CN105130309A - Preparation method of environment friendly brick - Google Patents

Preparation method of environment friendly brick Download PDF

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Publication number
CN105130309A
CN105130309A CN201510620691.XA CN201510620691A CN105130309A CN 105130309 A CN105130309 A CN 105130309A CN 201510620691 A CN201510620691 A CN 201510620691A CN 105130309 A CN105130309 A CN 105130309A
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China
Prior art keywords
building waste
waste residue
environmental protection
brick
cooled
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CN201510620691.XA
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Chinese (zh)
Inventor
陈毅忠
宋国
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Changzhou Ao Putaike Photoelectric Co Ltd
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Changzhou Ao Putaike Photoelectric Co Ltd
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Priority to CN201510620691.XA priority Critical patent/CN105130309A/en
Publication of CN105130309A publication Critical patent/CN105130309A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a preparation method of an environment friendly brick, belonging to the technical field of re-utilization of wastes. The invention aims at the problem that treating capacity of building waste residues in China is large so as to cause bulk deposition of solid wastes, in a traditional solution, the waste residues are applied to making bricks, due to the fact that the waste residues contain chemical substances such as sulfide, the chemical substances can react chemically with surface materials if the time is long, so that discoloration and deterioration of decorative materials occur, and attractive appearance of a building is influenced. The invention provides the environment friendly brick by the steps of smashing building waste residues and removing impurities such as metal, and evenly mixing with carbonized straw powder under the protection of helium, then adding substances such as sodium anthraquinone-2-sulfonate to remove the sulfide in the waste residues, the mass is light, and decorative materials are not influenced. Embodiments prove that the mass of the obtained environment friendly brick is 60-80% of the mass of a common brick, the strength of the environment friendly brick is 2 to 3 times that of the common brick, hazardous substances in air can be adsorbed, meanwhile air harm to human health after decoration is reduced, the building waste residues are fully utilized, and environmental pollution is reduced.

Description

A kind of preparation method of environmental protection brick
Technical field
The invention discloses a kind of preparation method of environmental protection brick, belong to waste reutilization technology field.
Background technology
At present, the quantity of China's building waste has accounted for the 30%-40% of municipal wastes total amount.The building waste of new generation will be a shocking numeral.But, overwhelming majority building waste is without any process, just transported to countryside or rural area by unit in charge of construction, air storage or landfill, consume the pork barrels such as a large amount of land acquisitions takes, refuse collection expense, meanwhile, clear and drop with dust, sand-lime fly upward etc. that problem causes again serious environmental pollution in stacking process.
At present, known brick made of building waste residuel by building waste residue, coal ash and cement production systD, due in coal ash containing sulfide, penetrate into tile floor surface, chemistry can be carried out with the powdering material whitewashed on brick body and reflect, powdering material is gone bad variable color, affect the attractive in appearance of buildings, be unfavorable for that room for building uses.
Summary of the invention
The technical problem that the present invention mainly solves: large for current China building waste residue treatment capacity, cause solid waste bulk deposition, and Traditional solutions waste residue is applied to make brick, owing to containing the chemical substances such as sulfide in waste residue, time one long meeting and surface mass generation chemical reaction, finishing material variable color is gone bad, impact building is attractive in appearance, the invention provides a kind of by building waste residue is pulverized removal metal impurities, again with charing after stalk powder, mix under helium protection, add zinc oxide wherein again, the materials such as anthraquinone disulphonate remove the sulfide in waste residue, ferment with air bladder again and increase viscosity, prepare quality light, do not affect the method for the environmental protection brick of finishing material.
In order to solve the problems of the technologies described above, the technical solution adopted in the present invention is:
(1) get building waste residue to put into crusher and carry out fragmentation, the metallics contained in building waste residue is removed by magnet, plastics and wooden impurity is removed again by hand picking, then put it in pulverizer and be ground into 100 ~ 120 order particles, again particle is put into batch mixing pond, add water wherein, make particulate matter water content be 10 ~ 15%, for subsequent use;
(2) get stalk to put into pulverizer and be ground into 70 ~ 80 order particles, particulate matter is put into stalk block making machine and is squeezed into block, again the stalk particle being squeezed into block is put into charring furnace, at temperature is 280 ~ 310 DEG C, charing 30 ~ 40min, taken out and be cooled to 30 ~ 35 DEG C, put into pulverizer and be ground into 100 ~ 120 order particulate matter;
(3) the batch mixing pond that the particulate matter of getting above-mentioned gained puts into step (1) mixes, add-on is 45 ~ 55% of building waste residue quality, is then sealed in batch mixing pond, is filled with the air in helium discharge pond wherein, temperature is set as 60 ~ 70 DEG C, stirs 1 ~ 3h;
(4) after above-mentioned stirring terminates, be cooled to 50 ~ 55 DEG C, helium in collecting tank, then the calcium sulphonate of 0.4 ~ 0.9% of building waste residue quality is added wherein, building waste residue quality 0.2 ~ 0.5% zinc oxide, building waste residue quality 0.9 ~ 1.2% sodium aluminate, the anthraquinone disulphonate of 0.8 ~ 1.5% of building waste residue quality and the carboxymethyl cellulose of 1.2 ~ 2.3% of building waste residue quality stir;
(5) mixture of above-mentioned gained is put into fermentation vat, the air bladder getting mixture quality 20 ~ 30% is put into wherein, mixes, sealing and fermenting, after air bladder fully fermenting, stirs 8 ~ 10h, leaves standstill 20 ~ 30min, remove surface liquid, obtain environmental protection brick raw material;
(6) the environmental protection brick raw material of above-mentioned gained is put into mould, be cooled to rapidly 10 ~ 15 DEG C, the pressure of 20 ~ 25MPa is used to be pressed into adobe, again that adobe is dry at the temperature of 110 ~ 150 DEG C, by dried base substrate with the heat-up rate of 4 ~ 7 DEG C/min, be heated to 900 ~ 1100 DEG C, insulation 1 ~ 2h, then be cooled to 28 ~ 35 DEG C, the demoulding, can environmental protection brick be obtained.
Application method of the present invention is: be applied in building by the environmental protection brick of gained, at its external coating finishing material, detect environmental protection brick and finishing material without any reaction, and the nuisance in decorated rear air is up to state standards.
The invention has the beneficial effects as follows:
(1) quality of the environmental protection brick of gained is 60 ~ 80% of common brick, and intensity is 2 ~ 3 times of common brick;
(2) objectionable impurities in the environmental protection brick absorbed air of gained of the present invention, reduces the air after finishing to the injury of HUMAN HEALTH simultaneously;
(3) take full advantage of building waste residue, decrease the pollution to environment.
Embodiment
Get building waste residue to put into crusher and carry out fragmentation, the metallics contained in building waste residue is removed by magnet, plastics and wooden impurity is removed again by hand picking, then put it in pulverizer and be ground into 100 ~ 120 order particles, again particle is put into batch mixing pond, add water wherein, make particulate matter water content be 10 ~ 15%, for subsequent use; Get stalk to put into pulverizer and be ground into 70 ~ 80 order particles, particulate matter is put into stalk block making machine and is squeezed into block, again the stalk particle being squeezed into block is put into charring furnace, at temperature is 280 ~ 310 DEG C, charing 30 ~ 40min, taken out and be cooled to 30 ~ 35 DEG C, put into pulverizer and be ground into 100 ~ 120 order particulate matter; The particulate matter of getting above-mentioned gained is put into above-mentioned batch mixing pond and is mixed, and add-on is 45 ~ 55% of building waste residue quality, is then sealed in batch mixing pond, and be filled with helium wherein and discharge air in pond, temperature is set as 60 ~ 70 DEG C, stirs 1 ~ 3h; After above-mentioned stirring terminates, be cooled to 50 ~ 55 DEG C, helium in collecting tank, then the calcium sulphonate of 0.4 ~ 0.9% of building waste residue quality is added wherein, building waste residue quality 0.2 ~ 0.5% zinc oxide, building waste residue quality 0.9 ~ 1.2% sodium aluminate, the anthraquinone disulphonate of 0.8 ~ 1.5% of building waste residue quality and the carboxymethyl cellulose of 1.2 ~ 2.3% of building waste residue quality stir; The mixture of above-mentioned gained is put into fermentation vat, and the air bladder getting mixture quality 20 ~ 30% is put into wherein, mixes, sealing and fermenting, after air bladder fully fermenting, stirs 8 ~ 10h, leaves standstill 20 ~ 30min, remove surface liquid, obtain environmental protection brick raw material; The environmental protection brick raw material of above-mentioned gained is put into mould, be cooled to rapidly 10 ~ 15 DEG C, the pressure of 20 ~ 25MPa is used to be pressed into adobe, again that adobe is dry at the temperature of 110 ~ 150 DEG C, by dried base substrate with the heat-up rate of 4 ~ 7 DEG C/min, be heated to 900 ~ 1100 DEG C, insulation 1 ~ 2h, then be cooled to 28 ~ 35 DEG C, the demoulding, can environmental protection brick be obtained.
Example 1
Get 5kg building waste residue to put into crusher and carry out fragmentation, the metallics contained in building waste residue is removed by magnet, plastics and wooden impurity is removed again by hand picking, then put it in pulverizer and be ground into 100 order particles, again particle is put into batch mixing pond, add water wherein, make particulate matter water content be 10%, for subsequent use; Get 4kg stalk to put into pulverizer and be ground into 70 order particles, particulate matter is put into stalk block making machine and is squeezed into block, again the stalk particle being squeezed into block is put into charring furnace, at temperature is 280 DEG C, charing 30min, taken out and be cooled to 30 DEG C, put into pulverizer and be ground into 100 order particulate matter; The particulate matter of getting the above-mentioned gained of 2.3kg is put into above-mentioned batch mixing pond and is mixed, and is then sealed in batch mixing pond, and be filled with helium wherein and discharge air in pond, temperature is set as 60 DEG C, stirs 1h; After above-mentioned stirring terminates, be cooled to 50 DEG C, the helium in collecting tank, then add the calcium sulphonate of building 0.02kg wherein, the zinc oxide of 0.01kg, the sodium aluminate of 0.045kg, the anthraquinone disulphonate of 0.04kg and the carboxymethyl cellulose of 0.06kg stir; The mixture of above-mentioned gained is put into fermentation vat, and the air bladder getting mixture quality 20% is put into wherein, mixes, sealing and fermenting, after air bladder fully fermenting, stirs 8h, leaves standstill 20min, remove surface liquid, obtain environmental protection brick raw material; The environmental protection raw material of above-mentioned gained is put into mould, be cooled to rapidly 10 DEG C, the pressure of 20MPa is used to be pressed into adobe, again that adobe is dry at the temperature of 110 DEG C, by dried base substrate with the heat-up rate of 4 DEG C/min, be heated to 900 DEG C, insulation 1h, then be cooled to 28 DEG C, the demoulding, can environmental protection brick be obtained.
The environmental protection brick of gained is applied in building, at its external coating finishing material, detect environmental protection brick and finishing material without any reaction, and the nuisance in decorated rear air is up to state standards, the quality of the environmental protection brick of gained is 60% of common brick, and intensity is 2 times of common brick.
Example 2
Get 5kg building waste residue to put into crusher and carry out fragmentation, the metallics contained in building waste residue is removed by magnet, plastics and wooden impurity is removed again by hand picking, then put it in pulverizer and be ground into 120 order particles, again particle is put into batch mixing pond, add water wherein, make particulate matter water content be 15%, for subsequent use; Get 4kg stalk to put into pulverizer and be ground into 80 order particles, particulate matter is put into stalk block making machine and is squeezed into block, again the stalk particle being squeezed into block is put into charring furnace, at temperature is 310 DEG C, charing 40min, taken out and be cooled to 35 DEG C, put into pulverizer and be ground into 120 order particulate matter; The particulate matter of getting the above-mentioned gained of 2.75kg is put into above-mentioned batch mixing pond and is mixed, and is then sealed in batch mixing pond, and be filled with helium wherein and discharge air in pond, temperature is set as 70 DEG C, stirs 3h; After above-mentioned stirring terminates, be cooled to 55 DEG C, the helium in collecting tank, then add the calcium sulphonate of 0.045kg wherein, the zinc oxide of 0.025kg, the sodium aluminate of 0.06kg, the anthraquinone disulphonate of 0.075kg and the carboxymethyl cellulose of 0.115kg stir; The mixture of above-mentioned gained is put into fermentation vat, and the air bladder getting mixture quality 30% is put into wherein, mixes, sealing and fermenting, after air bladder fully fermenting, stirs 10h, leaves standstill 30min, remove surface liquid, obtain environmental protection brick raw material; The environmental protection raw material of above-mentioned gained is put into mould, be cooled to rapidly 15 DEG C, the pressure of 25MPa is used to be pressed into adobe, again that adobe is dry at the temperature of 150 DEG C, by dried base substrate with the heat-up rate of 7 DEG C/min, be heated to 1100 DEG C, insulation 2h, then be cooled to 35 DEG C, the demoulding, can environmental protection brick be obtained.
The environmental protection brick of gained is applied in building, at its external coating finishing material, detect environmental protection brick and finishing material without any reaction, and the nuisance in decorated rear air is up to state standards, the quality of the environmental protection brick of gained is 80% of common brick, and intensity is 3 times of common brick.
Example 3
Get 5kg building waste residue to put into crusher and carry out fragmentation, the metallics contained in building waste residue is removed by magnet, plastics and wooden impurity is removed again by hand picking, then put it in pulverizer and be ground into 110 order particles, again particle is put into batch mixing pond, add water wherein, make particulate matter water content be 13%, for subsequent use; Get 4kg stalk to put into pulverizer and be ground into 75 order particles, particulate matter is put into stalk block making machine and is squeezed into block, again the stalk particle being squeezed into block is put into charring furnace, at temperature is 290 DEG C, charing 35min, taken out and be cooled to 32 DEG C, put into pulverizer and be ground into 110 order particulate matter; The particulate matter of getting the above-mentioned gained of 2.6kg is put into above-mentioned batch mixing pond and is mixed, and is then sealed in batch mixing pond, and be filled with helium wherein and discharge air in pond, temperature is set as 65 DEG C, stirs 2h; After above-mentioned stirring terminates, be cooled to 53 DEG C, the helium in collecting tank, then add the calcium sulphonate of 0.042kg wherein, the zinc oxide of 0.022kg, the sodium aluminate of 0.058kg, the anthraquinone disulphonate of 0.069kg and the carboxymethyl cellulose of 0.1kg stir; ; The mixture of above-mentioned gained is put into fermentation vat, and the air bladder getting mixture quality 25% is put into wherein, mixes, sealing and fermenting, after air bladder fully fermenting, stirs 9h, leaves standstill 25min, remove surface liquid, obtain environmental protection brick raw material; The environmental protection brick raw material of above-mentioned gained is put into mould, be cooled to rapidly 13 DEG C, the pressure of 22MPa is used to be pressed into adobe, again that adobe is dry at the temperature of 125 DEG C, by dried base substrate with the heat-up rate of 5 DEG C/min, be heated to 1000 DEG C, insulation 2h, then be cooled to 20 DEG C, the demoulding, can environmental protection brick be obtained.
The environmental protection brick of gained is applied in building, at its external coating finishing material, detect environmental protection brick and finishing material without any reaction, and the nuisance in decorated rear air is up to state standards, the quality of the environmental protection brick of gained is 70% of common brick, and intensity is 2 times of common brick.

