CN105088953B - A kind of steel strand wires with polyurea protection coating and preparation method thereof - Google Patents

A kind of steel strand wires with polyurea protection coating and preparation method thereof Download PDF

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Publication number
CN105088953B
CN105088953B CN201510084626.XA CN201510084626A CN105088953B CN 105088953 B CN105088953 B CN 105088953B CN 201510084626 A CN201510084626 A CN 201510084626A CN 105088953 B CN105088953 B CN 105088953B
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China
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strand wires
coating
steel strand
polyurea
protection coating
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CN201510084626.XA
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CN105088953A (en
Inventor
田宝华
陈克坚
邹易清
朱敏
张义君
张强
任万敏
王起坤
覃巍巍
梁黎霞
植磊
黄永玖
闫磊
袁友
宋强
龙跃
谢正元
李文献
华剑平
邓年春
邱敏
高宁妥
李启富
卢双桂
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China Railway Eryuan Engineering Group Co Ltd CREEC
Liuzhou OVM Machinery Co Ltd
China Railway 23rd Bureau Group Co Ltd
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China Railway Eryuan Engineering Group Co Ltd CREEC
Liuzhou OVM Machinery Co Ltd
China Railway 23rd Bureau Group Co Ltd
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Abstract

A kind of steel strand wires with polyurea protection coating, it is the steel strand wires I 1 with polyurea protection coating for having one layer of polyurea protection coating formed by polyurea materials on the surface of central hair and Bian Si, I 4, or there are the steel strand wires II 1 of one layer of polyurea protection coating formed by polyurea materials the periphery on central hair and Bian Si surface and whole steel strand wires simultaneously, II 4, its preparation method is first to be formed to be twisted together again after a strata urea overcoat by surface of the polyurea protection material coated in pretreated central hair and Bian Si that steel strand wires are made, polyurea materials are coated in the steel strand wires I 1 with polyurea protection coating again, I 4 periphery, it is formed in the steel strand wires II 1 with polyurea protection coating that the periphery polyurea protection coating of whole steel strand wires is formed, II 4.Steel strand wires anti-tensile tensile strength, the pliability with polyurea protection coating that the inventive method makes are good, and damping is high, and ageing-resistant, media-resistant, wear-resisting, damping property is good;Steel strand wires antiseptic power is greatly improved, extends steel strand wires service life.

Description

A kind of steel strand wires with polyurea protection coating and preparation method thereof
Technical field
The present invention relates to a kind of anticorrosive steel strand and preparation method thereof, particularly a kind of steel strand wires with polyurea protection coating And preparation method thereof.
Background technology
Drag-line is cable-supported bridge and the core component of building, based on the bridge of engineering and the projected life of building Even more than 100 years up to 70 years, and the service life of current guy of twisted steel cable only has 20 years to 30 years, so causes cable branch Holding bridge and building needs repeatedly to change rope in use, and the cost for changing rope is high and influences to use.Therefore steel strand wires are used as The unit block steel strand wires of drag-line are, it is necessary to new structure type, it is ensured that its high-durability.
Steel strand wires are typically twisted together and formed by central hair, side silk, and the anticorrosive steel strand that oneself has at present typically has two kinds, the first It is directly to be coated with one layer of anticorrosive coat in steel strand wires outer layer, second is that the central hair and each Gen Biansi that will form steel strand wires enter respectively Steel strand wires are twisted together into after row preservative treatment or form combined anti-corrosion layer steel strand wires, anticorrosion with painting in steel strand wires outer layer coating PE layers again Steel strand wires are one of them, and it is mainly epoxy coating strand to have anticorrosion with painting steel strand wires at present, there is epoxy powder full coat Two kinds of steel loading twisted wire and appearance entirety application steel strand wires, the master operation of epoxy powder whole coating steel twisted wire preparation method be by Steel strand wires deploy, and steel strand wires is entered with open mode by spray equipment, to the central hair under open mode and Mei mono- Gen Biansi Through being heating and curing, cooling down after row application epoxy resin powder, then side silk tussled onto central hair again.
Because epoxy resin is a kind of thermosetting polymer plastics, after thermosetting, hardness is high but toughness is poor, thus above-mentioned two No matter it applies thickness or thin to kind epoxy coating strand product, there is common drawback:
1. coating is easy to crack, comes off, pin hole is also also easy to produce, thus steel strand wires are easily corroded, so as to influence making for steel strand wires Use the life-span;
2. because the coating of appearance entirety application steel strand wires is thermosets epoxy resin, make the steel strand wires after application firm Property it is big, bendability is poor, and application has aging phenomenon to epoxy resin for a long time, and its anti-wear performance is poor.
Zinc-plated in addition, the steel strand wires such as plating zinc-aluminium use the anti-corrosion method of sacrificial dielectric, are not easy by local defects such as pin holes Influence, but its coating is easily lost, therefore its service life is generally not especially long.
Polyurea materials are a kind of elastomer substances by isocyanate component and the reaction generation of amino-compound component, are divided into Pure polyureas and half polyureas, the most basic characteristic of polyureas is exactly anti-corrosion and waterproof, wear-resisting etc., is used in space industry mostly at present.
Therefore, how polyurea materials are applied in the protection of steel strand wires, make a kind of steel with polyurea protection coating and twist Line and its drag-line are the technical barriers that prestressing technique drag-line technical field people are badly in need of solving at present.
The content of the invention
It is an object of the invention to provide a kind of steel strand wires with polyurea protection coating and preparation method thereof, the band polyureas is prevented The steel strand wires for protecting coating utilize the excellent properties of polyurea materials, the antiseptic property of steel strand wires and its drag-line can be greatly improved, to prolong Long steel strand wires and its drag-line service life provides a kind of effective solution.
To solve the above problems, the technical solution adopted by the present invention is:A kind of steel strand wires with polyurea protection coating, in Heart silk, side silk are twisted to be formed, the central hair and Bian Si or the bright steel wire made of ordinary steel wire or high tensile steel wire, or There is an anti-corrosion steel wire of a protective layer in ordinary steel wire or high tensile steel wire surface attachment, it is the protective layer or epoxy coating, zinc-plated Coating, plastic coating, the surface attachment coating of anti-corrosion grease coating or oiliness wax, or by zinc-plated, plating zinc-aluminium or place of turning blue Preservative treatment layer after reason;It is characterized in that:The steel strand wires or there is one layer by polyureas material on the surface of central hair and Bian Si The steel strand wires with polyurea protection coating that the polyurea protection coating IV that material is formed is formed, including the band being made up of bright steel wire gather The steel strand wires I 1 of urea protective coating or the steel strand wires I 4 with polyurea protection coating being made up of anti-corrosion steel wire;
Its further technical scheme is:It is to be formed on central hair and Bian Si surface coated with one layer by polyurea materials Polyurea protection coating IV, in the periphery of whole steel strand wires coated with one layer of polyurea protection coating I formed by polyurea materials A kind of steel strand wires with polyurea protection coating, including the steel strand wires II 1 with polyurea protection coating that are made up of bright steel wire or The steel strand wires II 4 with polyurea protection coating being made up of anti-corrosion steel wire.
Its further technical scheme is:The steel strand wires with polyurea protection coating are in the steel with polyurea protection coating The outside integral coating of twisted wire I 1, I 4, II 1 or II 4 has the steel strand wires I 7, I 8, II 7 or II with polyurea protection coating for the band that is wrapped 8。
Further technical scheme is again for it:The steel strand wires with polyurea protection coating are in band polyurea protection Coated Steels Integrally gathered coated with one layer by what polyurea materials were formed the periphery that twisted wire I 7, I 8, II 7 or II 8 outside integral coatings have the band that is wrapped Urea protective coating II form the steel strand wires I 9 with polyurea protection coating, I 10, II 9 or II 10.
Further technical scheme is again again for it:The steel strand wires with polyurea protection coating are in band polyurea protection coating Steel strand wires I 1, I 4, II 1, II 4, I 9, I 10, II 9 or II 10 outside integral coatings have PE sheaths form band polyurea protection apply The steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or II 12 of layer.
