CN105128456A - High vacuum barrier film - Google Patents

High vacuum barrier film Download PDF

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Publication number
CN105128456A
CN105128456A CN201510538076.4A CN201510538076A CN105128456A CN 105128456 A CN105128456 A CN 105128456A CN 201510538076 A CN201510538076 A CN 201510538076A CN 105128456 A CN105128456 A CN 105128456A
Authority
CN
China
Prior art keywords
layer
barrier layer
obstruct membrane
high vacuum
barrier film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510538076.4A
Other languages
Chinese (zh)
Inventor
张桂萍
张海军
刘文亮
丁军良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI BETTER NEW MATERIALS TECHNOLOGY CO LTD
Original Assignee
ANHUI BETTER NEW MATERIALS TECHNOLOGY CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI BETTER NEW MATERIALS TECHNOLOGY CO LTD filed Critical ANHUI BETTER NEW MATERIALS TECHNOLOGY CO LTD
Priority to CN201510538076.4A priority Critical patent/CN105128456A/en
Publication of CN105128456A publication Critical patent/CN105128456A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/02Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/088Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/712Weather resistant

Abstract

The invention relates to the technical field of vacuum heat insulating plate manufacturing, and particularly relates to a high vacuum barrier film. The barrier film sequentially comprises a glass fiber cloth layer, a barrier layer, an aluminum foil layer, a nylon layer and a polyethylene layer from outside to inside; the barrier layer adopts the barrier layer added with carbon nano materials. According to the high vacuum barrier film, the barrier layer with the carbon nano materials are additionally arranged, the tensile strength, the puncture strength and the barrier property of the barrier film are improved, higher vacuum degree can be borne by the barrier film, the weather resistance is improved, and the service life of the barrier film is greatly prolonged.

