CN1051369A - Gold is selected the synthetic method of extracting gold that reaches of polymeric adsorbent - Google Patents
Gold is selected the synthetic method of extracting gold that reaches of polymeric adsorbent Download PDFInfo
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- CN1051369A CN1051369A CN89104119A CN89104119A CN1051369A CN 1051369 A CN1051369 A CN 1051369A CN 89104119 A CN89104119 A CN 89104119A CN 89104119 A CN89104119 A CN 89104119A CN 1051369 A CN1051369 A CN 1051369A
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Abstract
Gold is selected the synthetic method of extracting gold that reaches of polymeric adsorbent.It is to be raw material with the chloroethyl crosslinked polystyrene that gold is selected polymeric adsorbent, in the presence of special additive Acetanilide (or formylaniline), uses ethylene dichloride---the oil of mirbane mixed solvent system makes by the Fu Shi crosslinking reaction.This resin absorption ability is strong, and desorb is easy, efficient is high, and intensity is good, and needn't regenerate and promptly can be recycled.The gold selection polymeric adsorbent that sampling the invention provides the method acquisition is a sorbent material, the method that from lode gold ore deposit or gold concentrate cyaniding leach liquor or cyanide pulp, extracts gold from, be in the presence of certain organic amine compound, extract gold from processing condition according to a certain ratio.
Description
The present invention relates to the method that from lode gold ore deposit or gold concentrate cyaniding leach liquor or cyanide pulp, extracts gold from, be a kind of in the presence of certain organic amine compound, the method that the gold selection polymeric adsorbent for preparing with synthetic method of the present invention extracts gold from from lode gold ore deposit or gold concentrate cyaniding leach liquor or cyanide pulp.
Traditional sorbent material of adsorbing and extracting gold is gac and ion exchange resin from the lode gold ore deposit cyaniding leach liquor of lower concentration.At present, industrial these two kinds of traditional sorbent materials adsorbing and extracting gold from the cyanide pulp of fine gold breeze that also adopts.According to the sorbent material difference that adopts, its technology is hereinafter referred to as carbon-in-pulp process technology and resin slurry process technology abroad.
For carbon-in-pulp process technology, because its sorbent material of selecting for use is a gac, and this gac needs to use earlier the strong solution transition of prussiate after the suction gold, then could desorb under high temperature and pressurized conditions, so just make the extraction process complexity, the extraction efficiency of gold is lower, pollutes also very serious simultaneously.And the high temperature regeneration activation treatment need be regularly carried out in the repeated use of gac.Moreover, also, be easy to shortcomings such as wearing and tearing, bring the extra losses of gold because the gac form is irregular.
For resin slurry process technology, because ion exchange resin is too strong with the bonding force of gold, extraction conditions is very harsh, generally will adopt acid thiocarbamide desorb or high temperature incineration with the separation and Extraction gold.The former is seriously polluted, and latter's cost is very high.
Therefore, it is the key of improving golden smelting technology that research and development select high adsorption capacity, desorption and regeneration to be easy to sorbent material to gold, and just is being subjected to this area researchist's extensive attention.Yet do not see the report that makes progress up to now.
A series of problems such as the lower and complex process of desorb difficulty, the efficient that the objective of the invention is to solve the present use golden sorbent material of tradition and bring provide a kind of high adsorption capacity, desorption technique is easy, desorption efficiency is high and regeneration is easy to novel golden selected adsorbent and corresponding technology thereof.