Further:The steel strand wires with polyurea protection coating be band polyurea protection coating steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or II 12 periphery is integrally formed coated with one layer of polyurea protection coating III formed by polyurea materials Band polyurea protection coating steel strand wires I 3, I 6, II 3, II 6, I 2, I 5, II 2 or II 5.
Its related another technical scheme is:A kind of preparation method of the steel strand wires with polyurea protection coating, its feature exist In:It is that surface of the polyurea anti-corrosion material coated in pretreated central hair and Bian Si first is formed into a strata urea protective coating It is twisted together again after IV and steel strand wires is made, forms a kind of band polyureas of central hair and the Bian Si surface coated with a strata urea protective coating The steel strand wires of protective coating, including the steel strand wires I 1 with polyurea protection coating that are made up of bright steel wire or by anti-corrosion steel wire structure Into the steel strand wires I 4 with polyurea protection coating;
Its specific steps includes:
A, the steel wire with polyurea protection coating is made;B, it is twisted together shaping;
Its committed step is:A, the steel wire with polyurea protection coating is made;
The step A, make the step of steel wire with polyurea protection coating and be:
A1:Steel wire is pre-processed, dried;
A2:Polyurea materials coat process IV;
A3:Into disk, packaging;
Described A2:Polyurea materials coating process IV is that polyurea materials are passed through into Extrusion Coating, spraying, immersion pumping painting or machine Device brushing form is coated in the epoxy coating, galvanizing coating, modeling that on single bright steel wire or single anti-corrosion Steel Wire Surface is attached with On the surface attachment coating or coating for expecting coating, anti-corrosion grease coating, oiliness wax or the coat of metal, band polyurea protection coating is formed Steel wire;
In A, make the steel wire step with polyurea protection coating:Polyurea materials are passed through into Extrusion Coating, spraying, immersion pumping painting Or the specific method of machine brushing form coating is:
By single bright steel wire or the single anti-corrosion steel wire of diaphragm-have in individual wire surface attachment has been attached with it Epoxy coating, galvanizing coating, plastic coating, anti-corrosion grease coating, the surface attachment coating or coating of oiliness wax or the coat of metal Anti-corrosion steel wire, one of in the following manner hereinafter referred to as steel wire, process IV is coated by polyurea materials, i.e.,:
1. Extrusion Coating:Steel wire passes through the hot-extrudable polyurea materials of extrusion moulding type equipment;
2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel wire;
3. soak pumping painting:Steel wire is immersed in carbamide paint by pulling equipment, after immersion by export cyclic structure into Type;
4. machine painting way:Polyurea materials are made to be coated uniformly on steel wire using machine brushing;
The surface of single bright steel wire is set to coat a strata urea protective coating IV or be attached with the list of diaphragm Epoxy coating, galvanizing coating, plastic coating, anti-corrosion grease coating, oiliness wax or the metal-plated that root anti-corrosion Steel Wire Surface is attached with A strata urea protective coating IV is coated with the surface attachment coating or coating of layer, is formed by single bright steel wire and coating In the steel wire with polyurea protection coating of the composition of polyurea protection coating IV of single bright steel wire periphery or by single plain bar The steel with polyurea protection coating with compound protective coating that compound protective coating outside silk and single anti-corrosion steel wire is formed Silk, hereafter referred to collectively as:Steel wire with polyurea protection coating, including central hair and Bian Si;
B, it is twisted together shaping;Central hair with polyurea protection coating and Bian Si are twisted together into steel strand wires, including by bright steel wire The steel strand wires I 1 with polyurea protection coating formed or the steel strand wires I 4 with polyurea protection coating being made up of anti-corrosion steel wire.
The further technical scheme of the preparation method of the steel strand wires with polyurea protection coating is:Above-mentioned steps are made The steel strand wires I 1 with polyurea protection coating being made up of bright steel wire or the band polyurea protection coating being made up of anti-corrosion steel wire Steel strand wires I 4 pass through C:Polyurea materials coat process I:In the steel strand wires I 1 with polyurea protection coating or by anti-corrosion steel wire structure Into the peripheries of the steel strand wires I 4 with polyurea protection coating coat one layer of polyurea materials and form polyurea protection coating I, form whole The periphery of root steel strand wires is coated with a kind of steel strand wires II 1, II 4 with polyurea protection coating of a strata urea protective coating;
C:Polyurea materials coating process I the specific practice be:By manufactured band polyurea protection coating made of above-mentioned steps Steel strand wires I 1, I 4 one of in the following manner:
1. Extrusion Coating:Steel strand wires I 1, I 4 are passed through into the hot-extrudable polyurea materials of extrusion moulding type equipment;
2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel strand wires I 1st, on I 4;
3. soak pumping painting:Steel strand wires I 1, I 4 are immersed in carbamide paint by pulling equipment, by exporting ring-type after immersion Shaping structures;
4. machine painting way:Polyurea materials are made to be coated uniformly on steel strand wires I 1, I 4 using machine brushing;
By periphery of the polyurea materials coated in whole steel strand wires I 1, I 4, be formed in the periphery of whole steel strand wires have one layer by The steel strand wires with polyurea protection coating that the polyurea protection coating I that polyurea materials are formed is formed, including be made up of bright steel wire Steel strand wires II 1 with polyurea protection coating;Or the steel strand wires II 4 with polyurea protection coating being made up of anti-corrosion steel wire.
The further technical scheme of this method is:The steel strand wires I with polyurea protection coating that will be made through above-mentioned steps 1st, I 4, II 1 or II 4 pass through step D again:The band for being fabricated to integral coating on the outside of steel strand wires with winding working procedure and having the band that is wrapped that is wrapped gathers The steel strand wires I 7, I 8, II 7 or II 8 of urea protective coating.
This method again further technical scheme be:The steel with polyurea protection coating made through above-mentioned steps D is twisted Line I 7, I 8, II 7 or II 8 passes through E again:One of polyurea materials coat process II, i.e., in the following manner:
1. Extrusion Coating:Steel strand wires I 7, I 8, II 7 or II 8 are passed through into the hot-extrudable polyurea materials of extrusion moulding type equipment;
2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel strand wires I 7th, on I 8, II 7 or II 8;
3. soak pumping painting:Steel strand wires I 7, I 8, II 7 or II 8 are immersed in carbamide paint by pulling equipment, are led to after immersion Cross outlet ring-type shaping structures;
4. machine painting way:Polyurea materials are made to be coated uniformly on steel strand wires I 7, I 8, II 7 or II 8 using machine brushing On;
Integral coating on the outside of steel strand wires is set to have the steel strand wires I 7, I 8, II 7 for the band that is wrapped or II 8 outer surfaces attachment polyureas to prevent Protect coating II;The periphery for forming the band that is wrapped integrally is formed with poly- coated with one layer of polyurea protection coating II formed by polyurea materials The steel strand wires I 9, I 10, II 9 or II 10 of urea protective coating.
The technical scheme further again of the preparation method of the described steel strand wires with polyurea protection coating is:Step will be passed through Rapid E:The steel strand wires I 9, I 10, II 9 or II 10 with polyurea protection coating that polyurea materials coating process II makes are again through step F: PE sheath extrusion molding processes, by extrusion moulding type equipment by high-density polyethylene plastics extrusion molding in steel strand wires I 1, I 4, II 1, II 4, I 9, I 10th, II 9 or II 10 outer layer, be fabricated to integral coating on the outside of steel strand wires have PE sheaths the steel strand wires I 13 with polyurea protection coating, I 14, II 13, II 14, I 11, I 12, II 11 or II 12.
