part nano aluminium oxide, 2-4 part nano silicon oxide and 4-6 part nano-sized iron oxide material mixing wherein even, then send in runner milling and mill, 2-2.6 part tetra-sodium type monoalkoxy class titanic acid ester is added in mill processes, the speed that adds of tetra-sodium type monoalkoxy class titanic acid ester is 0.2-0.4 part/h, add completely and continue the 1-2h that mills, obtain composite nano materials.
In the present invention, use urea-formaldehyde resin, aqueous polyvinyl acetate emulsion and poly alkyl alcohol ethylene oxide ether are as the base material of refractory materials, by rational proportion three ratio in the feed, and control three's gross weight shared in the feed, goods heat decomposition temperature is apparently higher than common refractory, with composite nano materials, aluminium hydroxide, bauxitic clay, magnesia, waste and old high alumina brick, glass microballon and kaolin acting in conjunction, goods fire performance strengthens further, the ammonium polyphosphate of further interpolation, the thermostability of ammonium borate is high, act synergistically with unclassified stores, goods long service life, fire performance strengthens further, wherein in composite nano materials, component acting in conjunction in composite nano materials, greatly can improve Mechanical Properties of Products, and resistance to elevated temperatures is high, and add nano aluminium oxide, nano silicon oxide, nano oxidized iron material and tetra-sodium type monoalkoxy class titanic acid ester can effective closed article internal porosities, improve product volume density, goods compactness is excellent, during presence of fire, the settled layer of one deck densification can be generated, goods fire performance is very excellent, and the dense deposited layer formed can effectively maintain flame retardant coating slump, products safety is excellent.Excellent fire retarding performance of the present invention, mechanical property is good, long service life.
Embodiment
Embodiment 1
A wallboard for heat and flame excellent in mechanical performance, comprise set gradually from the inside to the outside basic unit, tack coat, fireproofing, decorative coveringn and wearing layer, wherein fireproofing adopts refractory materials preparation;
The raw material of described refractory materials comprises by weight: urea-formaldehyde resin 20 parts, aqueous polyvinyl acetate emulsion 20 parts, 10 parts, poly alkyl alcohol ethylene oxide ether, composite nano materials 30 parts, 10 parts, aluminium hydroxide, bauxitic clay 20 parts, 10 parts, magnesia, waste and old high alumina brick 10 parts, glass microballon 10 parts, kaolin 30 parts, ammonium polyphosphate 3 parts, ammonium borate 3 parts, polypropene staple 5 parts, 12 parts, staple fibre, carboxymethyl cellulose 5 parts, 2 parts, tensio-active agent.
Embodiment 2
A wallboard for heat and flame excellent in mechanical performance, comprise set gradually from the inside to the outside basic unit, tack coat, fireproofing, decorative coveringn and wearing layer, wherein fireproofing adopts refractory materials preparation;
The raw material of described refractory materials comprises by weight: urea-formaldehyde resin 30 parts, aqueous polyvinyl acetate emulsion 10 parts, 15 parts, poly alkyl alcohol ethylene oxide ether, composite nano materials 20 parts, 20 parts, aluminium hydroxide, bauxitic clay 5 parts, 20 parts, magnesia, waste and old high alumina brick 5 parts, glass microballon 16 parts, kaolin 15 parts, ammonium polyphosphate 5 parts, ammonium borate 1 part, polypropene staple 10 parts, 10 parts, staple fibre, carboxymethyl cellulose 10 parts, 1 part, tensio-active agent.
Embodiment 3
A wallboard for heat and flame excellent in mechanical performance, comprise set gradually from the inside to the outside basic unit, tack coat, fireproofing, decorative coveringn and wearing layer, wherein fireproofing adopts refractory materials preparation;
The raw material of described refractory materials comprises by weight: urea-formaldehyde resin 24 parts, aqueous polyvinyl acetate emulsion 14 parts, 12 parts, poly alkyl alcohol ethylene oxide ether, composite nano materials 26 parts, 16 parts, aluminium hydroxide, bauxitic clay 14 parts, 12 parts, magnesia, waste and old high alumina brick 8 parts, glass microballon 12 parts, kaolin 24 parts, ammonium polyphosphate 3.5 parts, ammonium borate 2.6 parts, polypropene staple 6 parts, 11 parts, staple fibre, carboxymethyl cellulose 6 parts, 1.6 parts, tensio-active agent.
