CN105153544A - Polypropylene-bacterial cellulose composite material and preparation method thereof - Google Patents
Polypropylene-bacterial cellulose composite material and preparation method thereof Download PDFInfo
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- CN105153544A CN105153544A CN201510646381.5A CN201510646381A CN105153544A CN 105153544 A CN105153544 A CN 105153544A CN 201510646381 A CN201510646381 A CN 201510646381A CN 105153544 A CN105153544 A CN 105153544A
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- C08B3/08—Preparation of cellulose esters of organic acids of monobasic organic acids with three or more carbon atoms, e.g. propionate or butyrate
- C08B3/10—Preparation of cellulose esters of organic acids of monobasic organic acids with three or more carbon atoms, e.g. propionate or butyrate with five or more carbon-atoms, e.g. valerate
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Abstract
The invention relates to a polypropylene-bacteria cellulose composite material and a preparation method thereof. The composite material comprises the following components in percentage by weight: 97-99.5wt% of a polypropylene homopolymer and 0.5-3wt% of esterification modified bacteria cellulose powder. The invention further provides the preparation method which comprises the following steps: mixing the polypropylene homopolymer and the esterification modified bacteria cellulose powder, conducting melt-blending and extrusion on the mixture at 170-200 DEG C with a double-screw extruder, and then carrying out strip casting, pelletization and injection molding to obtain the composite material. The polypropylene homopolymer and the esterification modified bacteria cellulose powder are mixed by the double-screw extruder, so that the esterification modified bacteria cellulose powder can uniformly disperse in a matrix of the polypropylene homopolymer, and compared with pure polypropylene, the composite material has the advantages that the tensile strength, the impact strength and the tensile modulus are improved by about 13%, 18% and 13% respectively.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of polypropylene composite material, particularly a kind of polypropylene/bacteria cellulose composite material and preparation method thereof.
Background technology
Polypropylene (iPP) is owing to having the premium propertiess such as fusing point is high, tensile strength is high, relative density is low, corrosion-resistant, become in existing five large resins for universal use and consume the fastest resin of rate of growth, be widely used in aerospace, electrically, the field such as automobile.Although polypropylene has the premium properties such as compound with regular structure, degree of crystallinity height, traditional polypropylene has impact property difference, and embrittlement temperature is high, waits very important shortcoming.So greatly limit its range of application to a certain extent.
Natural fiber Reinforced Polypropylene is the emphasis that Recent study work is paid close attention to.Although natural fiber has the advantages such as light weight, inexpensive, raw material is easy to get, and the intensity of in most of the cases compound system can meet general application requiring.But the ununiformity of natural fiber and greatly limit its application in polypropylene with the uncompatibility of matrix resin.
Bacteria cellulose (BC), although have identical molecular structure unit with natural plant fiber, compares with natural cellulose and has much distinctive character.As homogeneous in appearance structure, smooth surface; Degree of crystallinity, the polymerization degree are higher; Tensile strength, Young's modulus are high; Can artificial regulatory etc. when biosynthesizing.Based on above characteristic, bacteria cellulose and polypropylene composite materials, not only can possess the advantage of polypropylene/natural-fiber composite material, can make up again the deficiency of natural fiber, thus give polypropylene better mechanical property.
In order to improve the consistency of bacteria cellulose and polypropylene matrix, need to carry out pre-treatment to bacteria cellulose.Usually, treatment process has coupling agent treatment, esterification modification etc.By the pre-treatment to bacteria cellulose, the mechanical property of matrix material can be significantly improved, crystal property etc.Relevant report is had no about this type of research.
Summary of the invention
The object of the present invention is to provide a kind of polypropylene/bacteria cellulose composite material of strong mechanical performance.
Another object of the present invention is to adopt capryl(yl)chloride as esterification modification agent, at a certain temperature esterification modification is carried out to bacteria cellulose, prepare the bacteria cellulose powder of esterification modification.
In order to realize foregoing invention object, technical scheme of the present invention is as follows: a kind of polypropylene/bacteria cellulose composite material, by weight percentage, composed of the following components: the bacteria cellulose powder 0.5 ~ 3wt% of homopolymer polypropylene 97 ~ 99.5wt% and esterification modification.The invention provides a kind of polypropylene/bacteria cellulose composite material of strong mechanical performance.
