CN105112096B - Method of applying insulin to coking diesel oil desulfurization - Google Patents
Method of applying insulin to coking diesel oil desulfurization Download PDFInfo
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- CN105112096B CN105112096B CN201510603643.XA CN201510603643A CN105112096B CN 105112096 B CN105112096 B CN 105112096B CN 201510603643 A CN201510603643 A CN 201510603643A CN 105112096 B CN105112096 B CN 105112096B
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Abstract
The invention discloses a method of applying insulin to coking diesel oil desulfurization. The method comprises the following steps: (1) adding medicinal dried hawthorn powder or hawthorn water into coking diesel oil, heating and stirring in a magnetic stirring machine, conducting reaction for 60-100 min, taking out the coking diesel oil, and cooling to the room temperature; (2) adding insulin into the coking diesel oil obtained in the step (1) according to the mass-to-volume ratio of (0.05-1):1, then placing in a thermostatic water bath environment, heating at constant temperature while stirring for 1-24 h; (3) adding a catalyst and an oxidant into the coking diesel oil in sequence, and conducting catalytic oxidation reaction in the magnetic stirring machine for 50-100 min; (4) cooling to the room temperature, adding an extracting agent according to the volume ratio of 1:1, stirring in the magnetic stirring machine for 5-10 min, then pouring the mixture into a separating funnel, leaving the mixture to stand for 20 min, and collecting the diesel oil layer. According to the method, the reaction conditions of desulfurization and refining are mild, environment can be protected, the desulfurization rate is high, the yield of the coking diesel oil is obvious, and the color and smell of the coking diesel oil are light.
Description
Technical field
The present invention relates to coker gas oil desulfurization technology is and in particular to the method for the coker gas oil desulfurization of high desulfurization rate.
Background technology
With the enhancing of people's environmental consciousness, people require increasingly strictly to sulfur content of fuel oil standard, and countries in the world are equal
Formulate more strict new regulation for the sulfur content in fuel oil.U.S.'s regulation diesel oil sulfur content in 2006 is by 500 μ g/g
It is reduced to 15 μ g/g；And Europe had been carried out the Europe v standard of sulfur content 10 μ g/g in 2009；Japan is the advanced of production clean gasoline
Country, performed jisk 2202 gasoline standard specifies, it is 50ppm that Japanese gasoline standard in 2005 limits sulfur content, and in
The national super low-sulfur oil standard that sulfur content is 10ppm of seeking unity of action in 2009.In China, derv fuel and gasoline were in 2005
Implement integrally European quality standard from July 1,2010 all up to standard it is stipulated that the sulfur content in gasoline is less than 150 μ g/g,
Sulfur content in diesel oil is less than 350 μ g/g.Beijing, Shanghai, Guangzhou etc. some one line cities execution the quasi- iv of Europe superscript it is stipulated that gasoline and
Sulfur content in diesel oil is less than 50 μ g/g.And current, up-to-date " state five " standard is by sulfur content index limits by fourth stage
50ppm is reduced to 10ppm, reduces 80%, implements in Beijing and Shanghai at present, and before the end of the year 2017, whole nation supply meets " state
Five " the automobile-used vapour of standard, diesel oil.Therefore, it can be said that domestic vehicle fuel will enter the low-sulfur epoch that sulfur content is less than 50 μ g/g.
In the face of the increasingly strict sulfur content of fuel oil standard and market great demand to low-sulfur clean fuel oil, various countries are caused to cause one after another
Power is in the research of various desulfurization technology.
