CN105084485A - High-efficient waste water flocculant and preparation method thereof - Google Patents
High-efficient waste water flocculant and preparation method thereof Download PDFInfo
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- CN105084485A CN105084485A CN201510540469.9A CN201510540469A CN105084485A CN 105084485 A CN105084485 A CN 105084485A CN 201510540469 A CN201510540469 A CN 201510540469A CN 105084485 A CN105084485 A CN 105084485A
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Abstract
The invention discloses a high-efficient waste water flocculant and a preparation method thereof and belongs to the field of water treatment agents. The high-efficient waste water flocculant is prepared from the following raw materials in parts by weight: 1 to 9 parts of sodium humate, 1 to 5 parts of sepiolite, 5 to 10 parts of aluminium polychlorid, 1 to 5 parts of poly-silicon aluminum sulfate, 3 to 9 parts of magnesium sulfate, 5 to 10 parts of polyoxyethylene, 2 to 8 parts of dimethylamine, 3 to 9 parts of alginic acid, 3 to 9 parts of barium carbonate, 5 to 20 parts of coal ash and 70 to 100 parts of water. The high-efficient waste water flocculant disclosed by the invention has the advantages that flocculent precipitation time is short, the effect is good and the cost is low; the active emulsifying ability of water molecules is improved, and hazardous substances and heavy metal of water are degraded; especially, both high-concentration and high-turbidity waste water and non-biochemicalized waste water can be effectively treated, and the treated water can be recycled.
Description
Technical field
The present invention relates to a kind of efficient waste water flocculant and preparation method thereof, belong to water conditioner field.
Background technology
Flocculation applies one of the most general key link in waste water treatment process, and it affects the operation condition of follow-up flow process, final outflow water quality and cost to a great extent, thus becomes Technological research development field important in environmental engineering.Efficient flocculation technique system should be combined closely and formed by the flocculation agent of excellence, reactor and automatic control three aspects of offeing medicine, and wherein flocculation agent plays the role of a nucleus.The key of flocculation treatment technology selects suitable flocculation agent.
The sorting technique of flocculation agent is a lot, different by composition, generally can be divided into inorganic flocculating agent, organic floculant, natural flocculating agent (as biological flocculant), if according to charged character after the height of flocculating agent molecule amount, the feature of functional group and functional group's dissociation, polymer, low molecule, cationic, anionic and flocculant in non-ion type etc. can be further divided into.Wherein, inorganic flocculating agent can be divided into the large class of aluminium salt system and molysite system two by metal-salt: aluminium salt is based on Tai-Ace S 150, aluminum chloride, and molysite is based on ferric sulfate, iron(ic) chloride.Inorganic polymer flocculant is the class novel flocculant grown up on traditional molysite, aluminium salt basis the sixties in 20th century, be main product and the main direction of studying of inorganic flocculating agent, mainly comprise polyaluminium sulfate, polymerize aluminum chloride, bodied ferric sulfate, poly-ferric chloride etc.Inorganic polymer flocculant has better flocculating effect than original traditional medicament and phase dutiable value is lower, and in Japan, Russia, West Europe, Chinese production and the application all having considerable scale, the production of polymeric type medicament accounts for 30 ~ 60% of flocculation agent total amount.
High-concentration industrial-water was both different from sanitary sewage, also general industrial sewage is different from, often containing pollutents such as multiple poisonous and hazardous hardly degraded organic substance, heavy metal ion and ammonia nitrogens, complicated component, the flocculation agent such as poly-aluminium, Polyferric Sulfate of current routine due to the single treatment effect to these high-concentration waste waters of flocculation component undesirable, particularly bad to the place to go effect of dissolubility pollutant in water.So for high-concentration waste water, also lack a kind of wide spectrum, the flocculation agent that efficient, good stability, specificity are strong, flocculating property is excellent, the ratio of performance to price is moderate at present.
Summary of the invention
The object of the invention is to make up the deficiencies in the prior art, a kind of efficient waste water flocculant and preparation method thereof is provided.The composite flocculation agent flocculation sediment time of process waste water of the present invention is short, effective, cost is low, the objectionable impurities of raising water molecules activated emulsion power, degradation water and heavy metal, especially to high density, high-turbidity water with can not can effectively process by biochemical waste water, the water quality after process can realize recycling.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: a kind of efficient waste water flocculant, comprises the raw material of following parts by weight: Sodium salts humic acids 1 ~ 9 part, sepiolite 1 ~ 5 part, polymerize aluminum chloride 5 ~ 10 parts, polymeric aluminum sulfate silicate 1 ~ 5 part, 3 ~ 9 parts, magnesium sulfate, polyoxyethylene 5 ~ 10 parts, dimethylamine 2 ~ 8 parts, Lalgine 3 ~ 9 parts, barium carbonate 3 ~ 9 parts, 5 ~ 20 parts, flyash and 70 ~ 100 parts, water.
