CN105088863A - Household paper and manufacturing process - Google Patents
Household paper and manufacturing process Download PDFInfo
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- CN105088863A CN105088863A CN201510411177.5A CN201510411177A CN105088863A CN 105088863 A CN105088863 A CN 105088863A CN 201510411177 A CN201510411177 A CN 201510411177A CN 105088863 A CN105088863 A CN 105088863A
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Abstract
The invention belongs to the technical field of paper making, and specifically relates to household paper and manufacturing process thereof. According to the invention, the obverse side of the household paper is provided with a lubrication type softening agent, and the reverse side of the household paper is provided with a wet strength agent. The process provided by the invention comprises the steps of pulp dispersing, pulp batching, diluting, screening, mesh shaping, press dewatering, drying, wrinkling, and primary reeling; and the process is characterized by adding the lubrication type softening agent and the wet strength agent into pulp batching process. The household paper prepared by using the process in the invention has good primary reeling physical property and significantly increases utilization rate of the softening agent and the wet strength agent.
Description
Technical field
The invention belongs to pulp technology for making paper, be specifically related to one way of life paper using, also relate to the manufacturing technique of above-mentioned paper for daily use.
Background technology
Along with the raising of people's living standard, the requirement of people to the function of paper for daily use is more and more higher, has both required the intensity of paper, requires again the pliability of paper.Under normal circumstances, intensity and the pliability of paper are inversely proportional to: intensity is higher, then pliability is lower; Intensity is lower, then pliability is higher.
Application number be 201310155454.1 patent of invention " manufacture method of paper for daily use " manufacture method of one way of life paper using is provided, comprise step with slurry, add the step of softener before with slurry or with slurry, and add the step of wet strength agent after with slurry or with slurry, and wet strength agent be added on the interpolation of softener after, this invention is by adding softener and wet strength agent respectively, and first add softener, the mode of rear interpolation wet strength agent, the utilization rate of softener and wet strength agent is promoted.But it is very large to the loss of strength of paper that solution of bonding softener is added in this invention, and in the case, wet-dry ratio is the highest can reach 16%.Therefore, need to improve for above-mentioned defect, design a kind of new life paper using manufacture method, significantly improve softener and wet strength agent utilization rate.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of utilization rate paper for daily use manufacture method that can significantly improve softener and wet strength agent.
The super soft paper for daily use of one of the present invention, comprises obverse and reverse two surfaces, and front is for pasting cylinder face, reverse side is non-subsides cylinder face, and there is lubricating type softener in paper for daily use front, and reverse side has wet strength agent, the front of paper for daily use contacts with human skin, and reverse side does not directly contact with human skin.
In paper for daily use, positive and negative all contains solution of bonding softener, and lubricating type softener consumption is 0.1-1kg/t paper, and wet strengthening agent is 0.5-2kg/t paper, and separating of bonding softener consumption is 0.5-3kg/t;
In step with slurry, add lubricating type softener and wet strength agent, any one step before with slurry in step as loose stock tank, loose slurry unload stock tank, defibrination, the medium step of defibrination accumulator tank add and separate of bonding softener.
The manufacturing technique of above-mentioned paper for daily use, comprises following step:
Loose slurry, with slurry, dilution, screening, Top wire former, press dewatering, oven dry, wrinkling, just roll up.
The manufacturing technique of paper for daily use of the present invention, comprises following step:
Loose slurry: long fine pulpboard carries out loose slurry in long fine loose stock tank; Short fiber pulpboard defibrination: carry out loose slurry in short fiber falls apart stock tank, remove the gred respectively;
The concentration of long fine pulpboard is 6%, and the concentration of short fiber pulpboard is 6%;
Long fibre carries out defibrination through fiberizer, and short fiber is discongested through fluffer;
With slurry: carry out with slurry being divided in pond with slurry and net side and blanket side, after with slurry, optionally refine slurry or discongest, defibrination disposed slurry enters net side machine chest and blanket side machine chest more respectively;
Dilution: at fan pump place, plain boiled water diluted slurry;
Screening: the slurry of net blanket side is again through screening;
Top wire former: paper machine is for after the slurry stage, and slurry is distributed to the fabric of Web-forming section with the concentration of 0.2% from paper head box, be shaped after a large amount of dehydration wet paper web on fabric, and paper web continues to run and dehydration further in paper web delivery section;
Press dewatering: wet web squeezes through at least two sections of vacuum draw pressure roller again;
Dry: drying cylinder portion is provided with drying cylinder coating apparatus, remover, sticker cylinder agent and drying cylinder protective agent mix uniformly, and uniformly sprayed on Flying Dutchman surface by shower, rear wet web is passed to the dryer surface of cylinder drying portion, follow while drying cylinder operates together, be further dried;
Wrinkling: to use scraper to improve smoothness and the pliability of paper;
First volume: the paper web after creping doctor is wrinkling is pulled and arrives limiting roll and peel off from dryer surface, paper web is conveyed to just volume cylinder and carries out just volume.