Deepening continuously with Petroleum Processing Technology, an important deep working method of residual oil is by coking, leads at present
There are autoclave coking and two kinds of delayed coking.Coker gas oil is the product that residual oil obtains through coking.Coker gas oil is at me
Occupy sizable ratio in the finished diesel fuel yield of state, account for the 10% of light diesel fuel yield.Without refined coker gas oil matter
Amount is poor, containing non-hydrocarbon compounds such as substantial amounts of unsaturated hydrocarbons, more sulfur, nitrogen, oxygen, not only black but also smelly, and the stability of diesel oil
Difference, gum level are high, colourity and insolubles content are higher.Substantial amounts of analysis and research show, the sulfur-containing compound in coker gas oil
Mainly there are elementary sulfur, hydrogen sulfide, mercaptan, thioether, thiophene, benzothiophene (bt), dibenzothiophenes (dbt) etc..Wherein, thiophene-based
Sulphur compound accounts for more than the 85% of coker gas oil total sulfur, and bt and dbt accounts for more than the 70% of thiophene-based.Therefore, study thiophene-based
The removing of sulfide becomes the emphasis of desulfurizing oil.Wherein elementary sulfur, hydrogen sulfide, mercaptan isoreactivity sulphur compound, set to oil refining
Have stronger corrosion failure effect.Elementary sulfur is a kind of 113 DEG C of fusing point, the water insoluble and solid that is dissolved in organic solvent,
There is good solvability in gasoline, but when temperature is higher than 115 DEG C, new sulfide and sulfur can be generated with some hydrocarbon reactions
Change hydrogen, hydrogen sulfide is gas that is colourless and having rotten egg abnormal smells from the patient, severe toxicity, slightly it is dissolved in water, is soluble in oil product, have very strong reduction
Ability and corrosive power, the hydrosulphuric acid being formed in water is weak binary acid.Mercaptan includes alkyl hydrosulfide, cycloalkyl mercaptan and aryl
Mercaptan, boiling point and water solublity are lower than the alcohol of same carbon number, are soluble in ethanol and ether.Mercaptan except there being disgusting foul smell,
Or a kind of oxidation inducing agent, makes the unstable component accelerated oxidation in gasoline generate colloid, so that quality of gasoline becomes
Difference.Although the inactive sulfur compound such as thioether and thiophene is relatively low to refining equipment corrosion, corrosion can be generated in combustion
The very strong material of property.The increase stability that the feature of disulphide and polysulfide is as number of sulfur atoms constantly declines, chemistry
Activity is continuously increased.When number of sulfur atoms is more than more than 3, its property and elementary sulfur are close.Heat is easily decomposed to thioether, list
Matter sulfur, mercaptan and alkene.The direct use of these diesel oil, does not only meet China and the sulfur content in fuel oil is specified, and sternly
Heavily contaminated environment, the serious threat mankind's is healthy.Therefore, can use after coker gas oil must refine.
At present, the desulfurization technology of domestic and international fuel oil is broadly divided into hydrodesulfurization technology and non-hydrodesulfurization two is big
Class, hydrodesulfurization technology produces low-sulfur diesel-oil, coker gas oil sulfur, nitrogen and colloid equal size can be greatly lowered, desulfurized effect is good,
The fine-quality diesel oil obtaining meeting national standard is still big due to investing, high processing costs (180 yuan/t), and general in large-scale oil refining
It is used widely in factory, and middle-size and small-size oil plant not only limited fund, moreover, hydrogen source is not enough, limits the method medium and small
The application of type oil plant.Non-hydrodesulfurizationof of Diesel Fuel Refining mainly include adsorb desulfurization, abstraction desulfurization, complexation desulfurization, biological desulphurization,
Oxidation sweetening etc..The fuel oil that traditional acid-alkali refining method is processed is extremely difficult to new low sulphur specifications, moreover technique itself exists
The problems such as pollution, seriously corroded；Because problem in terms of rate of sulphur expulsion and stability for the bioanalysises desulfurization technology does not obtain
Preferably solve, so bioanalysises desulfurization also fails to embody its clear superiority；Catalytic oxidation desulfurization technology is with its operating condition
Gentle production cost is relatively low, is welcome by middle-size and small-size oil plant very much.Therefore, carry out the research of coker gas oil Desulfurization Technology, open
The method sending out new non-hydrodesulfurization a kind of and refining coker gas oil is imperative.
