CN1051128A - Preparing method of emulsion and implement device thereof - Google Patents

Preparing method of emulsion and implement device thereof Download PDF

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Publication number
CN1051128A
CN1051128A CN89108138A CN89108138A CN1051128A CN 1051128 A CN1051128 A CN 1051128A CN 89108138 A CN89108138 A CN 89108138A CN 89108138 A CN89108138 A CN 89108138A CN 1051128 A CN1051128 A CN 1051128A
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China
Prior art keywords
steam
liquid component
emulsion
liquid
chamber
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CN89108138A
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Inventor
夫拉迪米尔·夫拉迪米罗维奇·费森科
朱里·帕夫洛维奇·斯卡库诺夫
夫拉迪米尔·吉沃吉维奇·鲁尼夫
瓦迪姆·埃费莫维奇·福克斯
朱里·阿纳托利维奇·阿夫克森蒂夫
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INZHENERNY TSENTR" TRANSZVUK "
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INZHENERNY TSENTR" TRANSZVUK "
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Publication of CN1051128A publication Critical patent/CN1051128A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30Injector mixers
    • B01F25/31Injector mixers in conduits or tubes through which the main component flows
    • B01F25/312Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof
    • B01F25/3122Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof the material flowing at a supersonic velocity thereby creating shock waves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30Injector mixers
    • B01F25/31Injector mixers in conduits or tubes through which the main component flows
    • B01F25/312Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof
    • B01F25/3124Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof characterised by the place of introduction of the main flow
    • B01F25/31242Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof characterised by the place of introduction of the main flow the main flow being injected in the central area of the venturi, creating an aspiration in the circumferential part of the conduit

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Colloid Chemistry (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

A kind of method for preparing emulsion is: feed steam with the speed of 500~800 meter per seconds, send in the steam with the liquid component that injection method will emulsification, with supersonic speed conveying two-phase vapour-liquid mixture.
A kind of device for preparing emulsion comprises cylindrical housings (1), aerosol chamber (2), steam jet (4), hybrid chamber (9); Steam jet (4) makes the Laval nozzle pattern, can move axially and between steam jet (4) cross section and aerosol chamber (2) inner surface, form injection region (5), hybrid chamber (9) have towards the Laval nozzle direction dwindle gradually the part (10), it changes cylindrical part (11) into, is thereafter diffusion part (12).