Preferably, the bacteria cellulose powder of described esterification modification is obtained by capryl(yl)chloride esterification modification bacteria cellulose.Esterification modification is carried out to bacteria cellulose, bacteria cellulose lipophilicity can be made to strengthen, make bacteria cellulose can form nano-dispersed in polypropylene matrix, thus improve the performance of polypropylene/bacteria cellulose composite material.
Preferably, the bacteria cellulose of described esterification modification is prepared by the following method: by the bacteria cellulose of 100 weight parts, 1000 ~ 3000 weight part capryl(yl)chlorides and 500 ~ 4000 weight part pyridines, join successively in reaction vessel, under 60 ~ 100 DEG C of conditions, react 4 ~ 8 hours, reaction product rinsed and dries, obtaining the bacteria cellulose of esterification modification.
Further, by the bacteria cellulose deionized water wash of described esterification modification to neutral, drying, pulverize and sieve, obtain the bacteria cellulose powder of described esterification modification, the particle diameter of the bacteria cellulose powder of described esterification modification is 20 ~ 200nm.
Preferably, by weight percentage, composed of the following components: the bacteria cellulose powder 2% of homopolymer polypropylene 98% and esterification modification.When the weight percentage of bacteria cellulose powder in polypropylene/bacteria cellulose composite material of described esterification modification is 2%, tensile strength and the shock strength of gained polypropylene/bacteria cellulose composite material are the highest, and during more than 2%, the tensile strength of matrix material and shock strength have decline to a certain degree; When the content of bacteria cellulose powder in polypropylene/bacteria cellulose composite material of esterification modification increases, the tensile modulus of gained polypropylene/bacteria cellulose composite material significantly improves.
Preferably, the particle diameter of the bacteria cellulose powder of described esterification modification is 20 ~ 200nm, and the weight-average molecular weight of described homopolymer polypropylene is 20 ~ 400,000.
The present invention also proposes a kind of preparation method of polypropylene/bacteria cellulose composite material, it is made up of following steps: carried out being mixed to get mixture by the bacteria cellulose powder of the homopolymer polypropylene of 97 ~ 99.5wt% and the esterification modification of 0.5 ~ 3wt%, then described mixture twin screw extruder is carried out at temperature is 170 ~ 200 DEG C that melt blending is extruded, Cast Strip, granulation and injection moulding, i.e. obtained described polypropylene/bacteria cellulose composite material.The present invention by blended for the bacteria cellulose powder of homopolymer polypropylene and esterification modification, makes the bacteria cellulose powder of esterification modification can be uniformly dispersed in homopolymer polypropylene matrix by twin screw extruder.
Preferably, the particle diameter of the bacteria cellulose powder of described esterification modification is 20 ~ 200nm, and the weight-average molecular weight of described homopolymer polypropylene is 20 ~ 400,000.
The invention has the beneficial effects as follows: the present invention by twin screw extruder by blended for the bacteria cellulose powder of homopolymer polypropylene and esterification modification, bacteria cellulose powder is made to can be uniformly dispersed in homopolymer polypropylene matrix, the relative virgin pp of tensile strength of the polypropylene/bacteria cellulose composite material of gained improves about 13%, shock strength is improve about 18% compared with virgin pp, and tensile modulus also improves about 13% compared with virgin pp.
Accompanying drawing explanation
Accompanying drawing 1 is the variation diagram of tensile strength with the bacterial fibers cellulose content of esterification modification of the polypropylene/bacteria cellulose composite material of homopolymer polypropylene and the embodiment of the present invention 1 ~ 4 and comparative example 1 and comparative example 2;
Accompanying drawing 2 is the variation diagram of tensile modulus with the bacterial fibers cellulose content of esterification modification of the polypropylene/bacteria cellulose composite material of homopolymer polypropylene and the embodiment of the present invention 1 ~ 4 and comparative example 1 and comparative example 2;
Accompanying drawing 3 is the variation diagram of shock strength with the bacterial fibers cellulose content of esterification modification of the polypropylene/bacteria cellulose composite material of homopolymer polypropylene and the embodiment of the present invention 1 ~ 4 and comparative example 1 and comparative example 2.
Embodiment
Below in conjunction with specific examples, illustrate the present invention further.Should be appreciated that, these embodiments only for illustration of the present invention, and are not intended to limit the scope of the invention.The improvement made according to the present invention of technician and adjustment, still belong to protection scope of the present invention in actual applications.
