CN105084925A - Ceramic cutting tool material prepared through waste glass and preparation method thereof - Google Patents
Ceramic cutting tool material prepared through waste glass and preparation method thereof Download PDFInfo
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- CN105084925A CN105084925A CN201510470869.7A CN201510470869A CN105084925A CN 105084925 A CN105084925 A CN 105084925A CN 201510470869 A CN201510470869 A CN 201510470869A CN 105084925 A CN105084925 A CN 105084925A
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Abstract
The invention discloses a ceramic cutting tool material prepared through waste glass and a preparation method thereof. The ceramic cutting tool material comprises, by weight, 50-70 parts of waste glass crushed aggregates, 6-8 parts of titanium carbide, 3-5 parts of calcium oxide, 1-2 parts of ethylene bis oleamide, 2-3 parts of diamond, 5-6 parts of bauxite, 1-2 parts of magnesium carbonate crystal whiskers, 1-3 parts of palygorskite fiber, 3-5 parts of zirconium oxide, 1-2 parts of hydroxypropyl guar gum, 2-3 parts of zinc molybdate, 0.5-1 part of modified starch, 1-2 parts of sodium carbonate, 4-6 parts of allyl alcohol and 6-7 parts of an addition agent. The waste glass is used as the main raw material for preparing the ceramic cutting tool material, the waste glass is secondarily utilized, resources are saved, and the production cost is lowered; in addition, the added titanium carbide, magnesium carbonate crystal whiskers and palygorskite fiber have the advantages of being high in strength, resistant to corrosion and abrasion, and good in heat stability, and therefore the produced ceramic cutting tool material is good in abrasion resistance and heat resistance and high in strength.
Description
Technical field
The present invention relates to technical field of ceramic material, is more particularly ceramic cutting tool material of preparing of a kind of discarded glass and preparation method thereof.
Background technology
In industry member, intermetallic composite coating cutting tool is a kind of very important product.Common Use Tools material is divided into following a few class: (1) high speed steel material; (2) Hardmetal materials; (3) ceramic cutting tool material; (4) ultrahard cutting tool material.Stupalith becomes the most promising cutter Materials for High Speed Cutting of current one with the thermotolerance of its excellence, wear resistance and chemical stability, has wide practical use aborning.More and more important role is play in high speed cutting field and cutting difficult-to-machine material.
Along with the raising day by day with living standards of the people that develops rapidly of science and technology, glass is not only widely used among the daily life of building construction and the people, and develops into research and production and the indispensable novel material of sophisticated technology.Inevitably produce many glass wastes simultaneously, form a large amount of cullet.By glasswork, under normal production scenarios, the corner glass scaled off from former of sheet glass accounts for the 15%-25% of glass production total amount, also has quite a few cullet to be the cullet that periodic shut down produces, accounts for the 5%-10% of glass production total amount.Produce melting furnaces processing temperature of having a surplus under abnormal condition fluctuates once in a while or raw materials quality and batch uniformity changes suddenly and misoperation etc. causes production instability generate cullet and the loss of glasswork in transport and use procedure, its quantity is then difficult to estimation [1].Glass waste silk is a kind of glass waste residue certainly led in fiber glass industry production process, and generation generally accounts for about 15% of glass output.The glass packaging Bottle & Can abandoned in people's daily life and the glass port fragment etc. smashed also are one of sources producing cullet.Cullet class material, its stable chemical nature, without putrefaction, does not burn, can not degrade, and a large amount of cullet brought inconvenience both to the production of people and life, created load again to environment.Therefore, how to carry out cullet resource and change into a current problem demanding prompt solution.
Summary of the invention
The object of the invention is to make up the deficiencies in the prior art, ceramic cutting tool material providing a kind of discarded glass to prepare and preparation method thereof.