Claims (1)

1. a preparation method for environmental protection brick, is characterized in that concrete preparation method:
(1) get building waste residue to put into crusher and carry out fragmentation, the metallics contained in building waste residue is removed by magnet, plastics and wooden impurity is removed again by hand picking, then put it in pulverizer and be ground into 100 ~ 120 order particles, again particle is put into batch mixing pond, add water wherein, make particulate matter water content be 10 ~ 15%, for subsequent use;
(2) get stalk to put into pulverizer and be ground into 70 ~ 80 order particles, particulate matter is put into stalk block making machine and is squeezed into block, again the stalk particle being squeezed into block is put into charring furnace, at temperature is 280 ~ 310 DEG C, charing 30 ~ 40min, taken out and be cooled to 30 ~ 35 DEG C, put into pulverizer and be ground into 100 ~ 120 order particulate matter;
(3) the batch mixing pond that the particulate matter of getting above-mentioned gained puts into step (1) mixes, add-on is 10 ~ 15% of building waste residue quality, is then sealed in batch mixing pond, is filled with the air in helium discharge pond wherein, temperature is set as 60 ~ 70 DEG C, stirs 1 ~ 3h;
(4) after above-mentioned stirring terminates, be cooled to 50 ~ 55 DEG C, helium in collecting tank, then the calcium sulphonate of 0.4 ~ 0.9% of building waste residue quality is added wherein respectively, building waste residue quality 0.2 ~ 0.5% zinc oxide, building waste residue quality 0.9 ~ 1.2% sodium aluminate, the anthraquinone disulphonate of 0.8 ~ 1.5% of building waste residue quality and the carboxymethyl cellulose of 1.2 ~ 2.3% of building waste residue quality stir;
(5) mixture of above-mentioned gained is put into fermentation vat, the air bladder getting mixture quality 20 ~ 30% is put into wherein, mixes, sealing and fermenting, after air bladder fully fermenting, stirs 8 ~ 10h, leaves standstill 20 ~ 30min, remove surface liquid, obtain environmental protection brick raw material;
(6) the environmental protection brick raw material of above-mentioned gained is put into mould, be cooled to rapidly 10 ~ 15 DEG C, the pressure of 20 ~ 25MPa is used to be pressed into adobe, again that adobe is dry at the temperature of 110 ~ 150 DEG C, by dried base substrate with the heat-up rate of 4 ~ 7 DEG C/min, be heated to 900 ~ 1100 DEG C, insulation 1 ~ 2h, then be cooled to 28 ~ 35 DEG C, the demoulding, can environmental protection brick be obtained.
CN201510620691.XA 2015-09-27 2015-09-27 Preparation method of environment friendly brick Pending CN105130309A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312349A (en) * 2017-06-20 2017-11-03 肥西县碧涛建材有限公司 A kind of environmental protection brick and preparation method thereof
CN108372193A (en) * 2018-02-13 2018-08-07 河南科技大学 A kind of method that Winter Wheat-Summer Maize Rotation System repairs lead contamination in calacareous soil
CN111778807A (en) * 2020-07-24 2020-10-16 道陶乎 Plastic stone brick

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012006923A1 (en) * 2010-07-13 2012-01-19 Shi Lei Modified inorganic powder composite material and preparation method thereof
CN102424539A (en) * 2011-08-31 2012-04-25 兰州理工大学 Production method of straw regeneration concrete brick and building block
CN102765927A (en) * 2012-07-05 2012-11-07 浙江特拉建材有限公司 Brick making method
CN103992134A (en) * 2014-05-13 2014-08-20 旌德县恒科新型建筑材料有限公司 An environmental-friendly brick and a production method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012006923A1 (en) * 2010-07-13 2012-01-19 Shi Lei Modified inorganic powder composite material and preparation method thereof
CN102424539A (en) * 2011-08-31 2012-04-25 兰州理工大学 Production method of straw regeneration concrete brick and building block
CN102765927A (en) * 2012-07-05 2012-11-07 浙江特拉建材有限公司 Brick making method
CN103992134A (en) * 2014-05-13 2014-08-20 旌德县恒科新型建筑材料有限公司 An environmental-friendly brick and a production method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312349A (en) * 2017-06-20 2017-11-03 肥西县碧涛建材有限公司 A kind of environmental protection brick and preparation method thereof
CN108372193A (en) * 2018-02-13 2018-08-07 河南科技大学 A kind of method that Winter Wheat-Summer Maize Rotation System repairs lead contamination in calacareous soil
CN111778807A (en) * 2020-07-24 2020-10-16 道陶乎 Plastic stone brick

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