Composite nano materials adopts following technique to prepare: take 10 parts of corundum bricks by weight, 20 parts of magnesia chrome bricks mix, add 5 parts of nano aluminium oxides, 6 parts of nano silicon oxides and 2 parts of nano-sized iron oxide material mixing wherein even, then send in runner milling and mill, 4 parts of tetra-sodium type monoalkoxy class titanic acid ester are added in mill processes, the speed that adds of tetra-sodium type monoalkoxy class titanic acid ester is 0.1 part/h, add completely and continue the 1h that mills, obtain composite nano materials.
Embodiment 4
A wallboard for heat and flame excellent in mechanical performance, comprise set gradually from the inside to the outside basic unit, tack coat, fireproofing, decorative coveringn and wearing layer, wherein fireproofing adopts refractory materials preparation;
The raw material of described refractory materials comprises by weight: urea-formaldehyde resin 26 parts, aqueous polyvinyl acetate emulsion 12 parts, 14 parts, poly alkyl alcohol ethylene oxide ether, composite nano materials 24 parts, 18 parts, aluminium hydroxide, bauxitic clay 10 parts, 16 parts, magnesia, waste and old high alumina brick 6 parts, glass microballon 14 parts, kaolin 20 parts, ammonium polyphosphate 4 parts, ammonium borate 2 parts, polypropene staple 8 parts, 10.4 parts, staple fibre, carboxymethyl cellulose 8 parts, 1.2 parts, tensio-active agent.
Composite nano materials adopts following technique to prepare: take 30 parts of corundum bricks by weight, 5 parts of magnesia chrome bricks mix, add 10 parts of nano aluminium oxides, 1 part of nano silicon oxide and 8 parts of nano-sized iron oxide material mixing wherein even, then send in runner milling and mill, 1 part of tetra-sodium type monoalkoxy class titanic acid ester is added in mill processes, the speed that adds of tetra-sodium type monoalkoxy class titanic acid ester is 0.5 part/h, add completely and continue the 2h that mills, obtain composite nano materials.
Embodiment 5
A wallboard for heat and flame excellent in mechanical performance, comprise set gradually from the inside to the outside basic unit, tack coat, fireproofing, decorative coveringn and wearing layer, wherein fireproofing adopts refractory materials preparation;
The raw material of described refractory materials comprises by weight: urea-formaldehyde resin 25 parts, aqueous polyvinyl acetate emulsion 13 parts, 13 parts, poly alkyl alcohol ethylene oxide ether, composite nano materials 25 parts, 17 parts, aluminium hydroxide, bauxitic clay 12 parts, 13 parts, magnesia, waste and old high alumina brick 7 parts, glass microballon 13 parts, kaolin 22 parts, ammonium polyphosphate 3.8 parts, ammonium borate 2.3 parts, polypropene staple 7 parts, 10.6 parts, staple fibre, carboxymethyl cellulose 7 parts, 1.4 parts, tensio-active agent.
Composite nano materials adopts following technique to prepare: take 20 parts of corundum bricks by weight, 12 parts of magnesia chrome bricks mix, add 8 parts of nano aluminium oxides, 4 parts of nano silicon oxides and 5 parts of nano-sized iron oxide material mixing wherein even, then send in runner milling and mill, 3 parts of tetra-sodium type monoalkoxy class titanic acid ester are added in mill processes, the speed that adds of tetra-sodium type monoalkoxy class titanic acid ester is 0.3 part/h, add completely and continue the 1.2h that mills, obtain composite nano materials.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (9)
1. a wallboard for heat and flame excellent in mechanical performance, is characterized in that, comprise set gradually from the inside to the outside basic unit, tack coat, fireproofing, decorative coveringn and wearing layer, wherein fireproofing adopts refractory materials preparation;
The raw material of described refractory materials comprises by weight: urea-formaldehyde resin 20-30 part, aqueous polyvinyl acetate emulsion 10-20 part, poly alkyl alcohol ethylene oxide ether 10-15 part, composite nano materials 20-30 part, aluminium hydroxide 10-20 part, bauxitic clay 5-20 part, magnesia 10-20 part, waste and old high alumina brick 5-10 part, glass microballon 10-16 part, kaolin 15-30 part, ammonium polyphosphate 3-5 part, ammonium borate 1-3 part, polypropene staple 5-10 part, staple fibre 10-12 part, carboxymethyl cellulose 5-10 part, tensio-active agent 1-2 part.