Description

Preparing method of emulsion and implement device thereof
The invention belongs to technical process and its implementation of emulsification and dispersion, specifically, belong to emulsion preparation method and implement device thereof.
The present invention can be used to prepare the liquid substitute of milk in food industry, also can be used to prepare stable water-fuel and water-oil emulsion in fuel-power industry and machine building industry.
Known a kind of method (Russian Patent, 701678) for preparing emulsion, it is that the various liquid components of skim are injected the center that the revolution of ionized gas supersonic speed is flowed along axis of rotation.Because various liquid components are forms with thin layer, be injected into the aerosol chamber under the unsure state assembling, so they are disperseed fast by air-flow.When air-flow turned round, the particle of various liquid components produced and mixes, and these particles are charged by the ionized particles of gas.The gas volume flow of this method surpasses tens times of liquid component flows.
The characteristics of said method are, the flow of liquid component depends on the vacuum of revolution air-flow core, and vacuum itself is decided by the speed of gyration of air-flow.Can cause the gas speed of gyration to change because add liquid component, so the vacuum variation, this concentration that just means liquid component will change.This can make emulsion debase.
The degree of in the method, disperseing, thereby also be the quality of emulsion, it depends on gas motion speed.But, in order to guarantee gas enough speed is arranged, the essential lot of energy that consumes, this also is the shortcoming of this method.
In addition, the gas flow of described method surpasses tens times of emulsion liquid component flows, and this just makes only could realize this method under the very little situation of the flow of emulsion finished product.Otherwise need a large amount of gases.This also causes economic benefit to reduce, and energy resource consumption increases and realizes that the device volume of the method increases.
Known a kind of fluid dynamic emulsifier (Russian Patent, A, 896263), it comprises a housing, has to carry emulsified and pipe lazy attitude liquid component a nozzle initiatively on it, hybrid chamber, and two fluid rotary devices and a pump with shaft sealer cooling chamber.The operation principle of fluid dynamic emulsifier is to form two bursts of component stream with different revolution degree in emulsifier, and in hybrid chamber, under certain angle these components are linked up, the formation emulsifying mixt.In the vortex that forms in the sealing device cooling chamber when axle is reciprocating, emulsion further disperses.
Known fluid dynamic emulsifier has following shortcoming: the of low quality and complex structure of emulsion.Emulsion reason of low quality is that the effect (phase shift during eddy motion) that makes emulsified component disperse weakens along with the motion of rotation logistics longshore current body power emulsifier runner.In addition, when axle was reciprocating, the strength of vortex that forms in the sealing device cooling chamber was little, and this also makes dispersion process worsen.Use known fluid dynamic emulsifier also will adopt two measuring pumps of carrying the emulsion liquid component, this makes its structure become complicated.
That knows at present also has a kind of method and implement device (Russian Patent, A, 812326) thereof that obtains watery emulsion.Method is such, and liquid component and vapor mixing that will emulsification add lazy attitude liquid component then, forms two-phase vapour-liquid mixture, makes the vapour phase condensation then and forms emulsion.The device of realizing this method comprises a cylindrical housings, dispose aerosol chamber and hybrid chamber in it, and in the aerosol chamber, have steam jet and supply to want the liquid component of emulsification and the pipe of steam, and the pipe of supplying lazy attitude liquid component is connected with hybrid chamber.
The method of the watery emulsion of described acquisition and implement device thereof can guarantee that the milk ejection component particle is of a size of about 50 microns.This emulsion quality is low, and its degree of scatter is low, and unstable.Liquid component that must use other pump to extract to want emulsification and lazy attitude liquid component make known method and implement device thereof become complicated, and cause additional energy consumption.
The shortcoming of known method also is, in order to obtain the satisfied emulsion of quality, the essential high steam (4~6kgf/cm that adopts 2).This causes emulsion unnecessary overheated, thereby causes additional energy consumption.In addition, the concentration of the emulsion stream that flows out from known devices is only reliable adopt special-purpose, carry and want the liquid component of emulsification and the measuring pump of lazy attitude liquid component could guarantee to immobilize, this also makes the method and device for carrying out said thereof complicated.
Basic task of the present invention is to create a kind of method and device for carrying out said thereof for preparing emulsion, and they rely on the corresponding proportion relation of setting up steam and two-phase vapour-liquid media flow speed to guarantee preparation emulsion stable, high dispersive.
Being proposed of task is to solve like this, and the method for preparing emulsion is to add the liquid component of wanting emulsification, and it is put into steam, adds lazy attitude liquid component and forms two-phase vapour-liquid mixture, and then the vapour phase condensation forms emulsion; According to the present invention, the transporting velocity of steam is 500~800 meter per seconds, the liquid component of emulsification to send in the steam by method for implanting, and two-phase vapour-liquid mixture is carried with supersonic speed, and the size of transporting velocity is different for different component mixtures.
