CN105137671B - Liquid crystal cell, the preparation method of liquid crystal cell and display panel - Google Patents

Liquid crystal cell, the preparation method of liquid crystal cell and display panel Download PDF

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Publication number
CN105137671B
CN105137671B CN201510655153.4A CN201510655153A CN105137671B CN 105137671 B CN105137671 B CN 105137671B CN 201510655153 A CN201510655153 A CN 201510655153A CN 105137671 B CN105137671 B CN 105137671B
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China
Prior art keywords
liquid crystal
substrate
crystal cell
curable glue
heat
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Expired - Fee Related
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CN201510655153.4A
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Chinese (zh)
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CN105137671A (en
Inventor
张飞飞
衣晓辉
张志男
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BOE Technology Group Co Ltd
Beijing BOE Optoelectronics Technology Co Ltd
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BOE Technology Group Co Ltd
Beijing BOE Optoelectronics Technology Co Ltd
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Priority to CN201510655153.4A priority Critical patent/CN105137671B/en
Publication of CN105137671A publication Critical patent/CN105137671A/en
Priority to US15/326,403 priority patent/US20170269403A1/en
Priority to PCT/CN2016/088578 priority patent/WO2017063394A1/en
Application granted granted Critical
Publication of CN105137671B publication Critical patent/CN105137671B/en
Expired - Fee Related legal-status Critical Current
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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1339Gaskets; Spacers; Sealing of cells
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/1303Apparatus specially adapted to the manufacture of LCDs
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1339Gaskets; Spacers; Sealing of cells
    • G02F1/13394Gaskets; Spacers; Sealing of cells spacers regularly patterned on the cell subtrate, e.g. walls, pillars
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1341Filling or closing of cells
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/136Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
    • G02F1/1362Active matrix addressed cells
    • G02F1/1368Active matrix addressed cells in which the switching element is a three-electrode device
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/133354Arrangements for aligning or assembling substrates
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/133711Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by organic films, e.g. polymeric films
    • G02F1/133723Polyimide, polyamide-imide
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1341Filling or closing of cells
    • G02F1/13415Drop filling process
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F2202/00Materials and properties
    • G02F2202/02Materials and properties organic material
    • G02F2202/022Materials and properties organic material polymeric
    • G02F2202/023Materials and properties organic material polymeric curable
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F2202/00Materials and properties
    • G02F2202/02Materials and properties organic material
    • G02F2202/022Materials and properties organic material polymeric
    • G02F2202/023Materials and properties organic material polymeric curable
    • G02F2202/025Materials and properties organic material polymeric curable thermocurable
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F2202/00Materials and properties
    • G02F2202/28Adhesive materials or arrangements

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Mathematical Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Liquid Crystal (AREA)

Abstract

The present invention provides the preparation method and display panel of a kind of liquid crystal cell, liquid crystal cell, belongs to liquid crystal display panel technical field.The preparation method of liquid crystal cell of the present invention, including step:The barrier wall structure of the fixed frame at least partly being used for being formed the liquid crystal cell is formed on the first substrate, and injects liquid crystal;The the first pure heat-curable glue for being used for being sealed to the frame of the liquid crystal cell is formed on second substrate;The first substrate and the second substrate operate box, so that the barrier wall structure of the first substrate is accordingly directed at the first pure heat-curable glue of the second substrate;And heat curing operation is carried out to seal the frame of the liquid crystal cell to the described first pure heat-curable glue.The preparation method of the present invention eliminates the frame Mura phenomenons in liquid crystal display panel, and display effect is good near frame.

Description

Liquid crystal cell, the preparation method of liquid crystal cell and display panel
Technical field
The invention belongs to liquid crystal display panel technical fields, are related to the preparation method of liquid crystal cell more particularly to liquid crystal cell.
Background technology
Liquid crystal display panel is answered more and more widely because the advantage of its protrusion is already known to the mainstream in display panel For various display fields, including apply in the portable electronic product of various small sizes.