2. the wallboard of heat and flame excellent in mechanical performance according to claim 1, is characterized in that, the weight ratio of urea-formaldehyde resin, aqueous polyvinyl acetate emulsion and poly alkyl alcohol ethylene oxide ether is 24-26:12-14:12-14.
3. the wallboard of heat and flame excellent in mechanical performance according to claim 1 and 2, it is characterized in that, composite nano materials, aluminium hydroxide, bauxitic clay, magnesia, waste and old high alumina brick, glass microballon and kaolinic weight ratio are 24-26:16-18:10-14:12-16:6-8:12-14:20-24.
4. the wallboard of the heat and flame excellent in mechanical performance according to any one of claim 1-3, is characterized in that, the weight ratio of ammonium polyphosphate and ammonium borate is 3.5-4:2-2.6.
5. the wallboard of the heat and flame excellent in mechanical performance according to any one of claim 1-4, it is characterized in that, the raw material of described refractory materials comprises by weight: urea-formaldehyde resin 24-26 part, aqueous polyvinyl acetate emulsion 12-14 part, poly alkyl alcohol ethylene oxide ether 12-14 part, composite nano materials 24-26 part, aluminium hydroxide 16-18 part, bauxitic clay 10-14 part, magnesia 12-16 part, waste and old high alumina brick 6-8 part, glass microballon 12-14 part, kaolin 20-24 part, ammonium polyphosphate 3.5-4 part, ammonium borate 2-2.6 part, polypropene staple 6-8 part, staple fibre 10.4-11 part, carboxymethyl cellulose 6-8 part, tensio-active agent 1.2-1.6 part.
6. the wallboard of the heat and flame excellent in mechanical performance according to any one of claim 1-5, it is characterized in that, composite nano materials adopts following technique to prepare: take 10-30 part corundum brick by weight, 5-20 part magnesia chrome brick mixes, add 5-10 part nano aluminium oxide wherein, 1-6 part nano silicon oxide and 2-8 part nano-sized iron oxide material mixing even, then send in runner milling and mill, 1-4 part tetra-sodium type monoalkoxy class titanic acid ester is added in mill processes, the speed that adds of tetra-sodium type monoalkoxy class titanic acid ester is 0.1-0.5 part/h, add completely and continue the 1-2h that mills, obtain composite nano materials.
7. the wallboard of heat and flame excellent in mechanical performance according to claim 6, is characterized in that, the weight ratio of corundum brick and magnesia chrome brick is 20-24:10-16.
8. the wallboard of the heat and flame excellent in mechanical performance according to claim 6 or 7, is characterized in that, the weight ratio of nano aluminium oxide, nano silicon oxide and nano oxidized iron material is 6-8:2-4:4-6.
9. the wallboard of the heat and flame excellent in mechanical performance according to any one of claim 1-8, it is characterized in that, composite nano materials adopts following technique to prepare: take 20-24 part corundum brick by weight, 10-16 part magnesia chrome brick mixes, add 6-8 part nano aluminium oxide wherein, 2-4 part nano silicon oxide and 4-6 part nano-sized iron oxide material mixing even, then send in runner milling and mill, 2-2.6 part tetra-sodium type monoalkoxy class titanic acid ester is added in mill processes, the speed that adds of tetra-sodium type monoalkoxy class titanic acid ester is 0.2-0.4 part/h, add completely and continue the 1-2h that mills, obtain composite nano materials.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510435590.5A CN105153636A (en) | 2015-07-21 | 2015-07-21 | Heat-resistant refractory wallboard with excellent mechanical properties |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510435590.5A CN105153636A (en) | 2015-07-21 | 2015-07-21 | Heat-resistant refractory wallboard with excellent mechanical properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105153636A true CN105153636A (en) | 2015-12-16 |
Family
ID=54794703
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510435590.5A Pending CN105153636A (en) | 2015-07-21 | 2015-07-21 | Heat-resistant refractory wallboard with excellent mechanical properties |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105153636A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105694323A (en) * | 2016-04-11 | 2016-06-22 | 苏州甫众塑胶有限公司 | Manufacturing method of fireproof heat-insulation energy-saving composite plate |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101672090A (en) * | 2009-08-07 | 2010-03-17 | 长沙威特消防新材料科技有限公司 | Light fireproofing heat preservation partition board and preparation method thereof |
