CN105130455A - Anti-oxidation refractory material and preparation method thereof - Google Patents
Anti-oxidation refractory material and preparation method thereof Download PDFInfo
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- CN105130455A CN105130455A CN201510398730.6A CN201510398730A CN105130455A CN 105130455 A CN105130455 A CN 105130455A CN 201510398730 A CN201510398730 A CN 201510398730A CN 105130455 A CN105130455 A CN 105130455A
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Abstract
The invention relates to an anti-oxidation refractory material and a preparation method thereof. The anti-oxidation refractory material is prepared through adding an auxiliary additive, graphene, a binder and nano-alumina to a main raw material magnesium aluminate spinel with different particle sizes. The above product has a uniform microstructure, so the strength and the thermal shock resistance of the product are improved; nanometer zinc oxide has fine granularity and can be used to fill fine pores, so the porosity of the product is reduced, and the bulk density is improved; and the anti-oxidation refractory material also has the advantages of high refractoriness, good anti-oxidation performance, excellent erosion resistance, good thermal shock resistance and wide sintering temperature range.
Description
Technical field
The invention belongs to technical field of refractory materials, be specifically related to that a kind of refractoriness is high, antioxidant property is high, erosion-resisting characteristics is excellent, thermal shock resistance is good, oxidation-resistant refractory that sintering range is wide and preparation method thereof.
Background technology
Along with the growing tension of the energy, various countries are to the development of hot industry energy-saving material, production and use pay attention to day by day, and high temperature kiln needs to use the refractory materials with excellent properties or specialized character in a large number.As in order to increase the service life and improve heat-exchange capacity, regenerator chamber of glass kiln needs the checker having excellent resistance to fouling, creep resistance and have special shape size.Further, the superstructure of oxy-fuel combustion glass melting furnace also needs use to have good anti-erosion, creep resistance, the spill refractory materials of central filler lagging material.
Chinese patent publication No. CN102557684A, date of publication on July 11st, 2012, name is called silica brick for coke oven, and described silica brick comprises stock and adjunct, represents with weight proportion, silica meal 200-500 part in composition of raw materials, powder 330-380 part in silica, silica fine powder 80-130 part, as residual silica brick 80-120 part of chamotte powder, auxiliary material comprise account for the mineralizer of raw material gross weight 1.2%, the milk of lime of 8% and 1% paper pulp, mineralizer is by the manganese powder of Manganse Dioxide content >=25%; The iron phosphorus powder of ferrous oxide content >=65% mixes in the ratio of 1:1; Powder, silica fine powder and the residual silica brick as chamotte powder in silica meal, silica added in wet stone roller, then adding mineralizer and be dry mixed 4-5 minute, then adding milk of lime, after rolling 10-15 minute, then add paper pulp, mixing even to pug, roll, shaping base.Its weak point is, work-ing life is low, it is high to consume, and kind less waste is large.
Summary of the invention
The object of the invention is in order to solve existing refractory materials work-ing life low, consume high, the defect that kind less waste is large and provide that a kind of refractoriness is high, erosion-resisting characteristics is excellent, thermal shock resistance is good, the oxidation-resistant refractory that sintering range is wide.
Another object of the present invention is the preparation method in order to provide this refractory materials.
To achieve these goals, the present invention is by the following technical solutions:
A kind of oxidation-resistant refractory, described oxidation-resistant refractory for main raw material with the magnesium-aluminium spinel of different-grain diameter, adds supplementary additive, Graphene, bonding agent and nano aluminium oxide and makes.In the technical program, bauxitic clay base sintering magnesium-aluminium spinel adopts Al
20
3the high-quality alumina of content more than 76% and the high-quality light-burning magnesium powder of content of MgO more than 95%, through multistage homogenizing process, form through 1800 ° of more than C high temperature sinterings in ultra-high-temperature tunnel kiln, volume density is large, and mineral facies content is high, and grain development is good, even structure, steady quality.Magnesium-aluminium spinel has good anti-erosion, and burn into peel-ability is strong, and slag resistance is good, abrasion resistance, good thermal shock stability, the performance characteristics such as high temperature resistant is the desirable feedstock of producing the refractory productss such as the thermal zone Mg-Al spinel brick of cement rotary kiln, ladle brick, Refractory Carstables for Ladles.There is good corrosion resistance, abrasion resistance, good thermal shock stability.Its topmost purposes: one is replace magnesia-chrome sand to manufacture Mg-Al spinel brick for cement rotary kiln, not only avoids chromium public hazards, and has good resistance to flaking; Two is for making Refractory Carstables for Ladles, greatly improves the corrosion resistance of steel plate lining.
As preferably, the particle diameter of magnesium-aluminium spinel is respectively 0.35-0.88mm, 0.012-0.3mm, 0.0125-1 μm and 1.75-10nm.
