CN105086974A - Nanometer paraffin removal and inhibition agent for high-water content oil product - Google Patents
Nanometer paraffin removal and inhibition agent for high-water content oil product Download PDFInfo
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- CN105086974A CN105086974A CN201410479271.XA CN201410479271A CN105086974A CN 105086974 A CN105086974 A CN 105086974A CN 201410479271 A CN201410479271 A CN 201410479271A CN 105086974 A CN105086974 A CN 105086974A
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- paraffin removal
- removing agent
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Abstract
The invention discloses a nanometer paraffin removal and inhibition agent for a high-water content oil product. A preparation method of the nanometer paraffin removal and inhibition agent comprises selecting an appropriate traditional paraffin removal and inhibition agent, selecting an appropriate nano-material, determining a mixing ratio of the paraffin removal and inhibition agent to the nano-material, processing the materials to form axiolitic or cylindrical particles or carrying out refrigeration crushing to obtain powder, selecting an appropriate dispersant, cosolvent and stabilizing agent, carrying out heating dissolution to obtain a uniform solution, transporting the solution to a place, and in necessity, forming a high-liquidity uniform liquid by heating and thermal insulation. The nanometer paraffin removal and inhibition agent can reduce a wax precipitation point of oil wells, gas wells and gathering and transportation pipes with high water content and reduces oil product viscosity and condensation point. When the addition amount is higher than a certain value (ppm), paraffin inhibition efficiency is generally 40% or more and paraffin removal effects are obvious. The nanometer paraffin removal and inhibition agent can prolong an oil well hot washing period, has effects of demulsification and viscosity reduction, and can be used as a well washing solution and a viscosity reducer.
Description
Technical field
The present invention relates to a kind of Oilfield Chemicals, namely a kind of can be used for water content higher, the chemical agent of the gathering line of oil well, gasser and the conveying content of wax (moisture) oil product of producing waxy crude oil and condensate oil, the crystallization of paraffin in oil product (moisture), dispersing characteristic can be improved, improve the mobility of oil product in pit shaft and pipeline, clear up, suppress and prevent wax in the deposition of inside pipe wall and attachment.
Background technology
Wax removing agent is for oil well, gas well, the content of wax oil product of gathering line, dissolves the stone wax already having deposited and be attached to inside pipe wall, reduces a kind of chemical agent of oil product condensation point, viscosity.
Oil base wax removing agent (comprising Wax coagulation preventing agent), has been widely used on oil well, gasser and gathering line.But because medicament is to the susceptibility of water-content, make still there is many problems on effect.Such as when water content is higher, the medicament of this kind of oil base is just difficult to play wax removal effect, and wax control result is also undesirable.
In recent years, along with the widespread use of nano material in oilfield chemistry, nano material is combined with traditional wax removing agent, be equipped with other auxiliary agents suitable and solvent again, the result of use of this kind of medicament under the higher operating mode of water content can be improved significantly, promote economic benefit and the safety assurance of user.
Summary of the invention
Technical problem to be solved by this invention is, there is provided a kind of can be used for water content higher, the chemical agent of the gathering line of oil well, gasser and the conveying content of wax (moisture) oil product of producing waxy crude oil and condensate oil, the crystallization of paraffin in oil product (moisture), dispersing characteristic can be improved, improve the mobility of oil product in pit shaft and pipeline, clear up, suppress and prevent wax the deposition of inside pipe wall and attachment, the nanometer wax removing agent that is applicable to the higher oil product of water content.
The present invention is achieved through the following technical solutions: a kind of nanometer wax removing agent being applicable to the higher oil product of water content, specifically comprises following step:
Traditional wax removing agent that step one, selection are suitable for is as raw material;
Step 2, select suitable nano material, nano material is joined in wax removing agent, determine nano material and wax removing agent compound proportion, carry out composite to them;
3rd step, the mixture obtained to step one and step 2 utilize granulator granulation, are processed into ellipsoid shape or columned particle;
4th step, to particle out made by step 3 by freezing and pulverizing, be processed into powder;
Add suitable solvent in 5th step, the product that obtains in above-mentioned steps, after adding solvent, heating for dissolving is carried out to it, form homogeneous solution;
6th step, when being transported to onsite application, suitably carrying out heating and thermal insulation, form runny uniform liquid;
7th step, join in the fluid of oil well, gas well and gathering line in proportion, its ratio is generally 300-1000ppm, the polar active component in medicament, is adsorbed or adheres to tube wall metal surface, thus reaches the deposition suppressing paraffin at tube wall surface.