| CN102040790A (en) * | 2009-08-18 | 2011-05-04 | 中国科学院成都有机化学有限公司 | Fireproof polyvinyl acetate emulsion and preparation method thereof |
| CN202925697U (en) * | 2012-08-01 | 2013-05-08 | 王志勇 | Composite insulation board |
| CN103641496A (en) * | 2013-11-26 | 2014-03-19 | 江苏博思源防火材料科技有限公司 | Expansive type tunnel fireproof paint |
| CN203834794U (en) * | 2014-05-28 | 2014-09-17 | 中铁十一局集团有限公司 | Building heat-preservation wall board for civil engineering |
-
2015
- 2015-07-21 CN CN201510435590.5A patent/CN105153636A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101672090A (en) * | 2009-08-07 | 2010-03-17 | 长沙威特消防新材料科技有限公司 | Light fireproofing heat preservation partition board and preparation method thereof |
| CN102040790A (en) * | 2009-08-18 | 2011-05-04 | 中国科学院成都有机化学有限公司 | Fireproof polyvinyl acetate emulsion and preparation method thereof |
| CN202925697U (en) * | 2012-08-01 | 2013-05-08 | 王志勇 | Composite insulation board |
| CN103641496A (en) * | 2013-11-26 | 2014-03-19 | 江苏博思源防火材料科技有限公司 | Expansive type tunnel fireproof paint |
| CN203834794U (en) * | 2014-05-28 | 2014-09-17 | 中铁十一局集团有限公司 | Building heat-preservation wall board for civil engineering |
Non-Patent Citations (4)
| Title |
|---|
| 包彦坤等: "《熔模精密铸造技术》", 31 August 2012 * |
| 李小明: "《铁合金生产概论》", 30 September 2014 * |
| 林育炼: "《耐火材料与洁净钢生产技术》", 30 April 2012 * |
| 谈国强: "《硅酸盐工业产品性能及测试分析》", 31 August 2004 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105694323A (en) * | 2016-04-11 | 2016-06-22 | 苏州甫众塑胶有限公司 | Manufacturing method of fireproof heat-insulation energy-saving composite plate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10941074B2 (en) | Composition for plasterboards and products obtained | |
| CN104788115A (en) | Fireproof spraying coating for steel ladle working lining and preparation method of fireproof spraying coating | |
| CN105565794A (en) | Preparation method of low-heat-conductivity magnesia-alumina spinel brick | |
| EP2690077A1 (en) | Ceramic compositions | |
| JP7381744B2 (en) | All-fiber burna tile and method for manufacturing the same | |
| EP4026876B1 (en) | High-temperature-resistant nano composite coating and preparation method therefor | |
| Wang et al. | The preparation and property analysis of B4C modified inorganic amorphous aluminum phosphates-based intumescent flame retardant coating | |
| CN105152676A (en) | High-performance heat-insulating inner wall board | |
| CN105153636A (en) | Heat-resistant refractory wallboard with excellent mechanical properties | |
| CA1144307A (en) | Refractory gun mix | |
| CN106699207A (en) | Fired magnesia-calcium brick and preparation method thereof | |
| US6090315A (en) | Fire retarding additive | |
| CN104829246A (en) | Refractory spray paint for a steel ladle work lining and preparation method thereof | |
| CN106433341A (en) | Indoor expansive type fireproof steel structure coating and preparation method thereof | |
| CN105153706A (en) | High-performance refractory wallboard | |
| WO2013147354A1 (en) | Cementless high strength amorphous refractory material | |
| CN110723955A (en) | Fireproof material and preparation method thereof | |
| CN105481408A (en) | Composite refractory brick | |
| CN102417323A (en) | Silicon-aluminum-magnesium fire-proof plate | |
| CN105399431A (en) | Light-weight thermal-insulation refractory material and preparation technology thereof | |
| CN105669220A (en) | Recycled alumina-chrome brick for Ausmelt furnace inner liner, and making method thereof | |
| JP6244813B2 (en) | Inorganic fiber fireproof insulation lining construction method | |
| RU2792077C1 (en) | High-temperature nanocomposite coating and method of its preparation, as well as coating for flexible packaging in the form of a small bag | |
| EP3914567A1 (en) | Building material | |
| US20130122207A1 (en) | Method of forming ceramic coatings and ceramic coatings and structures formed thereby |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151216 |
|
| RJ01 | Rejection of invention patent application after publication |