Description

A kind of high vacuum Obstruct membrane
Technical field
The present invention relates to vacuum heat-insulating plate manufacturing technology field, particularly a kind of high vacuum Obstruct membrane.
Background technology
Vacuum heat-insulating plate (VacuumInsulationPanel, be called for short VIP) be a kind of Novel super insulation material, its thermal conductivity factor is less than 0.004wmk, be only 1/ (16 ~ 18) of polyurethane rigid foam plastic, there is outstanding insulation capacity, also have joint space-efficient feature simultaneously.At present, VIP plate has started to be applied to the adiabatic fields of insulation such as the household appliances such as refrigerator, refrigerator, electric heater and medical, cold chain, building, and energy-saving effect is obvious.VIP plate is loaded in barrier by core good for heat-proof quality, seals the sheet material of formation after vacuumizing again.Barrier is bag shaped structure, and effect is encapsulated formation vacuum state after being vacuumized by core, therefore requires that this structure has the ability of good obstruct gas, also will have certain intensity to protect vacuum chamber simultaneously.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, a kind of high vacuum Obstruct membrane is provided, the barrier layer being added with carbon nanomaterial is provided with in this Obstruct membrane, this barrier layer can improve Obstruct membrane tensile strength, pierce through slight and barrier, Obstruct membrane is enable to tolerate higher vacuum, and improve resistance to thick property, substantially prolongs the service life of Obstruct membrane.
For solving the problem, the invention provides following technical scheme:
A kind of high vacuum Obstruct membrane, this Obstruct membrane comprises fiberglass cloth, barrier layer, aluminium foil layer, nylon layer and polyethylene layer from outside to inside successively; Described barrier layer is the barrier layer being added with carbon nanomaterial.
Further, in described barrier layer, the mass ratio of carbon nanomaterial is 20% ~ 35%.
Further, in described barrier layer, the mass ratio of carbon nanomaterial is 20%.
Further, in described barrier layer, the mass ratio of carbon nanomaterial is 35%.
Further, the thickness of described barrier layer is 0.05mm ~ 0.1mm.
Further, the thickness of described Obstruct membrane is 0.05mm.
Further, the thickness of Obstruct membrane is 0.1mm.
Further, described barrier layer is PET film layer or KPET thin layer.
Further, described polyethylene layer is linear low density polyethylene layer.
Further, the specification of described glass fabric is 125-140g/ ㎡.
Beneficial effect: a kind of high vacuum Obstruct membrane of the present invention, by arranging the barrier layer being added with carbon nanomaterial in Obstruct membrane, improve the tensile strength of Obstruct membrane, pierce through slight and barrier, Obstruct membrane is enable to tolerate higher vacuum, and improve resistance to thick property, substantially prolongs the service life of Obstruct membrane.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention;
Description of reference numerals: fiberglass cloth 1, barrier layer 2, aluminium foil layer 3, nylon layer 4, polyethylene layer 5.
Detailed description of the invention
Below in conjunction with Figure of description and embodiment, specific embodiments of the invention are described in further detail:
Specific embodiment one:
With reference to a kind of high vacuum Obstruct membrane shown in Fig. 1, this Obstruct membrane comprises fiberglass cloth 1, barrier layer 2, aluminium foil layer 3, nylon layer 4 and polyethylene layer 5 from outside to inside successively; Described barrier layer 2 is for being added with the barrier layer of carbon nanomaterial.
In described barrier layer 2, the mass ratio of carbon nanomaterial is 20% ~ 35%.
In described barrier layer 2, the mass ratio of carbon nanomaterial is 20%.
The thickness of described barrier layer 2 is 0.05mm ~ 0.1mm.
The thickness of described Obstruct membrane is 0.05mm.
Described barrier layer 2 is PET film layer or KPET thin layer.
Described polyethylene layer 5 is linear low density polyethylene layer 5.
The specification of described glass fabric is 125-140g/ ㎡.
Specific embodiment two:
With reference to a kind of high vacuum Obstruct membrane shown in Fig. 1, this Obstruct membrane comprises fiberglass cloth 1, barrier layer 2, aluminium foil layer 3, nylon layer 4 and polyethylene layer 5 from outside to inside successively; Described barrier layer 2 is for being added with the barrier layer of carbon nanomaterial.
In described barrier layer 2, the mass ratio of carbon nanomaterial is 20% ~ 35%.
In described barrier layer 2, the mass ratio of carbon nanomaterial is 20%.
The thickness of described barrier layer 2 is 0.05mm ~ 0.1mm.
The thickness of described Obstruct membrane is 0.1mm.
Described barrier layer 2 is PET film layer or KPET thin layer.
Described polyethylene layer 5 is linear low density polyethylene layer 5.
The specification of described glass fabric is 125-140g/ ㎡.
Specific embodiment three:
With reference to a kind of high vacuum Obstruct membrane shown in Fig. 1, this Obstruct membrane comprises fiberglass cloth 1, barrier layer 2, aluminium foil layer 3, nylon layer 4 and polyethylene layer 5 from outside to inside successively; Described barrier layer 2 is for being added with the barrier layer of carbon nanomaterial.
In described barrier layer 2, the mass ratio of carbon nanomaterial is 20% ~ 35%.
In described barrier layer 2, the mass ratio of carbon nanomaterial is 35%.
The thickness of described barrier layer 2 is 0.05mm ~ 0.1mm.
The thickness of described Obstruct membrane is 0.05mm.
Described barrier layer 2 is PET film layer or KPET thin layer.
Described polyethylene layer 5 is linear low density polyethylene layer 5.
The specification of described glass fabric is 125-140g/ ㎡.
Specific embodiment four:
With reference to a kind of high vacuum Obstruct membrane shown in Fig. 1, this Obstruct membrane comprises fiberglass cloth 1, barrier layer 2, aluminium foil layer 3, nylon layer 4 and polyethylene layer 5 from outside to inside successively; Described barrier layer 2 is for being added with the barrier layer of carbon nanomaterial.
In described barrier layer 2, the mass ratio of carbon nanomaterial is 20% ~ 35%.
In described barrier layer 2, the mass ratio of carbon nanomaterial is 35%.
The thickness of described barrier layer 2 is 0.05mm ~ 0.1mm.
The thickness of described Obstruct membrane is 0.1mm.
Described barrier layer 2 is PET film layer or KPET thin layer.
Described polyethylene layer 5 is linear low density polyethylene layer 5.
The specification of described glass fabric is 125-140g/ ㎡.
It should be noted that, the barrier layer 2 of carbon nanomaterial improves the tensile strength of Obstruct membrane, pierces through slight and barrier, enables Obstruct membrane tolerate higher vacuum, and improves resistance to thick property, substantially prolongs the service life of Obstruct membrane.
The above, it is only preferred embodiment of the present invention, not any restriction is made to technical scope of the present invention, thus every above embodiment is done according to technical spirit of the present invention any trickle amendment, equivalent variations and modification, all still belong in the scope of technical scheme of the present invention.