The preparation method of the described steel strand wires with polyurea protection coating again again further technical scheme be:It will pass through Step F:The steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II with polyurea protection coating that PE sheath extrusion moldings process makes 11 or II 12 pass through G again:Polyurea materials coat process III:One of i.e. in the following manner:
1. Extrusion Coating:Steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or II 12 are passed through into extrusion moulding type equipment Hot-extrudable polyurea materials;
2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel strand wires I 13rd, on I 14, II 13, II 14, I 11, I 12, II 11 or II 12;
3. soak pumping painting:Steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or II 12 are soaked by pulling equipment In carbamide paint, by exporting ring-type shaping structures after immersion;
4. machine painting way:Polyurea materials are made to be coated uniformly on steel strand wires I 13, I 14, II 13, II using machine brushing 14th, on I 11, I 12, II 11 or II 12;
Apply the periphery of steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or the PE sheaths of II 12 integral coatings Cover one layer of polyurea protection coating III formed by polyurea materials, form the steel strand wires I 3 with polyurea protection coating, I 6, II 3, II 6, Ⅰ2、Ⅰ5、Ⅱ2、Ⅱ5。
Due to taking above technical scheme, a kind of steel strand wires with polyurea protection coating of the present invention have the characteristics that and Beneficial effect:
1. polyurea coating or elastomer are the materials by isocyanate component and the reaction generation of Amino End Group compound component, Be it is external nearly ten years, it is low after high solid coating, water paint, radiation curable coating, powdery paints etc.(Nothing)Pollute application After technology, to adapt to a kind of novel solvent-free, the free of contamination green construction technology that ecological requirements are developed, developed, polyureas With performances such as excellent anti-tensile tensile strength, pliability, ageing-resistant, media-resistant, wearabilities.
Due in the steel strand wires with polyurea protection coating of the present invention, coated in steel strand wires central hair and Bian Si surroundings and filling out The polyurea materials filled in its twisted space are with being to have good waterproof, anti-coated in the outermost polyurea materials of steel strand wires Corrosive nature, adhesiveness is good, ductility and the good polyurea materials of ageing resistace, hereby it is ensured that coating will not produce pin hole, no It is easy to crack, come off, can greatly improve steel strand wires antiseptic power, extend steel strand wires service life, while do not influence the thing of steel strand wires Rationality energy.
2. the performance of existing coating or coating steel strand wires can be improved, steel strand wires antiseptic power is greatly improved, and it is resistance to increase its Mill property, extend steel strand wires service life:
Steel strand wires of the invention with polyurea protection coating are to be coated with polyurea materials in central hair and Bian Si periphery Steel strand wires with polyurea protection coating, the central hair and Bian Si or the plain bar made of ordinary steel wire or high tensile steel wire Silk, or have the anti-corrosion steel wire of a protective layer in ordinary steel wire or high tensile steel wire surface attachment, for anti-corrosion steel wire, it is Epoxy coating, galvanizing coating, plastic coating, anti-corrosion grease coating or oiliness wax etc table are attached with central hair or side silk table face Face adhering coating 4 or have by it is zinc-plated, plating zinc-aluminium or turn blue processing after preservative treatment layer 4 on, re-coating polyurea materials shape Into composite anticorrosion coating layer, it can protect the central hair of steel strand wires and side silk table face is attached with epoxy coating, plastic coating or Anti-corrosion grease coating is non-aging, can slow down galvanizing coating and easily be lost, easily influenceed by local defects such as pin holes, greatly improve this The antiseptic power of class steel strand wires, and increase its anti-wear performance, extend steel strand wires service life.
3. the polyurea protection coating wear resistance that the steel strand wires with polyurea protection coating of the present invention are made up of polyurea materials Excellent, damping is high, and damping property is good.
4. the strand structure with polyurea protection coating of the present invention is compact, frictional force is small between steel strand wires, antifatigue strong Degree improves:
The steel strand wires with polyurea protection coating of the present invention coated in steel strand wires central hair and Bian Si surroundings and being filled in The performance of polyurea protection coating of the polyurea materials with forming anticorrosive coat coated in outermost layer side silk periphery in its twisted space Excellent, therefore, polyurea protection coating need not be very thick, when they are formed into presstressed reinforcing steel, can closely be arranged between each steel strand wires Arrange, frictional force is small between compact-sized, steel strand wires, and fatigue resistance improves.
5. a kind of preparation method of steel strand wires with polyurea protection coating of the present invention is easy to operate, reasonable, solve as Polyurea materials are applied in the protection of steel strand wires by what, make a kind of technical barrier of the steel strand wires with polyurea protection coating.
Mode currently used for brushing polyureas is made for brushing by hand and equipment injection, use range for broader place Industry, because the external form profile of steel strand wires is smaller, brushing, which easily produces, by hand brushes uneven uniform and sagging phenomenon, and conventional equipment Spraying equipment is larger, and projected area is larger, larger to spraying single steel strand polyurea materials waste, and more than 90% waste of material falls. Because the film forming speed of polyureas is very fast, if manual operations is improper, spraying grasp it is inaccurate wait then easily cause coating became uneven, Apparent out-of-flatness, the problems such as aberration is big.If construction experience lacks, selection base treatment agent is improper, and basic unit is not up to construction requirement When, easily cause polyurea protection coating foaming, pinprick, layering, bond loosely phenomena such as.Painting way deficiency more than is existing As the specific method that polyurea materials are coated by Extrusion Coating or the coated form of spraying is by the inventive method:
One of by steel wire or steel strand wires in the following manner:
1. Extrusion Coating:Steel wire or steel strand wires are passed through into the hot-extrudable polyurea materials of extrusion moulding type equipment respectively;Pass through extrusion molding Formula equipment is heated the polyurea materials particle matched, makes polyurea materials abundant under extrusion moulding type equipment molten condition Reaction, passes through the hot-extrudable polyurea materials of extrusion moulding type equipment by steel wire or steel strand wires;
2. spray:By equipment temperature-pressure, raw material mixed at nozzle after by lance ejection polyurea materials to steel wire or On steel strand wires;Emitted dose is controlled by machine nozzle, is uniformly extruded onto Steel Wire Surface, can effectively control polyureas thick layer, Can be according to the characteristics of steel wire small volume, the spraying equipment of ring-like or small hole nozzle is researched and developed in special design, in the production of streamline Even application reduces the waste rate of material in Steel Wire Surface on line:
3. soak pumping painting:Steel wire or steel strand wires are immersed in carbamide paint by pulling equipment, pass through outlet after immersion Cyclic structure is molded;Steel wire or steel strand wires are immersed in carbamide paint by pulling equipment drag-line, make its soak after by going out Choma shape shaping structures, can be coated uniformly on steel strand wires;
4. machine painting way:Polyurea materials are brushed on steel wire or steel strand wires by machine;It is automatic using machinery equipment Changing brushing function makes polyurea materials be coated uniformly on steel wire or steel strand wires.
It is current by way of extrusion moulding type equipment Extrusion Coating, the spraying of ring-like or aperture, immersion pumping painting or machine brushing In the market the change of spraying method, polyureas is not only accurately controlled to the steel wire of small volume without the spraying method occurred Thickness, and prevent the waste of material.
Below, in conjunction with the accompanying drawings and embodiments to a kind of steel strand wires with polyurea protection coating of the present invention and preparation method thereof Technical characteristic be further described.
Brief description of the drawings
Fig. 1-1~Fig. 1-3, Fig. 1-4~Fig. 1-6 are the surface coatings of a kind of central hair and Bian Si of the embodiment of the present invention one There is the structural representation of the steel strand wires with polyurea protection coating of a strata urea protective coating, wherein:
Fig. 1-1:Central hair and Bian Si are bright steel wire, have one layer to be formed by polyurea materials on the surface of central hair and Bian Si Polyurea protection coating IV form the steel strand wires I 1 with polyurea protection coating:
Fig. 1-2:It is wrapped band in the outside integral coating of steel strand wires I 1, the band outer application that is wrapped has polyurea protection coating II, Extrusion molding has PE sheaths again, and PE sheath outer applications have the steel strand wires I 2 with polyurea protection coating of polyurea protection coating III;
Fig. 1-3:There are PE sheaths in the outside integral extrusion of steel strand wires I 1, PE sheath outer applications have polyurea protection coating III The steel strand wires I 3 with polyurea protection coating;
Fig. 1-4:Central hair and Bian Si are anti-corrosion steel wire, have one layer to be formed by polyurea materials on the surface of central hair and Bian Si Polyurea protection coating IV form the steel strand wires I 4 with polyurea protection coating;
Fig. 1-5:It is wrapped band in the outside integral coating of steel strand wires I 4, the band outer application that is wrapped has polyurea protection coating II, Extrusion molding has PE sheaths again, and PE sheath outer applications have the steel strand wires I 5 with polyurea protection coating of polyurea protection coating III;
Fig. 1-6:There are PE sheaths in the outside integral extrusion of steel strand wires I 4, PE sheath outer applications have polyurea protection coating III The steel strand wires I 6 with polyurea protection coating.
