CN105131506A - Composite ABS plastic for automobile interior trim parts - Google Patents
Composite ABS plastic for automobile interior trim parts Download PDFInfo
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- CN105131506A CN105131506A CN201510662295.3A CN201510662295A CN105131506A CN 105131506 A CN105131506 A CN 105131506A CN 201510662295 A CN201510662295 A CN 201510662295A CN 105131506 A CN105131506 A CN 105131506A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/375—Thiols containing six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5425—Silicon-containing compounds containing oxygen containing at least one C=C bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
Abstract
The invention discloses composite ABS plastic for automobile interior trim parts. The composite ABS plastic comprises, by weight, 200 parts of ABS resin, 1-5 parts of 3-(isobutylene acyl oxygen)propyl trimethoxy silane, 0.5-1.5 parts of a composite antiaging agent, 0.5-1.5 parts of a scratch resistant agent, 0.5-2 parts of a composite antistatic agent, and 0.3-0.5 part of a composite light stabilizer. The composite ABS plastic has the excellent aging resistance, scratch resistance, static electricity resistance and illumination aging resistance, the preparation technology is simple, the product cost is low, and the comprehensive performance of the product is excellent. The composite ABS plastic for the automobile interior trim parts can be easily machined into parts in various shapes through the injection molding technology and is particularly suitable for injection molding to form various automobile interior trim parts.
Description
Technical field
The present invention relates to a kind of plastic material, particularly relate to a kind of automotive upholstery compound ABS plastic.
Background technology
ABS resin is the acronym of AcrylonitrileButadieneStyrene, is that a kind of intensity is high, good toughness, is easy to thermoplastics type's Polymer Materials ' Structure of machine-shaping.
ABS is the general thermoplastic engineering plastic grown up 1940's, it is the very outstanding plastics variety of a comprehensive mechanical property, not only there is good rigidity, hardness and processing fluidity, and there is high tenacity feature, can injection moulding, extrude or thermoforming.
Major part trolley part is all with injection molding forming method processing, and the advantage of ABS resin is impact-resistance, sound-proofing, scratch-resistant, and thermotolerance is better, more attractive in appearance than PP, is specially adapted to horizontal impact-resistance and the comparatively strict parts of use temperature.ABS resin uses in automobile to be only second to Polyurethane and polyacrylic the third-largest resin.ABS resin can be used for Che Nei and car outer enclosure, and bearing circle, oil guide pipe and the widget such as handle and button, car outside comprises front radiator grill and lampshade etc.
But at present not a kind of ABS resin has excellent anti-aging, antistatic, damage resistant and illumination aging resisting performance simultaneously.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention provides a kind of automotive upholstery compound ABS plastic, has the performance of good anti-aging, antistatic, damage resistant and illumination aging resisting four aspect simultaneously.
The present invention seeks to be achieved through the following technical solutions:
A kind of automotive upholstery compound ABS plastic, comprise the component of following weight parts: ABS resin 200 parts, 3-(iso-butylene acyl-oxygen) propyl trimethoxy silicane 1-5 part, compound antiaging agent 0.5-1.5 part, damage resistant agent 0.5-1.5 part, composite antistatic agent 0.5-2 part, composite light stabilizer 0.3-0.5 part.
Described compound antiaging agent, is made up of the component of following weight per-cent: 4,6-bis-(pungent thiomethyl) ortho-cresol 10-30%, 2,6 di tert butyl 4 methyl phenol 70-90%.
The agent of described compound damage resistant is made up of the component of following weight per-cent: amine hydroxybenzene 40-60% and N, N-ethylene bis-oleamide 40-60%.
Described composite antistatic agent is made up of the component of following weight per-cent: sodium allyl sulfonate 30-50%, [3-(ten dioxo)-2-hydroxypropyl] two (2-hydroxyethyl) ammonium methyl methyl sulfate 20-40%, methyl-trimethylammonium-3-[(1-oxo dodecyl) is amino] propyl group ammonium sulfate 20-40%.