Wherein, oxidation sweetening (ods) technology reaction condition is gentle, process is simple, non-hydrogen operate, operating cost is low, safety
Environmental protection, equipment investment is few, and oil-source rock correlation catalytic hydrogenation being difficult to remove also has higher desulfuration efficiency, can reach
To the requirement of ultra-deep desulfurization, thus oxidizing process is referred to as green desulfurization technique geared to the 21st century, become in recent years one new
Study hotspot.Oxidation sweetening refers under strong oxidizer acts on, the relatively low thioether of polarity and thiophene-based sulfur-bearing chemical combination in oil product
Thing is oxidized to the higher sulfoxide of polarity and sulfone compound, and these sulfide absorb oxygen atom and increased dipole moment, thus increasing
Add the dissolubility in polar solvent, then be removed by solvent extraction, to reach desulfurization purpose.At present, selectivity oxygen
Change desulfurization technology gentle with its process conditions, the features such as desulfurized effect is obvious, receive the very big concern of oil refining industry.
In the catalytic oxidation process of coker gas oil, presently used oxidant mainly has hydrogen peroxide, o3, air, oil-soluble
Oxidant etc.；The use of organic acid, inorganic heteropolyacid, light or metal-oxide etc. is catalyst；In order to improve desulfuration efficiency, also tie
Unify a little supplementary meanss and carry out oxidation sweetening, such as ultrasound oxidation technology method, plasma oxidation etc..By the sulfide in diesel oil through oxygen
The sulfone that metaplasia becomes and sulfoxide pass through conventional extractant during extraction removes and mainly have dimethyl sulfoxide, acetonitrile, n- methyl pyrrole
Pyrrolidone (nmp), n, n- dimethylformamide (dmf), furfural, nitromethane, ethylenediamine etc., research shows these organic solvents
Similar to sulfone class polarity, can well by the sulfone class extract and separate in diesel oil after oxidation out.Widely studied both at home and abroad at present
Oxidative desulfurization techniques mainly include hydrogen peroxide oxidation desulfurization, Oxygen Catalytic Oxidation desulfurization, ultrasound oxidation technology desulfurization and photochemistry oxygen
Change desulfurization etc., wherein because of h2o2Have the advantages that oxidisability is strong, oxidation Decomposition thing receives much concern to environment non-hazardous, de- in oxidation
Apply wider in sulfur research.
In recent years, Non-hydrogenation Desulfurization Technique of Fuel Oil develops rapidly, and the method is oxidation removal under conditions of catalyst
Thioether in coker gas oil, mercaptan and thiophene sulfides, produce excellent desulfurized effect, thus reaching decolouring, deodorize, taking off
Slag, thus improving the purpose of diesel oil stability, gentle operating condition in addition, low production cost, environmentally friendly life
Product process, is increasingly paid close attention to by excessively inside and outside researcher.
Content of the invention
The technical problem to be solved in the present invention is to provide a kind of desulfuration purification reaction condition gentle, environmental protection, desulfurization degree
Height, the method that the insulin that coker gas oil yield is notable and the shallow taste of color is light is applied to coker gas oil desulfurization.
The present invention adopts the following technical scheme that solution above-mentioned technical problem:
The method that insulin is applied to coker gas oil desulfurization, comprises the following steps:
(1), by 0.2-0.8g/ml, medicinal dry hawthorn fruit or Fructus Crataegi water are added in coker gas oil, use magnetic agitation
Device heats and stirs, and temperature is 40 DEG C -100 DEG C, and speed of agitator is 20rpm, reacts 60-100min, then takes out and be cooled to room
Temperature；
(2), insulin is added in the coker gas oil of step (1) gained, is subsequently placed in constant temperature in water bath with thermostatic control environment
Heated and stirred, temperature is 36.5 DEG C -38 DEG C, reacting by heating 1-24 hour, and speed of agitator is 20-40rpm；Described insulin is note
Penetrate with injectable powder insulin or injection shape insulin, the addition of powder ampoule agent for injection insulin is 0.01-0.10mg/ml；
Injection shape insulin is 2: 100-5: 100 with the volume ratio of coker gas oil；
(3), catalyst and oxidant priority are added in the coker gas oil after step (2) is processed, catalyst is trichlorine
Acetic acid or formic acid, the hydrogenperoxide steam generator that oxidant is 30% for mass concentration；The volume of coker gas oil, catalyst and oxidant
Than for 10: 2: 1-10: 4: 4, magnetic stirring apparatuss carry out catalytic oxidation, the response time is 50-100min, temperature is 50
DEG C -80 DEG C, mixing speed is 40rpm；
(4) after, step (3) gained coker gas oil is cooled to room temperature, 1: 1 addition extractant by volume, extractant is n,
N- dimethylformamide or furfural, use magnetic stirrer 5-10min, and mixing speed is 40rpm, then pours separatory funnel into,
Standing 20min, collects diesel oil layer.
