CN105130293B - A kind of production method of ecological revetment material - Google Patents

A kind of production method of ecological revetment material Download PDF

Info

Publication number
CN105130293B
CN105130293B CN201510442191.1A CN201510442191A CN105130293B CN 105130293 B CN105130293 B CN 105130293B CN 201510442191 A CN201510442191 A CN 201510442191A CN 105130293 B CN105130293 B CN 105130293B
Authority
CN
China
Prior art keywords
parts
water
cement
sand
concrete
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201510442191.1A
Other languages
Chinese (zh)
Other versions
CN105130293A (en
Inventor
姚仕明
唐峰
潘保柱
渠庚
何广水
岳红艳
朱勇辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changjiang River Scientific Research Institute Changjiang Water Resources Commission
Original Assignee
Changjiang River Scientific Research Institute Changjiang Water Resources Commission
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changjiang River Scientific Research Institute Changjiang Water Resources Commission filed Critical Changjiang River Scientific Research Institute Changjiang Water Resources Commission
Priority to CN201510442191.1A priority Critical patent/CN105130293B/en
Publication of CN105130293A publication Critical patent/CN105130293A/en
Application granted granted Critical
Publication of CN105130293B publication Critical patent/CN105130293B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Revetment (AREA)

Abstract

The present invention is a kind of production method of novel ecological embankment material:Mass fraction is weighed as 129~133 parts of water, 206~213 parts of cement, 52~53 parts of flyash, 647~653 parts of sand, 1330~1342 parts of stones, 2.06~2.13 parts of water-reducing agents and 0.015~0.016 part of air entraining agent according to raw material proportioning;Mixing stirs, and pours out the performance of detection concrete mix after a certain period of time, ensures slump value in the range of 40mm~60mm, air content is pressed in the range of 4%~4.5%;Mixture is poured into mold, is vibrated with vibrator, vibration compacting;Form removal after test specimen is stood for 24 hours after being molded, is put into standard curing room maintenance 28 days or watering conserves in a natural environment.The present invention as raw material and is aided with the materials such as rubble or coarse sand and cement and produces the material of suitable river bank slope protection using silt in river and water, and prepare material be easily obtained, prepare it is simple, of low cost.