The component composition of described composite light stabilizer following weight per-cent: 2-[2-hydroxyl-4-(2,2,6,6-tetramethyl piperidine-4-oxygen base) carbomethoxy phenyl]-2H-benzotriazole 40-60%, N, N '-bis-(2,2,6,6-tetramethyl--4-piperidyl)-N, N '-dialdehyde-based hexanediamine 40-60%.
4,6-bis-(pungent thiomethyl) ortho-cresol and 2,6 di tert butyl 4 methyl phenol are uniformly mixed, this antiaging agent can be obtained.
Amine hydroxybenzene and N, N-ethylene bis-oleamide are uniformly mixed, this damage resistant agent can be obtained.
Sodium allyl sulfonate, [3-(ten dioxo)-2-hydroxypropyl] two (2-hydroxyethyl) ammonium methyl methyl sulfate and methyl-trimethylammonium-3-[(1-oxo dodecyl) is amino] propyl group ammonium sulfate are uniformly mixed, this static inhibitor can be obtained.
By 2-[2-hydroxyl-4-(2,2,6,6-tetramethyl piperidine-4-oxygen base) carbomethoxy phenyl]-2H-benzotriazole and N, N '-bis-(2,2,6,6-tetramethyl--4-piperidyl)-N, N '-dialdehyde-based hexanediamine is uniformly mixed, and can obtain this photostabilizer.
Present invention also offers the preparation method of above-mentioned automotive upholstery compound ABS plastic: take each component by proportioning, after mixing, melting mixing, extruding pelletization, namely obtain described automotive upholstery compound ABS plastic.
Concrete, can for take each component by proportioning, in high-speed mixer, control rotating speed under room temperature at 300-400 rev/min, mixing 5-10 minute, proceeds to after taking-up in screw extrusion press, extruding pelletization at 160-190 DEG C of temperature, namely obtains described automotive upholstery compound ABS plastic.
Obviously, in the present invention for improving other performances of product, other auxiliary agents can also be added adaptively, as fire retardant, tinting material etc.
Tinting material can be ultramarine blue, phthalocyanine blue, carbon black, titanium white etc., and the add-on of tinting material is 0.2-2 weight part.After the mixing of each component, directly can add tinting material, then proceed in screw extrusion press, extruding pelletization, obtain painted after automotive upholstery compound ABS plastic.The automotive upholstery compound ABS plastic using various tinting material to obtain, all has good damage resistant effect.4,6-bis-(pungent thiomethyl) ortho-cresol, No. CAS: 110553-27-0.
2,6 di tert butyl 4 methyl phenol, No. CAS: 128-37-0.
Amine hydroxybenzene, No. CAS: 301-02-0.
N, N-ethylene bis-oleamide, No. CAS: 110-31-6.
3-(iso-butylene acyl-oxygen) propyl trimethoxy silicane, No. CAS: 2530-85-0.
Sodium allyl sulfonate, No. CAS: 2495-39-8.
[3-(ten dioxo)-2-hydroxypropyl] two (2-hydroxyethyl) ammonium methyl methyl sulfate, No. CAS: 18602-17-0.
Methyl-trimethylammonium-3-[(1-oxo dodecyl) is amino] propyl group ammonium sulfate, No. CAS: 10595-49-0.
N, N '-bis-(2,2,6,6-tetramethyl--4-piperidyl)-N, N '-dialdehyde-based hexanediamine, No. CAS: 124172-53-8.
2-[2-hydroxyl-4-(2,2,6,6-tetramethyl piperidine-4-oxygen base) carbomethoxy phenyl]-2H-benzotriazole, molecular formula is C
23h
28n
4o
4.Structural formula is as follows:
Contriver is drawn by great many of experiments, and antiaging agent 4,6-bis-(pungent thiomethyl) ortho-cresol and 2,6 di tert butyl 4 methyl phenol are carried out reasonable composite use, and antiageing effect is obvious; Amine hydroxybenzene and N, N-ethylene bis-oleamide are carried out reasonable composite use, damage resistant successful, there is collaborative damage resistant effect.Especially for automotive upholstery compound ABS plastic, there is anti-aging, damage resistant simultaneously, antistatic and illumination aging resisting four aspect effect is more excellent, draw high intensity, flexural strength, modulus in flexure and shock strength and all comparatively meet the demands;
The resistance to deterioration of this product, scratch resistance, static resistance and illumination aging resisting are more excellent, and preparation technology is simple, and product cost is low, and the over-all properties of product is more excellent.