Fig. 1-7~Fig. 1-14 is become based on the steel strand wires I 1, I 4 with polyurea protection coating of the embodiment of the present invention one The strand structure schematic diagram with polyurea protection coating to swap out, wherein:
Fig. 1-7:The outside integral coating of steel strand wires I 1 is wrapped the steel strand wires I 7 with polyurea protection coating of band;
Fig. 1-8:The outside integral coating of steel strand wires I 4 is wrapped the steel strand wires I 8 with polyurea protection coating of band;
Fig. 1-9:In the steel with polyurea protection coating that has polyurea protection coating II with outer application of being wrapped of steel strand wires I 7 Twisted wire I 9;
Fig. 1-10:In the steel with polyurea protection coating that has polyurea protection coating II with outer application of being wrapped of steel strand wires I 8 Twisted wire I 10;
Fig. 1-11:In the steel strand wires I 11 with polyurea protection coating that have PE sheaths with outside extrusion molding of being wrapped of steel strand wires I 9;
Fig. 1-12;In the steel strand wires I with polyurea protection coating that have PE sheaths with outside extrusion molding of being wrapped of steel strand wires I 10 12;
Fig. 1-13:There are the steel strand wires I 13 with polyurea protection coating of PE sheaths in the outside extrusion molding of steel strand wires I 1;
Fig. 1-14:There are the steel strand wires I 14 with polyurea protection coating of PE sheaths in the outside extrusion molding of steel strand wires I 4.
Fig. 2-1~Fig. 2-3, Fig. 2-4~Fig. 2-6 are the embodiment of the present invention two on central hair and Bian Si surface and whole The periphery of root steel strand wires is coated with the structural representation of the steel strand wires with polyurea protection coating of polyurea protection coating simultaneously;Its In:
Fig. 2-1:Central hair and Bian Si are bright steel wire, in the periphery on central hair and Bian Si surface and whole steel strand wires The steel strand wires II 1 with polyurea protection coating formed simultaneously coated with polyurea protection coating:
Fig. 2-2:It is wrapped band in the outside integral coating of steel strand wires II 1, the band outer application that is wrapped has polyurea protection coating II, Extrusion molding has PE sheaths again, and PE sheath outer applications have the steel strand wires II 2 with polyurea protection coating of polyurea protection coating III;
Fig. 2-3:There are PE sheaths in the outside integral extrusion of steel strand wires II 1, PE sheath outer applications have polyurea protection coating III steel strand wires II 3 with polyurea protection coating;
Fig. 2-4:Central hair and Bian Si are anti-corrosion steel wire, in the periphery on central hair and Bian Si surface and whole steel strand wires The steel strand wires II 4 with polyurea protection coating formed simultaneously coated with polyurea protection coating;
Fig. 2-5:It is wrapped band in the outside integral coating of steel strand wires II 4, the band outer application that is wrapped has polyurea protection coating II, Extrusion molding has PE sheaths again, and PE sheath outer applications have the steel strand wires II 5 with polyurea protection coating of polyurea protection coating III;
Fig. 2-6:There are PE sheaths in the outside integral extrusion of steel strand wires II 4, PE sheath outer applications have polyurea protection coating III steel strand wires II 6 with polyurea protection coating.
Fig. 2-7~Fig. 2-14 is based on the steel strand wires II 1, II 4 with polyurea protection coating of the embodiment of the present invention two Become the strand structure schematic diagram with polyurea protection coating to swap out, wherein:
Fig. 2-7:Be wrapped the steel strand wires II 7 with polyurea protection coating of band in the outside integral coating of steel strand wires II 1;
Fig. 2-8:Be wrapped the steel strand wires II 8 with polyurea protection coating of band in the outside integral coating of steel strand wires II 4;
Fig. 2-9:In the steel with polyurea protection coating that has polyurea protection coating II with outer application of being wrapped of steel strand wires II 7 Twisted wire II 9;
Fig. 2-10:Steel strand wires II 8 be wrapped with outer application have polyurea protection coating II with polyurea protection coating Steel strand wires II 10;
Fig. 2-11:In the steel strand wires II with polyurea protection coating that have PE sheaths with outside extrusion molding of being wrapped of steel strand wires II 9 11;
Fig. 2-12;In the steel strand wires II with polyurea protection coating that have PE sheaths with outside extrusion molding of being wrapped of steel strand wires II 10 12;
Fig. 2-13:There are the steel strand wires II 13 with polyurea protection coating of PE sheaths in the outside extrusion molding of steel strand wires II 1;
Fig. 2-14;There are the steel strand wires II 14 with polyurea protection coating of PE sheaths in the outside extrusion molding of steel strand wires II 4.
In figure:
1- central hairs, 2- sides silk, 31a- polyurea protections coating I, 31b- polyurea protections coating II, 31c- polyurea protection coatings III, 31d- polyurea protection coating IV, 4- protective layers, 5- are wrapped band, 6-PE sheaths.
(One)A kind of surface of central hair and Bian Si is coated with the steel with polyurea protection coating of a strata urea protective coating Twisted wire,
101- central hairs and the steel strand wires I 1 with polyurea protection coating that Bian Si is bright steel wire;
102- is wrapped band in the outside integral coating of steel strand wires I 1, and the band outer application that is wrapped has polyurea coating, then extrusion molding has PE sheaths, PE sheath outer applications have the steel strand wires I 2 with polyurea protection coating of polyurea coating;
103- has PE sheaths in the outside integral extrusion of steel strand wires I 1, and PE sheath outer applications have the band polyureas of polyurea coating The steel strand wires I 3 of protective coating;
104- central hairs and the steel strand wires I 4 with polyurea protection coating that Bian Si is anti-corrosion steel wire;
105- is wrapped band in the outside integral coating of steel strand wires I 4, and the band outer application that is wrapped has polyurea coating, then extrusion molding has PE sheaths, PE sheath outer applications have the steel strand wires I 5 with polyurea protection coating of polyurea coating;
106- has PE sheaths in the outside integral extrusion of steel strand wires I 4, and PE sheath outer applications have the band polyureas of polyurea coating The steel strand wires I 6 of protective coating.
107- is wrapped the steel strand wires I 7 with polyurea protection coating of band in the outside integral coating of steel strand wires I 1;
108- is wrapped the steel strand wires I 8 with polyurea protection coating of band in the outside integral coating of steel strand wires I 4;
109- twists in the steel with polyurea protection coating that has polyurea protection coating II with outer application of being wrapped of steel strand wires I 7 Line I 9;
110- twists in the steel with polyurea protection coating that has polyurea protection coating II with outer application of being wrapped of steel strand wires I 8 Line I 10;
The be wrapped steel strand wires I 11 with polyurea protection coating that with outside extrusion molding have PE sheath of the 111- in steel strand wires I 9;
The be wrapped steel strand wires I 12 with polyurea protection coating that with outside extrusion molding have PE sheath of the 112- in steel strand wires I 10;
113- has the steel strand wires I 13 with polyurea protection coating of PE sheaths in the outside extrusion molding of steel strand wires I 1;
114- has the steel strand wires I 14 with polyurea protection coating of PE sheaths in the outside extrusion molding of steel strand wires I 4.
(Two)The surface of a kind of central hair and Bian Si and the periphery of whole steel strand wires are coated with polyurea protection coating simultaneously The steel strand wires with polyurea protection coating:
201- central hairs and the steel strand wires II 1 with polyurea protection coating that Bian Si is bright steel wire;
202- is wrapped band in the outside integral coating of steel strand wires II 1, and the band outer application that is wrapped has polyurea coating, then extrusion molding has PE sheaths, PE sheath outer applications have the steel strand wires II 2 with polyurea protection coating of polyurea coating;
203- has PE sheaths in the outside integral extrusion of steel strand wires II 1, and the band that PE sheath outer applications have polyurea coating gathers The steel strand wires II 3 of urea protective coating;
204- central hairs and the steel strand wires II 4 with polyurea protection coating that Bian Si is anti-corrosion steel wire;
205- is wrapped band in the outside integral coating of steel strand wires II 4, and the band outer application that is wrapped has polyurea coating, then extrusion molding has PE sheaths, PE sheath outer applications have the steel strand wires II 5 with polyurea protection coating of polyurea coating;
206- has PE sheaths in the outside integral extrusion of steel strand wires II 4, and the band that PE sheath outer applications have polyurea coating gathers The steel strand wires II 6 of urea protective coating.