Gold provided by the invention is selected the synthetic method of polymeric adsorbent, be to be raw material with the chloroethyl crosslinked polystyrene, in the presence of special additive Acetanilide (or formylaniline), adopt ethylene dichloride-oil of mirbane mixed solvent system, by a kind of synthetic method of known Fu Shi crosslinking reaction.This method whole reaction system each component proportioning (by weight) is:
100 parts of chloroethyl crosslinked polystyrenes (chlorine ball)
120～180 parts of ethylene dichloride
120～200 parts in oil of mirbane
1～10 part of Acetanilide (or formylaniline)
10～30 parts of aluminum chlorides (or zinc chloride)
And synthetic by following processing step and condition:
1〉in the chloroethyl crosslinked polystyrene (chlorine ball) of 75 ± 5 ℃ of oven dry, add ethylene dichloride-oil of mirbane mixed solvent by proportioning, stirred swelling 1～10 hour;
2〉add the Acetanilide (or formylaniline) and the aluminum chloride (or zinc chloride) of proportioning again, continue to stir swelling 0～2 hour;
3〉be warming up to 60～150 ℃ with 2～3 ℃/minute speed, reacted 4～8 hours;
4〉cooling, suction filtration, resin is used methyl alcohol extracting 0～4 hour then.
In above-mentioned prescription and processing condition, can select following proportioning and processing condition:
100 parts of chloroethyl crosslinked polystyrenes (chlorine ball)
120 parts of ethylene dichloride
180 parts in oil of mirbane
5 parts of Acetanilides (or formylaniline)
15 parts of aluminum chlorides (or zinc chloride)
1〉in the chloroethyl crosslinked polystyrene (chlorine ball) of 75 ± 5 ℃ of oven dry, add ethylene dichloride-oil of mirbane mixed solvent, stirred swelling 2 hours;
2〉add Acetanilide (or formylaniline) and aluminum chloride (or zinc chloride) again, stirred swelling 0.5 hour;
3〉be warming up to 95 ℃ with 2～3 ℃/minute speed, reacted 6 hours;
4〉cooling, suction filtration, resin is used methyl alcohol extracting 2 hours then.
Selecting polymeric adsorbent with the gold of prescription provided by the invention and processing condition preparation is a kind of Melon yellow or dun opaque ball, size range 0.3～1.2mm, specific surface area 150～500m
2/ g, pore volume 0.4～0.6ml/g, average pore radius 50～250 dusts, compressive strength 1000～2000g/ grain (when particle diameter is 0.8mm).Its feature is approaching to the adsorptive power of gold and gac and ion exchange resin under neutrallty condition; At alkaline condition with provided by the inventionly have a R
1R
2NR
3R
4Organic amine compound (the R that forms
1, R
2, R
3, R
4Can be hydrogen, alkyl or aryl.The exemplary of this compounds is methylbenzylamine, dimethyl benzylamine, tri methyl benzyl ammonium etc.) existence under, the adsorptive power of this resin is better than gac and ion exchange resin, simultaneously desorption technique is easy, desorption efficiency is near 100%.In addition, the intensity of this resin is good, not easy to wear, also needn't regenerate, and can recycle repeatedly.
Employing the invention provides method synthetic gold and selects polymeric adsorbent, and the corresponding process method of extracting gold from lode gold ore deposit or gold concentrate cyaniding leach liquor or cyanide pulp is:
One, from lode gold ore deposit or gold concentrate cyaniding leach liquor, extracts the method for gold
The proportioning (by weight) that lode gold ore deposit or gold concentrate cyaniding leach liquor extract the system each component is:
500～3000 parts of lode gold ore deposit (or gold concentrate) cyaniding leach liquors
Wherein: gold content 0.1～50 mg/litre
Potassium cyanide (or sodium cyanide) 10～500 mg/litre
Organic amine compound 1～200 mg/litre
Gold is selected 0.5～5 part of polymeric adsorbent
The processing step of its extraction and condition are:
1〉organic amine compound of the certain proportioning of adding in the cyaniding leach liquor is with sodium hydroxide or lime regulator solution PH=9.5～12;
2〉control solution flows through adsorption column with 40～100 milliliters/hour flow velocity, when gold content in the effluent liquid surpasses prescribed value (as 0.02～0.05 mg/litre), stops absorption;
3〉in adsorption column, add the methyl alcohol desorb, control methyl alcohol flows through adsorption column with 10～20 milliliters/hour flow velocity, collects stripping liquid;
4〉methyl alcohol is reclaimed in stripping liquid distillation after, technology reclaiming metals gold routinely.