Claims (10)

1. a high vacuum Obstruct membrane, is characterized in that: this Obstruct membrane comprises fiberglass cloth (1), barrier layer (2), aluminium foil layer (3), nylon layer (4) and polyethylene layer (5) from outside to inside successively; Described barrier layer (2) is for being added with the barrier layer of carbon nanomaterial.
2. a kind of high vacuum Obstruct membrane according to claim 1, is characterized in that: in described barrier layer (2), the mass ratio of carbon nanomaterial is 20% ~ 35%.
3. a kind of high vacuum Obstruct membrane according to claim 2, is characterized in that: in described barrier layer (2), the mass ratio of carbon nanomaterial is 20%.
4. a kind of high vacuum Obstruct membrane according to claim 2, is characterized in that: in described barrier layer (2), the mass ratio of carbon nanomaterial is 35%.
5. a kind of high vacuum Obstruct membrane according to claim 1, is characterized in that: the thickness of described barrier layer (2) is 0.05mm ~ 0.1mm.
6. a kind of high vacuum Obstruct membrane according to claim 5, is characterized in that: the thickness of described Obstruct membrane is 0.05mm.
7. a kind of high vacuum Obstruct membrane according to claim 5, is characterized in that: the thickness of described Obstruct membrane is 0.1mm.
8. a kind of high vacuum Obstruct membrane according to claim 1, is characterized in that: described barrier layer (2) is PET film layer or KPET thin layer.
9. a kind of high vacuum Obstruct membrane according to claim 1, is characterized in that: described polyethylene layer (5) is linear low density polyethylene layer (5).
10. a kind of high vacuum Obstruct membrane according to claim 1, is characterized in that: the specification of described glass fabric is 125-140g/ ㎡.
CN201510538076.4A 2015-08-28 2015-08-28 High vacuum barrier film Pending CN105128456A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510538076.4A CN105128456A (en) 2015-08-28 2015-08-28 High vacuum barrier film

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Application Number Priority Date Filing Date Title
CN201510538076.4A CN105128456A (en) 2015-08-28 2015-08-28 High vacuum barrier film

Publications (1)

Publication Number Publication Date
CN105128456A true CN105128456A (en) 2015-12-09

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202448411U (en) * 2012-02-16 2012-09-26 昆山蓝胜建材有限公司 Novel high-separation vacuum film
CN102936352A (en) * 2012-11-21 2013-02-20 光明乳业股份有限公司 Reinforced barrier film and preparation method thereof
CN203210787U (en) * 2013-02-26 2013-09-25 昆山蓝胜建材有限公司 High-barrier membrane for vacuum insulated panel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202448411U (en) * 2012-02-16 2012-09-26 昆山蓝胜建材有限公司 Novel high-separation vacuum film
CN102936352A (en) * 2012-11-21 2013-02-20 光明乳业股份有限公司 Reinforced barrier film and preparation method thereof
CN203210787U (en) * 2013-02-26 2013-09-25 昆山蓝胜建材有限公司 High-barrier membrane for vacuum insulated panel

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Application publication date: 20151209