207- is wrapped the steel strand wires II 7 with polyurea protection coating of band in the outside integral coating of steel strand wires II 1;
208- is wrapped the steel strand wires II 8 with polyurea protection coating of band in the outside integral coating of steel strand wires II 4;
209- twists in the steel with polyurea protection coating that has polyurea protection coating II with outer application of being wrapped of steel strand wires II 7 Line II 9;
210- twists in the steel with polyurea protection coating that has polyurea protection coating II with outer application of being wrapped of steel strand wires II 8 Line II 10;
The be wrapped steel strand wires II 11 with polyurea protection coating that with outside extrusion molding have PE sheath of the 211- in steel strand wires II 9;
The be wrapped steel strand wires II 12 with polyurea protection coating that with outside extrusion molding have PE sheath of the 212- in steel strand wires II 10;
213- has the steel strand wires II 13 with polyurea protection coating of PE sheaths in the outside extrusion molding of steel strand wires II 1;
214- has the steel strand wires II 14 with polyurea protection coating of PE sheaths in the outside extrusion molding of steel strand wires II 4.
Embodiment
Embodiment one
A kind of surface of central hair and Bian Si twists coated with steel of the 31d of a strata urea protective coating IV with polyurea protection coating Line, it is twisted together and is formed by central hair 1, side silk 2, the central hair and Bian Si are the plain bars made of ordinary steel wire or high tensile steel wire Silk, the steel strand wires are to be coated with one layer of polyurea protection coating IV formed by polyurea materials on central hair 1 and Bian Si 2 surface 31d, i.e., a kind of steel strand wires I 1 with polyurea protection coating shown in Fig. 1-1.
As the conversion of the embodiment of the present invention one, including:
The band 5 1. the outside integral coating of steel strand wires I 1 with polyurea protection coating is wrapped, be wrapped the overall coating in the outside of band 5 Have the 31b of a strata urea protective coating II, then PE sheaths 6 be coated with the outside of entirety, the outside of PE sheaths 6 it is overall coated with one layer by The steel strand wires I with polyurea protection coating a kind of as shown in Figure 1-2 that the 31c of polyurea protection coating III that polyurea materials are formed is formed 2;
Or the outside integral coating of steel strand wires I 1 with polyurea protection coating has a PE sheaths 6, the outside of PE sheaths 6 have one layer by A kind of steel strand wires with polyurea protection coating as Suo Shi Fig. 1-3 that the 31c of polyurea protection coating III that polyurea materials are formed is formed Ⅰ3。
2. the central hair 1 and Bian Si 2 that form a kind of steel strand wires with polyurea protection coating are in ordinary steel wire or high-strength Steel Wire Surface is attached with the anti-corrosion steel wire of a protective layer 4, i.e. a kind of steel strand wires I 4 with polyurea protection coating shown in Fig. 1-4, The protective layer 4 or epoxy coating, galvanizing coating, plastic coating, the surface attachment coating of anti-corrosion grease coating or oiliness wax, Or the preservative treatment layer after zinc-plated, plating zinc-aluminium or processing of turning blue.
3. a kind of Fig. 1-4 outside integral coating of steel strand wires I 4 with polyurea protection coating is wrapped band 5, be wrapped band 5 Outside is integrally coated with the 31b of a strata urea protective coating II, then PE sheaths 6 are coated with the outside of entirety, and the outside of PE sheaths 6 is overall The steel strand wires I 5 with polyurea protection coating a kind of as Figure 1-5 formed coated with the 31c of a strata urea protective coating III;
Or there are PE sheaths 6, PE sheaths 6 in a kind of Fig. 1-4 outside integral coating of steel strand wires I 4 with polyurea protection coating Outside is integrally coated with a kind of steel strand wires I with polyurea protection coating shown in a strata urea protective coating III 31c, i.e. Fig. 1-6 6。
Embodiment two
The surface of a kind of central hair and Bian Si and the periphery of whole steel strand wires are coated with the band of polyurea protection coating simultaneously The steel strand wires of polyurea protection coating, it is twisted together and is formed by central hair 1, side silk 2, the central hair and Bian Si are by ordinary steel wire or height Bright steel wire made of strong steel wire, the steel strand wires are to be coated with to be gathered by what polyurea materials were formed on central hair and Bian Si surface The 31d of urea protective coating IV at the same in the periphery of whole steel strand wires coated with polyurea protection coating I 31a, i.e., one shown in Fig. 2-1 Steel strand wires II 1 of the kind with polyurea protection coating.
As the conversion of the embodiment of the present invention two, including:
1. integral coating is wrapped band 5 on the outside of the steel strand wires with polyurea protection coating, being wrapped, the outside of band 5 is overall to be coated with The 31b of one strata urea protective coating II, then PE sheaths 6 are coated with the outside of entirety, the outside of PE sheaths 6 is overall to be coated with one layer by gathering A kind of steel strand wires II 2 with polyurea protection coating shown in polyurea protection coating III 31c, i.e. Fig. 2-2 that urea material is formed;
Or integral coating has PE sheaths 6 on the outside of the steel strand wires with polyurea protection coating, the outside of PE sheaths 6 is overall to be coated with A kind of steel strand wires with polyurea protection coating shown one layer of polyurea protection coating III 31c, i.e. Fig. 2-3 formed by polyurea materials Ⅱ3。
2. the central hair 1 and Bian Si 2 that form a kind of steel strand wires with polyurea protection coating are in ordinary steel wire or high-strength The steel with polyurea protection coating a kind of as in Figure 2-4 that the anti-corrosion steel wire that Steel Wire Surface is attached with a protective layer 4 is formed twists Line II 4, the protective layer 4 or epoxy coating, galvanizing coating, plastic coating, the surface of anti-corrosion grease coating or oiliness wax are attached Coating, or the preservative treatment layer after zinc-plated, plating zinc-aluminium or processing of turning blue.
3. a kind of Fig. 2-4 outside integral coating of steel strand wires II 4 with polyurea protection coating is wrapped band 5, be wrapped band 5 Outside is integrally coated with the 31b of a strata urea protective coating II, then PE sheaths 6 are coated with the outside of entirety, and the outside of PE sheaths 6 is overall Coated with a kind of one layer of the polyurea protection coating III formed by polyurea materials 31c, i.e. Fig. 2-5 Suo Shi with polyurea protection coating Steel strand wires II 5;
Or there are PE sheaths 6, PE sheaths 6 in a kind of Fig. 2-4 outside integral coating of steel strand wires II 4 with polyurea protection coating Integrally prevent coated with one kind band polyureas shown in one layer of polyurea protection coating III 31c, i.e. Fig. 2-6 formed by polyurea materials in outside Protect the steel strand wires II 6 of coating.
One~embodiment of above-described embodiment two only lists the structure of conventional several steel strand wires with polyurea protection coating Form, can according to the actual needs, using a kind of central hair and Bian Si described in embodiment one in implementation process of the present invention Surface be coated with the 31d of a strata urea protective coating IV the steel strand wires I 1 or I 4 with polyurea protection coating;Or embodiment two The surface of a kind of central hair and Bian Si and the periphery of whole steel strand wires are coated with the band polyureas of polyurea protection coating simultaneously The steel strand wires II 1 or II 4 of protective coating are basic structure;Plus the band 5 that is wrapped on the outside of these basic structures, or again in the band that is wrapped Outside extrusion molding PE sheaths 6;Or the extrusion molding PE sheaths 6 directly on the outside of this basic structure, form various combination, there is multiple protective knot The various steel strand wires with polyurea protection coating of structure.