Description

A kind of production method of ecological revetment material
Technical field
The present invention relates to water conservancy and hydropower technical fields, especially relate to a kind of making side of novel ecological embankment material Method.
Background technology
Alluvial stream is under nature evolution state, and river regime, channel planform and water front etc. are in uncontrollable shape State can constitute a threat to littoral socio-economic development safely with the people's lives and property, be unfavorable for playing the comprehensive function in river. Therefore, it is to stablize water front, control river regime, stable boat slot etc. to control river requirements of one's work to carry out dredging waterway and bank slope protection, with profit In the comprehensive function for giving full play to river.Bank slope protection is the important component in river training works, in river management work Generally existing in journey.For middle and lower reach of Yangtze River channel revetment engineering, more than 90% be riprap protection pattern, the shield in other rivers Bank engineering is also similar, and based on riprap protection, riprap protection biggest advantage is that materials are relatively easy, adapts to riverbed majority Deformability is strong, is easy to reinforcing etc..Riprap protection needs a large amount of building stones, and building stones are obtained typically by exploitation mountain stone Source, the exploitation mountain stone of large area can lead to the serious destruction of local environment, damage the image of the fine territory of motherland.Therefore, Seek the direction that alternative materials control river worker effort always.In recent years, for river bank slope protection, the country has carried out other more The experimental project of kind pattern, achieves positive achievement.For example, the new material, new that channel revetment engineering in the middle and lower reach of Yangtze River uses Technology, new process mainly have hinged concrete row, mold-bagged concrete, six side four sides water-permeable frames, cobble pad, nethike embrane cobble row Deng, in these shore protection patterns cobble pad or cobble row in contrast comparative ecology, shore protection main raw material(s) take from river, fit When exploitation river cobble will not generate the ecological environment in material source area big influence, and life of this kind of bank-protection works to guard plot State environment is influenced smaller or even can be made moderate progress.But the cobble reserves of natural river course are limited, and exhaustive exploitation can cause river A series of problems, such as road incision, water level reduce.Alluvial streams riverbed is mainly made of medium-fine sand or fine sand, how to be taken on the spot Material using the silt in river as main raw material(s) by suitably processing formation and the equivalent embankment material of cobble is crucial.Cause This, is badly in need of inventing a kind of novel revetment material to substitute previous traditional embankment material, to meet dredging waterway and bank slope protection Needs, while also farthest mitigate these engineering constructions to ecological environment adverse effect.
Invention content
In view of the above-mentioned problems, the present invention proposes a kind of production method of novel ecological embankment material, silt in river is utilized As raw material and it is aided with the material that the materials such as rubble or coarse sand and cement produce suitable river bank slope protection, and make with water Standby material is easily obtained, it is simple, of low cost to prepare.
To achieve the above object, the present invention takes following technical scheme:
A kind of production method of novel ecological embankment material, it is characterised in that:The production method of the embankment material is:It presses Mass fraction is weighed as 129~133 parts of water, 206~213 parts of cement according to raw material proportioning, 52~53 parts of flyash, 647~653 Part sand, 1330~1342 parts of stones, 2.06~2.13 parts of water-reducing agents and 0.015~0.016 part of air entraining agent;Mixing stirs, a timing Between after pour out the performance of detection concrete mix, ensure slump value in the range of 40mm~60mm, air content presses 4%~ In the range of 4.5%;Mixture is poured into mold, is vibrated with vibrator, vibration compacting;Test specimen standing after molding is torn open afterwards for 24 hours Mould, is put into standard curing room maintenance 28 days or watering conserves in a natural environment.
Preferably, the cement is meets GB 200-2003 moderate-heat portland cements, low-heat portland cement, low-heat ore deposit 42.5 moderate heat cements of slag portland cement technology requirement meet the requirement of GB 175-2007 common portland cements technology 42.5 ordinary cements.
Preferably, the flyash is to meet the I that DL/T 5055-2007 concrete for hydraulic structure mixes flyash technical specification Grade flyash.
Preferably, the sand is to meet DL/T 5151-2001 concrete for hydraulic structure sandstone aggregate testing regulations technologies to require Artificial rubble or coarse sand;Stone uses graduation two aggregate, i.e., the middle stone that grain size is 5~20mm gravelstone, grain size are 20~40mm; Two kinds of aggregate ratios, with experiment, choose the grading ratio that tapped bulk density is maximum, porosity is minimum by coarse aggregate combination stage.
Preferably, the water-reducing agent and air entraining agent are the height for meeting the requirement of GB 8076-2008 concrete admixtures technology Performance water-reducing agent and air entraining agent.
The embankment material is flat sphere, and it is 0.1~0.3m that preferred shape, which is major semiaxis, semi-minor axis for 0.05~ 0.15m, thickness are the oval ball of 0.05~0.15m.
The present invention has the following advantages:
(1) present invention makes full use of the raw material of natural river course to make to form embankment material, is conducive to energy conservation and environmental protection.
(2) embankment material of the invention can adjust size and shape according to actual needs, to meet different flow conditions Protection with bank slope boundary condition needs.
(3) because the embankment material of the present invention for bulk solid or forms isostere, after carrying out bank slope protection, there is preferable riverbed Adaptability is deformed, and the gap between protection body is conducive to improve the microhabitat of aquatile.
(4) embankment material of the invention is adaptable to dredging waterway and the bank slope protection in large, medium and small river, it can also be used to Other kinds of bank slope protection.
Attached drawing
Fig. 1 makes the grading case of natural sand that embankment material uses;
The structure diagram of Fig. 2 representativeness embankment materials;
Fig. 3 makes the structure diagram of the mold of embankment material.
Specific embodiment
For a better understanding of the technical solution of the present invention, technology provided by the invention is described in detail with reference to embodiment Scheme.
The present invention relates to a kind of production method of novel ecological embankment material, this method includes the basic material made, matches Than, embankment material size and shape determine and manufacture craft.
1st, the selection and requirement of basic material are made
The novel ecological embankment material as main raw material(s) and is aided with powder by the use of water, silt, rubble or coarse sand and cement Coal ash and additive complete.
The present invention has raw material following requirement:
(1) cement
Meet GB 200-2003《Moderate-heat portland cement, low-heat portland cement, low heat portland blast-furnace-slag cement》Technology It is required that 42.5 moderate heat cements or meet GB 175-2007《Common portland cement》42.5 ordinary cements of technology requirement;
(2) flyash
Meet DL/T 5055-2007《Concrete for hydraulic structure mixes flyash technical specification》I grades of flyash;
(3) fine aggregate
Meet DL/T 5151-2001《Concrete for hydraulic structure sandstone aggregate testing regulations》The sand of technology requirement, artificial grain fineness number Modulus in 2.4~2.8 ranges, natural grain fineness number modulus in 2.2~3.0 ranges, as shown in Figure 1, fine aggregate answer quality it is hard, Cleaning, grading are good;
(4) coarse aggregate
Meet DL/T 5151-2001《Concrete for hydraulic structure sandstone aggregate testing regulations》The artificial rubble of technology requirement, uses Graduation two aggregate, i.e. gravelstone (5-20mm), middle stone (20-40mm);Two kinds of aggregate ratios, with experiment, are chosen by coarse aggregate combination stage The grading ratio that tapped bulk density is maximum, porosity is minimum.
(5) additive
Meet GB 8076-2008《Concrete admixture》The high-performance water reducing agent and air entraining agent of technology requirement.
2nd, ratio requirement
(1) concrete preparation strength is determining
The novel ecological embankment material concrete strength is determined as C20 according to identical bank-protection works material concrete strength, According to DL/T 5330-2005《Mix proportion of concrete design discipline》, concrete preparation strength is calculated as follows:
fcu,0=fcu,k+tσ (1)
In formula:fcu,oThe preparation strength of-concrete, MPa;
fcu,kThe strength standard value of-Concrete Design age, MPa;
T-degree of probability coefficient;It is selected by given fraction P, when design age is 28d, compression strength fraction P It is 95%, corresponding t=1.645;
σ-concrete strength standard deviation, MPa for C20 concrete, can use 4.0.
It is computed, C20 Concrete Designs preparation strength is 26.6MPa.
(2) mix Design
Foundation《Mix proportion of concrete design discipline》, it is basic to choose the mix-designs such as water-cement ratio, water consumption, sand coarse aggregate ratio Parameter carries out trial, adjustment and performance test, determining final concrete mix and is shown in Table 2:
2 graduation two Normal Concrete Construction match ratio of table
Note:1. material property need to meet the technology requirement of corresponding specification in table.
2. table Central Plains density of material is respectively cement 3.10kg/m3, flyash 2.30kg/m3, sand 2.67kg/m3, stone 2.70kg/m3, in practice of construction, dosage water, sand coarse aggregate ratio and admixture dosage are changed according to material property and mix workability It finely tunes.
3. machine outlet graduation two normal concrete slump value is controlled by 40mm~60mm;Air content is by 4%~4.5% control System.
Example 1:Using the match ratio in table 2, choose Sichuan and praise magnificent 42.5 moderate heat cements, Xuanwei of Yunnan Province I grades of fine coal, limestones Artificial sand, limestone artificial aggregate, the JM-II efficient retarding and water reducing agents of Jiangsu Botexin Materials Co., Ltd's production and Wuhan The HS-8 type air entraining agents of Huashuo Science Co., Ltd of work research institute production, are tested, 28d compression strength through compressive strength test For 27.2MPa, meet the configuration intensity requirement of C20 concrete 26.6MPa.
Example 2:Using the match ratio in table 2, choose Yunnan protect forever 42.5 ordinary cements and I grades of Sichuan inland river flyash, The HLC-NAF retardation setting high efficiency diminishings that griotte artificial sand, griotte artificial aggregate, Nanjing R & D High Technology Co., Ltd. produce Agent and the concrete of HLC-A air entraining agents configuration, are tested, 28d compression strength is 28.4MPa, meets C20 and mixes through compressive strength test The configuration intensity requirement of solidifying soil 26.6MPa.
According to upper table 2
3rd, embankment material size and shape is determining