The object of the invention is to be achieved through the following technical solutions:
A ceramic cutting tool material prepared by discarded glass, is made up of following raw material: discarded glass particle 50-70, titanium carbide 6-8, calcium oxide 3-5, ethylene two amine hydroxybenzene 1-2, diamond 2-3, bauxitic clay 5-6, magnesium carbonate whisker 1-2, polygorskite fiber 1-3, zirconium white 3-5, hydroxypropylguar gum 1-2, zinc molybdate 2-3, modified starch 0.5-1, sodium carbonate 1-2, vinylcarbinol 4-6, additive 6-7;
Described additive is made up of following raw material: zirconium silicate 20-30, waste ceramic rejected material 12-15, aluminium nitride 2-3, titanium dioxide 4-6, Desert Sand 2-4, slag micro powder 6-8, water glass 4-6, sodium lignosulfonate 0.5-1, mandarin oil 2-4, Trisilver phosphate 1-2; Preparation method is: joined in appropriate water by sodium lignosulfonate, stir, then adds zirconium silicate, waste ceramic rejected material, aluminium nitride, titanium dioxide, Desert Sand, slag micro powder, water glass, be heated to 65-70 DEG C, after stirring reaction 30-40 minute, add mandarin oil, Trisilver phosphate, stir 20-30 minute, ultrasonic disperse 5-7 minute, filters, and dries, pulverize, cross 40 mesh sieves, under nitrogen atmosphere, 1-2 hour is calcined at 1360-1420 DEG C, pulverize, cross 40 mesh sieves, to obtain final product.
A preparation method for ceramic cutting tool material prepared by discarded glass, comprises the following steps:
(1) discarded glass particle, titanium carbide, calcium oxide, diamond, bauxitic clay, zirconium white are joined in high-speed mixer, mix under rotating speed 60-120r/min;
(2) by all the other residue compositions and appropriate water mixing, add hanker stir, after to be dissolved at 60-70 DEG C constant temperature process 30-40 minute;
(3) raw material of step (1) and step (2) is mixed, put into ball mill ball milling 2.5-4.5 hour;
(4) raw material after ball milling in step (3) is put into high temperature sintering furnace and carry out high temperature sintering, high temperature sintering furnace temperature rise rate is 250 DEG C/min, first being warming up to high temperature sintering in-furnace temperature is 650-720 DEG C, Isothermal sinter, sintering time is 2-4h, then to raise high temperature sintering in-furnace temperature be 980-1110 DEG C, Isothermal sinter, sintering time is 3-4h, and slow cooling, to obtain final product.
The invention has the advantages that:
The present invention adopts discarded glass as the main raw material preparing ceramic cutting tool material, second stage employ is carried out to discarded glass, save resource, reduce production cost, in addition, the titanium carbide added in this material, magnesium carbonate whisker, polygorskite fiber have the feature of high strength, corrosion-resistant, wear-resisting, Heat stability is good, and the ceramic cutting tool material produced is wear-resisting, good heat resistance, and intensity is high.
Embodiment
Embodiment 1
A ceramic cutting tool material prepared by discarded glass, is made up of following weight (kg) raw material: discarded glass particle 50, titanium carbide 6, calcium oxide 3, ethylene two amine hydroxybenzene 1, diamond 2, bauxitic clay 5, magnesium carbonate whisker 1, polygorskite fiber 1, zirconium white 3, hydroxypropylguar gum 1, zinc molybdate 2, modified starch 0.5, sodium carbonate 1, vinylcarbinol 4, additive 6;
Described additive is made up of following weight part (kg) raw material: zirconium silicate 20, waste ceramic rejected material 12, aluminium nitride 2, titanium dioxide 4, Desert Sand 2, slag micro powder 6, water glass 4, sodium lignosulfonate 0.5, mandarin oil 2, Trisilver phosphate 1; Preparation method is: joined in appropriate water by sodium lignosulfonate, stir, then adds zirconium silicate, waste ceramic rejected material, aluminium nitride, titanium dioxide, Desert Sand, slag micro powder, water glass, be heated to 65 DEG C, stirring reaction added mandarin oil, Trisilver phosphate after 30 minutes, stirred 20 minutes, ultrasonic disperse 5 minutes, filters, and dries, pulverize, cross 40 mesh sieves, under nitrogen atmosphere, calcine 1 hour at 1360 DEG C, pulverize, cross 40 mesh sieves, to obtain final product.
A preparation method for ceramic cutting tool material prepared by discarded glass, comprises the following steps:
(1) discarded glass particle, titanium carbide, calcium oxide, diamond, bauxitic clay, zirconium white are joined in high-speed mixer, mix under rotating speed 60r/min;
(2) by all the other residue compositions and the mixing of appropriate water, add and hanker stirring, constant temperature process 30 minutes at 60 DEG C after to be dissolved;
(3) raw material of step (1) and step (2) is mixed, put into ball mill ball milling 2.5 hours;
(4) raw material after ball milling in step (3) is put into high temperature sintering furnace and carry out high temperature sintering, high temperature sintering furnace temperature rise rate is 250 DEG C/min, first being warming up to high temperature sintering in-furnace temperature is 650 DEG C, Isothermal sinter, sintering time is 2h, then to raise high temperature sintering in-furnace temperature be 980 DEG C, Isothermal sinter, sintering time is 3h, and slow cooling, to obtain final product.