Automotive upholstery compound ABS plastic of the present invention, the part of different shape can be processed into easily by Shooting Technique, can be used for making in automobile and car outer enclosure, bearing circle, oil guide pipe and the widget such as handle and button, car outside comprises front radiator grill and lampshade etc.
Embodiment
ABS resin, the trade mark adopting Jilin Petrochemical company of CNPC to produce is the ABS resin of 0215A.
Embodiment 1-5
Each raw material is taken according to embodiment 1-5 data corresponding in table 1.
Each component is joined in high-speed mixer, controls rotating speed under room temperature at 350 revs/min, mix 10 minutes, ultramarine blue 1 kilogram is added after taking-up, proceed in screw extrusion press, extruding pelletization at 180 DEG C of temperature, namely obtain described automotive upholstery compound ABS plastic.
All adding ultramarine blue in embodiment as the object of tinting material is, to use colourimeter to record scratch front and rear surfaces misalignment △ E, investigates scratch resistant performance.Concrete test result is in table 1:
Table 1: automotive upholstery compound ABS plastic Example formulations list position: kilogram
The structural formula of the compounds X in table 1 is as follows:
Test case 1
According to thermo-oxidative ageing experimental standard GB/T7141-2008, artificially roughening (90 DEG C, 500h) is carried out to the automotive upholstery compound ABS plastic of embodiment 1-3.Concrete test result is in table 2:
Table 2: compound ABS plastic ageing resistance test chart (90 DEG C, 500h)
| Sample | Stretching strength retentivity, % | Shock strength conservation rate, % |
| Embodiment 1 | 84.8 | 84.8 |
| Embodiment 2 | 78.1 | 79.9 |
| Embodiment 3 | 80.9 | 80.2 |
Can significantly be drawn by test data, through 90 DEG C, after 500h artificial accelerated aging, the stretching strength retentivity of embodiment 1 and shock strength conservation rate are apparently higher than embodiment 2-3.
As can be seen here, 4,6-bis-(pungent thiomethyl) ortho-cresol, 2,6 di tert butyl 4 methyl phenol are carried out reasonable composite use, antiageing effect is obvious, and the antiageing effect especially for automotive upholstery compound ABS plastic is more excellent.
Test case 2
The automotive upholstery compound ABS plastic traditional performance of embodiment 1 and embodiment 4-5 and scratch resistant performance are tested.
The testing method of scratch resistant performance scratches tester evaluation scuffing degree for using.Show to scrape a line segment figure in automotive upholstery compound ABS plastic with a mechanically operated scraper.Each scraper is only scraped once in one direction.Then the misalignment △ E utilizing a colourimeter to record non-surface scratch to compare.
Test condition is:
Temperature: 23 ± 5 DEG C, anchorage force: 10N, scratches speed: 1000mm/min, scraper diameter: 1mm.Concrete test result is in table 3:
Table 3: compound ABS plastic scratch resistant performance test chart
| Sample | Aberration △ E after scuffing |
| Embodiment 1 | 0.12 |
| Embodiment 4 | 0.21 |
| Embodiment 5 | 0.30 |
Significantly can be drawn by test data, amine hydroxybenzene and N, N-ethylene bis-oleamide be carried out reasonable composite use, damage resistant successful, have collaborative damage resistant effect, the damage resistant effect especially for automotive upholstery compound ABS plastic is more excellent.
Test case 3
The automotive upholstery compound ABS plastic surface resistivity of embodiment 1-3 is tested, carries out according to GB/T1410-2006.Concrete test result is in table 4:
Table 4: compound ABS plastic antistatic property test chart
| Sample | Surface resistivity, Ω |
| Embodiment 1 | 1.2×10 8 |
| Embodiment 2 | 1.8×10 8 |
| Embodiment 3 | 2.1×10 8 |
The automotive upholstery compound ABS plastic antistatic property test data of embodiment 1-3 can significantly draw, the present invention has excellent antistatic property in addition.