Except special instruction, the raw material that the present invention uses, reagent and equipment for the art routine commercial, the method that the present invention adopts is the method that the art routine uses.
Wherein, polypropylene copolymer S1003 is purchased from Beijing yanshan petrochemical company limited, and homopolymer polypropylene is S1003, and the weight-average molecular weight of homopolymer polypropylene is 20 ~ 400,000; Bacteria cellulose is provided by Hainan hundred million moral Food Co., Ltd, and Acetyl Chloride 98Min., propionyl chloride, capryl(yl)chloride are provided by Aladdin reagent company limited, and pyridine is provided by great Mao chemical plant, Tianjin.
The mensuration of the testing method foundation GB/T1040.2-2006 plastic tensile performance of tensile strength, tensile modulus and shock strength.
Embodiment 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part capryl(yl)chlorides, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 99.5% and 0.5% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part Acetyl Chloride 98Min.s, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 99.5% and 0.5% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part propionyl chlorides, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 99.5% and 0.5% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Embodiment 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part capryl(yl)chlorides, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 99% and 1% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part Acetyl Chloride 98Min.s, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 99% and 1% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part propionyl chlorides, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 99% and 1% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Embodiment 3
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part capryl(yl)chlorides, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 98% and 2% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part Acetyl Chloride 98Min.s, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 98% and 2% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part propionyl chlorides, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 98% and 2% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Embodiment 4
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part capryl(yl)chlorides, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 97% and 3% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part Acetyl Chloride 98Min.s, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 97% and 3% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 2000 weight part propionyl chlorides, 2000 weight part pyridines, under 80 DEG C of conditions, react 6 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 97% and 3% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Comparative example 3
By weight percentage, the homopolymer polypropylene twin screw extruder of 100% is carried out melt blending at temperature is 170 ~ 200 DEG C, obtains polypropylene material by injection moulding machine injection moulding.
Embodiment 1 ~ 4 and comparative example 1 thereof and comparative example 2, prepare the bacteria cellulose composite material (iPP/CA) of the bacteria cellulose composite material (iPP/CO) of gained polypropylene and capryl(yl)chloride esterification modification, polypropylene and Acetyl Chloride 98Min. esterification modification and the bacteria cellulose composite material (iPP/CP) of polypropylene and propionyl chloride esterification modification respectively, with comparative example 3 for contrast, its mechanical property compares, and concrete mechanical property is shown in shown in Fig. 1,2,3.
As can be seen from Fig. 1, Fig. 2, Fig. 3, the mechanical property of the polypropylene/bacteria cellulose composite material of gained is according to the order of adding Acetyl Chloride 98Min., propionyl chloride, capryl(yl)chloride modified bacteria cellulose, the relative neat polypropylene homopolymer of tensile strength of matrix material improves about 1%, 11%, 13% respectively, tensile modulus is improve about 14%, 16%, 18% compared with neat polypropylene homopolymer, and shock strength is improve about 6%, 15%, 18% compared with neat polypropylene homopolymer.
Therefore, when the content of bacteria cellulose powder in polypropylene/bacteria cellulose composite material of esterification modification increases, the tensile modulus of gained polypropylene/bacteria cellulose composite material significantly improves, along with the bacteria cellulose of the growth institute modification of acyl chlorides molecule carbon chain and polyacrylic composite materials property also have very large growth.
Embodiment 5
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part capryl(yl)chlorides, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 99.5% and 0.5% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part Acetyl Chloride 98Min.s, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 99.5% and 0.5% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part propionyl chlorides, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 99.5% and 0.5% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Embodiment 6
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part capryl(yl)chlorides, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 99% and 1% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part Acetyl Chloride 98Min.s, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 99% and 1% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part propionyl chlorides, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 99% and 1% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Embodiment 7
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part capryl(yl)chlorides, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 98% and 2% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part Acetyl Chloride 98Min.s, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 98% and 2% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part propionyl chlorides, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 98% and 2% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Embodiment 8
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part capryl(yl)chlorides, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 97% and 3% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part Acetyl Chloride 98Min.s, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 97% and 3% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 1000 weight part propionyl chlorides, 500 weight part pyridines, under 60 DEG C of conditions, react 4 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 97% and 3% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Comparative example 3
By weight percentage, the homopolymer polypropylene twin screw extruder of 100% is carried out melt blending at temperature is 170 ~ 200 DEG C, obtains polypropylene material by injection moulding machine injection moulding.