The device of realizing this method comprises a cylindrical housings, it has an aerosol chamber, in the chamber, dispose steam jet coaxially, carry the pipe of the liquid component of wanting emulsification to link to each other with this chamber, device also comprises one with the hybrid chamber of aerosol chamber arranged coaxial and carry the pipe of lazy attitude liquid component, and this pipe is fixed on the cylindrical housings; According to the present invention, steam jet makes the Laval nozzle pattern, can move axially, and between steam jet cross section and aerosol inner cavity surface, form the injection region, and hybrid chamber can move axially, it has a constriction gradually towards the Laval nozzle direction, and this part is converted into column part again, and its back then is a diffusion part.
The aerosol chamber delivery outlet diameter and the diameter of hybrid chamber cylindrical part are compared in 1~2 scope.
Like this, adopt described method for preparing emulsion and implement device thereof can obtain high degree of dispersion (emulsified liquid component particle is of a size of about 0.5~3 micron), stable and the uniform emulsion of concentration.When the device outlet pressure changes, realize that the ultrasonic flow of two-phase vapour-liquid stream can be so that concentration of emulsion used be invariable.Adopt said method can lower the energy resource consumption for preparing emulsion, can also reduce the metal consumption of the device of realizing the method.
Below use concrete examples of implementation, and quote accompanying drawing the present invention is described, represent in the accompanying drawings always to scheme according to the cross section of the device of preparation emulsion of the present invention.
We investigate preparation method of emulsion: it be will emulsification liquid component inject steam, steam is sent into the speed of 500~800 meter per seconds, at this moment form aerosol, lazy attitude liquid component is added in the aerosol, and carry formed two-phase vapour-liquid mixture with supersonic speed, vary in size for various component mixture supersonic speed.Carrying with above-mentioned supersonic speed in the process of two-phase vapour-liquid mixture, under the situation of pressure transonic speed sudden change, the vapour phase condensation forms the stable emulsion of concentration of component simultaneously.When vapor (steam) velocity during less than 500 meter per seconds, utilize the emulsion quality of described method preparation low, this is because emulsified liquid component degree of scatter causes inadequately, can cause the volume content of steam in the two-phase vapour-liquid mixture to increase and increase vapor (steam) velocity greater than 800 meter per seconds, its consequence is, two-phase vapour-liquid mixture can not be made supersonic speed and flow, and this also has adverse effect to resulting emulsion quality.
Now investigate preparation method of emulsion with the example of the liquid substitute for preparing pure milk.Take off the liquid component that emulsification is wanted in the conduct of row mixture: bone ester molten mass, oil base vitamin A 1With And corresponding proportion is 20: 0.006: 3.7 a phosphide concentrate.Formed mixture is heated to 55~60 ℃, and mixture is injected water vapour, the supply pressure of water vapour is 1.5kgf/cm 2, speed is 600 meter per seconds, simultaneously under 30 ℃ of temperature, the lazy attitude liquid component of liquid skimmed milk form is added in the formed aerosol.Formed two-phase vapour-liquid mixture is carried with the speed of 300 meter per seconds, and sonic propagation speed is in 10~15 meter per second scopes in this mixture, and promptly formed mixture has supersonic speed.The condensation of vapor phase is to realize under the situation of pressure transonic speed sudden change, and this sudden change turns to pure milk-based liq substitute emulsion with the circulation of two-phase vapour-liquid, and to flow its emulsified liquid component particle size be 0.5~3 micron.The oil content of resulting pure cows milk substitute equals 2%.The concentration of component of the pure milk-based liq substitute that is obtained is invariable.
Like this, said method can obtain high degree of dispersion, uniformly and concentration of component invariable emulsion.
The device of realizing preparation emulsion method comprises a cylindrical housings 1, and aerosol chamber 2 of configuration in it carries the pipe 3 of the liquid component of wanting emulsification to be connected with it.In aerosol chamber 2, dispose a steam jet 4 that makes the Laval nozzle form coaxially, steam jet 4 can be by being threaded, relatively aerosol chamber 2 moves axially, like this can be between the inner surface in the cross section of steam jet 4 and aerosol chamber 2 injection region 5 of wanting the liquid component of emulsification of formation.Steam is sent in the steam jet 4 along pipeline 6.Carry the pipe 8 of lazy attitude liquid component to be connected with the inner chamber 7 of cylindrical housings 1.In housing 1, be coaxially installed with hybrid chamber 9 with aerosol chamber 2, it can move axially by the relative housing 1 that is threaded, and comprise that one is dwindled part 10 gradually towards steam jet 4 directions, be positioned at thereafter cylindrical part 11 and diffusion part 12, and the diameter ratio of the cylindrical part 11 of the diameter of aerosol chamber 2 delivery outlets 13 and hybrid chamber 9 is in 1~2 scope.At the pipe 6 of delivering vapor with carry correspondingly to be equipped with on the pipe 3 and 8 of the liquid component of wanting emulsification and lazy attitude liquid component and end-adjusting valve member 14,15,16.
Realize that the device of described method works in the following manner.Steam is by ending-regulate valve member 14, send in the steam jet 4 along pipeline 6, because steam jet 4 makes the Laval nozzle pattern, thereby guaranteed that steam makes ultrasonic flow with the speed of 500~800 meter per seconds, because the ultrasonic flow of steam, on the cross section of steam jet 4, produce vacuum, guarantee through by-regulate the injection region 5 that the liquid component of wanting emulsification that valve member 15 sends into along the pipe 3 of carrying the liquid component of wanting emulsification can inject aerosol chamber 2.At this moment want the liquid component of emulsification to disperse, form the aerosol that constitutes by steam and the particle of wanting the liquid component of emulsification simultaneously.The size that moves axially the injection region 5 that can regulate the liquid component of wanting emulsification of steam jet 4, thereby can regulate the flow of these components.Lazy attitude liquid component is sent into the inner chamber 7 of cylindrical housings 1 by ending-regulate valve member 16 along the pipe 8 of carrying lazy attitude liquid component, form two-phase vapour-liquid mixture, these mixtures are carried with supersonic speed, and ultrasonic size is different for different component mixtures.In the cylindrical part 11 of hybrid chamber 9, the sudden change of pressure generation transonic speed wants the particle of the liquid component of emulsification to spread out in this zone, and this pressure jump turns to subsonic single-phase emulsifying liquid liquid stream with ultrasonic two-phase vapour-liquid circulation.For the flow that changes lazy attitude liquid component must move axially hybrid chamber 9.