As preferably, the mass fraction content of each raw material of described oxidation-resistant refractory is respectively: magnesium-aluminium spinel 30-35 part of magnesium-aluminium spinel 60-75 part of 0.35-0.88mm, magnesium-aluminium spinel 35-45 part of 0.012-0.3mm, 0.0125-1 μm, magnesium-aluminium spinel 10-15 part of 1.75-10nm, supplementary additive 5-9 part, Graphene 1-4 part, bonding agent 3-7 part and nano aluminium oxide 2-6 part.
As preferably, supplementary additive is the mixture of diatom ooze, boron nitride, glass microballon and nano zine oxide, and the mass ratio of diatom ooze, boron nitride, glass microballon and nano zine oxide is 5:3:4:7.In the technical program, glass microballon granularity is suitable, good fluidity, dispersity is high, add glass microballon, refractory materials internal height can be made dispersed, acceleration of sintering, and have evenly weave construction, improve intensity and the thermal shock resistance of goods, the granularity of nano zine oxide is tiny, can fill fine pores, reduce the void content of goods, improve volume density.Can make the adding of diatom ooze nano aluminium oxide with Graphene be transformed into active nano aluminium oxide with and Graphene, make its performance more outstanding.
As preferably, bonding agent is the mixture of maltodextrin, Sodium phosphate dibasic, alkali lignin, and the mass ratio of maltodextrin, Sodium phosphate dibasic, alkali lignin is 3:1:2.In the technical program, magnesium-aluminium spinel generally uses silicon ash or pure calcium aluminate cement as bonding agent, but the silicon-dioxide in the calcium oxide in cement or silicon ash can have a strong impact on the performance of material, and the present invention adopts the mixture of maltodextrin, Sodium phosphate dibasic and alkali lignin as bonding agent, magnesium-aluminium spinel can be allowed better to be formed in conjunction with phase with nano aluminium oxide, Graphene, make the anti-erosion of goods, creep-resistant property better.
As preferably, add glass microballon and nano zine oxide after diatom ooze mixes in ethanol with boron nitride, ultrasonic vibration 2h in 75 DEG C of water-baths, after dry, cold cycling obtains for 5-10 time, cold cycling is be incubated 2 hours, at being then cooled to-4 DEG C freezing 3 hours at 240 DEG C.
As preferably, maltodextrin is dissolved in deionized water, is heated to 60-75 DEG C, add Sodium phosphate dibasic and alkali lignin passes into nitrogen, gas velocity 4m/s.
A preparation method for oxidation-resistant refractory, each raw material weighs by above proportioning, obtains base substrate through mixing, shaping, maintenance, through 234-256 DEG C of dry 12-16h, then through 1700-1850 DEG C burn till, inspection process obtains oxidation-resistant refractory.
As preferably, after burning till through 1700-1850 DEG C, cool the temperature to 1200-1350 DEG C of insulation 2h, continue to be cooled to 600-850 DEG C of insulation 3.5h, be then cooled to 240-280 DEG C of insulation 6h and be cooled to room temperature detection again.
Beneficial effect of the present invention,
1) goods of the present invention have evenly weave construction, improve the intensity of goods and thermal shock resistance, the granularity of nano zine oxide is tiny, can fill fine pores, reduces the void content of goods, improves volume density;
2) goods refractoriness of the present invention is high, erosion-resisting characteristics is excellent, thermal shock resistance good, and sintering range is wide.
Embodiment
Below in conjunction with specific embodiment, the present invention is further explained, the restriction not to its protection domain.
Method therefor of the present invention, refers in particular to as non-, is conventional means.
The particle diameter of magnesium-aluminium spinel is respectively 0.35-0.88mm, 0.012-0.3mm, 0.0125-1 μm and 1.75-10nm.
Supplementary additive is the mixture of diatom ooze, boron nitride, glass microballon and nano zine oxide, and the mass ratio of diatom ooze, boron nitride, glass microballon and nano zine oxide is 5:3:4:7.Glass microballon and nano zine oxide is added after diatom ooze mixes in ethanol with boron nitride, ultrasonic vibration 2h in 75 DEG C of water-baths, after dry, cold cycling obtains for 5-10 time, and cold cycling is insulation 2 hours at 240 DEG C, at being then cooled to-4 DEG C freezing 3 hours.
Bonding agent is the mixture of maltodextrin, Sodium phosphate dibasic, alkali lignin, and the mass ratio of maltodextrin, Sodium phosphate dibasic, alkali lignin is 3:1:2.Maltodextrin is dissolved in deionized water, is heated to 60-75 DEG C, add Sodium phosphate dibasic and alkali lignin passes into nitrogen, gas velocity 4m/s.