Such as:For embodiment one, including:
Outside integral coating shown in Fig. 1-7 in steel strand wires I 1 is wrapped the 7- of steel strand wires I with polyurea protection coating of band 107;
Outside integral coating shown in Fig. 1-8 in steel strand wires I 4 is wrapped the 8- of steel strand wires I with polyurea protection coating of band 108;
Shown in Fig. 1-9 steel strand wires I 7 be wrapped with outer application have polyurea protection coating II with polyurea protection coating The 9-109 of steel strand wires I;
In the band polyurea protection coating that has polyurea protection coating II with outer application of being wrapped of steel strand wires I 8 shown in Fig. 1-10 The 10-110 of steel strand wires I;
In the steel strand wires I with polyurea protection coating that have PE sheaths with outside extrusion molding of being wrapped of steel strand wires I 9 shown in Fig. 1-11 11-111;
In the steel strand wires with polyurea protection coating that have PE sheaths with outside extrusion molding of being wrapped of steel strand wires I 10 shown in Fig. 1-12 Ⅰ12-112;
The shown outside extrusion moldings in steel strand wires I 1 of Fig. 1-13 have the 13- of steel strand wires I with polyurea protection coating of PE sheaths 113;
The shown outside extrusion moldings in steel strand wires I 4 of Fig. 1-14 have the 14- of steel strand wires I with polyurea protection coating of PE sheaths 114。
For embodiment two, including:
Outside integral coating shown in Fig. 2-7 in steel strand wires II 1 is wrapped the 7- of steel strand wires II with polyurea protection coating of band 207;
Outside integral coating shown in Fig. 2-8 in steel strand wires II 4 is wrapped the 8- of steel strand wires II with polyurea protection coating of band 208;
In the band polyurea protection coating that has polyurea protection coating II with outer application of being wrapped of steel strand wires II 7 shown in Fig. 2-9 The 9-209 of steel strand wires II;
In the band polyurea protection coating that has polyurea protection coating II with outer application of being wrapped of steel strand wires II 8 shown in Fig. 2-10 The 10-210 of steel strand wires II;
In the steel strand wires with polyurea protection coating that have PE sheaths with outside extrusion molding of being wrapped of steel strand wires II 9 shown in Fig. 2-11 Ⅱ11-211;
The steel with polyurea protection coating that has PE sheaths with outside extrusion molding of being wrapped shown in Fig. 2-12 in steel strand wires II 10 twists The 12-212 of line II;
The shown outside extrusion moldings in steel strand wires II 1 of Fig. 2-13 have the 13- of steel strand wires II with polyurea protection coating of PE sheaths 213;
The shown outside extrusion moldings in steel strand wires II 4 of Fig. 2-14 have the 14- of steel strand wires II with polyurea protection coating of PE sheaths 214。
Embodiment three
Prevent coated with the 31d of a strata urea protective coating IV band polyureas on a kind of surface of central hair and Bian Si described in embodiment one The preparation method for protecting the steel strand wires of coating.
This method is that surface of the polyurea anti-corrosion material coated in pretreated central hair 1 and Bian Si 2 first is formed into one layer It is twisted together again after the 31d of polyurea protection coating IV and steel strand wires is made, the surface for forming central hair and Bian Si is coated with one layer of polyurea protection A kind of steel strand wires with polyurea protection coating of coating, including the steel strand wires I 1 with polyurea protection coating being made up of bright steel wire Or the steel strand wires I 4 with polyurea protection coating being made up of anti-corrosion steel wire;
Its specific steps includes:A, the steel wire with polyurea protection coating is made;B, it is twisted together shaping;
Its committed step is:A, the steel wire with polyurea protection coating is made;
The step A, make the step of steel wire with polyurea protection coating and be:
A1:Steel wire is pre-processed, dried;
A2:Polyurea materials coat process IV;
A3:Into disk, packaging;
Described A2:Polyurea materials coating process IV is that polyurea materials are passed through into Extrusion Coating, spraying, immersion pumping painting or machine Device brushing form is coated in the epoxy coating, galvanizing coating, modeling that on single bright steel wire or single anti-corrosion Steel Wire Surface is attached with On the surface attachment coating or coating for expecting coating, anti-corrosion grease coating, oiliness wax or the coat of metal, band polyurea protection coating is formed Steel wire;
In A, make the steel wire step with polyurea protection coating:Polyurea materials are passed through into Extrusion Coating, spraying, immersion pumping painting Or the specific method of machine brushing form coating is:
By single bright steel wire or the individual wire of diaphragm-have epoxy in individual wire surface attachment has been attached with it Coating, galvanizing coating, plastic coating, anti-corrosion grease coating, oiliness wax or the surface attachment coating of the coat of metal or preventing for coating One of rotten steel wire, hereinafter referred to as steel wire, process IV is coated by polyurea materials, i.e., in the following manner:
1. Extrusion Coating:Steel wire passes through the hot-extrudable polyurea materials of extrusion moulding type equipment;
2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel wire;
3. soak pumping painting:Steel wire is immersed in carbamide paint by pulling equipment, after immersion by export cyclic structure into Type;
4. machine painting way:Polyurea materials are made to be coated uniformly on steel wire using machine brushing;
The surface of single bright steel wire is set to coat the 31d of a strata urea protective coating IV or be attached with diaphragm Epoxy coating, galvanizing coating, plastic coating, anti-corrosion grease coating, oiliness wax or the metal that single anti-corrosion Steel Wire Surface is attached with The 31d of a strata urea protective coating IV is coated with the surface attachment coating or coating of coating, formed by single bright steel wire and The steel wire with polyurea protection coating that the 31d of polyurea protection coating IV coated in single bright steel wire periphery is formed or by list The band polyurea protection with compound protective coating that compound protective coating outside root bright steel wire and single bright steel wire is formed The anti-corrosion steel wire of coating, hereafter referred to collectively as:Steel wire with polyurea protection coating, including central hair 1 and Bian Si 2;
B, it is twisted together shaping;Central hair 1 and Bian Si 2 with polyurea protection coating are twisted together into steel strand wires, including by bright steel wire The steel strand wires I 1 with polyurea protection coating formed(Referring to Fig. 1-1)Or by anti-corrosion steel wire form with polyurea protection coating Steel strand wires I 4(Referring to Fig. 1-4).
Example IV
The surface of a kind of central hair and Bian Si described in embodiment two and the periphery of whole steel strand wires are coated with polyureas simultaneously The preparation method of the steel strand wires with polyurea protection coating of protective coating:
Steel strand wires I 1 with polyurea protection coating being made up of bright steel wire that embodiment three is made or by anticorrosive steel The steel strand wires I 4 with polyurea protection coating that silk is formed pass through C again:Polyurea materials coat process I:With polyurea protection coating The periphery of steel strand wires I 1 or the steel strand wires I 4 with polyurea protection coating being made up of anti-corrosion steel wire coats one layer of polyurea materials shape Into the 31a of polyurea protection coating I, a kind of band polyurea protection of the periphery of whole steel strand wires coated with a strata urea protective coating is formed The steel strand wires of coating, including the steel strand wires II 1 with polyurea protection coating being made up of bright steel wire(Referring to Fig. 2-1)Or by preventing The steel strand wires II 4 with polyurea protection coating that rotten steel wire is formed(Referring to Fig. 2-4).
The C:Polyurea materials coat process I:Comprise the concrete steps that:Steel strand wires I 1, I 4 with polyurea protection coating are passed through One of in the following manner:
1. Extrusion Coating:Steel strand wires I 1, I 4 are passed through into the hot-extrudable polyurea materials of extrusion moulding type equipment;
2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel strand wires I 1st, on I 4;
3. soak pumping painting:Steel strand wires I 1, I 4 are immersed in carbamide paint by pulling equipment, by exporting ring-type after immersion Shaping structures;
4. machine painting way:Polyurea materials are made to be coated uniformly on steel strand wires I 1, I 4 using machine brushing;
By periphery of the polyurea materials coated in whole steel strand wires I 1, I 4, be formed in the periphery of whole steel strand wires have one layer by The steel strand wires with polyurea protection coating that the 31a of polyurea protection coating I that polyurea materials are formed is formed, including by bright steel wire structure Into the steel strand wires II 1 with polyurea protection coating;Or the steel strand wires II 4 with polyurea protection coating being made up of anti-corrosion steel wire.
