CN105111592A - Heat resistant and oil resistant ethylene propylene diene monomer rubber/acrylate rubber cable material - Google Patents
Heat resistant and oil resistant ethylene propylene diene monomer rubber/acrylate rubber cable material Download PDFInfo
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- CN105111592A CN105111592A CN201510505231.2A CN201510505231A CN105111592A CN 105111592 A CN105111592 A CN 105111592A CN 201510505231 A CN201510505231 A CN 201510505231A CN 105111592 A CN105111592 A CN 105111592A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses a heat resistant and oil resistant ethylene propylene diene monomer rubber/acrylate rubber material. The raw material comprises the following components: ethylene propylene diene monomer rubber, acrylate rubber, EPDM rubber grafted with maleic anhydride, ethylene acrylate rubber, carbon black, organically modified montmorillonite, zinc oxide, stearate, magnesia, zinc methacrylate, dicumyl peroxide, trimerization thiocyanate, diallyl phthalate ester, accelerator M, accelerant DZ, an accelerator CZ, an antioxidant, diethylene glycol dibenzoate, epoxy soybean oil, N-cyclohexylthio phthalimide and a silane coupling agent. The heat resistant and oil resistant ethylene propylene diene monomer rubber/acrylate rubber material disclosed by the invention is high in mechanical strength,excellent in oil resistance, heat resistance and resistance to aging, and the cable made from the material is long in service life, so that the cost can be reduced.
Description
Technical field
The present invention relates to cable material technical field, particularly relate to a kind of heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material.
Background technology
Terpolymer EP rubber has the processing characteristics of excellent weather, resistance to ozone, heat-resisting, acid and alkali-resistance, resistance to water vapour, colour stability, electrical property, oil-filled property and excellence, applies widely in cable industry.But its for a long time in the environment of high temperature, oiliness use can cause the decline of its performance, its use range still has certain limitation.
Summary of the invention
The present invention proposes a kind of heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material, it has high physical strength, excellent oil-proofness, thermotolerance and ageing resistance, and the cable long service life made with it can be cost-saving.
The present invention proposes a kind of heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material, its raw material comprises following component by weight: terpolymer EP rubber 50-70 part, acrylic elastomer 30-50 part, grafting maleic anhydride with ethylene propylene terpolymer 15-25 part, ethylene-acrylate rubber 10-25 part, carbon black 3-10 part, organic modification montmonrillonite 5-20 part, zinc oxide 1-2.5 part, stearic acid 0.8-2 part, magnesium oxide 2-8 part, zinc methacrylate 1-6 part, dicumyl peroxide 0.3-1 part, trithiocyanuric acid 0.5-1.2 part, diallyl phthalate 0.1-0.5 part, captax 0.1-0.5 part, accelerator DZ 0.3-0.8 part, accelerant CZ 0.2-1 part, anti-aging agent 0.8-2 part, diethylene glycol dibenzoate 0.3-1.2 part, epoxy soybean oil 1-3 part, N-cyclohexylthiophthalimide 0.1-0.3 part, silane coupling agent 1-4 part.
Preferably, in its raw material, the weight ratio of terpolymer EP rubber, acrylic elastomer, grafting maleic anhydride with ethylene propylene terpolymer, ethylene-acrylate rubber is 55-67:33-47:17-23:13-22.
Preferably, in its raw material, the weight ratio of dicumyl peroxide, trithiocyanuric acid, captax, accelerator DZ, accelerant CZ, N-cyclohexylthiophthalimide is 0.4-0.8:0.6-1.0:0.15-0.4:0.38-0.65:0.4-0.8:0.13-0.27.
Preferably, in its raw material, the weight ratio of diethylene glycol dibenzoate, epoxy soybean oil, diallyl phthalate is 0.5-1.1:1.6-2.3:0.15-0.45.
Preferably, its raw material comprises following component by weight: terpolymer EP rubber 57-63 part, acrylic elastomer 35-43 part, grafting maleic anhydride with ethylene propylene terpolymer 20-22 part, ethylene-acrylate rubber 17-20 part, carbon black 7-9 part, organic modification montmonrillonite 12-16 part, zinc oxide 1.8-2.2 part, stearic acid 1.2-1.8 part, magnesium oxide 3.5-6.8 part, zinc methacrylate 3.2-5.6 part, dicumyl peroxide 0.6-0.8 part, trithiocyanuric acid 0.8-1.0 part, diallyl phthalate 0.22-0.35 part, captax 0.25-0.35 part, accelerator DZ 0.6-0.7 part, accelerant CZ 0.6-0.78 part, anti-aging agent 1.3-1.6 part, diethylene glycol dibenzoate 0.7-1.0 part, epoxy soybean oil 1.8-2.3 part, N-cyclohexylthiophthalimide 0.18-0.25 part, silane coupling agent 1.9-2.6 part.
Preferably, its raw material comprises following component by weight: terpolymer EP rubber 60 parts, acrylic elastomer 40 parts, grafting maleic anhydride with ethylene propylene terpolymer 21 parts, ethylene-acrylate rubber 18.5 parts, carbon black 8.3 parts, organic modification montmonrillonite 14 parts, 2.1 parts, zinc oxide, stearic acid 1.5 parts, 5.3 parts, magnesium oxide, zinc methacrylate 5.2 parts, dicumyl peroxide 0.68 part, trithiocyanuric acid 0.93 part, diallyl phthalate 0.25 part, captax 0.3 part, accelerator DZ 0.62 part, accelerant CZ 0.7 part, 1.5 parts, anti-aging agent, diethylene glycol dibenzoate 0.85 part, epoxy soybean oil 2 parts, N-cyclohexylthiophthalimide 0.2 part, silane coupling agent 2.5 parts.
Preferably, described anti-aging agent is one or more the mixture in anti-aging agent RD, antioxidant A W, antioxidant MB.
In the present invention, have employed oil resistant, heat-resisting acrylic elastomer cooperation terpolymer EP rubber as the major ingredient of rubber, compensate for the deficiency of single terpolymer EP rubber performance, improve thermotolerance and the oil-proofness of cable material, grafting maleic anhydride with ethylene propylene terpolymer and ethylene-acrylate rubber join in cable material, silane coupling agent auxiliary under, improve the consistency of terpolymer EP rubber and acrylate, the interface cohesion of terpolymer EP rubber and acrylic elastomer is strengthened, form the more uniform mixture of phase, in the process that cable material is stressed, uniform force, improve 100% stress at definite elongation and the tensile strength of cable material, and due to the effect of maleic anhydride polar ester groups, the oxidation activity of terpolymer EP rubber is reduced, improve the ageing-resistant performance of cable material, ethylene-acrylate rubber joins in cable material, can with rubber major ingredient generation covulcanization, improve the processing characteristics of cable material, vulcanization characteristics, property of compression fatigue, oil resistance and high and low temperature resistance, magnesium oxide coordinates with zinc methacrylate and joins in cable material, free radical can be produced with terpolymer EP rubber, acrylic elastomer, grafting maleic anhydride with ethylene propylene terpolymer, ethylene-acrylate rubber simultaneously, thus formation cross-link bond, have adjusted the crosslinking structure of cable material, improve the cross-linking density of cable material, hardness, tensile strength, tensile elongation and tear strength, and owing to defining cross-linked network, improve the thermotolerance of cable material, select superoxide and trithiocyanuric acid as linking agent, avoid the reduction adding the cable material thermotolerance caused because of sulphur, N-cyclohexylthiophthalimide joins in cable material, coordinate with captax, accelerator DZ, accelerant CZ, improve the curability of cable material, and can as scorch retarder, the processing safety of control cables material, improves the package stability of cable material, diethylene glycol dibenzoate joins in cable material, good with other materials compatibility, improve the winter hardiness of cable material, static resistance, resistance to crocking, thermally-stabilised, and volatility is low in cable material, toxicity is little with epoxy soybean oil after coordinating.
Carry out Performance Detection to heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material of the present invention, its tensile strength is 18.3-21.5MPa; Elongation at break is 436-485%; Shore A hardness is 63-67; 20# oil 100 DEG C × 50h elongation at break conservation rate is 84.3-89.4%, and stretching strength retentivity is 83.4-87.6%; Be 92.6-95.3% through 120 DEG C × 100h stretching strength retentivity, elongation at break conservation rate is 93.4-96.7%.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In a particular embodiment, heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material of the present invention, its raw material is as follows by weight: the weight part of terpolymer EP rubber can be 50,53,57,58.6,59,62,63,65,67.3,68.4,69.3,70 parts; The weight part of acrylic elastomer can be 30,32,33,34.5,36,38,39.4,42,43,45.6,47,48.3,49,50 parts; The weight part of grafting maleic anhydride with ethylene propylene terpolymer can be 15,16,17.3,18,19.3,20,21,21.4,22,23.6,24,24.5,25 parts; The weight part of ethylene-acrylate rubber can be 10,11,12,13,14,15.6,16,17,17.4,18,19.3,20,21,21.3,22,23,24.5,25 parts; The weight part of carbon black can be 3,3.6,4,4.3,5,5.7,6,6.8,8,8.3,9,10 parts; The weight part of organic modification montmonrillonite can be 5,5.6,6,6.7,7,8,8.5,9,9.6,10,10.4,11,12,12.4,13,14,15,15.8,16,17.3,18,18.3,19,19.3,20 parts; The weight part of zinc oxide can be 1,1.2,1.5,1.75,1.8,1.86,1.9,2,2.1,2.2,2.34,2.45,2.5 part; Stearic weight part can be 0.8,0.9,1,1.3,1.4,1.56,1.6,1.75,1.8,1.93,2 part; Magnesian weight part can be 2,2.3,2.6,3,3.4,3.8,4,4.3,5,5.6,6,6.5,7,7.3,8 parts; The weight part of zinc methacrylate can be 1,1.3,1.7,2,2.3,2.8,3,3.4,4,4.6,5,5.3,6 part; The weight part of dicumyl peroxide can be 0.3,0.4,0.5,0.64,0.7,0.75,0.8,0.83,0.9,0.93,1 part; The weight part of trithiocyanuric acid can be 0.5,0.56,0.7,0.78,0.8,0.87,0.9,0.93,1,1.1,1.15,1.2 part; The weight part of diallyl phthalate can be 0.1,0.13,0.2,0.25,0.27,0.3,0.34,0.4,0.46,0.5 part; The weight part of captax can be 0.1,0.14,0.15,0.2,0.25,0.3,0.38,0.42,0.5 part; The weight part of accelerator DZ can be 0.3,0.38,0.4,0.46,0.5,0.53,0.6,0.64,0.7,0.74,0.8 part; The weight part of accelerant CZ can be 0.2,0.26,0.3,0.34,0.4,0.47,0.5,0.53,0.6,0.64,0.7,0.75,0.8,0.94,1 part; The weight part of anti-aging agent can be 0.8,0.86,0.94,1,1.2,1.4,1.56,1.7,1.86,1.9,2 part; The weight part of diethylene glycol dibenzoate can be 0.3,0.4,0.46,0.54,0.6,0.7,0.85,0.9,1,1.1,1.15,1.2 part; The weight part of epoxy soybean oil can be 1,1.3,1.6,1.9,2,2.1,2.3,2.5,2.67,2.8,2.9,3 part; The weight part of N-cyclohexylthiophthalimide can be 0.1,0.15,0.2,0.23,0.27,0.3 part; The weight part of silane coupling agent can be 1,1.2,1.5,1.8,2,2.1,2.4,2.57,2.8,2.93,3,3.2,3.6,3.8,3.9,4 part.
Embodiment 1
Heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material of the present invention, its raw material comprises following component by weight: terpolymer EP rubber 50 parts, acrylic elastomer 50 parts, grafting maleic anhydride with ethylene propylene terpolymer 15 parts, ethylene-acrylate rubber 25 parts, carbon black 3 parts, organic modification montmonrillonite 20 parts, 1 part, zinc oxide, stearic acid 2 parts, 2 parts, magnesium oxide, zinc methacrylate 6 parts, dicumyl peroxide 0.3 part, trithiocyanuric acid 1.2 parts, diallyl phthalate 0.1 part, captax 0.5 part, accelerator DZ 0.3 part, accelerant CZ 1 part, 0.8 part, anti-aging agent, diethylene glycol dibenzoate 1.2 parts, epoxy soybean oil 1 part, N-cyclohexylthiophthalimide 0.3 part, silane coupling agent 1 part.
Embodiment 2
Heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material of the present invention, its raw material comprises following component by weight: terpolymer EP rubber 70 parts, acrylic elastomer 30 parts, grafting maleic anhydride with ethylene propylene terpolymer 25 parts, ethylene-acrylate rubber 10 parts, carbon black 10 parts, organic modification montmonrillonite 5 parts, 2.5 parts, zinc oxide, stearic acid 0.8 part, 8 parts, magnesium oxide, zinc methacrylate 1 part, dicumyl peroxide 1 part, trithiocyanuric acid 0.5 part, diallyl phthalate 0.5 part, captax 0.1 part, accelerator DZ 0.8 part, accelerant CZ 0.2 part, 2 parts, anti-aging agent, diethylene glycol dibenzoate 0.3 part, epoxy soybean oil 3 parts, N-cyclohexylthiophthalimide 0.1 part, silane coupling agent 4 parts.
Embodiment 3
Heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material of the present invention, its raw material comprises following component by weight: terpolymer EP rubber 57 parts, acrylic elastomer 43 parts, grafting maleic anhydride with ethylene propylene terpolymer 20 parts, ethylene-acrylate rubber 20 parts, carbon black 7 parts, organic modification montmonrillonite 16 parts, 1.8 parts, zinc oxide, stearic acid 1.8 parts, 3.5 parts, magnesium oxide, zinc methacrylate 5.6 parts, dicumyl peroxide 0.6 part, trithiocyanuric acid 1.0 parts, diallyl phthalate 0.22 part, captax 0.35 part, accelerator DZ 0.6 part, accelerant CZ 0.78 part, 1.3 parts, anti-aging agent, diethylene glycol dibenzoate 0.7 part, epoxy soybean oil 2.3 parts, N-cyclohexylthiophthalimide 0.18 part, silane coupling agent 2.6 parts.
Embodiment 4
Heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material of the present invention, its raw material comprises following component by weight: terpolymer EP rubber 63 parts, acrylic elastomer 35 parts, grafting maleic anhydride with ethylene propylene terpolymer 22 parts, ethylene-acrylate rubber 17 parts, carbon black 9 parts, organic modification montmonrillonite 12 parts, 2.2 parts, zinc oxide, stearic acid 1.2 parts, 6.8 parts, magnesium oxide, zinc methacrylate 3.2 parts, dicumyl peroxide 0.8 part, trithiocyanuric acid 0.8 part, diallyl phthalate 0.35 part, captax 0.25 part, accelerator DZ 0.7 part, accelerant CZ 0.6 part, anti-aging agent RD 0.3 part, antioxidant A W0.5 part, antioxidant MB 0.8 part, diethylene glycol dibenzoate 1.0 parts, epoxy soybean oil 1.8 parts, N-cyclohexylthiophthalimide 0.25 part, silane coupling agent 1.9 parts.
Embodiment 5
Heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material of the present invention, its raw material comprises following component by weight: terpolymer EP rubber 65 parts, acrylic elastomer 43 parts, grafting maleic anhydride with ethylene propylene terpolymer 21.4 parts, ethylene-acrylate rubber 21 parts, carbon black 6.8 parts, organic modification montmonrillonite 18 parts, 2.34 parts, zinc oxide, stearic acid 1.8 parts, 5.6 parts, magnesium oxide, zinc methacrylate 4.6 parts, dicumyl peroxide 0.83 part, trithiocyanuric acid 0.87 part, diallyl phthalate 0.34 part, captax 0.42 part, accelerator DZ 0.8 part, accelerant CZ 0.64 part, antioxidant A W0.66 part, antioxidant MB 0.9 part, diethylene glycol dibenzoate 1.15 parts, epoxy soybean oil 2.8 parts, N-cyclohexylthiophthalimide 0.27 part, silane coupling agent 3.8 parts.
Embodiment 6
Heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material of the present invention, its raw material comprises following component by weight: terpolymer EP rubber 60 parts, acrylic elastomer 40 parts, grafting maleic anhydride with ethylene propylene terpolymer 21 parts, ethylene-acrylate rubber 18.5 parts, carbon black 8.3 parts, organic modification montmonrillonite 14 parts, 2.1 parts, zinc oxide, stearic acid 1.5 parts, 5.3 parts, magnesium oxide, zinc methacrylate 5.2 parts, dicumyl peroxide 0.68 part, trithiocyanuric acid 0.93 part, diallyl phthalate 0.25 part, captax 0.3 part, accelerator DZ 0.62 part, accelerant CZ 0.7 part, anti-aging agent RD 1.5 parts, diethylene glycol dibenzoate 0.85 part, epoxy soybean oil 2 parts, N-cyclohexylthiophthalimide 0.2 part, silane coupling agent 2.5 parts.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (7)
1. heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material, it is characterized in that, its raw material comprises following component by weight: terpolymer EP rubber 50-70 part, acrylic elastomer 30-50 part, grafting maleic anhydride with ethylene propylene terpolymer 15-25 part, ethylene-acrylate rubber 10-25 part, carbon black 3-10 part, organic modification montmonrillonite 5-20 part, zinc oxide 1-2.5 part, stearic acid 0.8-2 part, magnesium oxide 2-8 part, zinc methacrylate 1-6 part, dicumyl peroxide 0.3-1 part, trithiocyanuric acid 0.5-1.2 part, diallyl phthalate 0.1-0.5 part, captax 0.1-0.5 part, accelerator DZ 0.3-0.8 part, accelerant CZ 0.2-1 part, anti-aging agent 0.8-2 part, diethylene glycol dibenzoate 0.3-1.2 part, epoxy soybean oil 1-3 part, N-cyclohexylthiophthalimide 0.1-0.3 part, silane coupling agent 1-4 part.
2. heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material according to claim 1, it is characterized in that, in its raw material, the weight ratio of terpolymer EP rubber, acrylic elastomer, grafting maleic anhydride with ethylene propylene terpolymer, ethylene-acrylate rubber is 55-67:33-47:17-23:13-22.
3. heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material according to claim 1 or 2, it is characterized in that, in its raw material, the weight ratio of dicumyl peroxide, trithiocyanuric acid, captax, accelerator DZ, accelerant CZ, N-cyclohexylthiophthalimide is 0.4-0.8:0.6-1.0:0.15-0.4:0.38-0.65:0.4-0.8:0.13-0.27.
4. heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material according to any one of claim 1-3, it is characterized in that, in its raw material, the weight ratio of diethylene glycol dibenzoate, epoxy soybean oil, diallyl phthalate is 0.5-1.1:1.6-2.3:0.15-0.45.
5. heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material according to any one of claim 1-4, it is characterized in that, its raw material comprises following component by weight: terpolymer EP rubber 57-63 part, acrylic elastomer 35-43 part, grafting maleic anhydride with ethylene propylene terpolymer 20-22 part, ethylene-acrylate rubber 17-20 part, carbon black 7-9 part, organic modification montmonrillonite 12-16 part, zinc oxide 1.8-2.2 part, stearic acid 1.2-1.8 part, magnesium oxide 3.5-6.8 part, zinc methacrylate 3.2-5.6 part, dicumyl peroxide 0.6-0.8 part, trithiocyanuric acid 0.8-1.0 part, diallyl phthalate 0.22-0.35 part, captax 0.25-0.35 part, accelerator DZ 0.6-0.7 part, accelerant CZ 0.6-0.78 part, anti-aging agent 1.3-1.6 part, diethylene glycol dibenzoate 0.7-1.0 part, epoxy soybean oil 1.8-2.3 part, N-cyclohexylthiophthalimide 0.18-0.25 part, silane coupling agent 1.9-2.6 part.
6. heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material according to any one of claim 1-5, it is characterized in that, its raw material comprises following component by weight: terpolymer EP rubber 60 parts, acrylic elastomer 40 parts, grafting maleic anhydride with ethylene propylene terpolymer 21 parts, ethylene-acrylate rubber 18.5 parts, carbon black 8.3 parts, organic modification montmonrillonite 14 parts, 2.1 parts, zinc oxide, stearic acid 1.5 parts, 5.3 parts, magnesium oxide, zinc methacrylate 5.2 parts, dicumyl peroxide 0.68 part, trithiocyanuric acid 0.93 part, diallyl phthalate 0.25 part, captax 0.3 part, accelerator DZ 0.62 part, accelerant CZ 0.7 part, 1.5 parts, anti-aging agent, diethylene glycol dibenzoate 0.85 part, epoxy soybean oil 2 parts, N-cyclohexylthiophthalimide 0.2 part, silane coupling agent 2.5 parts.
7. heat-resisting oil resistant terpolymer EP rubber/acrylic elastomer cable material according to any one of claim 1-6, is characterized in that, described anti-aging agent is one or more the mixture in anti-aging agent RD, antioxidant A W, antioxidant MB.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102964698A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | High cold-resistance ethylene propylene diene copolymer insulated cable material and preparation method thereof |
CN103509256A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Oil-resistant low-temperature-resistant cable material and preparation method thereof |
-
2015
- 2015-08-17 CN CN201510505231.2A patent/CN105111592A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102964698A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | High cold-resistance ethylene propylene diene copolymer insulated cable material and preparation method thereof |
CN103509256A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Oil-resistant low-temperature-resistant cable material and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
广廷洪 等主编: "《密封件使用手册》", 31 December 1994 * |
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