The present invention is raw materials used can buy from market.
Embodiment 1
The mass fraction content of each raw material of oxidation-resistant refractory is respectively: the magnesium-aluminium spinel 30 parts of the magnesium-aluminium spinel 60 parts of 0.35-0.88mm, the magnesium-aluminium spinel 35 parts of 0.012-0.3mm, 0.0125-1 μm, the magnesium-aluminium spinel 10 parts of 1.75-10nm, supplementary additive 5 parts, Graphene 1 part, bonding agent 3 parts and nano aluminium oxide 2 parts.
A kind of preparation method of oxidation-resistant refractory, each raw material weighs by above proportioning, base substrate is obtained through mixing, shaping, maintenance, through 234 DEG C of dry 12h, after burning till through 1700 DEG C, cool the temperature to 1200 DEG C of insulation 2h, continue to be cooled to 600 DEG C of insulation 3.5h, be then cooled to 240 DEG C of insulation 6h and be cooled to the obtained oxidation-resistant refractory of room temperature detection again.
Embodiment 2
The mass fraction content of each raw material of oxidation-resistant refractory is respectively: the magnesium-aluminium spinel 32 parts of the magnesium-aluminium spinel 70 parts of 0.35-0.88mm, the magnesium-aluminium spinel 40 parts of 0.012-0.3mm, 0.0125-1 μm, the magnesium-aluminium spinel 13 parts of 1.75-10nm, supplementary additive 7 parts, Graphene 3 parts, bonding agent 5 parts and nano aluminium oxide 4 parts.
A kind of preparation method of oxidation-resistant refractory, each raw material weighs by above proportioning, base substrate is obtained through mixing, shaping, maintenance, through 243 DEG C of dry 14h, after burning till through 1800 DEG C, cool the temperature to 1250 DEG C of insulation 2h, continue to be cooled to 750 DEG C of insulation 3.5h, be then cooled to 255 DEG C of insulation 6h and be cooled to the obtained oxidation-resistant refractory of room temperature detection again.
Embodiment 3
The mass fraction content of each raw material of oxidation-resistant refractory is respectively: the magnesium-aluminium spinel 35 parts of the magnesium-aluminium spinel 75 parts of 0.35-0.88mm, the magnesium-aluminium spinel 45 parts of 0.012-0.3mm, 0.0125-1 μm, the magnesium-aluminium spinel 15 parts of 1.75-10nm, supplementary additive 9 parts, Graphene 4 parts, bonding agent 7 parts and nano aluminium oxide 6 parts.
A kind of preparation method of oxidation-resistant refractory, each raw material weighs by above proportioning, base substrate is obtained through mixing, shaping, maintenance, through 256 DEG C of dry 16h, after burning till through 1850 DEG C, cool the temperature to 1350 DEG C of insulation 2h, continue to be cooled to 850 DEG C of insulation 3.5h, be then cooled to 280 DEG C of insulation 6h and be cooled to the obtained oxidation-resistant refractory of room temperature detection again.
Comparative example 1, commercially available refractory materials.
The performance of the refractory materials of refractory materials prepared by embodiment 1-3 and comparative example 1 is in table 1.
Table 1, performance
| Void content, % | Volume density, g/ Cm 3 | Compressive strength, Mpa | Conforming product rate % | |
| Embodiment 1 | 14.3 | 2.12 | 66.5 | 96 |
| Embodiment 2 | 14.7 | 2.08 | 68.1 | 95 |
| Embodiment 3 | 15.6 | 2.21 | 63.7 | 94 |
| Comparative example 1 | 22.3 | 1.9 | 45.6 | 80 |
Claims (9)
1. an oxidation-resistant refractory, is characterized in that, described oxidation-resistant refractory for main raw material with the magnesium-aluminium spinel of different-grain diameter, adds supplementary additive, Graphene, bonding agent and nano aluminium oxide and makes.
2. a kind of oxidation-resistant refractory according to claim 1, is characterized in that, the particle diameter of magnesium-aluminium spinel is respectively 0.35-0.88mm, 0.012-0.3mm, 0.0125-1 μm and 1.75-10nm.
3. a kind of oxidation-resistant refractory according to claim 1 and 2, it is characterized in that, the mass fraction content of each raw material of described oxidation-resistant refractory is respectively: magnesium-aluminium spinel 30-35 part of magnesium-aluminium spinel 60-75 part of 0.35-0.88mm, magnesium-aluminium spinel 35-45 part of 0.012-0.3mm, 0.0125-1 μm, magnesium-aluminium spinel 10-15 part of 1.75-10nm, supplementary additive 5-9 part, Graphene 1-4 part, bonding agent 3-7 part and nano aluminium oxide 2-6 part.
