CN105097148A - Composite insulator, core rod of composite insulator and preparation method of core rod - Google Patents
Composite insulator, core rod of composite insulator and preparation method of core rod Download PDFInfo
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- CN105097148A CN105097148A CN201510465473.3A CN201510465473A CN105097148A CN 105097148 A CN105097148 A CN 105097148A CN 201510465473 A CN201510465473 A CN 201510465473A CN 105097148 A CN105097148 A CN 105097148A
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Abstract
The invention relates to a core rod of a composite insulator. The core rod comprises fiber bundles, a resin body which wraps the fiber bundles and insulating heat-conduction particles distributed in the resin body. Due to the fact that the insulating heat-conduction particles are added into the resin body, the insulating heat-conduction particles can form a series of heat transfer paths in the resin body, heat conduction is accelerated, and further once pultrusion molding of the large-diameter core rod can be realized. The invention also provides a preparation method of the core rod of the composite insulator as well as the composite insulator.
Description
Technical field
The present invention relates to composite insulator technical field, particularly relate to a kind of composite electric insulator core bar and preparation method thereof and composite insulator.
Background technology
The insulator that high pressure or ultrahigh voltage power conveying circuit use is porcelain insulator or glass insulator the earliest.Along with composite insulator is in the appearance of eighties of last century, the inner support of composite insulator---plug is also more and more subject to the attention in industry.
Now, general diameter is more ripe in the composite electric insulator core bar production technology of below 90mm.But, the production technology of major diameter composite electric insulator core bar, especially more than diameter 110mm, also immature.The mode of production of current major diameter composite electric insulator core bar generally adopts repeatedly pultrusion molding process.
Repeatedly pultrusion molding process is generally, the fibre bundle pultrusion of flooding epoxy resin adhesive liquid is become minor diameter plug, then with this minor diameter plug for matrix carries out once or once above ethoxyline resin composite material drawing and extruding expanding technology, namely with minor diameter plug for matrix still carries out expanding pultrusion with the fibre bundle flooding epoxy resin adhesive liquid to it in forming machine using drawing and extrusion.
Repeatedly pultrusion molding process, its production cycle is long, and the electric property of the composite electric insulator core bar produced is poor.
Summary of the invention
Based on this, be necessary the problem needing repeatedly pultrusion for major diameter composite insulator, provide one can a large diameter composite electric insulator core bar of pultrusion.
A kind of composite electric insulator core bar, it comprises fibre bundle, wraps up the resin matrix of described fibre bundle and is distributed in the insulating heat-conductive particle in described resin matrix, and described insulating heat-conductive particle is electrical insulating material particle.
Above-mentioned composite electric insulator core bar, owing to being added with insulating heat-conductive particle in resin matrix, insulating heat-conductive particle can form the path of a series of transferring heat in resin matrix, thus accelerates heat conduction, and then realizes a pultrusion of major diameter composite electric insulator core bar.
Wherein in an embodiment, with the quality of described resin matrix for benchmark, the mass fraction of described insulating heat-conductive particle is 40 ~ 80wt%.
Wherein in an embodiment, described insulating heat-conductive particle is selected from one or more in metal oxide heat filling, metal nitride heat filling or carbide heat filling.
Wherein in an embodiment, described metal oxide heat filling is selected from one or more in beryllium oxide, magnesium oxide, alundum (Al2O3), calcium oxide or nickel monoxide; Described metal nitride heat filling is selected from aluminium nitride or boron nitride; Carbide heat filling is selected from carborundum or boron carbide.
Wherein in an embodiment, described insulating heat-conductive particle comprises the first particle and the second particle, and the particle size range of described first particle is 3 ~ 20 microns, and the particle size range of described second particle is 10 ~ 25 nanometers.
Wherein in an embodiment, the mass ratio of described first particle and described second particle is 1:1 ~ 1:5.