Extract in the system of gold by above-mentioned processing step and condition, each component proportioning (by weight) also may be selected to be:
500～1000 parts of lode gold ore deposit (or gold concentrate) cyaniding leach liquors
Wherein: gold content 0.5～50 mg/litre
Potassium cyanide (or sodium cyanide) 100～300 mg/litre
Organic amine compound 15～50 mg/litre
Gold is selected 1.0 parts of polymeric adsorbents
Two, from lode gold ore deposit or gold concentrate cyanide pulp, extract the method for gold
The proportioning (by weight) that lode gold ore deposit or gold concentrate cyanide pulp extract the system each component is:
500～1000 parts of lode gold ore deposit (or gold concentrate) cyanide pulps
Wherein: 300～400 parts of breezes (≤150 order)
Gold content 10～200 gram/tons
300～700 parts in water
0.3～1.0 part in potassium cyanide (or sodium cyanide)
0.05～1.0 part of organic amine compound
Gold is selected 1～10 part of polymeric adsorbent
The processing step of its extraction and condition are:
1〉the breeze adding is dissolved with in the water of potassium cyanide (or sodium cyanide), regulates ore pulp PH=10～12 with sodium hydroxide or lime;
2〉stir 1～5 hour at a slow speed, add again and select polymeric adsorbent and organic amine compound, continue to stir 0.5～3 hour with the gold of water infiltration;
3〉resin is sieved from ore pulp, wash, in the adsorption column of packing into, use the methyl alcohol desorb, control methyl alcohol flows through adsorption column with 10～20 milliliters/hour flow velocity, collects stripping liquid;
4〉methyl alcohol is reclaimed in stripping liquid distillation after, technology reclaiming metals gold routinely.
Said ratio and processing condition also may be selected to be:
1000 parts of lode gold ore deposit (or gold concentrate) cyanide pulps
Wherein: 350 parts of breezes (＜150 order)
Gold content 10～200 gram/tons
650 parts in water
0.5 part in potassium cyanide (or sodium cyanide)
0.05 part of organic amine compound
Gold is selected 5 parts of polymeric adsorbents
1〉the breeze adding is dissolved with in the water of potassium cyanide (or sodium cyanide), regulates ore pulp PH=10～12 with sodium hydroxide or lime;
2〉stir 2～5 hours at a slow speed, add again and select polymeric adsorbent and organic amine compound, continue to stir 0.5～3 hour with the gold of water infiltration;
3〉resin is sieved from ore pulp, wash, in the adsorption column of packing into, use the methyl alcohol desorb, control methyl alcohol flows through adsorption column with 10～20 milliliters/hour flow velocity, collects stripping liquid;
4〉methyl alcohol is reclaimed in stripping liquid distillation after, technology reclaiming metals gold routinely.
Adopt gold provided by the invention to select polymeric adsorbent and processing method thereof, the smelting technology of lode gold ore deposit or gold concentrate is simplified greatly (being mainly reflected in desorption step and gold selects the reprocessing cycle of polymeric adsorbent to use), the separation and Extraction rate of gold improves (reaching as high as 99.5%), and production cost descends.
Embodiment one:
Take by weighing in the there-necked flask of 500 milliliters of 75 ± 5 ℃ of chloroethyl crosslinked polystyrenes (chlorine ball) of drying down, 100 gram addings, add ethylene dichloride 120 grams and oil of mirbane 180 grams again, the stirring swelling is after 2 hours; Add Acetanilide 5 grams and aluminum chloride 15 grams, stirred swelling 0.5 hour; Be warming up to 95 ℃ with 2～3 ℃/minute speed then, reacted 6 hours; Cooling, after suction filtration mother liquor, resin were washed Polyester three times with methyl alcohol, extracting got final product in 2 hours in apparatus,Soxhlet's.