4. a kind of oxidation-resistant refractory according to claim 1 and 2, it is characterized in that, supplementary additive is the mixture of diatom ooze, boron nitride, glass microballon and nano zine oxide, and the mass ratio of diatom ooze, boron nitride, glass microballon and nano zine oxide is 5:3:4:7.
5. a kind of oxidation-resistant refractory according to claim 1 and 2, is characterized in that, bonding agent is the mixture of maltodextrin, Sodium phosphate dibasic, alkali lignin, and the mass ratio of maltodextrin, Sodium phosphate dibasic, alkali lignin is 3:1:2.
6. a kind of oxidation-resistant refractory according to claim 4, it is characterized in that, glass microballon and nano zine oxide is added after diatom ooze mixes in ethanol with boron nitride, ultrasonic vibration 2h in 75 DEG C of water-baths, after dry, cold cycling obtains for 5-10 time, cold cycling is be incubated 2 hours, at being then cooled to-4 DEG C freezing 3 hours at 240 DEG C.
7. a kind of oxidation-resistant refractory according to claim 5, is characterized in that, maltodextrin is dissolved in deionized water, be heated to 60-75 DEG C, adds Sodium phosphate dibasic and alkali lignin passes into nitrogen, gas velocity 4m/s.
8. the preparation method of an oxidation-resistant refractory as claimed in claim 1, it is characterized in that, each raw material weighs by above proportioning, obtains base substrate through mixing, shaping, maintenance, through 234-256 DEG C of dry 12-16h, then through 1700-1850 DEG C burn till, inspection process obtains oxidation-resistant refractory.
9. the preparation method of a kind of oxidation-resistant refractory according to claim 8 is characterized in that, after burning till through 1700-1850 DEG C, cool the temperature to 1200-1350 DEG C of insulation 2h, continue to be cooled to 600-850 DEG C of insulation 3.5h, be then cooled to 240-280 DEG C of insulation 6h and be cooled to room temperature detection again.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107500748A (en) * | 2017-09-29 | 2017-12-22 | 瑞泰科技股份有限公司 | A kind of magnesium aluminate spinel graphene fire resistive material product and its preparation technology |
| CN107629498A (en) * | 2017-11-03 | 2018-01-26 | 周炳利 | A kind of graphene quantum dot composite refractory coating and preparation method thereof |
| CN109020508A (en) * | 2018-07-12 | 2018-12-18 | 吉林长玉特陶新材料技术股份有限公司 | A kind of three-dimensional grapheme bridging oxide ceramics and preparation method thereof |
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| CN102260084A (en) * | 2010-05-25 | 2011-11-30 | 长兴亿维冶金炉料有限公司 | Corundum refractory castable |
| CN102276276A (en) * | 2011-07-22 | 2011-12-14 | 中钢集团洛阳耐火材料研究院有限公司 | Alumina hollow ball insulation product |
| CN103601506A (en) * | 2013-10-09 | 2014-02-26 | 瑞泰科技股份有限公司 | Low-porosity magnesium aluminate spinel-zirconia composite sintered refractory material and production technology thereof |
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- 2015-07-09 CN CN201510398730.6A patent/CN105130455A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260084A (en) * | 2010-05-25 | 2011-11-30 | 长兴亿维冶金炉料有限公司 | Corundum refractory castable |
| CN102276276A (en) * | 2011-07-22 | 2011-12-14 | 中钢集团洛阳耐火材料研究院有限公司 | Alumina hollow ball insulation product |
| CN103601506A (en) * | 2013-10-09 | 2014-02-26 | 瑞泰科技股份有限公司 | Low-porosity magnesium aluminate spinel-zirconia composite sintered refractory material and production technology thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107500748A (en) * | 2017-09-29 | 2017-12-22 | 瑞泰科技股份有限公司 | A kind of magnesium aluminate spinel graphene fire resistive material product and its preparation technology |
| CN107500748B (en) * | 2017-09-29 | 2020-08-11 | 瑞泰科技股份有限公司 | Magnesia-alumina spinel-graphene refractory material product and preparation process thereof |
| CN107629498A (en) * | 2017-11-03 | 2018-01-26 | 周炳利 | A kind of graphene quantum dot composite refractory coating and preparation method thereof |
| CN109020508A (en) * | 2018-07-12 | 2018-12-18 | 吉林长玉特陶新材料技术股份有限公司 | A kind of three-dimensional grapheme bridging oxide ceramics and preparation method thereof |
| CN109020508B (en) * | 2018-07-12 | 2021-04-23 | 吉林长玉特陶新材料技术股份有限公司 | Three-dimensional graphene bridged oxide ceramic and preparation method thereof |
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Application publication date: 20151209 |