The protective mechanism of bank-protection works is that not only had the adjustment capability for adapting to river-bed deformation, but also slope surface can be protected from flow Scouring capability.For embankment material, it is necessary to meet individual or the stability of cell cube and anti-impact requirement.Formula (2) is oblique The initial velocity calculation formula of bulk solid on slope.
In formula:CD, CLFor thrust and the coefficient of uplift force, W, FDRespectively the underwater effective gravity of bulk solid particle with along flow The thrust in direction, α012The respectively corresponding area coefficient of gravity, uplift force, sliding force, γs, γ is respectively shore protection individual material With the severe of water;H, D are respectively the grain size of the depth of water and bulk solid particle;M is the index in exponential velocity formula;α is acted on for underflow speed In the coefficient of bed surface sand grain height;λ is bourn acting force and horizontal angle;φ is river longitudinal direction base slope slope angle;G attaches most importance to Power acceleration;θ is riverbank slope angle, if θ is critical slope, tan θ=f (internal friction angle);β1For torque coefficient;For sand grain The direction of motion and the angle of downslide force direction, Just For formula (2), for coarse sediment, the coefficient in formula can be taken as CD=0.7, CL=0.18, β1=0.38, m=6, α =1.0.Can be seen that by formula (2), bulk solid particle under different flows and boundary condition, on bank slope the initial velocity of particle with The factors such as its size, bank slope angle, riverbed longitudinal direction base slope are related.For example, initial velocity increases with the increase of grain diameter, with The steepening of bank slope and reduce, reduce with the increase of riverbed longitudinal direction base slope.
3 are the results are shown in Table according to what formula (2) calculated.Particle is considered with the shape of sphere in formula (2).The present invention considers Mutually under the conditions of equal appearance grain size, shape uses ellipse, because the granular material of ellipse is opposite small by flow action area, It is difficult compared with the mutually equal sphere for holding grain size that it is started, and therefore, the impact resilience of embankment material of the invention should be better than the calculating in table 3 As a result.In view of the actual needs of middle and lower reach of Yangtze River bank-protection works, underwater embankment material individual of the invention holds grain size according to grade 0.2m (V=4.2 × 10-3m3;M=10kg it) is designed, bank protection combination stone pad waterborne carries out, and embankment material individual holds according to grade Grain size 0.1m (V=5.2 × 10-4m3;M=1.3kg it) is designed, shape is oval-shaped ball, is conducive to increase it in this way Impact resilience.Fig. 2 is etc. to hold the individual shapes cases of design that grain size is 0.2m, 0.1m, as shown in the figure, the long axis of oval ball is a, Short axle is b, a=0.2m, b=0.1m.
The initial velocity U of bulk solid particle under the conditions of the different bank slopes of table 3c(m/s)
Note:The condition of initial velocity in table, depth of water 20.0m, there are φ=0, λ=0 for aspergillus ficuum;γs=2.4 × 103kg/m3
4th, the manufacture craft of ecological revetment material
Manufacture craft is divided into following 3 steps:
(1) it prepares
Concrete weighs various raw material by proportioning in table, pours into concrete mixer and water stirring is added (or manually to mix System), mixing is poured out after the stipulated time, detection concrete mixture characteristic (parameters such as slump and air content);
(2) it is die-filling
Mold design is shown in Fig. 3, and mold is the platypelloid type cylinder 1 that there is oval ball empty slot 2 at a middle part.Mixture is poured into In mold, vibrated with vibrator, vibration compacting;
(3) it conserves
Scheme 1:Form removal after test specimen is stood for 24 hours after being molded is put into temperature as 20 ± 2 DEG C, more than 95% relative humidity Standard curing room conserves 28 days, and concrete crushing strength can reach configuration intensity 26.6MPa;
Scheme 2:It is covered in a natural environment with wet gunnysack, watering conserves, holding moisture state, while under the same conditions Formation of concrete cube specimen, after curing age 28d, using SL352-2006《Concrete for hydraulic structure testing regulations》Experiment side The compressive strength of concrete of maintenance is accompanied in method test, which, which reaches configuration intensity 26.6MPa, can stop conserving;If Intensity is not up to configured in compressive strength of concrete, then continues maintenance until configuration intensity is reached.
The present invention has the following advantages:
(1) present invention makes full use of the raw material of natural river course to make to form embankment material, is conducive to energy conservation and environmental protection.
(2) embankment material of the invention can adjust size and shape according to actual needs, to meet different flow conditions Protection with bank slope boundary condition needs.
(3) because the embankment material of the present invention for bulk solid or forms isostere, after carrying out bank slope protection, there is preferable riverbed Adaptability is deformed, and the gap between protection body is conducive to improve the microhabitat of aquatile.
(4) embankment material of the invention is adaptable to dredging waterway and the bank slope protection in large, medium and small river, it can also be used to Other kinds of bank slope protection.
The foregoing is merely the detailed descriptions of specific embodiments of the present invention, do not limit the present invention with this, all at this All any modification, equivalent and improvement made in the mentality of designing of invention etc., should be included in protection scope of the present invention it It is interior.