5 produce the following physical process that makes the liquid component dispersion of wanting emulsification in the injection region.When liquid was spurted into the vacuum space, liquid dispersion was many fine particles.When adopting said method on the device of stating preparation emulsion method in realization, the vacuum space is in injection region 5, relies on steam to give birth to the velocity flow movable property of 500~800 meter per seconds.When the liquid component of wanting emulsification was injected into the vacuum space that is produced, these components promptly spread out.In addition, thin layer liquid flows in the high velocity air and can cause liquid to be in metastable condition, and liquid is crushed into many fine particles, promptly causes liquid dispersion and forms aerosol.
Effect has the power of surging on the motion drop that supersonic speed flows, and these power make the breakup of drop.
In addition because the mechanical disturbance (pressure variation) that comes from the back reading field can not the reverse hypersonic flow that passes, therefore the supersonic speed of the steam state that flows can guarantee the stable and aerocolloidal speed of vacuum of injection region 5, thereby guarantees emulsified liquid component stability of flow.Like this, the supersonic speed of the steam state that flows has guaranteed the raising of emulsion quality by the additional dispersion of the liquid component drop of wanting emulsification, and has guaranteed the stable of these composition flow rate.Because velocity of sound is about 500 meter per seconds in steam, so in order to obtain above-mentioned emulsion quality, the transporting velocity of steam should be not less than 500 meter per seconds.
Increase vapor (steam) velocity and greater than 800 meter per seconds the volume content of steam in the two-phase vapour-liquid mixture is increased, and increase the pressure in the inner chamber 7, the result causes preparing the device job insecurity of emulsion.
When lazy attitude liquid component is sent into the inner chamber 7 of cylindrical housings 1, lazy attitude liquid component is separated into aerocolloidal supersonic speed and flows, and this is to cause owing to lazy attitude liquid component being sent into the mobile fluid dynamic exercising result to lazy attitude liquid component of vacuum space and aerocolloidal supersonic speed.Because like this, the result has just formed the two-phase vapour-liquid mixture with the diffusing homogeneous texture of differential.In this two-phase vapour-liquid medium, acoustic wave propagation velocity is 10~50 meter per seconds.Because with before lazy attitude liquid component mixes, aerosol speed surpasses 500 meter per seconds, so formed two-phase vapour-liquid mixture moves with supersonic speed.For different component mixtures, the movement velocity difference of this mixture, and by the decision of the parameter of emulsion components: the pressure of steam and speed, aerocolloidal speed, the pressure of lazy attitude liquid component and temperature.In this mixture, steam meeting condensation, its volume content in mixture can reduce, and this can cause two-phase vapour-liquid mixture speed to reduce.In order to keep the ultrasonic flow state of this mixture, in the device of preparation emulsion, considered to make flow constriction by the part 10 that reduces gradually.Secondly, two-phase vapour-liquid mixture transmits along cylindrical part 11, and steam continues condensation herein, because like this, the speed of this mixture lowers, and static pressure increases.This makes two-phase vapour-liquid mixture be in metastable condition, and under the situation of pressure transonic speed sudden change, steam is condensation more and more fiercely.At this moment, two-phase vapour-liquid mixture is converted into the emulsion stream with the subsonic speed motion.Pressure after the sudden change surpasses 9~999 times of the preceding pressure of sudden change, and this causes wanting the liquid component drop aggravation of emulsification to disperse.
Like this, the transonic sudden change of pressure is to be guaranteed to realize by the ultrasonic flow of two-phase vapour-liquid mixture along the cylindrical part 11 of hybrid chamber 9.As previously discussed, the maintenance of two-phase vapour-liquid mixture ultrasonic flow state is to be guaranteed in the flow constriction that reduces part 10 gradually by this mixture, and this end that reduces part gradually is exactly a cylindrical part 11.
Therefore, when the diameter ratio of the cylindrical part 11 of the diameter of the delivery outlet 13 in aerosol chamber 2 and hybrid chamber 9 less than 1 the time, the ultrasonic flow that can not keep two-phase vapour-liquid mixture, this ultrasonic flow are to rely on this mixture to cause in the acceleration that reduces part 10 gradually.But, the double pressure of the inner chamber 7 that can make cylindrical housings 1 of this ratio is increased, and makes the device job insecurity of preparation emulsion.
In addition, the transonic speed sudden change of pressure has guaranteed the additional dispersion of emulsified liquid component, it also can stop the mechanical disturbance of bringing in from the output of preparation emulsion device (pressure oscillation) to be penetrated into the inner chamber 7 of this device, this helps the stable of this cavity pressure, thereby also helps the stable of steam flow and the lazy attitude liquid component of emulsion flow.The stable assurance of above-mentioned flow obtains the invariable emulsion of concentration of component, also can stablize the temperature that obtains emulsion.
Like this, adopt said method and device for carrying out said thereof can obtain in rapid succession uniformly in order to prepare emulsion, high degree of dispersion with stable, and the emulsion of stable composition flow rate is arranged.