Wherein in an embodiment, described insulating heat-conductive particle comprises the 3rd particle and the 4th particle, and the draw ratio scope of described 3rd particle is 1 ~ 5, and the draw ratio scope of described 4th particle is 20 ~ 100.
Wherein in an embodiment, the mass ratio of described 3rd particle and described 4th particle is 1:1.5 ~ 1:4.
Wherein in an embodiment, the surface of described insulating heat-conductive particle is through coupling agent treatment.
Wherein in an embodiment, described coupling agent is selected from γ-glycidoxypropyltrime,hoxysilane and/or γ-glycidoxypropyl group triethoxysilane.
Wherein in an embodiment, the diameter of described composite electric insulator core bar is more than or equal to 110mm.
Present invention also offers a kind of preparation method of composite electric insulator core bar.
A preparation method for composite electric insulator core bar, it comprises the steps:
Insulating heat-conductive particle is mixed with resin adhesive liquid, obtains mixed liquor;
Fibre bundle is immersed in described mixed liquor, then carry out pultrusion;
Product solidified by after pultrusion, obtains composite electric insulator core bar.
The preparation method of composite electric insulator core bar of the present invention, can a pultrusion, and processing step is simple, with short production cycle.
Wherein in an embodiment, described preparation method also comprises and carries out coupling processing to described insulating heat-conductive particle.
Present invention also offers a kind of composite insulator, this composite insulator comprises composite electric insulator core bar provided by the present invention.
Above-mentioned composite insulator is owing to comprising composite electric insulator core bar provided by the present invention, and preparation technology is simple, with low cost.
Accompanying drawing explanation
Fig. 1 is the schematic cross-section of the composite electric insulator core bar of one embodiment of the present invention.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
See Fig. 1, a kind of composite electric insulator core bar, it insulating heat-conductive particle 3 comprising fibre bundle 1, wrap up the resin matrix 2 of described fibre bundle 1 and be distributed in described resin matrix 2.
Composite electric insulator core bar of the present invention is solid mandrel, is more specifically the solid mandrel of post composite insulator.Preferably, the diameter of described composite electric insulator core bar is more than or equal to 110mm.Certainly, the diameter of composite electric insulator core bar is not particularly limited, and can also be less than 110mm.
Wherein, fibre bundle plays skeleton function in composite electric insulator core bar, mainly plays load effect.Fibre bundle is known in those skilled in the art.Such as glass fiber bundle, aramid fiber bundle, polyester fiber bundle, nylon fiber bundle etc.Preferred glass fibers bundle of the present invention.
Fibre diameter in fibre bundle of the present invention is preferably 3 ~ 30 μm.
Resin matrix of the present invention refers to the solidfied material after resin adhesive liquid solidification, and resin adhesive liquid comprises resin, curing agent and curing accelerator.
Wherein, resin can select epoxy resin, unsaturated polyester resin, polyurethane resin, phenolic resins, polyimide resin, vinylite etc.Resin of the present invention is preferably epoxy resin.
Particularly, epoxy resin is preferably selected from one or more in cycloaliphatic epoxy resin, novolac epoxy resin, glycidyl ester type epoxy resin, bisphenol A epoxide resin, bisphenol F epoxy resin or polyfunctional group tetraglycidel ether epoxy resin.
Wherein, curing agent is preferably selected from acid anhydrides system curing agent, is specifically selected from one or more in methyl tetrahydro phthalic anhydride, phthalic anhydride, tetrahydrophthalic anhydride, HHPA, methyl hexahydrophthalic anhydride or methyl Na Dike acid anhydrides.
Wherein, curing accelerator is preferably selected from one or more in benzyl dimethylamine, three-(dimethylamino methyl) phenol, liquid imidazole compound.
Preferably, in resin adhesive liquid, the mass ratio of resin, curing agent and curing accelerator is 100:50 ~ 120:0.1 ~ 5.