Embodiment two:
In the glass adsorption column of φ 8 * 300mm, the 10ml that packs into selects polymeric adsorbent by the invention provides method synthetic gold.Preparation gold (Au
+ 1), potassium cyanide (KCN) and interfering ion iron (Fe
2+), copper (Cu
2+), nickel (Ni
2+), zinc (Zn
2+) ionic concn is respectively 0.1～10,100～300,50,50,20, the simulation cyanating solution 50l of 30mg/l, the organic amine compound 1.25g that adds concentration and be 1～50mg/l is with sodium hydroxide or lime regulator solution PH=9.5～12; Control solution flows through adsorption column with 40～100ml/ hour flow velocity, and (this moment, the suction gold amount of resin was 10～30mg/g resin) stopped absorption when gold concentration surpassed prescribed value 0.05mg/l in effluent liquid; Add methyl alcohol in adsorption column, control methyl alcohol flows through adsorption column with 10～20ml/ hour flow velocity, collects stripping liquid; Adsorption column water 50～150ml drip washing drains bubble, can adsorb next time; After stripping liquid distillation reclaimed methyl alcohol, technology reclaiming metals gold routinely.The total yield of gold is 98～99.5%.
Embodiment three:
Lode gold ore deposit all sliming cyanidation leach liquor 50l, wherein gold concentration is 3～8mg/l, and potassium cyanide concentration is 100～300mg/l, and organic amine compound concentration is 15～50mg/l.By embodiment two described operations, condition adsorb, desorb, recovery solvent and electrolysis.The suction gold amount of resin is 8～25mg/g, and the total yield of gold is 98～99%.
Embodiment four:
The 350g granularity is dissolved with in the 650g water of 0.5g potassium cyanide less than the adding of 150 purpose breezes, adds organic amine compound 50mg, add lime and be adjusted to PH=10～12, stirred at a slow speed 2～5 hours; Add again and select polymeric adsorbent 1.5g greater than the gold of 0.8mm, continue to stir at a slow speed 1～3 hour with the granularity of water infiltration; Resin is sieved from ore pulp, wash, carry out desorb, reclaim solvent and electrolysis by embodiment two described operations, condition then.The total yield of gold is for leaching 96～98% of gold.
If carry out the operation of secondary countercurrent extraction, being about to another part fresh resin input front has sieved out in the poor golden cyanide pulp of resin, after carrying out whip attachment, with resin sieve out drop into again another part without absorption cyanide pulp in, by aforesaid operation, condition adsorb, screening, desorb, recovery solvent and electrolysis, with a fresh resin absorption, the rate of recovery of gold can reach 98.5～99.5% to remaining poor golden cyanide pulp again.
Claims (5)
1, a kind ofly obtain the synthetic method that gold is selected polymeric adsorbent, it is characterized in that with the chloroethyl crosslinked polystyrene being raw material, in the presence of special additive Acetanilide (or formylaniline), use ethylene dichloride by the Fu Shi crosslinking reaction--the oil of mirbane mixing; The agent system, whole reaction system each component proportioning (by weight) is:
100 parts of chloroethyl crosslinked polystyrenes (chlorine ball)
120～180 parts of ethylene dichloride
120～200 parts in oil of mirbane
1～10 part of Acetanilide (or formylaniline)
10～30 parts of aluminum chlorides (or zinc chloride)
And synthetic by following processing step and condition:
1〉in the chloroethyl crosslinked polystyrene (chlorine ball) of 75 ± 5 ℃ of oven dry, add ethylene dichloride--oil of mirbane mixed solvent by proportioning, stirred swelling 1～10 hour;
2〉add the Acetanilide and the aluminum chloride of proportioning again, continue to stir swelling 0～2 hour;
3〉be warming up to 60～150 ℃ with 2～3 ℃/minute speed, reacted 4～8 hours;
4〉cooling, suction filtration, the resin methanol wash, extracting is 0～4 hour then.
2, gold according to claim 1 is selected the synthetic method of polymeric adsorbent, it is characterized in that the best proportioning (by weight) that the reaction system each component is selected can be:
100 parts of chloroethyl crosslinked polystyrenes (chlorine ball)
120 parts of ethylene dichloride
180 parts in oil of mirbane
5 parts of Acetanilides (or formylaniline)
15 parts of aluminum chlorides (or zinc chloride)
Synthetic processing step and condition are:
1〉in the chloroethyl crosslinked polystyrene (chlorine ball) of 75 ± 5 ℃ of oven dry, add ethylene dichloride-oil of mirbane mixed solvent, stirred swelling 2 hours;
2〉add Acetanilide and aluminum chloride again, stirred swelling 0.5 hour;
3〉be warming up to 95 ℃ with 2～3 ℃/minute speed, reacted 6 hours;
4〉cooling, suction filtration, the resin methanol wash, extracting is 2 hours then.