Test case 4
Respectively the automotive upholstery compound ABS plastic masterbatch of embodiment 1 is put into vulcanizer and be pressed into the sheet that thickness is 1mm, then through coldmoulding, cut into the sample strip of 2cm × 5cm.
By plastics laboratory, GB/T16422.2-1999 light source exposure test method, be placed in xenon lamp and tan by the sun light aging test case and irradiate, then press GB2409-80 plastics yellowness index test method, survey its yellowness index △ YI.
The automotive upholstery compound ABS plastic illumination aging resisting performance test result of embodiment 1 is: after within 1000 hours, irradiating, yellowness index △ YI is 0.19, after within 2000 hours, irradiating, yellowness index △ YI is 0.45, can significantly be drawn by test data, the present invention has excellent illumination aging resisting performance in addition.
To the result of automotive upholstery compound ABS plastic traditional performance test be: tensile strength 40.8Mpa simultaneously, shock strength 12.7KJ/m2, flexural strength 59.4Mpa, modulus in flexure 2160Mpa, can significantly be drawn by test data, the present invention also maintains good tensile strength, shock strength, flexural strength and modulus in flexure.
Claims (5)
1. an automotive upholstery compound ABS plastic, it is characterized in that, comprise the component of following weight parts: ABS resin 200 parts, 3-(iso-butylene acyl-oxygen) propyl trimethoxy silicane 1-5 part, compound antiaging agent 0.5-1.5 part, damage resistant agent 0.5-1.5 part, composite antistatic agent 0.5-2 part, composite light stabilizer 0.3-0.5 part.
2. automotive upholstery compound ABS plastic as claimed in claim 1, it is characterized in that, described compound antiaging agent is made up of the component of following weight per-cent: 4,6-bis-(pungent thiomethyl) ortho-cresol 10-30%, 2,6 di tert butyl 4 methyl phenol 70-90%.
3. automotive upholstery compound ABS plastic as claimed in claim 1, it is characterized in that, the agent of described compound damage resistant is made up of the component of following weight per-cent: amine hydroxybenzene 40-60% and N, N-ethylene bis-oleamide 40-60%.
4. automotive upholstery compound ABS plastic as claimed in claim 1, it is characterized in that, described composite antistatic agent is made up of the component of following weight per-cent: sodium allyl sulfonate 30-50%, [3-(ten dioxo)-2-hydroxypropyl] two (2-hydroxyethyl) ammonium methyl methyl sulfate 20-40%, methyl-trimethylammonium-3-[(1-oxo dodecyl) is amino] propyl group ammonium sulfate 20-40%.
5. automotive upholstery compound ABS plastic as claimed in claim 1, it is characterized in that, the component composition of described composite light stabilizer following weight per-cent: 2-[2-hydroxyl-4-(2,2,6,6-tetramethyl piperidine-4-oxygen base) carbomethoxy phenyl]-2H-benzotriazole 40-60% and N, N '-bis-(2,2,6,6-tetramethyl--4-piperidyl)-N, N '-dialdehyde-based hexanediamine 40-60%.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510662295.3A CN105131506A (en) | 2015-10-14 | 2015-10-14 | Composite ABS plastic for automobile interior trim parts |
| PCT/CN2015/096801 WO2017063261A1 (en) | 2015-10-14 | 2015-12-09 | Composite abs plastic for automobile interior trim part |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510662295.3A CN105131506A (en) | 2015-10-14 | 2015-10-14 | Composite ABS plastic for automobile interior trim parts |
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| WO (1) | WO2017063261A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370147A (en) * | 2018-11-28 | 2019-02-22 | 惠州市威隆展业实业有限公司 | A kind of POS machine case material and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111234445A (en) * | 2020-02-18 | 2020-06-05 | 东莞市高能高分子材料有限公司 | Weather-resistant flame-retardant ABS plastic master batch and preparation method thereof |
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- 2015-10-14 CN CN201510662295.3A patent/CN105131506A/en active Pending
- 2015-12-09 WO PCT/CN2015/096801 patent/WO2017063261A1/en active Application Filing
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