Embodiment five:
Become the band polyurea protection to swap out based on the steel strand wires with polyurea protection coating described in embodiment one, embodiment two The preparation method of the steel strand wires of coating:
(One)The steel strand wires I 1, I 4, II 1 or II 4 with polyurea protection coating that embodiment three, example IV are made pass through again Cross step D:The steel with polyurea protection coating for being fabricated to integral coating on the outside of steel strand wires with winding working procedure and having the band 5 that is wrapped that is wrapped twists Line I 7, I 8, II 7 or II 8(Referring to Fig. 1-7, Fig. 1-8, Fig. 2-7, Fig. 2-8).
(Two)By above-mentioned through step D:Be wrapped a kind of steel strand wires I 7, I with polyurea protection coating made with winding working procedure 8th, II 7 or II 8 pass through E again:One of polyurea materials coat process II, i.e., in the following manner:
1. Extrusion Coating:Steel strand wires I 7, I 8, II 7 or II 8 are passed through into the hot-extrudable polyurea materials of extrusion moulding type equipment;
2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel strand wires I 7th, on I 8, II 7 or II 8;
3. soak pumping painting:Steel strand wires I 7, I 8, II 7 or II 8 are immersed in carbamide paint by pulling equipment, are led to after immersion Cross outlet ring-type shaping structures;
4. machine painting way:Polyurea materials are made to be coated uniformly on steel strand wires I 7, I 8, II 7 or II 8 using machine brushing On;
The outer surface that integral coating there are the steel strand wires I 7, I 8, II 7 or II 8 for the band 5 that is wrapped on the outside of steel strand wires is set to adhere to polyureas The 31b of protective coating II;The periphery for forming the band 5 that is wrapped integrally is coated with one layer of polyurea protection coating II formed by polyurea materials 31b forms the steel strand wires I 9, I 10, II 9 or II 10 with polyurea protection coating(Referring to Fig. 1-9, Fig. 1-10, Fig. 2-9, Fig. 2-10).
(Three)Steel strand wires I 1, I 4, II 1, II 4 with polyurea protection coating that embodiment three, example IV are made and Embodiment 5(One),(Two)The steel strand wires I 9, I 10, II 9 or II 10 with polyurea protection coating that step is made are again through step F:PE sheath extrusion molding processes, by extrusion moulding type equipment by high-density polyethylene plastics extrusion molding in steel strand wires I 1, I 4, II 1, II 4, I 9th, I 10, II 9 or II 10 outer layer, being fabricated to integral coating on the outside of steel strand wires has the steel strand wires with polyurea protection coating of PE sheaths 6 I 13, I 14, II 13, II 14, I 11, I 12, II 11 or II 12(Referring to Fig. 1-13, Fig. 1-14, Fig. 2-13, Fig. 2-14, Fig. 1-11, Fig. 1-12, Fig. 2-11, Fig. 2-12).
(Four)By embodiment 5(Three)The steel strand wires I 13, I 14, II 13, II 14, I with polyurea protection coating made 11st, I 12, II 11 or II 12 pass through G again:Polyurea materials coat process III:One of i.e. in the following manner:
1. Extrusion Coating:Steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or II 12 are passed through into extrusion moulding type equipment Hot-extrudable polyurea materials;
2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel strand wires I 13rd, on I 14, II 13, II 14, I 11, I 12, II 11 or II 12;
3. soak pumping painting:Steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or II 12 are soaked by pulling equipment In carbamide paint, by exporting ring-type shaping structures after immersion;
4. machine painting way:Polyurea materials are made to be coated uniformly on steel strand wires I 13, I 14, II 13, II using machine brushing 14th, on I 11, I 12, II 11 or II 12;
Apply the periphery of steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or the PE sheaths 6 of II 12 integral coatings Cover one layer of 31c of polyurea protection coating III formed by polyurea materials, form the steel strand wires I 3 with polyurea protection coating, I 6, II 3, Ⅱ6、Ⅰ2、Ⅰ5、Ⅱ2、Ⅱ5(Referring to Fig. 1-3, Fig. 1-6, Fig. 2-3, Fig. 2-6, Fig. 1-2, Fig. 1-5, Fig. 2-2, Fig. 2-5).
In one~embodiment of above-described embodiment five, the material of used polyurea anti-corrosion material and polyurea protection coating It is pure polyurea materials or half polyurea materials;Including following three types:
1)Aromatic polyureas, the polyureas are to utilize aromatic isocyanate(Such as MDI, liquefied mdi, PAPI)Gather with amino Ether, amino chain extender reaction form, and have the advantages that intensity is high, and price is more reasonable, the material for being useful in anti-corrosion, wear-resisting etc. is prevented Shield.
2)Aliphatic polyurea, the polyureas are to utilize aliphatic isocyanates(Tripolymer, HMDI, TMXDI such as HDI, HDI Deng)Prepared with amino-polyether, alicyclic ring amine chain extender reaction, there is color inhibition, good anti-corrosion property energy, excellent colour retention It can wait, for the decoration finish paint of outdoor architecture, be also used as the sealer of aromatic polyureas coating.
3)Polyaspartic Polyurea, the polyureas are to utilize aliphatic isocyanates and polyaspartic ester reaction system Standby, the reaction speed of coating is adjustable, and gel time can be from a few minutes to a few houres.It may be used at HTHP impacting type In hybird environment, have and be not easy to foam in low-temperature setting, coating not yellowing, solidification process, thick can apply construction, the attachment to ground The advantages that power is good.
Depending on the needs of construction, involved carbamide paint can be that polyurea water-proof applies for the selection of carbamide paint Material, polyurea anti-corrosion coating, polyureas damping coating, polyureas surface coating, polyureas subbing, polyureas filling paint, polyureas are wear-resisting Coating, polyureas antiskid coating etc..
It is by taking the HDPE sheaths that high density polyethylene (HDPE) makes as an example, as the embodiment of the present invention in various embodiments of the present invention A kind of conversion, the HDPE sheaths can also be the PE shields made using common low density polyethylene (LDPE), medium density polyethylene Set or other sheaths for being suitable to make material making such as rubber of bridge cable sheath for building, these are all equally to put Change, and the protection domain of this patent.
In various embodiments of the present invention, described " central hair and Bian Si or the light made of ordinary steel wire or high tensile steel wire Face steel wire, or have the anti-corrosion steel wire of a protective layer in ordinary steel wire or high tensile steel wire surface attachment " both included directly from market The ordinary steel wire of upper purchase, high tensile steel wire or there is the anticorrosive steel of a protective layer in ordinary steel wire or high tensile steel wire surface attachment Silk;Also the bright steel wire obtained after being broken up by common steel strand wires or high strength steel strand is included, or in common steel strand wires or high-strength The bright steel wire surface attachment that steel strand wires obtain after breaing up has the anti-corrosion steel wire of a protective layer 4 or the steel made of anti-corrosion steel wire Twisted wire breaks up the anti-corrosion steel wire of acquisition;Its production process is:" steel strand wires are broken up-coated or fill polyurea materials-steel strand wires and are twisted together Outer layer, which is made, in recovery the steel strand wires of polyurea protection material.
It is all known technology to be twisted together on the preconditioning technique of steel wire and by the steel wire after processing and steel strand wires are made, Here is omitted.