Fructus Crataegi water in described step (1) presses, for water, the Fructus Crataegi that 300ml/g adds medicinal dry Fructus Crataegi to obtain after decocting 2 hours
Water.
Magnetic stirring apparatuss in described step (1) and step (3) all heat magnetic agitation using df-101s instant-heating-type constant-temperature
Device.
Described step (2) adopts water bath with thermostatic control magnetic stirring apparatuss, and power is 40w.
Compared with prior art, it is an advantage of the current invention that:
1st, technological process is simple, and operation is simple；
2nd, the method is applied to coker gas oil desulfuration purification reaction condition gently, environmental protection, and desulfurization degree is high, as clear as crystal
Light yellow diesel yield notable.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is elaborated, but do not constitute and model is protected to the claims in the present invention
The restriction enclosed.
Embodiment 1:
Fructus Crataegi be parts of generic medicinal plants, also known as mountain in fruit, Fructus Pyri Pashiae, Rosaceae defoliation small arbor, its fruit contain flavonoid,
The chemical compositions such as flavanoid, triterpeness and organic acid, wherein hyperin, ursolic acid be flavonoid with triterpeness main become
Point, it is the active component of Antilipemic haw.Fructus Crataegi contains substantial amounts of fruit acid, Crataegolic acid, citric acid and Digestive Enzyme, lipolytic enzyme, energy
Promote steatolysiss, play the role of cholesterol degradation and triglyceride.Additionally, also containing choline (choline), acetylcholine
(acetylcholine) the organic amine chemical composition such as, is also the effective ingredient of lipid-loweringing.
Weigh the medicinal dry hawthorn fruit of 2g to be added in 10ml coker gas oil, put in beaker together, and with df-101s be
In hot type constant-temperature heating magnetic stirring apparatus, temperature is 40 DEG C, and speed of agitator is 20rpm, reacts 60min, takes out afterwards and is cooled to room
Temperature.It is added in coker gas oil for 2: 100 injection shape insulins by volume under room temperature；It is subsequently placed in water bath with thermostatic control environment
Middle heated at constant temperature stirring, heating-up temperature is 36.5 DEG C, reacting by heating 1 hour, and the power of the magnetic stirring apparatuss of constant temperature is 40w, turns
Speed is 20rpm；Catalyst and oxidant priority are added in coker gas oil, catalyst is trichloroacetic acid, oxidant is quality
Concentration is 30% hydrogenperoxide steam generator；Coker gas oil, catalyst and oxidant volume ratio are 10: 2: 1, then use df-101s collection
Carry out catalytic oxidation, the response time is 50min, heating-up temperature is 50 DEG C, stirring in hot type constant-temperature heating magnetic stirring apparatus
Speed is 40rpm；Then, coker gas oil is taken out and be cooled to after room temperature, add extractant n, n- dimethylformamide, extraction
Agent is 1: 1 with the volume ratio of coker gas oil, uses magnetic stirrer 5min, and mixing speed is 40rpm, then pours a point liquid leakage into
Bucket, stands 20min, collects diesel oil layer, and measures its volume, obtains diesel yield；Will be mono- with sinie7039xr for the diesel oil collected
It is 0.00634% that wavelength x fluorescence sulphur content analyzer surveys its sulfur content, and abstraction desulfurization rate is 97.70%, and diesel yield is 80%.
Embodiment 2:
Weigh the medicinal dry hawthorn fruit of 4g to be added in 10ml coker gas oil, put in beaker together, and with df-101s be
In hot type constant-temperature heating magnetic stirring apparatus, temperature is 60 DEG C, and speed of agitator is 20rpm, reacts 80min, takes out afterwards and is cooled to room
Temperature.Press the powder ampoule agent for injection insulin that addition is 0.05mg/ml under room temperature, be added in coker gas oil；It is subsequently placed in perseverance
Heated at constant temperature stirring in tepidarium environment, heating-up temperature is 37 DEG C, reacting by heating 15 hours, the power of the magnetic stirring apparatuss of constant temperature
For 40w, rotating speed is 30rpm；Catalyst and oxidant priority are added in coker gas oil, catalyst is formic acid, oxidant is
Mass concentration is 30% hydrogenperoxide steam generator；Coker gas oil, catalyst and oxidant volume ratio are 10: 2.5: 2, then use df-
It is stirred catalytic oxidation, the response time is 70min, heating-up temperature is in 101s heat collecting type constant-temperature heating magnetic stirring apparatus
60 DEG C, mixing speed is 40rpm；Coker gas oil is taken out and is cooled to after room temperature, add extractant furfural, extractant and coking
The volume ratio of diesel oil is 1: 1, then uses magnetic stirrer 7min, and mixing speed is 40rpm, then pours separatory funnel into, standing
20min, collects diesel oil layer, and measures its volume, obtain diesel yield；Will be glimmering with sinie7039xr Single wavelength x for the diesel oil collected
It is 0.00585% that light sulphur content analyzer surveys its sulfur content, and abstraction desulfurization rate is 98.19%, and diesel yield is 82%.
Embodiment 3:
Water is pressed 300ml/g and adds medicinal dry Fructus Crataegi to obtain Fructus Crataegi water after decocting 2 hours, 6g Fructus Crataegi water is added to 10ml burnt
Change in diesel oil, put in beaker together, and with, in df-101s instant-heating-type constant-temperature heating magnetic stirring apparatuss, temperature is 80 DEG C, stirring
Rotating speed is 20rpm, reacts 90min, takes out afterwards and is cooled to room temperature.The injection powder pin that addition is 0.08mg/ml is pressed under room temperature
Agent insulin, is added in coker gas oil；It is subsequently placed in heated at constant temperature stirring in water bath with thermostatic control environment, heating-up temperature is 37.5
DEG C, reacting by heating 20 hours, the power of the magnetic stirring apparatuss of constant temperature is 40w, and rotating speed is 35rpm；First to catalyst and oxidant
After be added in coker gas oil, catalyst be trichloroacetic acid, the hydrogenperoxide steam generator that oxidant is 30% for mass concentration；Coking
Diesel oil, catalyst and oxidant volume ratio are 10: 3: 3, then with being stirred in df-101s heat collecting type constant-temperature heating magnetic stirring apparatus
Mix catalytic oxidation, the response time is 90min, heating-up temperature is 70 DEG C, mixing speed is 40rpm；Then, coker gas oil
After taking-up is cooled to room temperature, add extractant n, n- dimethylformamide, extractant and coker gas oil agent oil volume are than for 1:
1, then use magnetic stirrer 8min, mixing speed is 40rpm, then pours separatory funnel into, stands 20min, collects diesel oil layer,
And measure its volume, obtain diesel yield, the diesel oil of collection is surveyed its sulfur with sinie7039xr Single wavelength x fluorescence sulphur content analyzer
Content is 0.00463%, and abstraction desulfurization rate is 98.68%, and diesel yield is 85%.
Embodiment 4:
Weigh the medicinal dry hawthorn fruit of 8g to be added in 10ml coker gas oil, put in beaker together, and with df-101s be
In hot type constant-temperature heating magnetic stirring apparatus, temperature is 100 DEG C, and speed of agitator is 20rpm, reacts 100min, takes out afterwards and is cooled to
Room temperature.It is added in coker gas oil for 5: 100 injection shape insulins by volume under room temperature；It is subsequently placed in water bath with thermostatic control ring
Heated at constant temperature stirring in border, heating-up temperature is 38 DEG C, reacting by heating 24 hours, and the power of the magnetic stirring apparatuss of constant temperature is 40w, turns
Speed is 40rpm；Catalyst and oxidant priority are added in coker gas oil, catalyst is formic acid, oxidant is mass concentration
Hydrogenperoxide steam generator for 30%；Coker gas oil, catalyst and oxidant volume ratio are 10: 4: 4, oxidizing temperature is 80 DEG C, stirs
Mixing speed is 40rpm, then with carrying out catalytic oxidation, response time in df-101s heat collecting type constant-temperature heating magnetic stirring apparatus
For 100min, 80 DEG C of heating-up temperature；Coker gas oil is taken out and is cooled to after room temperature, add extractant furfural, extractant and Jiao
The agent oil volume ratio changing diesel oil is for 1: 1, then use magnetic stirrer 10min, and mixing speed is 40rpm, then pours point liquid into and leak
Bucket, stands 20min, collects diesel oil layer, and measures its volume, obtains diesel yield, will be mono- with sinie7039xr for the diesel oil collected
It is 0.00402% that wavelength x fluorescence sulphur content analyzer surveys its sulfur content, and abstraction desulfurization rate is 99.29%, and diesel yield is 87%.
Claims (3)
1. insulin is applied to the method for coker gas oil desulfurization it is characterised in that comprising the following steps:
(1), by 0.2 0.8g/ml, medicinal dry hawthorn fruit or Fructus Crataegi water are added in coker gas oil, with magnetic stirring apparatuss plus
Heat simultaneously stirs, and temperature is 40 DEG C 100 DEG C, and speed of agitator is 20rpm, reacts 60 100min, then takes out and be cooled to room temperature；
(2), insulin is added in the coker gas oil of step (1) gained, is subsequently placed in heated at constant temperature in water bath with thermostatic control environment
Stirring, temperature is 36.5 DEG C 38 DEG C, reacting by heating 1 24 hours, and speed of agitator is 20 40rpm；Described insulin is note
Penetrate with injectable powder insulin or injection shape insulin, the addition of powder ampoule agent for injection insulin is 0.01 0.10mg/ml；
Injection shape insulin is 2:100 5:100 with the volume ratio of coker gas oil；
(3), catalyst and oxidant priority are added in the coker gas oil after step (2) is processed, catalyst is trichloroacetic acid
Or formic acid, the hydrogenperoxide steam generator that oxidant is 30% for mass concentration；The volume ratio of coker gas oil, catalyst and oxidant is
10: 2: 1 10: 4: 4, magnetic stirring apparatuss carry out catalytic oxidation, the response time is 50 100min, temperature is 50
DEG C 80 DEG C, mixing speed is 40rpm；
(4) after, step (3) gained coker gas oil is cooled to room temperature, 1: 1 addition extractant by volume, extractant is n, n- bis-
Methylformamide or furfural, use magnetic stirrer 5-10min, and mixing speed is 40rpm, then pours separatory funnel into, standing
20min, collects diesel oil layer；
Fructus Crataegi water in described step (1) presses, for water, the Fructus Crataegi water that 300ml/g adds medicinal dry Fructus Crataegi to obtain after decocting 2 hours.
2. insulin according to claim 1 is applied to the method for coker gas oil desulfurization it is characterised in that described step
(1) magnetic stirring apparatuss and in step (3) are all using df-101s heat collecting type constant-temperature heating magnetic stirring apparatus.
3. insulin according to claim 1 is applied to the method for coker gas oil desulfurization it is characterised in that described step
(2) water bath with thermostatic control magnetic stirring apparatuss are adopted, power is 40w.
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| US5358870A (en) * | 1990-02-28 | 1994-10-25 | Institute Of Gas Technology | Microemulsion process for direct biocatalytic desulfurization of organosulfur molecules |
| CN1169159A (en) * | 1994-12-08 | 1997-12-31 | 能量生物系统公司 | Method of desulfurization of fossil fuel with flavoprotein |
| US6402940B1 (en) * | 2000-09-01 | 2002-06-11 | Unipure Corporation | Process for removing low amounts of organic sulfur from hydrocarbon fuels |
| CN100513524C (en) * | 2005-02-05 | 2009-07-15 | 中国石油化工股份有限公司 | Method for producing low-sulfur diesel-oil by oxidation desulfurization |
| CN100371438C (en) * | 2005-04-27 | 2008-02-27 | 中国石油化工股份有限公司 | Rhodococcus erythropolis for biological desulfurization and its use |
| CN101302437A (en) * | 2008-06-28 | 2008-11-12 | 中国海洋大学 | Method for removing organic sulfide from diesel by using composite extractive agent |
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