Claims (1)

1. a kind of production method of ecological revetment material, it is characterised in that:The production method of the embankment material is:According to raw material Proportioning weighs mass fraction as 129 ~ 133 parts of water, 206 ~ 213 parts of cement, 52 ~ 53 parts of flyash, 647 ~ 653 parts of sand, 1330 ~ 1342 parts of stones, 2.06 ~ 2.13 parts of water-reducing agents and 0.015 ~ 0.016 part of air entraining agent;Mixing stirs, and it is mixed to pour out detection after a certain period of time The performance of solidifying soil mixture, ensures slump value in the range of 40mm ~ 60mm, air content is pressed in the range of 4% ~ 4.5%;By mix Object is poured into mold, is vibrated with vibrator, vibration compacting;Form removal after test specimen is stood for 24 hours after being molded, is put into standard curing room and supports It protects 28 days or watering conserves in a natural environment;
The cement is meets GB 200-2003 moderate-heat portland cements, low-heat portland cement, low heat portland blast-furnace-slag cement Technology requirement 42.5 moderate heat cements or meet GB 175-2007 common portland cements technology requirement 42.5 in light water Mud;
The flyash is to meet the I grade flyash that DL/T 5055-2007 concrete for hydraulic structure mixes flyash technical specification;
The sand be meet DL/T 5151-2001 concrete for hydraulic structure sandstone aggregate testing regulations technology requirement artificial rubble or Coarse sand;Stone uses graduation two aggregate, i.e., the middle stone that grain size is the gravelstone of 5 ~ 20mm, grain size is 20 ~ 40mm;Two kinds of aggregate ratios by Coarse aggregate combination stage chooses the grading ratio that tapped bulk density is maximum, porosity is minimum with experiment;
The water-reducing agent and air entraining agent be meet GB 8076-2008 concrete admixtures technology requirement high-performance water reducing agent and Air entraining agent;
The size of the embankment material is derived by the initial velocity calculation formula of bulk solid on slope, and following formula is on slope The initial velocity calculation formula of bulk solid, for embankment material, it is necessary to which the stability for meeting individual or cell cube will with anti-impact It asks, the grain size of bulk solid particle is confirmed by the formula;
In formula:,For thrust and the coefficient of uplift force,The respectively corresponding area of gravity, uplift force, sliding force Coefficient,Respectively shore protection individual material and the severe of water;The respectively depth of water and the grain size of bulk solid particle;To refer to Index in number velocity formula;The coefficient of bed surface sand grain height is acted on for underflow speed;For river longitudinal direction base slope slope Angle;For acceleration of gravity;For riverbank slope angle, ifFor critical slope, then tan=For torque coefficient;For silt The grain direction of motion and the angle of downslide force direction;
Consider under the conditions of mutually equal appearance grain size, for shape using ellipse, the embankment material is flat sphere, specially long Semiaxis is 0.1 ~ 0.3m, and semi-minor axis is 0.05 ~ 0.15m, and thickness is the oval ball of 0.05 ~ 0.15m.
CN201510442191.1A 2015-07-24 2015-07-24 A kind of production method of ecological revetment material Active CN105130293B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510442191.1A CN105130293B (en) 2015-07-24 2015-07-24 A kind of production method of ecological revetment material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510442191.1A CN105130293B (en) 2015-07-24 2015-07-24 A kind of production method of ecological revetment material