Embodiment 5 ~ 8 and comparative example 1 thereof and comparative example 2, prepare the bacteria cellulose composite material (iPP/CO) of gained polypropylene and capryl(yl)chloride esterification modification respectively, the bacteria cellulose composite material (iPP/CA) of polypropylene and Acetyl Chloride 98Min. esterification modification and the bacteria cellulose composite material (iPP/CP) of polypropylene and propionyl chloride esterification modification, with comparative example 3 for contrast, its mechanical property compares, the mechanical property of the polypropylene/bacteria cellulose composite material of gained is according to interpolation Acetyl Chloride 98Min., propionyl chloride, the order of capryl(yl)chloride modified bacteria cellulose, along with the bacteria cellulose of the growth institute modification of acyl chlorides molecule carbon chain and polyacrylic composite materials property have very large growth, tensile strength, tensile modulus and shock strength all increase.
Embodiment 9
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part capryl(yl)chlorides, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 99.5% and 0.5% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part Acetyl Chloride 98Min.s, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 99.5% and 0.5% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part propionyl chlorides, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 99.5% and 0.5% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Embodiment 10
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part capryl(yl)chlorides, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 99% and 1% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part Acetyl Chloride 98Min.s, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 99% and 1% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part propionyl chlorides, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 99% and 1% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Embodiment 11
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part capryl(yl)chlorides, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 98% and 2% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part Acetyl Chloride 98Min.s, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 98% and 2% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part propionyl chlorides, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 98% and 2% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Embodiment 12
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part capryl(yl)chlorides, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CO) of capryl(yl)chloride esterification modification.
By weight percentage, the bacteria cellulose powder of capryl(yl)chloride esterification modification of the homopolymer polypropylene of 97% and 3% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CO matrix material by injection moulding machine injection moulding.
Comparative example 1
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part Acetyl Chloride 98Min.s, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CA) of Acetyl Chloride 98Min. esterification modification.
By weight percentage, the bacteria cellulose powder of Acetyl Chloride 98Min. esterification modification of the homopolymer polypropylene of 97% and 3% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CA matrix material by injection moulding machine injection moulding.
Comparative example 2
The bacteria cellulose of film like is extremely neutral with a large amount of deionized water wash, put into the dry 24h of freeze drier, pulverize with ball mill, then bacteria cellulose powder is crossed mesh screen, obtain the bacteria cellulose powder that particle diameter is 20 ~ 200nm.
By the bacteria cellulose powder of 100 weight parts of oven dry, 3000 weight part propionyl chlorides, 4000 weight part pyridines, under 100 DEG C of conditions, react 8 hours, reaction terminates rear deionized water and alcohol flushing product and dries, and obtains the bacteria cellulose (CP) of propionyl chloride esterification modification.
By weight percentage, the bacteria cellulose powder of propionyl chloride esterification modification of the homopolymer polypropylene of 97% and 3% is carried out Homogeneous phase mixing and obtains mixture, then mixture twin screw extruder is carried out melt blending at temperature is 170 ~ 200 DEG C, obtain iPP/CP matrix material by injection moulding machine injection moulding.
Comparative example 3
By weight percentage, the homopolymer polypropylene twin screw extruder of 100% is carried out melt blending at temperature is 170 ~ 200 DEG C, obtains polypropylene material by injection moulding machine injection moulding.
Embodiment 9 ~ 12 and comparative example 1 thereof and comparative example 2, prepare the bacteria cellulose composite material (iPP/CO) of gained polypropylene and capryl(yl)chloride esterification modification respectively, the bacteria cellulose composite material (iPP/CA) of polypropylene and Acetyl Chloride 98Min. esterification modification and the bacteria cellulose composite material (iPP/CP) of polypropylene and propionyl chloride esterification modification, with comparative example 3 for contrast, its mechanical property compares, the mechanical property of the polypropylene/bacteria cellulose composite material of gained is according to interpolation Acetyl Chloride 98Min., propionyl chloride, the order of capryl(yl)chloride modified bacteria cellulose, along with the bacteria cellulose of the growth institute modification of acyl chlorides molecule carbon chain and polyacrylic composite materials property have very large growth, tensile strength, tensile modulus and shock strength all increase.