Insulating heat-conductive particle of the present invention is electric insulation particle, insulating heat-conductive particle electric insulation, also just says, insulating heat-conductive particle adopts electrical insulating material to make, and can avoid the insulation property affecting composite electric insulator core bar like this.
In order to not affect the performance of resin matrix, the insulating heat-conductive particle of the preferred stable chemical nature of insulating heat-conductive particle of the present invention, namely in whole composite electric insulator core bar manufacturing process, insulating heat-conductive particle does not all react with resin, glass fibre.
Preferably, described insulating heat-conductive particle is selected from one or more in metal oxide heat filling, metal nitride heat filling or carbide heat filling.
Wherein, metal oxide heat filling is preferably selected from beryllium oxide BeO, magnesium oxide MgO, alundum (Al2O3) Al
2o
3, one or more in calcium oxide CaO or nickel monoxide NiO; Metal nitride heat filling is preferably selected from aluminium nitride AlN or boron nitride BN; Carbide heat filling is preferably selected from carborundum SiC or boron carbide B
4c
3.
Preferably, with the quality of described resin matrix for benchmark, the mass fraction of described insulating heat-conductive particle is 40 ~ 80wt%.Like this, both achieved good heat conductivility, the mechanical performance of core rod of insulator can have been ensured again.
Preferably, the average grain diameter of insulating heat-conductive particle is 0.01 ~ 20 micron.
In order to make insulating heat-conductive particle form more effective thermally conductive pathways, described insulating heat-conductive particle preferably includes the first particle and the second particle.Wherein, the particle size range of the first particle is 3 ~ 20 microns, and the particle size range of described second particle is 10 ~ 25 nanometers.First particle and the second particle are filled mutually, form effective thermally conductive pathways, and then strengthen the heat conductivility of plug.
More preferably, the mass ratio of described first particle and described second particle is 1:1 ~ 1:5.Such first particle and the second particle fill to obtain consolidation more mutually, make to form more thermally conductive pathways between insulating heat-conductive particle, increase overall heat conductivility further.
In another preferred embodiment, described insulating heat-conductive particle comprises the 3rd particle and the 4th particle, and the draw ratio scope of described 3rd particle is 1/1 ~ 5/1, and the draw ratio scope of described 4th particle is 20/1 ~ 100/1.
Added by the mixing of the 3rd particle and the 4th particle, in pultrusion process, the thermal conductive contact point of plug entirety increases, thus improves the heat transfer in pultrusion process further.In addition, the mixing of the 3rd particle and the 4th particle adds the viscosity that makes glue and dispersiveness is better, more easily prepares major diameter composite electric insulator core bar.
Wherein, draw ratio refers to the most major diameter through inside particles, and with the ratio of its perpendicular most major diameter.
Preferably, the 3rd particle and the 4th particle are rod-shaped particle.
More preferably, the mass ratio of described 3rd particle and described 4th particle is 1:1.5 ~ 1:4.Thermal conductive contact point can be increased further like this, further improve the heat transfer in pultrusion process.
In order to the interface performance of reinforced insulation conductive particle, the surface of described insulating heat-conductive particle is preferable through coupling agent treatment.The interface binding power of surface treated insulating heat-conductive particle and resin adhesive liquid strengthens, thus improves the electric property of composite electric insulator core bar further.
Wherein, coupling agent is preferably selected from organo silane coupling agent.More preferably, described coupling agent is selected from γ-glycidoxypropyltrime,hoxysilane and/or γ-glycidoxypropyl group triethoxysilane.Certain coupling agent can also be other organo silane coupling agent.
The present inventor finds, the main cause that cannot realize a major diameter composite electric insulator core bar pultrusion in prior art is, substrate ring epoxy resins is slower to the conduction of heat in pultrusion process, the radius of pultrusion composite electric insulator core bar is larger, the more difficult internal delivery to composite electric insulator core bar of heat of mould, thus La get Tai can cause sticking to mould slowly, La get Tai can cause not solidifying completely in the middle of composite electric insulator core bar soon.Composite electric insulator core bar of the present invention, insulating heat-conductive particle is added with inside resin adhesive liquid, insulating heat-conductive particle can form the path of a series of transferring heat in resin adhesive liquid, thus accelerates heat conduction, and then realizes a pultrusion of major diameter composite electric insulator core bar.
Composite electric insulator core bar of the present invention, on the basis of original pultrusion molding process, what do not need change mode of heating that heat just can be allowed to transmit to center is faster, and then realize a pultrusion, with short production cycle, technological operation is simple, and solid mandrel inside does not have macroscopic interface, does not affect axial electric property.
Present invention also offers a kind of composite insulator, this composite insulator comprises composite electric insulator core bar provided by the present invention.
Above-mentioned composite insulator is owing to comprising composite electric insulator core bar provided by the present invention, and preparation technology is simple, with low cost.
Present invention also offers a kind of preparation method of composite electric insulator core bar, this preparation method comprises the steps:
Insulating heat-conductive particle is mixed with resin adhesive liquid, obtains mixed liquor;
Fibre bundle is immersed in described mixed liquor, then carry out pultrusion;
Product solidified by after pultrusion, obtains composite electric insulator core bar.
Wherein, insulating heat-conductive particle can adopt surface coupling agent process, also can adopt non-surface-treated.The present invention preferably adopts surface coupling agent process.
Wherein, surface coupling agent process preferably includes following steps: join in the insulating heat-conductive particle of 100 weight portions by 0.1 ~ 1.1 weight portion coupling agent, and 120 DEG C stir, and leaves standstill 5 ~ 10 minutes.
Preferably, the insulating heat-conductive particle of 40 ~ 80 weight portions is mixed with the resin adhesive liquid of 100 weight portions.
Preferably, 15 ~ 40min is stirred during mixing.
Fibre bundle after fibre finish is immersed in the above-mentioned mixed liquor mixed, makes fibre bundle surface all with mixed liquor, then pultrusion is carried out to it.
Preferably, draw in pultrusion process, the temperature of mixed liquor is 30 ~ 50 DEG C
Pultrusion is known in those skilled in the art, and usually, pultrusion realizes in extruder.
Be cured as known in those skilled in the art, the effect of solidification forms resin matrix,
General extruder can also be cured the product after pultrusion.That is pultrusion and these two steps of solidification can realize successively in extruder.
The pultrusion temperature of extruder adopts range selector temperature, different section different temperatures.That is in pultrusion process, each section is passed through successively.Preferably, the temperature of each section is followed successively by 85 ~ 145 DEG C, 135 ~ 185 DEG C, 145 ~ 175 DEG C.
In like manner, Post RDBMS temperature also adopts range selector temperature, and preferably, the temperature of each section is followed successively by 115 ~ 135 DEG C, 75 ~ 85 DEG C, 50 ~ 70 DEG C.
Extruded velocity is preferably 2 ~ 8cm/min.
The preparation method of composite electric insulator core bar of the present invention, owing to the addition of insulating heat-conductive particle in resin adhesive liquid, what do not need change mode of heating that heat just can be allowed to transmit to center is faster, and then realizes a pultrusion, and with short production cycle, technological operation is simple.
Below in conjunction with specific embodiment, the present invention is further elaborated.
Embodiment 1
Insulating heat-conductive particle: average grain diameter is the AlN of 5 μm.
Resin adhesive liquid: 100 parts by weight epoxy resin, 85 weight portion curing agent methyl tetrahydro phthalic anhydrides, 0.3 weight portion curing accelerator benzyl dimethylamine.
Fiber: diameter is 15 μm, line density is the glass fibre of 9600tex.
By the insulating heat-conductive particle of 50 weight portions, add in the resin adhesive liquid of 100 weight portions, stir 30min and form mixed liquor.