Claims (6)

  1. A kind of 1. preparation method of the steel strand wires with polyurea protection coating, it is characterised in that:It is first to apply polyurea anti-corrosion material Overlay on pretreated central hair(1)With side silk(2)Surface formed a strata urea protective coating IV(31d )It is twisted together system again afterwards Into steel strand wires, central hair and a kind of Bian Si steel with polyurea protection coating of the surface coated with a strata urea protective coating are formed Twisted wire, including prevented by the bright steel wire steel strand wires I 1 with polyurea protection coating formed or the band polyureas being made up of anti-corrosion steel wire Protect the steel strand wires I 4 of coating;
    Its specific steps includes:A, the steel wire with polyurea protection coating is made;B, it is twisted together shaping;
    Its committed step is:A, the steel wire with polyurea protection coating is made;
    The step A, make the step of steel wire with polyurea protection coating and be:
    A1:Steel wire is pre-processed, dried;
    A2:Polyurea materials coat process IV;
    A3:Into disk, packaging;
    Described A2:Polyurea materials coating process IV is to apply polyurea materials by Extrusion Coating, spraying, immersion pumping painting or machine Scopiform formula is coated in the epoxy coating, galvanizing coating, plastics that on single bright steel wire or single bright steel wire surface attachment has and applied On the surface attachment coating or coating of layer, anti-corrosion grease coating, oiliness wax or the coat of metal, the steel with polyurea protection coating is formed Silk;
    In A, make the steel wire step with polyurea protection coating:Polyurea materials are passed through into Extrusion Coating, spraying, immersion pumping painting or machine Device brushing form coating specific method be:
    By single bright steel wire or the single anti-corrosion steel wire of diaphragm-have epoxy in individual wire surface attachment has been attached with it Coating, galvanizing coating, plastic coating, anti-corrosion grease coating, oiliness wax or the surface attachment coating of the coat of metal or preventing for coating One of rotten steel wire, hereinafter referred to as steel wire, process IV is coated by polyurea materials, i.e., in the following manner:
    1. Extrusion Coating:Steel wire passes through the hot-extrudable polyurea materials of extrusion moulding type equipment;
    2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel wire;
    3. soak pumping painting:Steel wire is immersed in carbamide paint by pulling equipment, by exporting ring-type shaping structures after immersion;
    4. machine painting way:Polyurea materials are made to be coated uniformly on steel wire using machine brushing;
    The surface of single bright steel wire is set to coat a strata urea protective coating IV (31d) or be attached with the list of diaphragm Epoxy coating, galvanizing coating, plastic coating, anti-corrosion grease coating, oiliness wax or the metal-plated that root anti-corrosion Steel Wire Surface is attached with A strata urea protective coating IV (31d) is coated with the surface attachment coating or coating of layer, formed by single bright steel wire and The steel wire with polyurea protection coating that polyurea protection coating IV (31d) coated in single bright steel wire periphery is formed or by The band polyureas with compound protective coating that compound protective coating outside single bright steel wire and single anti-corrosion steel wire is formed is prevented The steel wire of coating is protected, hereafter referred to collectively as:Steel wire with polyurea protection coating, including central hair(1)With side silk(2);
    B, it is twisted together shaping;Central hair with polyurea protection coating(1)With side silk(2)Steel strand wires are twisted together into, including by bright steel wire The steel strand wires I 1 with polyurea protection coating formed or the steel strand wires I 4 with polyurea protection coating being made up of anti-corrosion steel wire.
  2. 2. the preparation method of the steel strand wires according to claim 1 with polyurea protection coating, it is characterised in that:Will be by smooth surface The steel strand wires I 1 with polyurea protection coating of steel wire composition or the steel strand wires I with polyurea protection coating being made up of anti-corrosion steel wire 4 pass through C:Polyurea materials coat process I:In the steel strand wires I 1 with polyurea protection coating or the band polyureas being made up of anti-corrosion steel wire The periphery of the steel strand wires I 4 of protective coating coats one layer of polyurea materials and forms polyurea protection coating I (31a), forms whole steel and twists The periphery of line is coated with a kind of steel strand wires II 1, II 4 with polyurea protection coating of a strata urea protective coating;
    C:Polyurea materials coat process I:One of i.e. by steel strand wires made of claim 1 I 1, I 4 in the following manner:
    1. Extrusion Coating:Steel strand wires I 1, I 4 are passed through into the hot-extrudable polyurea materials of extrusion moulding type equipment;
    2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel strand wires I 1, I 4 On;
    3. soak pumping painting:Steel strand wires I 1, I 4 are immersed in carbamide paint by pulling equipment, by exporting cyclic structure after immersion Shaping;
    4. machine painting way:Polyurea materials are made to be coated uniformly on steel strand wires I 1, I 4 using machine brushing;
    By periphery of the polyurea materials coated in whole steel strand wires I 1, I 4, being formed in the periphery of whole steel strand wires has one layer by polyureas The polyurea protection coating I that material is formed(31a)The steel strand wires with polyurea protection coating formed, including be made up of bright steel wire The steel strand wires II 1 with polyurea protection coating;Or the steel strand wires II 4 with polyurea protection coating being made up of anti-corrosion steel wire.
  3. 3. the preparation method of the steel strand wires according to claim 1 or 2 with polyurea protection coating, it is characterised in that:By band The steel strand wires I 1, I 4, II 1 or II 4 of polyurea protection coating are by step D:The band winding working procedure that is wrapped is fabricated to whole on the outside of steel strand wires Body is coated with the band that is wrapped(5)The steel strand wires I 7, I 8, II 7 or II 8 with polyurea protection coating.
  4. A kind of 4. preparation method of steel strand wires with polyurea protection coating according to claim 3, it is characterised in that:By band The steel strand wires I 7, I 8, II 7 or II 8 of polyurea protection coating pass through E again:Polyurea materials coat process II, i.e., in the following manner it One:
    1. Extrusion Coating:Steel strand wires I 7, I 8, II 7 or II 8 are passed through into the hot-extrudable polyurea materials of extrusion moulding type equipment;
    2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel strand wires I 7, I 8th, on II 7 or II 8;
    3. soak pumping painting:Steel strand wires I 7, I 8, II 7 or II 8 are immersed in carbamide paint by pulling equipment, by going out after immersion Choma shape shaping structures;
    4. machine painting way:Polyurea materials are made to be coated uniformly on steel strand wires I 7, I 8, II 7 or II 8 using machine brushing;
    Integral coating is set on the outside of steel strand wires to be wrapped band(5)Steel strand wires I 7, I 8, II 7 or II 8 outer surfaces attachment polyurea protection Coating II (31b);Composition is wrapped band(5)Periphery be integrally coated with one layer of polyurea protection coating II formed by polyurea materials (31b)Form the steel strand wires I 9, I 10, II 9 or II 10 with polyurea protection coating.
  5. 5. a kind of preparation method of steel strand wires with polyurea protection coating according to claim 1,2 or 4, its feature exist In:By the steel strand wires I 1, I 4, II 1, II 4, I 9, I 10, II 9 or II 10 with polyurea protection coating again through step F:PE sheath extrusion moldings Process, by extrusion moulding type equipment by high-density polyethylene plastics extrusion molding in steel strand wires I 1, I 4, II 1, II 4, I 9, I 10, II 9 or II 10 outer layers, being fabricated to integral coating on the outside of steel strand wires has PE sheaths(6)The steel strand wires I 13, I 14, II with polyurea protection coating 13rd, II 14, I 11, I 12, II 11 or II 12.
  6. A kind of 6. preparation method of steel strand wires with polyurea protection coating according to claim 5, it is characterised in that:By band The steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or II 12 of polyurea protection coating pass through G again:Polyurea materials coat Process III:One of i.e. in the following manner:
    1. Extrusion Coating:Steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or II 12 are passed through into extrusion moulding type equipment hot extrusion The polyurea materials gone out;
    2. spray:By equipment temperature-pressure, raw material is after mixing at nozzle by lance ejection polyurea materials to steel strand wires I 13, I 14th, on II 13, II 14, I 11, I 12, II 11 or II 12;
    3. soak pumping painting:Steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or II 12 are immersed in poly- by pulling equipment In urea coating, by exporting ring-type shaping structures after immersion;
    4. machine painting way:Polyurea materials are made to be coated uniformly on steel strand wires I 13, I 14, II 13, II 14, I using machine brushing 11st, on I 12, II 11 or II 12;
    Make steel strand wires I 13, I 14, II 13, II 14, I 11, I 12, II 11 or the PE sheaths of II 12 integral coatings(6)Periphery coating One layer of polyurea protection coating III formed by polyurea materials(31c), form the steel strand wires I 3 with polyurea protection coating, I 6, II 3, Ⅱ6、Ⅰ2、Ⅰ5、Ⅱ2、Ⅱ5。
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