It is to be noted, the step such as loose slurry, defibrination, with slurry, dilution, screening completes in particular device, each step likely adopts again specific storage device to deposit the product of this step gained after having operated temporarily, is likely to be again delivered to by products therefrom in the particular device that next step carries out by modes such as pipelines after the operation of this step completes.
Therefore the present invention is alleged adds special additive in a certain step, can be understood as and be added in equipment that a certain step carries out, or add in the conveyance conduit before the equipment that occurs of a step after entering, or add in the storage device before equipment that a step after entering occurs.
For example, if it is in step with slurry that softener adds point, then softener can be added in occurred dosing chamber with slurry, or before the machine being added on rear storing slurry with slurry in groove, or be added on be delivered to stuff box or trash separator, net fore worker (namely screening the equipment that purifying step occurs) these equipment conveyance conduit in.
Beneficial effect of the present invention is, adopts the paper for daily use obtained by technique of the present invention, and first Roll Sushi is good, Roll Sushi as first in embodiments of the invention 2 is: paper tensile index is 4.2Nm/g, and wet is 18N/m by force, and wet-dry ratio is 29.5%, pliability is 18mN, TSA feel test HF value is 90.The first Roll Sushi of embodiment 6 is: paper tensile index is 4.0Nm/g, and wet is 22N/m by force, and wet-dry ratio is 37.9%, and pliability is 13mN, TSA feel test HF value is 95.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
The manufacturing technique of one way of life paper using, comprises following step:
The quantitative of the paper that paper machine is manufactured paper with pulp is 14.5g/ ㎡.
Wherein, softener (softener is lubricating type softener) is added on net side machine chest, and ton paper addition is 0.5kg/t, and wet strength agent is added on blanket side machine chest, and ton slurry addition is 0.9kg/t;
First Roll Sushi is: paper tensile index is 9.37Nm/g, and wet is 20N/m by force, and wet-dry ratio is 14.7%, and pliability is 28mN, TSA feel test HF value is 79.
Embodiment 2
The manufacturing technique of one way of life paper using, comprises following step:
The quantitative of the paper that paper machine is manufactured paper with pulp is 14.5g/ ㎡.
Wherein, softener (softener is for separating of bonding softener) adds loose stock tank, and ton slurry addition is 1kg/t, softener (softener is lubricating type softener) is added on net side machine chest simultaneously, ton paper addition is 0.5kg/t, and wet strength agent is added on blanket side machine chest, and ton slurry addition is 0.9kg/t.
First Roll Sushi is: paper tensile index is 4.2Nm/g, and wet is 18N/m by force, and wet-dry ratio is 29.5%, and pliability is 18mN, TSA feel test HF value is 90;
Add in above-mentioned loose slurry step and separate of bonding softener, can make increase the contact time of softener and fiber, guarantee that softener fully can be combined with fiber.Reduce the intensity of paper, thus improve the pliability of paper.Add lubricating type softener at net side machine chest again, significantly improve the feel of paper.