3, a kind of from lode gold ore deposit or gold concentrate the cyaniding leach liquor or cyanide pulp extract the method for gold, it is characterized in that in the presence of certain organic amine compound, adopting claim 1,2 method synthetic gold to select polymeric adsorbent is sorbent material, and lode gold ore deposit or gold concentrate cyaniding leach liquor extract system each component proportioning (by weight) and be:
500～3000 parts of lode gold ore deposit (or gold concentrate) cyaniding leach liquors
Wherein: gold content 0.1～50 mg/litre
Potassium cyanide (or sodium cyanide) 10～500 mg/litre
Organic amine compound 1～200 mg/litre
Gold is selected 0.5～5 part of polymeric adsorbent
The processing step of its extraction and condition are:
1〉organic amine compound of the certain proportioning of adding in the cyaniding leach liquor is with sodium hydroxide or lime regulator solution PH=9.5～12;
2〉control solution flows through adsorptivity with 40～100 milliliters/hour flow velocity, when gold content in the effluent liquid surpasses prescribed value (as 0.02～0.05 mg/litre), stops absorption;
3〉in adsorption column, add the methyl alcohol desorb, control methyl alcohol flows through adsorption column with 10～20 milliliters/hour flow velocity, collects stripping liquid;
4〉methyl alcohol is reclaimed in stripping liquid distillation after, technology reclaiming metals gold routinely.Lode gold ore deposit or gold concentrate cyanide pulp extract system each component proportioning (by weight):
500～1000 parts of lode gold ore deposit (or gold concentrate) cyanide pulps
Wherein: 300～400 parts of breezes (≤150 order)
Gold content 10～200 gram/tons
300～700 parts in water
0.3～1.0 part in potassium cyanide (or sodium cyanide)
0.05～1.0 part of organic amine compound
Gold is selected 1～10 part of polymeric adsorbent
The processing step of its extraction and condition are:
1〉the breeze adding is dissolved with in the water of potassium cyanide (or sodium cyanide), regulates ore pulp PH=10～12 with sodium hydroxide or lime;
2〉stir 1～5 hour at a slow speed, add again and select polymeric adsorbent and organic amine compound, continue to stir 0.5～3 hour with the gold of water infiltration;
3〉resin is sieved from ore pulp, wash, in the adsorption column of packing into, use the methyl alcohol desorb, control methyl alcohol flows through adsorption column with 10～20 milliliters/hour flow velocity, collects stripping liquid;
4〉methyl alcohol is reclaimed in stripping liquid distillation after, technology reclaiming metals gold routinely.