Mixed liquor is put into the immersion liquid groove of extruder, glass fibre is immersed the immersion liquid groove at extruder, pultrusion and solidification in extruder.
The temperature of each section of setting pultrusion is followed successively by 125 ± 15 DEG C, 150 ± 20 DEG C, 175 ± 10 DEG C, the temperature of each section of setting Post RDBMS is followed successively by 125 ± 10 DEG C, 95 ± 10 DEG C, 60 ± 10 DEG C, setting extruded velocity is 3cm/min, finally obtains composite electric insulator core bar A1.
After testing, composite electric insulator core bar A1 does not find phenomenon uncured in the middle of mucous membrane, middle cracking, edge cure.
Embodiment 2
Insulating heat-conductive particle: 100 weight portion particle diameters are the Al of 3 μm
2o
3, 200 weight portion particle diameters are the Al of 14nm
2o
3.
Resin adhesive liquid: 100 parts by weight epoxy resin, 85 weight portion curing agent methyl tetrahydro phthalic anhydrides, 0.8 weight portion curing accelerator benzyl dimethylamine.
Glass fibre: diameter is 15 μm, line density is the glass fibre of 9600tex.
By the insulating heat-conductive particle of 60 weight portions, add in the epoxy resin adhesive liquid of 100 weight portions, stir 30min and form mixed liquor.
Mixed liquor is put into the immersion liquid groove of extruder, glass fibre is immersed the immersion liquid groove at extruder, rubbish and solidification in extruder.
The temperature of each section of mould of setting pultrusion is respectively 95 ± 15 DEG C, 145 ± 20 DEG C, 160 ± 10 DEG C, and the temperature of each section of setting Post RDBMS is respectively 125 ± 10 DEG C, 95 ± 10 DEG C, 60 ± 10 DEG C, and setting extruded velocity is 5cm/min.Finally obtain composite electric insulator core bar A2.
After testing, composite electric insulator core bar A2 does not find phenomenon uncured in the middle of mucous membrane, middle cracking, edge cure.
Embodiment 3
Insulating heat-conductive particle: 100 weight portion draw ratios are the AlN of 3,150 weight portion draw ratios are the AlN of 20.
Resin adhesive liquid: 100 parts by weight epoxy resin, 85 weight portion curing agent methyl tetrahydro phthalic anhydrides, 0.8 weight portion curing accelerator benzyl dimethylamine.
Glass fibre: diameter is 15 μm, line density is the glass fibre of 9600tex.
By the insulating heat-conductive particle of 50 weight portions, add in the epoxy resin adhesive liquid of 100 weight portions, stir 30min and form mixed liquor.
Mixed liquor is put into the immersion liquid groove of extruder, glass fibre is put into the steeping vat of extruder, pultrusion and solidification in extruder.
The temperature of each section of mould of setting pultrusion is respectively 95 ± 15 DEG C, 145 ± 20 DEG C, 160 ± 10 DEG C, and the temperature of each section of setting Post RDBMS is respectively 125 ± 10 DEG C, 95 ± 10 DEG C, 60 ± 10 DEG C, and setting extruded velocity is 6cm/min.Finally obtain composite electric insulator core bar A3.
After testing, composite electric insulator core bar A3 does not find phenomenon uncured in the middle of mucous membrane, middle cracking, edge cure.
Each technical characteristic of the above embodiment can combine arbitrarily, for making description succinct, the all possible combination of each technical characteristic in above-described embodiment is not all described, but, as long as the combination of these technical characteristics does not exist contradiction, be all considered to be the scope that this specification is recorded.
The above embodiment only have expressed several execution mode of the present invention, and it describes comparatively concrete and detailed, but can not therefore be construed as limiting the scope of the patent.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection range of patent of the present invention should be as the criterion with claims.
Claims (14)
1. a composite electric insulator core bar, it comprises fibre bundle, wraps up the resin matrix of described fibre bundle and is distributed in the insulating heat-conductive particle in described resin matrix.
2. composite electric insulator core bar according to claim 1, is characterized in that, with the quality of described resin matrix for benchmark, the mass fraction of described insulating heat-conductive particle is 40 ~ 80wt%.
3. composite electric insulator core bar according to claim 1, is characterized in that, described insulating heat-conductive particle is selected from one or more in metal oxide heat filling, metal nitride heat filling or carbide heat filling.
4. composite electric insulator core bar according to claim 3, is characterized in that, described metal oxide heat filling is selected from one or more in beryllium oxide, magnesium oxide, alundum (Al2O3), calcium oxide or nickel monoxide; Described metal nitride heat filling is selected from aluminium nitride or boron nitride; Carbide heat filling is selected from carborundum or boron carbide.
5. composite electric insulator core bar according to claim 1, is characterized in that, described insulating heat-conductive particle comprises the first particle and the second particle, and the particle size range of described first particle is 3 ~ 20 microns, and the particle size range of described second particle is 10 ~ 25 nanometers.
6. composite electric insulator core bar according to claim 5, is characterized in that, the mass ratio of described first particle and described second particle is 1:1 ~ 1:5.
7. composite electric insulator core bar according to claim 1, is characterized in that, described insulating heat-conductive particle comprises the 3rd particle and the 4th particle, and the draw ratio scope of described 3rd particle is 1 ~ 5, and the draw ratio scope of described 4th particle is 20 ~ 100.
8. composite electric insulator core bar according to claim 7, is characterized in that, the mass ratio of described 3rd particle and described 4th particle is 1:1.5 ~ 1:4.
9. composite electric insulator core bar according to claim 1, is characterized in that, the surface of described insulating heat-conductive particle is with coupling layer.
10. composite electric insulator core bar according to claim 9, is characterized in that, described coupling agent is selected from γ-glycidoxypropyltrime,hoxysilane and/or γ-glycidoxypropyl group triethoxysilane.
11. composite electric insulator core bars according to claim 1, is characterized in that, the diameter of described composite electric insulator core bar is more than or equal to 110mm.
The preparation method of 12. 1 kinds of composite electric insulator core bars, it comprises the steps:
Insulating heat-conductive particle is mixed with resin adhesive liquid, obtains mixed liquor;
Fibre bundle is immersed in described mixed liquor, then carry out pultrusion;
Product solidified by after pultrusion, obtains composite electric insulator core bar.
The preparation method of 13. composite electric insulator core bars according to claim 12, is characterized in that, described preparation method also comprises and carries out coupling processing to described insulating heat-conductive particle.
14. 1 kinds of composite insulators, is characterized in that, described composite insulator comprises the composite electric insulator core bar described in any one of claim 1-11.
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| CN201510465473.3A CN105097148B (en) | 2015-07-31 | 2015-07-31 | Composite electric insulator core bar and preparation method thereof and composite insulator |
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| CN201510465473.3A CN105097148B (en) | 2015-07-31 | 2015-07-31 | Composite electric insulator core bar and preparation method thereof and composite insulator |
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| CN106495701A (en) * | 2016-10-25 | 2017-03-15 | 郑平珍 | A kind of shock resistance ceramic insulator and its manufacture method |
| CN108192286A (en) * | 2017-12-27 | 2018-06-22 | 江苏神马电力股份有限公司 | Composite insulator and preparation method thereof |
| CN113045863A (en) * | 2021-04-22 | 2021-06-29 | 襄阳银鼎电力设备有限责任公司 | Large-diameter core rod and preparation method thereof |
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| CN113045863A (en) * | 2021-04-22 | 2021-06-29 | 襄阳银鼎电力设备有限责任公司 | Large-diameter core rod and preparation method thereof |
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|---|---|
| CN105097148B (en) | 2017-03-08 |
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