Claims (3)

1, a kind of method for preparing emulsion is as follows: add the liquid component of wanting emulsification, these components are put into steam, add lazy attitude liquid component and form two-phase vapour-liquid mixture, then make the vapor phase condensation and form emulsion; The characteristics of this method are: the transporting velocity of steam is 500~800 meter per seconds, adopt the liquid component that injection method will emulsification to send in the steam, carry two-phase vapour-liquid mixture with supersonic speed, simultaneously for various component mixture, transporting velocity varies in size.
2, the device of preparation emulsion comprises a cylindrical housings (1), housing has aerosol chamber (2), wherein disposing a steam jet (4) coaxially, the pipe (3) that adds the liquid component of wanting emulsification is connected with aerosol chamber (2), this device also comprises one with the coaxial hybrid chamber of laying in aerosol chamber (9) be fixed on the cylindrical housings, adds the pipe (8) of lazy attitude liquid component; Apparatus features is: steam jet (4) makes the Laval nozzle pattern and can move axially, a formation injection region (5) between the inner surface of the cross section of steam jet (4) and aerosol chamber (2) simultaneously, hybrid chamber (9) can move axially, it has a diminishing part (10) towards the Laval nozzle direction, this part was converted into cylindrical part (11) afterwards, was a diffusion part (12) thereafter.
3, according to the device of claim 2, it is characterized by: the diameter ratio of the diameter of the delivery outlet (13) of aerosol chamber (2) and the cylindrical part (11) of hybrid chamber (9) is in 1~2 scope.
CN89108138A 1988-04-25 1989-10-24 Preparing method of emulsion and implement device thereof Pending CN1051128A (en)

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PCT/SU1988/000099 WO1989010184A1 (en) 1988-04-25 1988-04-25 Method and device for preparation of emulsions

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JP (1) JPH02504600A (en)
CN (1) CN1051128A (en)
BR (1) BR8807896A (en)
DK (1) DK664389A (en)
FI (1) FI896196A0 (en)
WO (1) WO1989010184A1 (en)

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CN103522118A (en) * 2013-09-26 2014-01-22 上海金兆节能科技有限公司 Nested type three-phase mixing nozzle of water, oil and gas and nozzle system with same
CN107754705A (en) * 2016-08-17 2018-03-06 温州飞龙聚氨酯设备工程有限公司 A kind of pouring head mixed using hydrodynamic ultrasonic wave
CN108472604A (en) * 2015-12-17 2018-08-31 南特大学 Device and method for the continuous emulsification liquid for implementing two kinds of immiscible liquids
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CN102307557A (en) * 2008-12-29 2012-01-04 叶夫根尼·彼得罗维奇·格列比翁尼科夫 Method for producing liposomal drugs and a device for producing a liposome
CN102307557B (en) * 2008-12-29 2014-10-22 叶夫根尼·彼得罗维奇·格列比翁尼科夫 Method for producing liposomal drugs and a device for producing a liposome
CN103522118A (en) * 2013-09-26 2014-01-22 上海金兆节能科技有限公司 Nested type three-phase mixing nozzle of water, oil and gas and nozzle system with same
CN108472604A (en) * 2015-12-17 2018-08-31 南特大学 Device and method for the continuous emulsification liquid for implementing two kinds of immiscible liquids
CN107754705A (en) * 2016-08-17 2018-03-06 温州飞龙聚氨酯设备工程有限公司 A kind of pouring head mixed using hydrodynamic ultrasonic wave
CN108479445A (en) * 2018-04-16 2018-09-04 昆明理工大学 A kind of nano gas colloidal sol generator
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CN115646339A (en) * 2022-12-13 2023-01-31 湖南金石智造科技有限公司 Mixing device for pharmacy and mixing effect detection method thereof

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EP0399041A4 (en) 1991-07-24
WO1989010184A1 (en) 1989-11-02
JPH02504600A (en) 1990-12-27
FI896196A0 (en) 1989-12-21
DK664389A (en) 1990-02-09
DK664389D0 (en) 1989-12-22
BR8807896A (en) 1990-11-20
EP0399041A1 (en) 1990-11-28

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