As preferred technical scheme, described solvent is dispersion agent or solubility promoter or stablizer or wax crystal modifier.
As preferred technical scheme, described nano material is not limited to the silicon-dioxide commonly used and polyester/silicon dioxide material, also can be the nano material that any one can join in wax removing agent.
The invention has the beneficial effects as follows: for oil well, gas well and gathering line that water ratio is higher, after using the present invention, wax precipitation piont can be reduced, reduce viscosity and the condensation point of oil product, when add-on is more than certain dosage (ppm), its wax control efficiency generally can reach more than 40%, and its wax removal effect is also fairly obvious; In addition, while the prolongation thermal well flushing cycle, also can have certain breakdown of emulsion and viscosity reduction effect, and can be used as flushing fluid, viscosity-depression agent uses.
Substitute traditional oil base, water based dewaxing agent, by the combination of conventional art with nanotechnology, the level of lifting Paraffin Removal technology and practical function.
Embodiment
All features disclosed in this specification sheets, or the step in disclosed all methods or process, except mutually exclusive feature and/or step, all can combine by any way.
A kind of nanometer wax removing agent being applicable to the higher oil product of water content of the present invention, specifically comprises following step:
Traditional wax removing agent that step one, selection are suitable for is as raw material;
Step 2, select suitable nano material, nano material is joined in wax removing agent, determine nano material and wax removing agent compound proportion, carry out composite to them;
3rd step, the mixture obtained to step one and step 2 utilize granulator granulation, are processed into ellipsoid shape or columned particle;
4th step, to particle out made by step 3 by freezing and pulverizing, be processed into powder;
Add suitable solvent in 5th step, the product that obtains in above-mentioned steps, after adding solvent, heating for dissolving is carried out to it, form homogeneous solution;
6th step, when being transported to onsite application, suitably carrying out heating and thermal insulation, form runny uniform liquid;
7th step, join in the fluid of oil well, gas well and gathering line in proportion, its ratio is generally 300-1000ppm, the polar active component in medicament, is adsorbed or adheres to tube wall metal surface, thus reaches the deposition suppressing paraffin at tube wall surface.
As preferred embodiment, solvent is dispersion agent or solubility promoter or stablizer or wax crystal modifier.
As preferred embodiment, nano material is not limited to the silicon-dioxide commonly used and polyester/silicon dioxide material, can be also the nano material that any one can join in wax removing agent, select silicon-dioxide and polyester/silicon dioxide material in the present embodiment.
The invention has the beneficial effects as follows: for oil well, gas well and gathering line that water ratio is higher, after using the present invention, wax precipitation piont can be reduced, reduce viscosity and the condensation point of oil product, when add-on is more than certain dosage (ppm), its wax control efficiency generally can reach more than 40%, and its wax removal effect is also fairly obvious; In addition, while the prolongation thermal well flushing cycle, also can have certain breakdown of emulsion and viscosity reduction effect, and can be used as flushing fluid, viscosity-depression agent uses.
Substitute traditional oil base, water based dewaxing agent, by the combination of conventional art with nanotechnology, the level of lifting Paraffin Removal technology and practical function.
The above, be only the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, and any change of expecting without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (3)
1. be applicable to a nanometer wax removing agent for the higher oil product of water content, it is characterized in that: specifically comprise following step:
Traditional wax removing agent that step one, selection are suitable for is as raw material;
Step 2, select suitable nano material, nano material is joined in wax removing agent, determine nano material and wax removing agent compound proportion, carry out composite to them;
3rd step, the mixture obtained to step one and step 2 utilize granulator granulation, are processed into ellipsoid shape or columned particle;
4th step, to particle out made by step 3 by freezing and pulverizing, be processed into powder;
Add suitable solvent in 5th step, the product that obtains in above-mentioned steps, after adding solvent, heating for dissolving is carried out to it, form homogeneous solution;
6th step, when being transported to onsite application, suitably carrying out heating and thermal insulation, form runny uniform liquid;
7th step, join in the fluid of oil well, gas well and gathering line in proportion, its ratio is generally 300-1000ppm, the polar active component in medicament, is adsorbed or adheres to tube wall metal surface, thus reaches the deposition suppressing paraffin at tube wall surface.