Comparative example 1
The manufacturing technique of one way of life paper using, comprises following step:
The quantitative of the paper that paper machine is manufactured paper with pulp is 14.5g/ ㎡;
Loose slurry: long fine pulpboard (concentration 6%) carries out loose slurry, short fiber pulpboard (concentration 6%) defibrination in long fine loose stock tank: carry out loose slurry in short fiber falls apart stock tank, remove the gred respectively;
Long fibre carries out defibrination through fiberizer, and short fiber is discongested through fluffer;
With slurry: to carry out with slurry being divided in pond with slurry and net side and blanket side.After with slurry, can optionally refine slurry or discongest.Defibrination disposed slurry enters net side machine chest and blanket side machine chest more respectively;
Dilution: at fan pump place, plain boiled water diluted slurry;
Screening: the slurry of net blanket side is again through screening;
Top wire former: paper machine is for after the slurry stage, and slurry is distributed to the fabric of Web-forming section with the concentration of 0.2% from paper head box, be shaped after a large amount of dehydration wet paper web on fabric, and paper web continues to run and dehydration further in paper web delivery section;
Press dewatering: wet web squeezes through at least two sections of vacuum draw pressure roller again;
Dry: drying cylinder portion is provided with drying cylinder coating apparatus, remover, sticker cylinder agent and drying cylinder protective agent mix uniformly, and uniformly sprayed on Flying Dutchman surface by shower, rear wet web is passed to the dryer surface of cylinder drying portion, follow while drying cylinder operates together, be further dried;
Wrinkling: to use scraper to improve smoothness and the pliability of paper;
First volume: the paper web after creping doctor is wrinkling is pulled and arrives limiting roll and peel off from dryer surface.Paper web is conveyed to just volume cylinder and carries out just volume;
Wherein: net side machine chest and blanket side machine chest have interpolation softener (softener is lubricating type softener), ton slurry addition is 0.5kg/t, and net side machine chest and blanket side machine chest have interpolation wet strength agent, and ton slurry addition is 0.9kg/t;
First Roll Sushi is: paper tensile index is 9.37Nm/g, and wet is 20N/m by force, and wet-dry ratio is 14.71%, and pliability is 28mN, TSA feel test HF value is 68.
Embodiment 2 is compared with comparative example 1, and paper tensile index is down to original 44.8%, and the wet-dry ratio of paper improves 100%, and pliability improves 55.6%, TSA feel test HF value and improves 32%.
The addition point separating of bonding softener can be with slurry before any one step (as loose stock tank, loose slurry unload stock tank, defibrination, defibrination accumulator tank) in step, also can be all add softener in two or more in above-mentioned steps.Adding softener in multiple steps can make the interpolation of softener more disperse, thus provides convenient for softener and fiber are fully combined.As what change, can also be add softener in successional mode.Such as by measuring pump and control valve, the softener be stored in storage tank is joined softener addition point at regular time and quantity.Continuity is interpreted as adding operating in continuous certain time of softener and completes.This kind of addition manner also can reach the identical or close effect of the mode that adds softener in multiple steps.
Embodiment 3
The manufacturing technique of one way of life paper using, comprises following step:
The quantitative of the paper that paper machine is manufactured paper with pulp is 14.5g/ ㎡.
Wherein, softener (softener is lubricating type softener) is added on net side machine chest, and ton paper addition is 0.1kg/t, and wet strength agent is added on blanket side machine chest, and ton slurry addition is 0.5kg/t;
First Roll Sushi is: paper tensile index is 9.31Nm/g, and wet is 12.5N/m by force, and wet-dry ratio is 9.26%, and pliability is 27mN.TSA feel test HF value is 70.
Embodiment 4
The manufacturing technique of one way of life paper using, comprises following step:
The quantitative of the paper that paper machine is manufactured paper with pulp is 14.5g/ ㎡.
Wherein, softener (softener is for separating of bonding softener) adds loose stock tank, ton slurry addition is 0.5kg/t, softener (softener is lubricating type softener) is added on net side machine chest simultaneously, ton paper addition is 0.1kg/t, wet strength agent is added on blanket side machine chest, and ton slurry addition is 0.5kg/t.
First Roll Sushi is: paper tensile index is 6.79Nm/g, and wet is 12N/m by force, and wet-dry ratio is 12.8%, and pliability is 22mN.TSA feel test HF value is 85;
Add in above-mentioned loose slurry step and separate of bonding softener, can make increase the contact time of softener and fiber, guarantee that softener fully can be combined with fiber.Reduce the intensity of paper, thus improve the pliability of paper.Add lubricating type softener at net side machine chest again, significantly improve the feel of paper.