Liquid crystal cell is the basic element of character of liquid crystal display panel comprising TFT(Thin film transistor (TFT))Substrate, CF(Colorized optical filtering Piece)Substrate and the liquid crystal layer being formed between TFT substrate and CF substrates.During preparing liquid crystal cell, need by display ruler It is very little liquid crystal layer to be sealed to form the liquid crystal cell of corresponding size.
Fig. 1 show schematic diagram of existing liquid crystal cell during sealing and curing.In existing liquid crystal cell production technology, As shown in Figure 1, after TFT substrate 11 is aligned with CF substrates 13, frame uses UV(Ultraviolet radioactive)With heat cure epoxy glue class The sealant 13 of type is sealed, and specific sealing and curing process is:Sealant 13 is cured using UV first, makes 13 part of sealant Then solidification carries out heat cure to prevent liquid crystal from being diffused into periphery to sealant 13, sealant 13 is made fully to cure.But In UV solidification process, as shown in Figure 1, even if being blocked using mask plate 15, UV is inevitably radiated sealant 13 The PI of edge placement(Polyimides)Oriented layer 14, to will produce ion in the frame neighboring area 141 of liquid crystal cell(e-).Base In the display panel that the liquid crystal cell is formed, in screen, the ion that the frame neighboring area 141 of liquid crystal cell generates can lead to side The voltage on frame periphery is different from the voltage of normal region, keeps the liquid crystal deflection near the frame of liquid crystal cell abnormal, therefore, is easy Display exception occurs for the surrounding of display panel, forms " frame Mura " phenomenon(Such as display brightness it is uneven, cause showing for trace As).
Problem above is relatively prominent in small size display panel, especially in narrow frame, small size display panel.
Invention content
It is an object of the present invention to avoid the PI when the sealant of liquid crystal cell carries out UV solidifications to liquid crystal cell from being orientated The UV radiation effects of the generation of film, to avoid the frame Mura phenomenons in display panel.
To realize that object above or other purposes, the present invention provide following technical scheme.
It is an aspect of this invention to provide that providing a kind of preparation method of liquid crystal cell, including step:
The barrier wall structure of the fixed frame at least partly being used for being formed the liquid crystal cell is formed on the first substrate, and is noted Enter liquid crystal;
The the first pure heat-curable glue for being used for being sealed to the frame of the liquid crystal cell is formed on second substrate;
The first substrate and the second substrate operate box, so that the barrier wall structure phase of the first substrate The first pure heat-curable glue of the second substrate should be directed at;And
Heat curing operation is carried out to seal the frame of the liquid crystal cell to the described first pure heat-curable glue.
The preparation method of liquid crystal cell according to an embodiment of the invention, wherein form fixed barricade on the first substrate In the step of structure, including sub-step:
It is coated with the second pure heat-curable glue in the first substrate;
Heat curing operation is carried out to form the barrier wall structure to the described second pure heat-curable glue.
Optionally, the described first pure pure solidification glue of heat-curable glue/the second be epoxy resin, acrylate or thermal curing agents, Or it is two or more arbitrary mixture in them.
Preferably, both the described first pure heat-curable glue and the second pure solidification glue use identical material.
According to the preparation method of the liquid crystal cell of further embodiment of this invention, wherein the barrier wall structure passes through resin material Or acrylic polymer is formed.
In any of the above-described embodiment preparation method, in the heat curing operation, kept under the conditions of 150 DEG C -230 DEG C 20-40 minutes.
In any of the above-described embodiment preparation method, the height of the barrier wall structure is the 1/2 of the thickness of the liquid crystal cell To 3/4.
In any of the above-described embodiment preparation method, the first substrate is CF substrates/TFT substrate, the second substrate For TFT substrate/CF substrates.
In any of the above-described embodiment preparation method, in the operation to box, the barrier wall structure is pure by described first Heat-curable glue coats.