On the basis of technique scheme, the present invention can also do following improvement.
Further, the raw material of following parts by weight is comprised: Sodium salts humic acids 5 parts, sepiolite 3 parts, polymerize aluminum chloride 7 parts, polymeric aluminum sulfate silicate 3 parts, 6 parts, magnesium sulfate, polyoxyethylene 7 parts, dimethylamine 5 parts, Lalgine 6 parts, barium carbonate 6 parts, 12 parts, flyash and 85 parts, water.
A kind of preparation method of efficient waste water flocculant, comprise the steps: the raw material getting following parts by weight: Sodium salts humic acids 1 ~ 9 part, sepiolite 1 ~ 5 part, polymerize aluminum chloride 5 ~ 10 parts, polymeric aluminum sulfate silicate 1 ~ 5 part, 3 ~ 9 parts, magnesium sulfate, polyoxyethylene 5 ~ 10 parts, dimethylamine 2 ~ 8 parts, Lalgine 3 ~ 9 parts, barium carbonate 3 ~ 9 parts, 5 ~ 20 parts, flyash, after mixing, pulverize, add the water that parts by weight are 70 ~ 100 parts, after ball milling, dry, sieve, obtain described efficient waste water flocculant.
On the basis of technique scheme, the present invention can also do following improvement.
Further, the parts by weight of described raw material are: Sodium salts humic acids 5 parts, sepiolite 3 parts, polymerize aluminum chloride 7 parts, polymeric aluminum sulfate silicate 3 parts, 6 parts, magnesium sulfate, polyoxyethylene 7 parts, dimethylamine 5 parts, Lalgine 6 parts, barium carbonate 6 parts, 12 parts, flyash, the parts by weight of described water are 85 parts, described in the order number that sieves be 100 ~ 200 orders.
The invention has the beneficial effects as follows:
(1) the efficient waste water flocculant flocculation sediment time of the present invention is short, effective, cost is low, the objectionable impurities of raising water molecules activated emulsion power, degradation water and heavy metal, especially to high density, high-turbidity water with can not can effectively process by biochemical waste water, the water quality after process can realize recycling.
(2) simple, with low cost, the excellent property of formula of the present invention, is applicable to large-scale production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
A kind of efficient waste water flocculant, comprises the raw material of following weight: Sodium salts humic acids 1kg, sepiolite 5kg, polymerize aluminum chloride 5kg, polymeric aluminum sulfate silicate 5kg, magnesium sulfate 3kg, polyoxyethylene 10kg, dimethylamine 2kg, Lalgine 9kg, barium carbonate 3kg, flyash 20kg and water 70L.
A kind of preparation method of efficient waste water flocculant, comprise the steps: the raw material getting following weight: Sodium salts humic acids 1kg, sepiolite 5kg, polymerize aluminum chloride 5kg, polymeric aluminum sulfate silicate 5kg, magnesium sulfate 3kg, polyoxyethylene 10kg, dimethylamine 2kg, Lalgine 9kg, barium carbonate 3kg, flyash 20kg, after mixing, pulverize, add the water of 70L, after ball milling, dry, cross 100 ~ 200 mesh sieves, obtain described efficient waste water flocculant.
Embodiment 2:
A kind of efficient waste water flocculant, comprises the raw material of following weight: Sodium salts humic acids 5kg, sepiolite 3kg, polymerize aluminum chloride 7kg, polymeric aluminum sulfate silicate 3kg, magnesium sulfate 6kg, polyoxyethylene 7kg, dimethylamine 5kg, Lalgine 6kg, barium carbonate 6kg, flyash 12kg and water 85L.
A kind of preparation method of efficient waste water flocculant, comprise the steps: the raw material getting following weight: Sodium salts humic acids 5kg, sepiolite 3kg, polymerize aluminum chloride 7kg, polymeric aluminum sulfate silicate 3kg, magnesium sulfate 6kg, polyoxyethylene 7kg, dimethylamine 5kg, Lalgine 6kg, barium carbonate 6kg, flyash 12kg, after mixing, pulverize, add the water of 85L, after ball milling, dry, cross 100 ~ 200 mesh sieves, obtain described efficient waste water flocculant.
Embodiment 3:
A kind of efficient waste water flocculant, comprises the raw material of following weight: Sodium salts humic acids 9kg, sepiolite 1kg, polymerize aluminum chloride 10kg, polymeric aluminum sulfate silicate 1kg, magnesium sulfate 9kg, polyoxyethylene 5kg, dimethylamine 8kg, Lalgine 3kg, barium carbonate 9kg, flyash 5kg and water 100L.