Comparative example 2
The manufacturing technique of one way of life paper using, comprises following step:
The quantitative of the paper that paper machine is manufactured paper with pulp is 14.5g/ ㎡;
Loose slurry: long fine pulpboard (concentration 6%) carries out loose slurry, short fiber pulpboard (concentration 6%) defibrination in long fine loose stock tank: carry out loose slurry in short fiber falls apart stock tank, remove the gred respectively;
Long fibre carries out defibrination through fiberizer, and short fiber is discongested through fluffer;
With slurry: to carry out with slurry being divided in pond with slurry and net side and blanket side.After with slurry, can optionally refine slurry or discongest.Defibrination disposed slurry enters net side machine chest and blanket side machine chest more respectively;
Dilution: at fan pump place, plain boiled water diluted slurry;
Screening: the slurry of net blanket side is again through screening;
Top wire former: paper machine is for after the slurry stage, and slurry is distributed to the fabric of Web-forming section with the concentration of 0.2% from paper head box, be shaped after a large amount of dehydration wet paper web on fabric, and paper web continues to run and dehydration further in paper web delivery section;
Press dewatering: wet web squeezes through at least two sections of vacuum draw pressure roller again;
Dry: drying cylinder portion is provided with drying cylinder coating apparatus, remover, sticker cylinder agent and drying cylinder protective agent mix uniformly, and uniformly sprayed on Flying Dutchman surface by shower, rear wet web is passed to the dryer surface of cylinder drying portion, follow while drying cylinder operates together, be further dried;
Wrinkling: to use scraper to improve smoothness and the pliability of paper;
First volume: the paper web after creping doctor is wrinkling is pulled and arrives limiting roll and peel off from dryer surface.Paper web is conveyed to just volume cylinder and carries out just volume;
Wherein: net side machine chest and blanket side machine chest have interpolation softener (softener is lubricating type softener), ton slurry addition is 0.1kg/t, and net side machine chest and blanket side machine chest have interpolation wet strength agent, and ton slurry addition is 0.5kg/t;
First Roll Sushi is: paper tensile index is 9.31Nm/g, and wet is 12.5N/m by force, and wet-dry ratio is 9.26%, and pliability is 27mN.TSA feel test HF value is 61.
Embodiment 4 is compared with comparative example 2, and paper tensile index is down to original 88%, and the wet-dry ratio of paper improves 38.2%.Pliability improves 22.7%, TSA feel test HF value and improves 39.3%.
The addition point separating of bonding softener can be with slurry before any one step (as loose stock tank, loose slurry unload stock tank, defibrination, defibrination accumulator tank) in step, also can be all add softener in two or more in above-mentioned steps.Adding softener in multiple steps can make the interpolation of softener more disperse, thus provides convenient for softener and fiber are fully combined.As what change, can also be add softener in successional mode.Such as by measuring pump and control valve, the softener be stored in storage tank is joined softener addition point at regular time and quantity.Continuity is interpreted as adding operating in continuous certain time of softener and completes.This kind of addition manner also can reach the identical or close effect of the mode that adds softener in multiple steps.
Embodiment 5
The manufacturing technique of one way of life paper using, comprises following step:
The quantitative of the paper that paper machine is manufactured paper with pulp is 14.5g/ ㎡.
Wherein, softener (softener is lubricating type softener) is added on net side machine chest, and ton paper addition is 1kg/t, and wet strength agent is added on blanket side machine chest, and ton slurry addition is 2kg/t;
First Roll Sushi is: paper tensile index is 8.3Nm/g, and wet is 25N/m by force, and wet-dry ratio is 20.8%, and pliability is 26mN.TSA feel test HF value is 88.
Embodiment 6
The manufacturing technique of one way of life paper using, comprises following step:
The quantitative of the paper that paper machine is manufactured paper with pulp is 14.5g/ ㎡.
Wherein, softener (softener is for separating of bonding softener) adds loose stock tank, and ton slurry addition is 3kg/t, softener (softener is lubricating type softener) is added on net side machine chest simultaneously, ton paper addition is 1kg/t, and wet strength agent is added on blanket side machine chest, and ton slurry addition is 2kg/t.
First Roll Sushi is: paper tensile index is 4.0Nm/g, and wet is 22N/m by force, and wet-dry ratio is 37.9%, and pliability is 13mN.TSA feel test HF value is 95;
Add in above-mentioned loose slurry step and separate of bonding softener, can make increase the contact time of softener and fiber, guarantee that softener fully can be combined with fiber.Reduce the intensity of paper, thus improve the pliability of paper.Add lubricating type softener at net side machine chest again, significantly improve the feel of paper.
Comparative example 3
The manufacturing technique of one way of life paper using, comprises following step:
The quantitative of the paper that paper machine is manufactured paper with pulp is 14.5g/ ㎡;
Loose slurry: long fine pulpboard (concentration 6%) carries out loose slurry, short fiber pulpboard (concentration 6%) defibrination in long fine loose stock tank: carry out loose slurry in short fiber falls apart stock tank, remove the gred respectively;
Long fibre carries out defibrination through fiberizer, and short fiber is discongested through fluffer;
With slurry: to carry out with slurry being divided in pond with slurry and net side and blanket side.After with slurry, can optionally refine slurry or discongest.Defibrination disposed slurry enters net side machine chest and blanket side machine chest more respectively;
Dilution: at fan pump place, plain boiled water diluted slurry;
Screening: the slurry of net blanket side is again through screening;
Top wire former: paper machine is for after the slurry stage, and slurry is distributed to the fabric of Web-forming section with the concentration of 0.2% from paper head box, be shaped after a large amount of dehydration wet paper web on fabric, and paper web continues to run and dehydration further in paper web delivery section;
Press dewatering: wet web squeezes through at least two sections of vacuum draw pressure roller again;
Dry: drying cylinder portion is provided with drying cylinder coating apparatus, remover, sticker cylinder agent and drying cylinder protective agent mix uniformly, and uniformly sprayed on Flying Dutchman surface by shower, rear wet web is passed to the dryer surface of cylinder drying portion, follow while drying cylinder operates together, be further dried;
Wrinkling: to use scraper to improve smoothness and the pliability of paper;
First volume: the paper web after creping doctor is wrinkling is pulled and arrives limiting roll and peel off from dryer surface.Paper web is conveyed to just volume cylinder and carries out just volume;
Wherein: net side machine chest and blanket side machine chest have interpolation softener (softener is lubricating type softener), ton slurry addition is 1kg/t, and net side machine chest and blanket side machine chest have interpolation wet strength agent, and ton slurry addition is 2kg/t;
First Roll Sushi is: paper tensile index is 8.3Nm/g, and wet is 25N/m by force, and wet-dry ratio is 20.8%, and pliability is 26mN.TSA feel test HF value is 83.
Embodiment 6 is compared with comparative example 3, and paper tensile index is down to original 48.2%, and the wet-dry ratio of paper improves 82.2%.Pliability improves 100%, TSA feel test HF value and improves 14.5%.
The addition point separating of bonding softener can be with slurry before any one step (as loose stock tank, loose slurry unload stock tank, defibrination, defibrination accumulator tank) in step, also can be all add softener in two or more in above-mentioned steps.Adding softener in multiple steps can make the interpolation of softener more disperse, thus provides convenient for softener and fiber are fully combined.As what change, can also be add softener in successional mode.Such as by measuring pump and control valve, the softener be stored in storage tank is joined softener addition point at regular time and quantity.Continuity is interpreted as adding operating in continuous certain time of softener and completes.This kind of addition manner also can reach the identical or close effect of the mode that adds softener in multiple steps.
Further, except continuity adds, intermittent mode softener can also be added.Intermittence is interpreted as softener and completes in the not once-through operation that adds that is added point, and the mode that can be added by the repeatedly continuity at interval is completed.For example, can take once to add operation continued for some time, then rest the some time, then continue interpolation operation next time again and continued for some time completes this and adds operation next time.Adopting this kind of mode to add softener can further make softener be combined with fiber more fully, promotes the utilization rate of softener.
Wet strength agent is similar to the addition manner of softener, and wet strength agent also can be add in multiple steps, make wet strength agent more fully with fiber-reactive, promote the utilization rate of wet strength agent.As the addition manner changed, successional mode also can be adopted to add wet strength agent.Further, except continuity adds, intermittent mode can also add softener, namely add wet strength agent with the mode of operation that repeatedly continuity adds.Such as by measuring pump and control valve, the wet strength agent be stored in storage tank is joined wet strength agent addition point at regular time and quantity.For example, can take once to add operation continued for some time, then rest the some time, then continue interpolation operation next time again and continued for some time completes this and adds operation next time.Adopt this kind of mode add wet strength agent can make wet strength agent more fully with fiber-reactive, promote the utilization rate of wet strength agent.
During above-mentioned physical data is equal except TSA, other are all record with the relevant test method of national regulation.Wet capable and experienced ratio, embody wet strong action effect, pliability and TSA embody the action effect of softener.
Claims (8)
1. one way of life paper using, is characterized in that, there is lubricating type softener in the front of described paper for daily use, and reverse side has wet strength agent.
2. one way of life paper using as claimed in claim 1, it is characterized in that, described lubricating type softener consumption is 0.1-1kg/t paper, and wet strengthening agent is 0.5-2kg/t paper.
3. one way of life paper using as claimed in claim 1, is characterized in that, the obverse and reverse of described paper for daily use all also has separates of bonding softener.
4. one way of life paper using as claimed in claim 1, is characterized in that, separating of bonding softener consumption is 0.5-3kg/t.
5. the manufacturing technique of one way of life paper using as claimed in claim 1, is characterized in that, in step with slurry, add lubricating type softener and wet strength agent, before with slurry, add solution of bonding softener.
6. the manufacturing technique of one way of life paper using as claimed in claim 6, comprises following step:
Loose slurry, with slurry, dilution, screening, Top wire former, press dewatering, oven dry, wrinkling, just roll up.
7. the manufacturing technique of one way of life paper using as claimed in claim 1, it is characterized in that, described technique comprises following step:
Loose slurry: long fine pulpboard carries out loose slurry in long fine loose stock tank; Short fiber pulpboard defibrination: carry out loose slurry in short fiber falls apart stock tank, remove the gred respectively;
The concentration of the fine pulpboard of described length is 6%, and the concentration of short fiber pulpboard is 6%;
Long fibre carries out defibrination through fiberizer, and short fiber is discongested through fluffer;
With slurry: carry out with slurry being divided in pond with slurry and net side and blanket side, after with slurry, optionally refine slurry or discongest, defibrination disposed slurry enters net side machine chest and blanket side machine chest more respectively;
Dilution: at fan pump place, plain boiled water diluted slurry;
Screening: the slurry of net blanket side is again through screening;
Top wire former: paper machine is for after the slurry stage, and slurry is distributed to the fabric of Web-forming section with the concentration of 0.2% from paper head box, be shaped after a large amount of dehydration wet paper web on fabric, and paper web continues to run and dehydration further in paper web delivery section;
Press dewatering: wet web squeezes through at least two sections of vacuum draw pressure roller again;
Dry: drying cylinder portion is provided with drying cylinder coating apparatus, remover, sticker cylinder agent and drying cylinder protective agent mix uniformly, and uniformly sprayed on Flying Dutchman surface by shower, rear wet web is passed to the dryer surface of cylinder drying portion, follow while drying cylinder operates together, be further dried;
Wrinkling;
First volume: the paper web after creping doctor is wrinkling is pulled and arrives limiting roll and peel off from dryer surface, paper web is conveyed to just volume cylinder and carries out just volume.
8. one way of life paper using as claimed in claim 2, it is characterized in that, described lubricating type softener consumption is 0.5kg/t paper, and wet strengthening agent is 0.8kg/t paper.
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| CN105672020A (en) * | 2016-01-28 | 2016-06-15 | 山东太阳生活用纸有限公司 | Stickies control process in high wet strength paper making process |
| CN106835817A (en) * | 2016-12-30 | 2017-06-13 | 安徽比伦生活用纸有限公司 | A kind of preparation technology of paper for daily use |
| CN108642966A (en) * | 2018-04-20 | 2018-10-12 | 浙江景兴纸业股份有限公司 | A kind of production method of the special moisturizing moisture retention paper of mother and baby |
| CN109235125A (en) * | 2017-07-11 | 2019-01-18 | 金红叶纸业集团有限公司 | Paper for daily use and preparation method thereof |
| CN111074682A (en) * | 2019-12-31 | 2020-04-28 | 恒安(中国)纸业有限公司 | Preparation method of super-tough, high-wet-strength and super-absorbent handkerchief paper |
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| CN111074682A (en) * | 2019-12-31 | 2020-04-28 | 恒安(中国)纸业有限公司 | Preparation method of super-tough, high-wet-strength and super-absorbent handkerchief paper |
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