Another aspect according to the invention provides and a kind of preparing the liquid crystal cell to be formed using as above any method.
Further aspect according to the invention provides a kind of display panel comprising liquid crystal cell described above.
The solution have the advantages that in the preparation process of entire liquid crystal cell, UV curings are avoided, especially right After box operation, it is only necessary to carry out heat cure, therefore, be completely avoided when UV cures to liquid crystal cell in the envelope frame operation of liquid crystal cell The UV radiation effects of the generation of PI alignment films will not will produce ion in the frame neighboring area of liquid crystal cell, eliminate liquid crystal Show the frame Mura phenomenons in panel.The display panel that liquid crystal cell prepared by the present invention is formed has the display effect near frame good The advantages of.
Description of the drawings
From the following detailed description in conjunction with attached drawing, it will keep the above and other purpose of the present invention and advantage more complete It is clear, wherein same or analogous element, which is adopted, to be indicated by the same numeral.
Fig. 1 is schematic diagram of existing liquid crystal cell during sealing and curing.
Fig. 2 is the preparation method flow chart according to the liquid crystal cell of one embodiment of the invention.
Fig. 3 is the liquid crystal cell that an embodiment is prepared according to preparation method shown in Fig. 2.
Fig. 4 is the preparation method flow chart according to the liquid crystal cell of further embodiment of this invention.
Fig. 5 is the liquid crystal cell that another embodiment is prepared according to preparation method shown in Fig. 4.
Specific implementation mode
Be described below be the present invention multiple possible embodiments in some, it is desirable to provide to the present invention it is basic Solution, it is no intended to confirm the crucial or conclusive element of the present invention or limit scope of the claimed.It is readily appreciated that, according to this The technical solution of invention, under the connotation for not changing the present invention, those of ordinary skill in the art can propose can be mutual Other realization methods replaced.Therefore, detailed description below and attached drawing are only the examples to technical scheme of the present invention Property explanation, and the whole or be considered as being not to be construed as the present invention defines or limits technical solution of the present invention.
In the accompanying drawings, for the sake of clarity, the thickness of certain layer and region is exaggerated, also, in attached drawing between each component Dimension scale relationship be only illustrative, do not reflect the actual size proportionate relationship between each component.
Fig. 2 is the preparation method flow chart according to the liquid crystal cell of one embodiment of the invention;Fig. 3 is prepared according to shown in Fig. 2 Method prepares the liquid crystal cell of an embodiment.Below in conjunction with Fig. 2 and Fig. 3 to preparing Fig. 3(e)The method of the liquid crystal cell of illustrated embodiment It is illustrated.
First, step S210 coats PI films on first substrate and second substrate(Polyimides)And cure.Referring specifically to Fig. 3(a)And Fig. 3(a'), wherein Fig. 3(a)It is shown on first substrate 31 and coats or print PI films 34', Fig. 3(a')It is shown in PI films 34' is coated on two substrates 32;PI films 34' is for forming oriented layer, and the specific thickness of PI films 34' is not limiting, Specific painting method is nor restrictive, such as can pass through composition and print PI liquid and complete.First substrate 31 is specifically as follows TFT substrate, is formed with tft array thereon, and second substrate 32 can be CF(Colorized optical filtering)Substrate(Or it is color membrane substrates), In another transformation embodiment, first substrate 31 or CF substrates, second substrate 32 may be TFT substrate.
Further, step S220 carries out friction orientation to PI films and forms PI oriented layer.Referring specifically to Fig. 3(b)And Fig. 3 (b'), the PI films 34' on first substrate 31 and second substrate 32 becomes PI oriented layer 34 by carry out friction orientation operation.At it In his embodiment, light orientation can also be used to operate.
Further, for first substrate, the operation of step S231 to step S233 is carried out.
Wherein, step S231 is coated with pure heat-curable glue on the first substrate.Referring to Fig. 3(c1), in corresponding first substrate 31 On the position of frame of the liquid crystal cell to be formed be coated with to form pure heat-curable glue 331', pure heat-curable glue 331' is in this embodiment It is the barrier wall structure that liquid crystal diffusion leakage is prevented for being formed.Pure heat-curable glue 331' is only to may be implemented by heat cure mode Basic fully cured sealant material specifically can be, but not limited to as epoxy resin, acrylate or thermal curing agents, or Mixture in them more than arbitrary the two or both.
Step S232 carries out heat curing operation to form barrier wall structure to pure heat-curable glue.Referring to Fig. 3(c2), pure thermosetting Change glue 331' to be thermally cured to form barrier wall structure 331, the height and/or width of barrier wall structure 331 can be formed according to being intended to respectively Liquid crystal cell frame height and/or width determine.Specifically, in the heat curing operation, at 150 DEG C -230 DEG C(Such as 200℃)Under the conditions of kept for 20-40 minutes(Such as 30 minutes).The height of barrier wall structure 331 is the thickness for the liquid crystal cell to be formed 1/2 to 3/4, for example, can be liquid crystal cell thickness 3/5.
Step S233 injects liquid crystal.Referring to Fig. 3(c3), liquid crystal 39 is injected in 331 area defined of barrier wall structure, It is used for forming the liquid crystal layer in liquid crystal cell;Liquid crystal 39 can be stopped by barrier wall structure 331 and prevent its diffusion leakage.
Synchronously, for second substrate, step S234 is carried out, pure heat-curable glue is coated on second substrate.Referring to Fig. 3 (c'), the position of the frame for the liquid crystal cell to be formed is coated with to form pure heat-curable glue 332', pure heat on corresponding second substrate 32 Solidification glue 332' is sealed for the frame to liquid crystal cell, to form the frame of favorable sealing property.Pure heat-curable glue 332' is that basic fully cured sealant material only may be implemented by heat cure mode, specifically be can be, but not limited to as ring Oxygen resin, acrylate or thermal curing agents or the mixture in them more than arbitrary the two or both.
Further, first substrate and second substrate operate box by step S240.Referring to Fig. 3(d), carry out pair When box operates, the barrier wall structure 331 of first substrate 31 is aligned with the pure heat-curable glue 332' of second substrate 32 and basic phase It is bonded together.Liquid crystal 39 is placed between first substrate 31 and second substrate 32.
Further, step S250 carries out heat curing operation with sealing fluid to the pure heat-curable glue above on second substrate The frame of brilliant box.Referring to Fig. 3(e), by Fig. 3(d)Structure be sent into Thermocuring equipment carry out heat curing operation after, pure heat-curable glue 332' is thermally cured and is blended together with barrier wall structure 331, so as to form the frame 33 of favorable sealing property.In the reality It applies in example, the substantially all material for for pure heat-curable glue formed after heat cure of frame 33.
So far, Fig. 3(e)The liquid crystal cell of illustrated embodiment prepares completion substantially.In the above operating process, carrying out to box After operation, it is only necessary to carry out heat cure, UV curing schedules are not present, therefore, be completely avoided in the envelope frame operation of step S250 To the UV radiation effects of the generation of the PI alignment films 34 of liquid crystal cell when UV cures, will not can be produced in the frame neighboring area of liquid crystal cell Raw ion, eliminates the frame Mura phenomenons in liquid crystal display panel.
Also, in this embodiment, upper and lower base plate(First substrate and second substrate)All be use pure heat-curable glue, namely Barrier wall structure 331 and pure heat-curable glue 332' has essentially identical material property, and compatible properties are very good, therefore, secondary solid The leakproofness of the frame 33 formed after change is very good.
It is pointed out that Fig. 3(e)In the liquid crystal cell of illustrated embodiment, frame 33 is cured by pure thermosetting material It is formed, the material type compared to sealant 13 shown in FIG. 1 is different.
Fig. 4 show the preparation method flow chart of the liquid crystal cell according to further embodiment of this invention;Fig. 5 is shown according to figure Preparation method shown in 4 prepares the liquid crystal cell of another embodiment.Below in conjunction with Fig. 4 and Fig. 5 to preparing Fig. 5(e)Illustrated embodiment The method of liquid crystal cell is illustrated.
First, step S510 coats PI films on first substrate and second substrate(Polyimides)And cure.Referring specifically to Fig. 5(a)And Fig. 5(a'), wherein Fig. 5(a)It is shown on first substrate 31 and coats or print PI films 34', Fig. 5(a')It is shown in PI films 34' is coated on two substrates 32;PI films 34' is for forming oriented layer, and the specific thickness of PI films 34' is not limiting, Specific painting method is nor restrictive, such as can pass through composition and print PI liquid and complete.First substrate 31 is specifically as follows TFT substrate, is formed with tft array thereon, and second substrate 32 can be CF(Colorized optical filtering)Substrate(Or it is color membrane substrates), In another transformation embodiment, first substrate 31 or CF substrates, second substrate 32 may be TFT substrate.
Further, step S520 carries out friction orientation to PI films and forms PI oriented layer.Referring specifically to Fig. 5(b)And Fig. 5 (b'), the PI films 34' on first substrate 31 and second substrate 32 becomes PI oriented layer 34 by carry out friction orientation operation.At it In his embodiment, light orientation can also be used to operate.
Further, for first substrate, the operation of step S531 to step S532 is carried out.
Wherein, step S531 uses resin material etc. to form barrier wall structure on the first substrate.Referring to Fig. 5(c1), The position composition of the frame for the liquid crystal cell to be formed forms the barrier wall structure 531 of resin material on corresponding first substrate 31, specifically Mask can be passed through(Mask)Technique forms the barrier wall structure 531, and concrete technology is not limiting.Compared to Fig. 2 institutes Show that embodiment, barrier wall structure 531 are formed not by heat cure, the height of barrier wall structure 531 is the liquid crystal cell to be formed The 1/2 to 3/4 of thickness, for example, can be the 3/5 of the thickness of liquid crystal cell.In other transformation embodiments, barrier wall structure 531 Other macromolecule organics similar with the monomer structure of pure heat-curable glue of sealant is used as may be used, for example, acrylic acid Lipopolymer.
Step S533 injects liquid crystal.Referring to Fig. 5(c2), liquid crystal 39 is injected in 531 area defined of barrier wall structure, It is used for forming the liquid crystal layer in liquid crystal cell;Liquid crystal 39 can be stopped by barrier wall structure 531 and prevent its diffusion leakage.
Synchronously, for second substrate, step S534 is carried out, pure heat-curable glue is coated on second substrate.Referring to Fig. 5 (c'), the position of the frame for the liquid crystal cell to be formed is coated with to form pure heat-curable glue 332', pure heat on corresponding second substrate 32 Solidification glue 332' is sealed for the frame to liquid crystal cell, to form the frame of favorable sealing property.Pure heat-curable glue 332' is that basic fully cured sealant material only may be implemented by heat cure mode, specifically be can be, but not limited to as ring Oxygen resin, acrylate or thermal curing agents or the mixture in them more than arbitrary the two or both.
Further, first substrate and second substrate operate box by step S540.Referring to Fig. 5(d), carry out pair When box operates, the barrier wall structure 531 of first substrate 31 is aligned with the pure heat-curable glue 332' of second substrate 32 and basic phase It is bonded together, the barrier wall structure 531 of the pure substantially resin-coated materials of heat-curable glue 332'.Liquid crystal 39 is placed in first substrate 31 Between second substrate 32.
Further, step S550 carries out heat curing operation with sealing fluid to the pure heat-curable glue above on second substrate The frame of brilliant box.Referring to Fig. 5(e), by Fig. 5(d)Structure be sent into Thermocuring equipment carry out heat curing operation after, pure heat-curable glue 332' is thermally cured and is integrally solidified togather with barrier wall structure 531, so as to form frame 53.In this embodiment, side Frame 53 includes the barrier wall structure 531 that pure heat-curable glue carries out the material and resin material that are formed after heat cure.
So far, Fig. 5(e)The liquid crystal cell of illustrated embodiment prepares completion substantially.In the above operating process, carrying out to box After operation, it is only necessary to heat cure is carried out, UV curing schedules are not present, equally avoids the problem caused by UV cures, therefore, Eliminate the frame Mura phenomenons in liquid crystal display panel.Also, in this embodiment, resin material need not be cured by UV, Resin material is similar with the monomer structure of pure heat-curable glue, compatible with barrier wall structure 531 after the pure hot 332' solidifications of heat-curable glue Property is good, and sealing effect is good.
It is pointed out that Fig. 5(e)In the liquid crystal cell of illustrated embodiment, frame 53 is to carry out heat by pure heat-curable glue The formation of barrier wall structure 531 of the material and resin material that are formed after solidification, compares the material type of sealant 13 shown in FIG. 1 It is different.
Example above primarily illustrates the preparation method of liquid crystal cell of the present invention and prepares the liquid crystal cell formed.Although only to it In some embodiments of the present invention be described, but those of ordinary skill in the art are it is to be appreciated that the present invention can be Without departing from its spirit in range in the form of many other implement.Therefore, the example shown is considered as showing with embodiment Meaning property and not restrictive, in the case where not departing from the spirit and scope of the present invention as defined in appended claims, The present invention may cover various modification and replacement.

Claims (7)

1. a kind of preparation method of liquid crystal cell, including step:
The barrier wall structure of the fixed frame at least partly being used for being formed the liquid crystal cell is formed on the first substrate, and injects liquid It is brilliant;
The the first pure heat-curable glue for being used for being sealed to the frame of the liquid crystal cell is formed on second substrate;
The first substrate and the second substrate operate box, so that the barrier wall structure of the first substrate is mutually coped with First pure heat-curable glue of the accurate second substrate;And
Heat curing operation is carried out without carrying out UV curing operations to the described first pure heat-curable glue to the described first pure heat-curable glue To seal the frame of the liquid crystal cell,
Wherein, the step of forming fixed barrier wall structure on the first substrate includes sub-step:
It is coated with the second pure heat-curable glue in the first substrate;
Kept under the conditions of 150 DEG C -230 DEG C 20-40 minutes to carry out heat curing operation to the described second pure heat-curable glue, without To the described second pure heat-curable glue progress UV curing operations to form the barrier wall structure,
The wherein described first pure heat-curable glue uses identical material with the second pure heat-curable glue, and in the step to box, The barrier wall structure is coated by the described first pure heat-curable glue.
2. preparation method as described in claim 1, which is characterized in that the first pure pure heat-curable glue of heat-curable glue/the second For epoxy resin, acrylate or thermal curing agents, or it is two or more arbitrary mixture in them.
3. preparation method as described in claim 1, which is characterized in that the barrier wall structure passes through resin material or acrylate Polymer is formed.
4. preparation method as described in claim 1, which is characterized in that the height of the barrier wall structure is the thickness of the liquid crystal cell The 1/2 to 3/4 of degree.
5. preparation method as described in claim 1, which is characterized in that the first substrate is CF substrates/TFT substrate, described Second substrate is TFT substrate/CF substrates.
6. a kind of method using as described in any one of claim 1 to 5 prepares the liquid crystal cell to be formed.
7. a kind of display panel, which is characterized in that including liquid crystal cell as claimed in claim 6.
CN201510655153.4A 2015-10-12 2015-10-12 Liquid crystal cell, the preparation method of liquid crystal cell and display panel Expired - Fee Related CN105137671B (en)

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