4, the method for extracting gold according to claim 3 is characterized in that lode gold ore deposit or gold concentrate cyaniding leach liquor extract the selectable proportioning of system each component (by weight) and be:
500～1000 parts of lode gold ore deposit (or gold concentrate) cyaniding leach liquors
Wherein: gold content 0.5～50 mg/litre
Potassium cyanide (or sodium cyanide) 100～300 mg/litre
Organic amine compound 1～50 mg/litre
Gold is selected 1.0 parts of polymeric adsorbents
The processing step and the condition of its extraction can be:
1〉organic amine compound of the certain proportioning of adding in the cyaniding leach liquor is with sodium hydroxide or lime regulator solution PH=9.5～12;
2〉control solution flows through adsorption column with 40～100 milliliters/hour flow velocity, when gold content in the effluent liquid surpasses prescribed value (as 0.02～0.05 mg/litre), stops absorption;
3〉add the methyl alcohol desorb in adsorption column, control methyl alcohol flows through adsorption column with 10～20 milliliters/hour flow velocity, collects stripping liquid;
4〉methyl alcohol is reclaimed in stripping liquid distillation after, technology reclaiming metals gold routinely, lode gold ore deposit (or gold concentrate) cyanide pulp extracts the selectable proportioning of system each component (by weight) and is:
1000 parts of lode gold ore deposit (or gold concentrate) cyanide pulps
Wherein: 350 parts of breezes (＜150 order)
Gold content 10～200 gram/tons
650 parts in water
0.5 part in potassium cyanide (or sodium cyanide)
0.05 part of organic amine compound
Gold is selected 5 parts of polymeric adsorbents
Its extraction process step and condition can be:
1〉the breeze adding is dissolved with in the water of potassium cyanide (or sodium cyanide), regulates ore pulp PH=10～12 with sodium hydroxide or lime;
2〉stir 2～5 hours at a slow speed, add again and select polymeric adsorbent and organic amine compound, continue to stir 0.5～3 hour with the gold of water infiltration;
3〉resin is sieved from ore pulp, wash, in the adsorption column of packing into, use the methyl alcohol desorb, control methyl alcohol flows through adsorption column with 10～20 milliliters/hour flow velocity, collects stripping liquid;
4〉methyl alcohol is reclaimed in stripping liquid distillation after, technology reclaiming metals gold routinely.
5, according to claim 3, the 4 described methods of extracting gold, it is characterized in that used organic amine compound is the organic compound with following composition:
R
1R
2NR
3R
4
R in the formula
1, R
2, R
3, R
4Can be hydrogen, alkyl or aryl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN89104119A CN1030088C (en) | 1989-10-31 | 1989-10-31 | Method for extracting gold from cyanated extract or cyanated ore pulp of vein gold deposit or gold concentrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN89104119A CN1030088C (en) | 1989-10-31 | 1989-10-31 | Method for extracting gold from cyanated extract or cyanated ore pulp of vein gold deposit or gold concentrate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1051369A true CN1051369A (en) | 1991-05-15 |
| CN1030088C CN1030088C (en) | 1995-10-18 |
Family
ID=4855439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN89104119A Expired - Fee Related CN1030088C (en) | 1989-10-31 | 1989-10-31 | Method for extracting gold from cyanated extract or cyanated ore pulp of vein gold deposit or gold concentrate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1030088C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483473A (en) * | 2013-09-17 | 2014-01-01 | 中国科学院南京土壤研究所 | Method for preparing immobilized cucurbiturils |
| CN104744618A (en) * | 2013-12-25 | 2015-07-01 | 浙江衢州万能达科技有限公司 | Preparation method for gold adsorption resin modified by lactam radical |
| CN113042113A (en) * | 2021-03-22 | 2021-06-29 | 中国科学院广州能源研究所 | Preparation method of macroporous weak base anion exchange resin special for gold extraction |
| CN115725850A (en) * | 2022-11-17 | 2023-03-03 | 北京华德创业环保设备有限公司 | Precious metal recovery device and method |
-
1989
- 1989-10-31 CN CN89104119A patent/CN1030088C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483473A (en) * | 2013-09-17 | 2014-01-01 | 中国科学院南京土壤研究所 | Method for preparing immobilized cucurbiturils |
| CN103483473B (en) * | 2013-09-17 | 2015-10-28 | 中国科学院南京土壤研究所 | The preparation method of immobilized melon ring |
| CN104744618A (en) * | 2013-12-25 | 2015-07-01 | 浙江衢州万能达科技有限公司 | Preparation method for gold adsorption resin modified by lactam radical |
| CN104744618B (en) * | 2013-12-25 | 2017-08-15 | 浙江衢州万能达科技有限公司 | A kind of preparation method of the golden polymeric adsorbent of lactams base group modification |
| CN113042113A (en) * | 2021-03-22 | 2021-06-29 | 中国科学院广州能源研究所 | Preparation method of macroporous weak base anion exchange resin special for gold extraction |
| CN115725850A (en) * | 2022-11-17 | 2023-03-03 | 北京华德创业环保设备有限公司 | Precious metal recovery device and method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1030088C (en) | 1995-10-18 |
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