Embodiment 2
A ceramic cutting tool material prepared by discarded glass, is made up of following weight (kg) raw material: discarded glass particle 60, titanium carbide 7, calcium oxide 4, ethylene two amine hydroxybenzene 1, diamond 3, bauxitic clay 5, magnesium carbonate whisker 2, polygorskite fiber 2, zirconium white 4, hydroxypropylguar gum 1, zinc molybdate 3, modified starch 0.8, sodium carbonate 1, vinylcarbinol 5, additive 7; Described additive is made up of following weight part (kg) raw material: zirconium silicate 25, waste ceramic rejected material 14, aluminium nitride 2, titanium dioxide 5, Desert Sand 3, slag micro powder 7, water glass 5, sodium lignosulfonate 0.7, mandarin oil 3, Trisilver phosphate 1; Preparation method is: joined in appropriate water by sodium lignosulfonate, stir, then adds zirconium silicate, waste ceramic rejected material, aluminium nitride, titanium dioxide, Desert Sand, slag micro powder, water glass, be heated to 68 DEG C, stirring reaction added mandarin oil, Trisilver phosphate after 35 minutes, stirred 25 minutes, ultrasonic disperse 6 minutes, filters, and dries, pulverize, cross 40 mesh sieves, under nitrogen atmosphere, calcine 1.5 hours at 1390 DEG C, pulverize, cross 40 mesh sieves, to obtain final product.
A preparation method for ceramic cutting tool material prepared by discarded glass, comprises the following steps:
(1) discarded glass particle, titanium carbide, calcium oxide, diamond, bauxitic clay, zirconium white are joined in high-speed mixer, mix under rotating speed 90r/min;
(2) by all the other residue compositions and the mixing of appropriate water, add and hanker stirring, constant temperature process 35 minutes at 65 DEG C after to be dissolved;
(3) raw material of step (1) and step (2) is mixed, put into ball mill ball milling 3 hours;
(4) raw material after ball milling in step (3) is put into high temperature sintering furnace and carry out high temperature sintering, high temperature sintering furnace temperature rise rate is 250 DEG C/min, first being warming up to high temperature sintering in-furnace temperature is 680 DEG C, Isothermal sinter, sintering time is 3h, then to raise high temperature sintering in-furnace temperature be 995 DEG C, Isothermal sinter, sintering time is 3.5h, and slow cooling, to obtain final product.
Embodiment 3
A ceramic cutting tool material prepared by discarded glass, is made up of following weight (kg) raw material: discarded glass particle 70, titanium carbide 8, calcium oxide 5, ethylene two amine hydroxybenzene 2, diamond 3, bauxitic clay 6, magnesium carbonate whisker 2, polygorskite fiber 3, zirconium white 5, hydroxypropylguar gum 2, zinc molybdate 3, modified starch 1, sodium carbonate 2, vinylcarbinol 6, additive 7; Described additive is made up of following weight part (kg) raw material: zirconium silicate 30, waste ceramic rejected material 15, aluminium nitride 3, titanium dioxide 6, Desert Sand 4, slag micro powder 8, water glass 6, sodium lignosulfonate 1, mandarin oil 4, Trisilver phosphate 2; Preparation method is: joined in appropriate water by sodium lignosulfonate, stir, then adds zirconium silicate, waste ceramic rejected material, aluminium nitride, titanium dioxide, Desert Sand, slag micro powder, water glass, be heated to 70 DEG C, stirring reaction added mandarin oil, Trisilver phosphate after 40 minutes, stirred 30 minutes, ultrasonic disperse 7 minutes, filters, and dries, pulverize, cross 40 mesh sieves, under nitrogen atmosphere, calcine 2 hours at 1420 DEG C, pulverize, cross 40 mesh sieves, to obtain final product.
A preparation method for ceramic cutting tool material prepared by discarded glass, comprises the following steps:
(1) discarded glass particle, titanium carbide, calcium oxide, diamond, bauxitic clay, zirconium white are joined in high-speed mixer, mix under rotating speed 120r/min;
(2) by all the other residue compositions and the mixing of appropriate water, add and hanker stirring, constant temperature process 40 minutes at 70 DEG C after to be dissolved;
(3) raw material of step (1) and step (2) is mixed, put into ball mill ball milling 4.5 hours;
(4) raw material after ball milling in step (3) is put into high temperature sintering furnace and carry out high temperature sintering, high temperature sintering furnace temperature rise rate is 250 DEG C/min, first being warming up to high temperature sintering in-furnace temperature is 720 DEG C, Isothermal sinter, sintering time is 4h, then to raise high temperature sintering in-furnace temperature be 1110 DEG C, Isothermal sinter, sintering time is 4h, and slow cooling, to obtain final product.
The salient features detected result of the ceramic cutting tool material that above-described embodiment 1-3 obtains is as shown in the table:
The salient features detected result of the ceramic cutting tool material that table 1 embodiment 1-3 obtains
Claims (2)
1. with a ceramic cutting tool material prepared by discarded glass, it is characterized in that: be made up of following raw material: discarded glass particle 50-70, titanium carbide 6-8, calcium oxide 3-5, ethylene two amine hydroxybenzene 1-2, diamond 2-3, bauxitic clay 5-6, magnesium carbonate whisker 1-2, polygorskite fiber 1-3, zirconium white 3-5, hydroxypropylguar gum 1-2, zinc molybdate 2-3, modified starch 0.5-1, sodium carbonate 1-2, vinylcarbinol 4-6, additive 6-7;
Described additive is made up of following raw material: zirconium silicate 20-30, waste ceramic rejected material 12-15, aluminium nitride 2-3, titanium dioxide 4-6, Desert Sand 2-4, slag micro powder 6-8, water glass 4-6, sodium lignosulfonate 0.5-1, mandarin oil 2-4, Trisilver phosphate 1-2; Preparation method is: joined in appropriate water by sodium lignosulfonate, stir, then adds zirconium silicate, waste ceramic rejected material, aluminium nitride, titanium dioxide, Desert Sand, slag micro powder, water glass, be heated to 65-70 DEG C, after stirring reaction 30-40 minute, add mandarin oil, Trisilver phosphate, stir 20-30 minute, ultrasonic disperse 5-7 minute, filters, and dries, pulverize, cross 40 mesh sieves, under nitrogen atmosphere, 1-2 hour is calcined at 1360-1420 DEG C, pulverize, cross 40 mesh sieves, to obtain final product.
2. the preparation method of ceramic cutting tool material for preparing of a kind of discarded glass according to claim 1, is characterized in that comprising the following steps:
(1) discarded glass particle, titanium carbide, calcium oxide, diamond, bauxitic clay, zirconium white are joined in high-speed mixer, mix under rotating speed 60-120r/min;
(2) by all the other residue compositions and appropriate water mixing, add hanker stir, after to be dissolved at 60-70 DEG C constant temperature process 30-40 minute;
(3) raw material of step (1) and step (2) is mixed, put into ball mill ball milling 2.5-4.5 hour;
(4) raw material after ball milling in step (3) is put into high temperature sintering furnace and carry out high temperature sintering, high temperature sintering furnace temperature rise rate is 250 DEG C/min, first being warming up to high temperature sintering in-furnace temperature is 650-720 DEG C, Isothermal sinter, sintering time is 2-4h, then to raise high temperature sintering in-furnace temperature be 980-1110 DEG C, Isothermal sinter, sintering time is 3-4h, and slow cooling, to obtain final product.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106396646A (en) * | 2016-08-25 | 2017-02-15 | 佛山市东方智柏纳米材料科技有限公司 | High wear resistant ceramic tool material and preparation method thereof |
| CN107417251A (en) * | 2017-07-17 | 2017-12-01 | 张翔 | Good special cermacis of a kind of wearability and preparation method thereof |
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Patent Citations (5)
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| CN104402434A (en) * | 2014-10-23 | 2015-03-11 | 青岛智谷创新技术有限公司 | Ceramic knife with high strength |
| CN104355652A (en) * | 2014-10-27 | 2015-02-18 | 合肥市东庐机械制造有限公司 | Ceramic with good abrasion resistance for cutting tools and preparation method of ceramic |
| CN104355622A (en) * | 2014-10-29 | 2015-02-18 | 安徽省皖捷液压科技有限公司 | Phosphogypsum ceramic nozzle and preparation method thereof |
| CN104387041A (en) * | 2014-11-11 | 2015-03-04 | 合肥皖为电气设备工程有限责任公司 | Aluminum oxide ceramic for self-lubricated cutter and preparation method of aluminum oxide ceramic |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106396646A (en) * | 2016-08-25 | 2017-02-15 | 佛山市东方智柏纳米材料科技有限公司 | High wear resistant ceramic tool material and preparation method thereof |
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