Publications (2)

Publication Number Publication Date
CN105130293A CN105130293A (en) 2015-12-09
CN105130293B true CN105130293B (en) 2018-07-03

Family

ID=54715942

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510442191.1A Active CN105130293B (en) 2015-07-24 2015-07-24 A kind of production method of ecological revetment material

Country Status (1)

Country Link
CN (1) CN105130293B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105819772A (en) * 2016-03-07 2016-08-03 华北水利水电大学 Grid bank concrete mechanical performance test method
CN111592286B (en) * 2020-05-18 2022-03-08 杭州元成规划设计集团有限公司 Ecological bank protection material with good biocompatibility
CN112250381B (en) * 2020-10-12 2022-06-24 中国三峡建设管理有限公司 High-strength high-crack-resistance abrasion-resistant concrete and preparation method thereof
CN114988794B (en) * 2022-05-23 2023-05-05 长江水利委员会长江科学院 High-strength ecological concrete for river and lake ecological bank protection and preparation method of test block

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102409638B (en) * 2011-09-02 2013-08-21 水利部交通运输部国家能源局南京水利科学研究院 Low water resistance anchoring piece
CN104088253B (en) * 2014-06-23 2016-08-24 桐乡市禾源水泥制品有限公司 Eco-concrete four even ball and production method thereof
CN104402352A (en) * 2014-10-23 2015-03-11 长江水利委员会长江科学院 Four-graded roller compacted concrete suitable for water power hydraulic engineering and preparation method thereof

Also Published As

Publication number Publication date
CN105130293A (en) 2015-12-09

Similar Documents

Publication Publication Date Title
Akroyd Concrete: properties and manufacture
CN101922236B (en) C50 machine-made sand ultra-high pump concrete construction method
Lo et al. Comparison of workability and mechanical properties of self-compacting lightweight concrete and normal self-compacting concrete
CN105130293B (en) A kind of production method of ecological revetment material
CN103159448A (en) Preparation method for artificial fish reef concrete material with slag as main raw material
CN108821687B (en) Hydraulic impact-resistant and wear-resistant concrete using high-density tailings as aggregate and preparation method thereof
CN102351477B (en) Mixture for preparing C55 high-intensity ultra-high-pumping concrete
CN108439907A (en) A kind of preparation process of cement base dregs concrete
Hoque et al. Influence of stone dust as partially replacing material of cement and sand on some mechanical properties of mortar
Li et al. Effect of a novel spherical tailings aggregate on the macro-and mesoscopic properties of pervious concrete
Subbulakshmi et al. Mechanical properties of high performance concrete in corporating with quarry wastes
CN108996963B (en) concrete pavement brick and preparation method thereof
Lin et al. Study on site construction technology of four-graded RCC
CN111484288A (en) Formula and preparation method of hydraulic ecological interlocking slope protection brick
Ravindrarajah High-strength self-compacting concrete for sustainable construction
Zhang et al. Artificial rockfill placement optimization in rock-filled concrete with massive solid waste
Courard et al. New developments in the recycling of Construction and Demolition Wastes for the concrete industry
Bian et al. Lightweight Aggregate Shotcrete: Part 1
Tan et al. Compression and Splitting Tensile Strength Model of Recycled Seawater and Sea Sand Concrete after Seawater Freeze–Thaw Cycles
KR20030080270A (en) concrete in contained copper slag
Wang et al. Mechanical properties of reactive powder concrete containing fly ash under different curing regimes
CN110117181B (en) Low-cost green artificial fish reef concrete material and preparation method thereof
Bakhrakh et al. High-performance self-compacting concrete with the use of coal burning waste
JP7401962B2 (en) Soil materials, soil material manufacturing methods, and ground preparation methods
Shukla et al. Effect of fines in sandstones manufactured sand concrete

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant