CN105108160A - Iron-cobalt based alloy microwave absorbing material and manufacturing method thereof - Google Patents
Iron-cobalt based alloy microwave absorbing material and manufacturing method thereof Download PDFInfo
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- CN105108160A CN105108160A CN201510565482.XA CN201510565482A CN105108160A CN 105108160 A CN105108160 A CN 105108160A CN 201510565482 A CN201510565482 A CN 201510565482A CN 105108160 A CN105108160 A CN 105108160A
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Abstract
The invention provides an iron-cobalt based alloy microwave absorbing material and a manufacturing method thereof, wherein the method comprises: high purity metals of Fe, Co, Y and Al are used as raw materials; the materials are matched by certain atom proportion and the material is smelted by utilizing a vacuum electric-arc furnace; the smelted alloy is put into a vacuum glass pipe to perform annealing processing evenly, quench processing, preliminary pulverizing processing and finally ball-milling processing by utilizing a planet-type ball milling machine under the protection of gasoline; and the alloy is taken out, thus an alloy micro powder wave absorbing material is acquired.
Description
Technical field
The present invention relates to a kind of preparation method of alloy microwave absorbing material, particularly a kind of preparation method of iron cobaltio base alloy microwave absorbing material.
Background technology
Along with modern science and technology fast development, it is further extensive that various electronic information technology is applied in every field, while bringing great convenience, also brings serious electromagnetic pollution to society, cause serious threat to the health of the mankind to the life of people.Microwave absorbing material as a kind of can the functional material of electromagnetic wave absorption, electromagnetic wave energy can be converted into other forms of energy by it, electromagnetic radiation and interference is suppressed with this, there is good effect, therefore countries in the world all fall over each other to drop into a large amount of manpowers and material resources to research and develop high performance absorbing material, become one of focus.
Traditional absorbing material mainly contains ferrite-type and magnetic metal (alloy) micro mist etc.Because ferrite saturation magnetization under 1-18GHz frequency range is low, microwave magnetic permeability is less, and wave-sucking performance is poor, and matching thickness thicker (Centimeter Level), and therefore Ferrite Material is subject to great limitation in the application of this frequency range.And sheet soft magnetic metal micro mist due to Curie temperature high, temperature stability is good, there are larger saturation magnetization and grain shape effect, higher complex permeability and lower eddy-current loss can be obtained under 1-18GHz frequency range simultaneously, matching thickness less (grade), has good application prospect as radio-radar absorber.Current magnetically soft alloy micro mist mainly contains Fe, Co, Ni and alloy powder etc. thereof.
FeCo base soft magnetic materials has higher saturation magnetization, magnetic conductivity, lower coercivity and small loss and other features, therefore be widely used in fields such as Aeronautics and Astronautics, navigation, military and civilians, also cause the great interest of scientific research personnel simultaneously, have lot of documents to report the performance being improved FeCo base soft magnetic materials by development new component in the world every year.The performances such as special optical, electrical, the magnetic that rare earth element has because of the particularity of its structure that other elements many do not have, are described as " treasure-house " of new material.Metal A l adds in metal, can put forward heavy alloyed ductility, in alloy mechanical milling process, makes micro mist thinner, explores further the absorbing property improving FeCo base alloy, and the present invention is by mixing rare earth element y and Al reaches the absorbing property improving FeCo base alloy.
Summary of the invention
The invention provides a kind of iron cobaltio base alloy microwave absorbing material and preparation method thereof, specifically comprise the steps:
(1) be greater than 99.5% with highly purified metal Fe, Co, Y, Al(purity) prepare burden by certain atomic ratio;
(2) the raw material vacuum arc furnace ignition prepared carries out melting;
(3) melted sample is placed in quartz glass tube and carries out vacuum seal;
(4) the glass tube that alloy sample is housed is put into stove, carry out homogenizing annealing process;
(5) quench with in mixture of ice and water after annealing in process;
(6) take out sample and carry out machinery tentatively pulverizing;
(7), by the sample after pulverizing, pour in ball grinder, under the protection of gasoline, carry out ball milling with planetary ball mill;
Ball milling terminate rear alloy powder take out dry, a kind of alloy powder absorbing material.
Preferentially, step (1) in, be Fe according to atomic ratio
10co
7nd
2-xal
x(0.5≤X≤1) prepares burden.
Preferentially, step (4) in, annealing temperature controls at 500-600 DEG C, annealing time 15 days.
Preferentially, step (7) in, planetary ball mill speeds control 200-300r/min runs, and Ball-milling Time is 50-70 hour.
The present invention has following advantages and characteristic:
(1) the sorbing material produced of the method is with low cost, and preparation technology is simple;
(2) inhale ripple bandwidth, absorption intensity is high.
Detailed description of the invention
Embodiment one:
Metal Fe, Co, Y, Al of 99.5% is greater than by Fe with purity
10co
7nd
1.5al
0.5atomic ratio prepares burden into 10g sample material, the raw material vacuum arc furnace ignition prepared is carried out being smelted into primary alloy ingot, melted alloy pig is put into quartz glass tube and is carried out vacuum seal, again the quartz glass tube of sealing is put into its sealing of built for in-water survey, chamber type electric resistance furnace is put into after inspection sealing is intact, homogenizing annealing process is carried out under 500 DEG C of environmental conditions, annealing in process is quenched with in mixture of ice and water for 15 days afterwards, taking-up sample to be cooled carries out machinery and tentatively pulverizes, collecting powder pulverized powder pours in ball grinder, under the protection of gasoline, ball milling is carried out with planetary ball mill, ball milling speed controls as 200r/min, ball milling is after 70 hours, alloy powder is taken out and dries, a kind of alloy powder absorbing material.
Embodiment two:
Metal Fe, Co, Y, Al of 99.5% is greater than by Fe with purity
10co
7nd
1.3al
0.7atomic ratio prepares burden into 10g sample material, the raw material vacuum arc furnace ignition prepared is carried out being smelted into primary alloy ingot, melted alloy pig is put into quartz glass tube and is carried out vacuum seal, again the quartz glass tube of sealing is put into its sealing of built for in-water survey, chamber type electric resistance furnace is put into after inspection sealing is intact, homogenizing annealing process is carried out under 550 DEG C of environmental conditions, annealing in process is quenched with in mixture of ice and water for 15 days afterwards, taking-up sample to be cooled carries out machinery and tentatively pulverizes, collecting powder pulverized powder pours in ball grinder, under the protection of gasoline, ball milling is carried out with planetary ball mill, ball milling speed controls as 250r/min, ball milling is after 60 hours, alloy powder is taken out and dries, a kind of alloy powder absorbing material.
Embodiment three:
Metal Fe, Co, Y, Al of 99.5% is greater than by Fe with purity
10co
7ndAl atomic ratio prepares burden into 20g sample material, the raw material vacuum arc furnace ignition prepared is carried out being smelted into primary alloy ingot, melted alloy pig is put into quartz glass tube and is carried out vacuum seal, again the quartz glass tube of sealing is put into its sealing of built for in-water survey, chamber type electric resistance furnace is put into after inspection sealing is intact, homogenizing annealing process is carried out under 600 DEG C of environmental conditions, annealing in process is quenched with in mixture of ice and water for 15 days afterwards, taking-up sample to be cooled carries out machinery and tentatively pulverizes, collecting powder pulverized powder pours in ball grinder, under the protection of gasoline, ball milling is carried out with planetary ball mill, ball milling speed controls as 300r/min, ball milling is after 50 hours, alloy powder is taken out and dries, a kind of alloy powder absorbing material.
Claims (4)
1. an iron cobaltio base alloy microwave absorbing material, is characterized in that, the preparation method of this microwave absorbing material comprises the steps:
(1) be greater than 99.5% with highly purified metal Fe, Co, Y, Al(purity) prepare burden by certain atomic ratio;
(2) the raw material vacuum arc furnace ignition prepared carries out melting;
(3) melted sample is placed in quartz glass tube and carries out vacuum seal;
(4) the glass tube that alloy sample is housed is put into stove, carry out homogenizing annealing process;
(5) quench with in mixture of ice and water after annealing in process;
(6) take out sample and carry out machinery tentatively pulverizing;
(7), by the sample after pulverizing, pour in ball grinder, under the protection of gasoline, carry out ball milling with planetary ball mill;
Ball milling terminate rear alloy powder take out dry, a kind of alloy powder absorbing material.