2. according to claim 1, the nanometer wax removing agent that is applicable to the higher oil product of water content, is characterized in that: described solvent is dispersion agent or solubility promoter or stablizer or wax crystal modifier.
3. according to claim 1, the nanometer wax removing agent that is applicable to the higher oil product of water content, it is characterized in that: described nano material is not limited to the silicon-dioxide commonly used and polyester/silicon dioxide material, also can be the nano material that any one can join in wax removing agent.
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CN201410479271.XA CN105086974A (en) | 2014-09-19 | 2014-09-19 | Nanometer paraffin removal and inhibition agent for high-water content oil product |
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CN201410479271.XA CN105086974A (en) | 2014-09-19 | 2014-09-19 | Nanometer paraffin removal and inhibition agent for high-water content oil product |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108165245A (en) * | 2018-01-08 | 2018-06-15 | 扬州工业职业技术学院 | A kind of preparation method of silicon dioxide carried cationic alkyl glycosides type pour point depressant for crude oil |
CN113654941A (en) * | 2021-09-01 | 2021-11-16 | 西南石油大学 | Multifunctional teaching experiment system and method for measuring pressure in petroleum field |
CN115418209A (en) * | 2022-09-30 | 2022-12-02 | 湖北三雄科技发展有限公司 | High-wax-content high-temperature high-mineralization oil well microbial paraffin removal and prevention agent and preparation method thereof |
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CN1544572A (en) * | 2003-11-17 | 2004-11-10 | 马冬兰 | Nano-surfactant for oil production and method for preparing the same |
CN102108292A (en) * | 2009-12-29 | 2011-06-29 | 中国石油天然气股份有限公司 | Viscosity-reducing and pour-point-reducing composition for crude oil |
CN102127409A (en) * | 2011-01-10 | 2011-07-20 | 中国科学院化学研究所 | Crude oil viscosity-breaking pour-point depressant composition, and preparation method and application thereof |
CN103320110A (en) * | 2013-06-26 | 2013-09-25 | 工合聚能(天津)石油精化科技发展有限公司 | Nano composite high-temperature-resistant extraction aid for thickened oil and super-thickened oil recovery and preparation method thereof |
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- 2014-09-19 CN CN201410479271.XA patent/CN105086974A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1544572A (en) * | 2003-11-17 | 2004-11-10 | 马冬兰 | Nano-surfactant for oil production and method for preparing the same |
CN102108292A (en) * | 2009-12-29 | 2011-06-29 | 中国石油天然气股份有限公司 | Viscosity-reducing and pour-point-reducing composition for crude oil |
CN102127409A (en) * | 2011-01-10 | 2011-07-20 | 中国科学院化学研究所 | Crude oil viscosity-breaking pour-point depressant composition, and preparation method and application thereof |
CN103320110A (en) * | 2013-06-26 | 2013-09-25 | 工合聚能(天津)石油精化科技发展有限公司 | Nano composite high-temperature-resistant extraction aid for thickened oil and super-thickened oil recovery and preparation method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108165245A (en) * | 2018-01-08 | 2018-06-15 | 扬州工业职业技术学院 | A kind of preparation method of silicon dioxide carried cationic alkyl glycosides type pour point depressant for crude oil |
CN113654941A (en) * | 2021-09-01 | 2021-11-16 | 西南石油大学 | Multifunctional teaching experiment system and method for measuring pressure in petroleum field |
CN113654941B (en) * | 2021-09-01 | 2024-04-05 | 西南石油大学 | Multifunctional teaching experiment system and method for measuring pressure in petroleum field |
CN115418209A (en) * | 2022-09-30 | 2022-12-02 | 湖北三雄科技发展有限公司 | High-wax-content high-temperature high-mineralization oil well microbial paraffin removal and prevention agent and preparation method thereof |
CN115418209B (en) * | 2022-09-30 | 2023-10-03 | 湖北三雄科技发展有限公司 | High-wax-content high-temperature high-mineralization oil well microorganism paraffin removal and prevention agent and preparation method thereof |
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Application publication date: 20151125 |