Claims (10)
1. polypropylene/bacteria cellulose composite material, is characterized in that, by weight percentage, composed of the following components: the bacteria cellulose powder 0.5 ~ 3wt% of homopolymer polypropylene 97 ~ 99.5wt% and esterification modification.
2. polypropylene/bacteria cellulose composite material according to claim 1, is characterized in that: the bacteria cellulose powder of described esterification modification is obtained by capryl(yl)chloride esterification modification bacteria cellulose.
3. polypropylene/bacteria cellulose composite material according to claim 1 and 2, it is characterized in that, the bacteria cellulose of described esterification modification is prepared by the following method: by the bacteria cellulose of 100 weight parts, 1000 ~ 3000 weight part capryl(yl)chlorides and 500 ~ 4000 weight part pyridines, join successively in reaction vessel, under 60 ~ 100 DEG C of conditions, react 4 ~ 8 hours, reaction product rinsed and dries, obtaining the bacteria cellulose of esterification modification.
4. polypropylene/bacteria cellulose composite material according to claim 3, is characterized in that: by the bacteria cellulose deionized water wash of described esterification modification to neutral, drying, pulverizes and sieves, and obtains the bacteria cellulose powder of described esterification modification.
5. polypropylene/bacteria cellulose composite material according to claim 4, is characterized in that: the particle diameter of the bacteria cellulose powder of described esterification modification is 20 ~ 200nm.
6. polypropylene/bacteria cellulose composite material according to claim 1, is characterized in that, by weight percentage, composed of the following components: the bacteria cellulose powder 2% of homopolymer polypropylene 98% and esterification modification.
7. polypropylene/bacteria cellulose composite material according to claim 1, is characterized in that: the weight-average molecular weight of described homopolymer polypropylene is 20 ~ 400,000.
8. the preparation method of polypropylene/bacteria cellulose composite material according to claim 1, it is characterized in that, be made up of following steps: the bacteria cellulose powder of the homopolymer polypropylene of 97 ~ 99.5wt% and the esterification modification of 0.5 ~ 3wt% is carried out being mixed to get mixture, then described mixture twin screw extruder is carried out at temperature is 170 ~ 200 DEG C that melt blending is extruded, Cast Strip, granulation and injection moulding, i.e. obtained described polypropylene/bacteria cellulose composite material.
9. the preparation method of polypropylene/bacteria cellulose composite material according to claim 8, is characterized in that, the particle diameter of the bacteria cellulose powder of described esterification modification is 20 ~ 200nm.
10. the preparation method of polypropylene/bacteria cellulose composite material according to claim 8, is characterized in that, the weight-average molecular weight of described homopolymer polypropylene is 20 ~ 400,000.
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CN107793623A (en) * | 2017-11-24 | 2018-03-13 | 肖宇萍 | A kind of degradable composite material and preparation method thereof |
CN109592779A (en) * | 2018-12-17 | 2019-04-09 | 湖北兴新河道治理有限公司 | A kind of carrier organism base and preparation method thereof |
CN115584081A (en) * | 2022-10-08 | 2023-01-10 | 常州机电职业技术学院 | Method for preparing antibacterial polypropylene material from silver-containing bacterial cellulose and application of antibacterial polypropylene material |
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CN101133107A (en) * | 2005-02-01 | 2008-02-27 | 日本电信电话株式会社 | Fiber-reinforced composite material and process for producing the same |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107793623A (en) * | 2017-11-24 | 2018-03-13 | 肖宇萍 | A kind of degradable composite material and preparation method thereof |
CN109592779A (en) * | 2018-12-17 | 2019-04-09 | 湖北兴新河道治理有限公司 | A kind of carrier organism base and preparation method thereof |
CN109592779B (en) * | 2018-12-17 | 2022-03-01 | 湖北兴新生态科技有限公司 | Carrier bio-base and preparation method thereof |
CN115584081A (en) * | 2022-10-08 | 2023-01-10 | 常州机电职业技术学院 | Method for preparing antibacterial polypropylene material from silver-containing bacterial cellulose and application of antibacterial polypropylene material |
CN115584081B (en) * | 2022-10-08 | 2023-07-25 | 常州机电职业技术学院 | Method for preparing antibacterial polypropylene material from silver-containing bacterial cellulose and application of antibacterial polypropylene material |
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