2. a kind of iron cobaltio base alloy microwave absorbing material according to claim 1, is characterized in that, step (1) in, be Fe according to atomic ratio
10co
7nd
2-xal
x(0.5≤X≤1) prepares burden.
3. a kind of iron cobaltio base alloy microwave absorbing material according to claim 1, is characterized in that, step (4) in, annealing temperature controls at 500-600 DEG C, annealing time 15 days.
4. a kind of iron cobaltio base alloy microwave absorbing material according to claim 1, is characterized in that, step (7) in, planetary ball mill speeds control 200-300r/min runs, and Ball-milling Time is 50-70 hour.
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| CN201510565482.XA CN105108160A (en) | 2015-09-08 | 2015-09-08 | Iron-cobalt based alloy microwave absorbing material and manufacturing method thereof |
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| CN201510565482.XA CN105108160A (en) | 2015-09-08 | 2015-09-08 | Iron-cobalt based alloy microwave absorbing material and manufacturing method thereof |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08109406A (en) * | 1994-10-07 | 1996-04-30 | Kurimoto Ltd | Treatment of sponge titanium powder |
| RU2007149614A (en) * | 2007-12-28 | 2009-07-10 | Александр Метталинович Тишин (RU) | POROUS MATERIALS WITH INTEGRATED NANOPARTICLES, METHODS FOR THEIR MANUFACTURE AND APPLICATION |
| CN104388818A (en) * | 2014-11-14 | 2015-03-04 | 桂林电子科技大学 | ErFeV magnetic wave-absorbing material and preparation method thereof |
| CN104831161A (en) * | 2015-05-07 | 2015-08-12 | 黄鹏腾 | Iron-based alloy wave absorbing material and preparation method thereof |
| CN104831159A (en) * | 2015-05-08 | 2015-08-12 | 黄鹏腾 | Preparation method of Fe-Nd-Al alloy microwave absorbing material |
| CN104827043A (en) * | 2015-05-07 | 2015-08-12 | 黄鹏腾 | Alloy micro-powder wave-absorbing material and preparation method thereof |
| CN104846272A (en) * | 2015-05-14 | 2015-08-19 | 黄鹏腾 | Nd and La-doped iron base alloy wave absorption material |
-
2015
- 2015-09-08 CN CN201510565482.XA patent/CN105108160A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08109406A (en) * | 1994-10-07 | 1996-04-30 | Kurimoto Ltd | Treatment of sponge titanium powder |
| RU2007149614A (en) * | 2007-12-28 | 2009-07-10 | Александр Метталинович Тишин (RU) | POROUS MATERIALS WITH INTEGRATED NANOPARTICLES, METHODS FOR THEIR MANUFACTURE AND APPLICATION |
| CN104388818A (en) * | 2014-11-14 | 2015-03-04 | 桂林电子科技大学 | ErFeV magnetic wave-absorbing material and preparation method thereof |
| CN104831161A (en) * | 2015-05-07 | 2015-08-12 | 黄鹏腾 | Iron-based alloy wave absorbing material and preparation method thereof |
| CN104827043A (en) * | 2015-05-07 | 2015-08-12 | 黄鹏腾 | Alloy micro-powder wave-absorbing material and preparation method thereof |
| CN104831159A (en) * | 2015-05-08 | 2015-08-12 | 黄鹏腾 | Preparation method of Fe-Nd-Al alloy microwave absorbing material |
| CN104846272A (en) * | 2015-05-14 | 2015-08-19 | 黄鹏腾 | Nd and La-doped iron base alloy wave absorption material |
Non-Patent Citations (2)
| Title |
|---|
| 潘顺康 等: "Dy和Al对 Fe-Co合金微波吸收性能的影响", 《稀有金属材料与工程》 * |
| 潘顺康 等: "球磨工艺对Y-Fe-Cr合金吸波性能影响", 《桂林电子科技大学学报》 * |
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Application publication date: 20151202 |
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