A kind of preparation method of efficient waste water flocculant, comprise the steps: the raw material getting following weight: Sodium salts humic acids 9kg, sepiolite 1kg, polymerize aluminum chloride 10kg, polymeric aluminum sulfate silicate 1kg, magnesium sulfate 9kg, polyoxyethylene 5kg, dimethylamine 8kg, Lalgine 3kg, barium carbonate 9kg, flyash 5kg, add the water of 100L, after ball milling, dry, cross 100 ~ 200 mesh sieves, obtain described efficient waste water flocculant.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. an efficient waste water flocculant, it is characterized in that, comprise the raw material of following parts by weight: Sodium salts humic acids 1 ~ 9 part, sepiolite 1 ~ 5 part, polymerize aluminum chloride 5 ~ 10 parts, polymeric aluminum sulfate silicate 1 ~ 5 part, 3 ~ 9 parts, magnesium sulfate, polyoxyethylene 5 ~ 10 parts, dimethylamine 2 ~ 8 parts, Lalgine 3 ~ 9 parts, barium carbonate 3 ~ 9 parts, 5 ~ 20 parts, flyash and 70 ~ 100 parts, water.
2. the efficient waste water flocculant of one according to claim 1, it is characterized in that, comprise the raw material of following parts by weight: Sodium salts humic acids 5 parts, sepiolite 3 parts, polymerize aluminum chloride 7 parts, polymeric aluminum sulfate silicate 3 parts, 6 parts, magnesium sulfate, polyoxyethylene 7 parts, dimethylamine 5 parts, Lalgine 6 parts, barium carbonate 6 parts, 12 parts, flyash and 85 parts, water.
3. the preparation method of an efficient waste water flocculant, it is characterized in that, comprise the steps: the raw material getting following parts by weight: Sodium salts humic acids 1 ~ 9 part, sepiolite 1 ~ 5 part, polymerize aluminum chloride 5 ~ 10 parts, polymeric aluminum sulfate silicate 1 ~ 5 part, 3 ~ 9 parts, magnesium sulfate, polyoxyethylene 5 ~ 10 parts, dimethylamine 2 ~ 8 parts, Lalgine 3 ~ 9 parts, barium carbonate 3 ~ 9 parts, 5 ~ 20 parts, flyash, after mixing, pulverize, add the water that parts by weight are 70 ~ 100 parts, after ball milling, dry, sieve, obtain described efficient waste water flocculant.
4. the preparation method of a kind of efficient waste water flocculant according to claim 3, it is characterized in that, the parts by weight of described raw material are: Sodium salts humic acids 5 parts, sepiolite 3 parts, polymerize aluminum chloride 7 parts, polymeric aluminum sulfate silicate 3 parts, 6 parts, magnesium sulfate, polyoxyethylene 7 parts, dimethylamine 5 parts, Lalgine 6 parts, barium carbonate 6 parts, 12 parts, flyash, the parts by weight of described water are 85 parts, described in the order number that sieves be 100 ~ 200 orders.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106186233A (en) * | 2016-08-18 | 2016-12-07 | 桂林市春晓环保科技有限公司 | A kind of efficiently waste water flocculant and preparation method thereof |
CN110092568A (en) * | 2019-04-11 | 2019-08-06 | 湖南锦佳环保科技有限公司 | A kind of filters pressing filter aid and its application method for shield engineering slurry |
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CN103351074A (en) * | 2013-07-23 | 2013-10-16 | 铸神科技无锡有限公司 | Electrochemical sewage disposal method |
CN104445550A (en) * | 2014-11-13 | 2015-03-25 | 无锡伊佩克科技有限公司 | Preparation method of heavy metal sewage treatment medicament |
CN104445556A (en) * | 2014-12-12 | 2015-03-25 | 天长市飞龙金属制品有限公司 | Efficient sewage treatment agent |
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- 2015-08-28 CN CN201510540469.9A patent/CN105084485A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103351074A (en) * | 2013-07-23 | 2013-10-16 | 铸神科技无锡有限公司 | Electrochemical sewage disposal method |
CN104445550A (en) * | 2014-11-13 | 2015-03-25 | 无锡伊佩克科技有限公司 | Preparation method of heavy metal sewage treatment medicament |
CN104445556A (en) * | 2014-12-12 | 2015-03-25 | 天长市飞龙金属制品有限公司 | Efficient sewage treatment agent |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106186233A (en) * | 2016-08-18 | 2016-12-07 | 桂林市春晓环保科技有限公司 | A kind of efficiently waste water flocculant and preparation method thereof |
CN110092568A (en) * | 2019-04-11 | 2019-08-06 | 湖南锦佳环保科技有限公司 | A kind of filters pressing filter aid and its application method for shield engineering slurry |
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