CN105060857A - Preparation method of ceramic material and application thereof - Google Patents

Preparation method of ceramic material and application thereof Download PDF

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Publication number
CN105060857A
CN105060857A CN201510508564.0A CN201510508564A CN105060857A CN 105060857 A CN105060857 A CN 105060857A CN 201510508564 A CN201510508564 A CN 201510508564A CN 105060857 A CN105060857 A CN 105060857A
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parts
hours
stupalith
ceramic material
ceramic
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CN105060857B (en
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周佳荣
邱鹏新
蓝永辉
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Lan Yonghui
Qiu Pengxin
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Shenzhen Feishang New Material Co Ltd
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Abstract

The invention discloses a preparation method of a ceramic material and application thereof. The ceramic material includes the following components: 20-30 parts of loess, 15-18 parts of zijin wash mud, 10-12 parts of medical stone, 7-10 parts of aluminum silica, 10-15 parts of clay, 15-18 parts of talcum powder and 8-10 parts of peat soil. The method includes the following steps: mixing the raw materials, grinding, and sintering to obtain the ceramic material; the ceramic material provides the functions of water purification, health care and sterilization, and solves the problem that the current ceramic products can only provide a single function; in addition, the ceramic material can reduce the heavy metal in water and improve the theaflavin content in tea and soup, and can also provide a sterilization function and the like.

Description

A kind of preparation method of stupalith and application thereof
Technical field
The present invention relates to a kind of preparation method of pottery, particularly a kind of preparation method of stupalith and application thereof.
Background technology
Along with improving constantly of people's living standard, environment and health consciousness progressively strengthens, green material and environmentfriendly products will day by day pay close attention to by people.Healthy, long-lived, the comfortable highest goal having become modern and pursued.Antibacterial, health care, environment-protecting product arises at the historic moment, and obtains and develop rapidly.And ceramic no matter as household china or as the building town of porcelain such as household, decoration and daily life closely bound up, so the health care function of people to all kinds of ceramic is had higher requirement.
In CN1339622A document, disclose a kind of preparation method of composite ceramics, but this pottery only has the function of radiated infrared, do not have line for germicidal action.
In CN1392115A, disclose a kind of making method and purposes of multifunctional ceramic, this pottery has radiation infrared, antibacterial, water-purifying function, but does not have increase theoflavin, reduces Fe 3+and Pb 2+the function of heavy metal ion.
In USP6034013 document, disclose the glass sphere goods of a kind of infrared radiation and generation negative ion for purifying waste water, but it does not possess sterilizing function.
Although there is the special cermacis of many difference in functionalitys at present on the market, its function is all more single, and the product can with health care and purification function can meet the stupalith of people to healthy and long-lived active demand and also not see research report.
Summary of the invention
The technical problem to be solved in the present invention is: provide one to possess water purification simultaneously, the preparation method of the multifunctional ceramic of health care and sterilizing function and application, solve the situation of current ceramic product function singleness, this stupalith can have heavy metal in reduction water simultaneously, improve the several functions such as theaflavin content and sterilization in millet paste.
The technical scheme that the present invention adopts for its technical problem of solution is as follows: a kind of preparation method of stupalith: comprise the steps:
Step one, preparation raw material: loess 20 ~ 30 parts, Zijin wash 15 ~ 18 parts, mud, medical stone 10 ~ 12 parts, 7 ~ 10 parts, aluminium silica, clay 10 ~ 15 parts, talcum powder 15 ~ 18 parts, peat soil 8 ~ 10 parts;
Step 2, mudflow journey processed:
(1) medical stone 10 ~ 12 parts and talcum powder 15 ~ 18 parts of threading ball mills, adding 500ml water grinding 30 ~ 36 hours, cross 250 mesh standard sieves, obtaining medical stone and talcous mixed slurry as substantially expecting A;
(2) again clay 10 ~ 15 parts, peat soil 8 ~ 10 parts, 7 ~ 10 parts, aluminium silica, loess 20 ~ 30 parts of threading ball mills, grind 36 ~ 40 hours, crossing 400 mesh standard sieves, obtaining mixture powder as substantially expecting B;
(3) basic material A and basic material B puts into stirrer and is uniformly mixed 3 ~ 6 hours, and finally add Zijin and wash 15 ~ 18 parts, mud, continue stirring and obtain coarse fodder in 6 ~ 10 hours, the different shape idiosome that is made by handwork is waited to fire;
Step 3, fire flow process:
(1) pre-burning: temperature 450 ~ 550 DEG C, 4 ~ 6 hours time, object makes idiosome consolidation; (2) burn till: temperature 850 ~ 900 DEG C, 6 ~ 8 hours time, object makes contained element first time in formula produce new trace element by firing hybrid reaction;
(3) sinter: temperature 1085 ~ 1100 DEG C, 4 ~ 6 hours time, object is fixing for the condensation of new trace element, naturally cools to room temperature and obtains stupalith.
An application for stupalith, stupalith for the manufacture of possessing water purification, heavy metal and improve the ceramic of theaflavin content function in millet paste in health care, sterilization, reduction water.
The beneficial effect of technical scheme of the present invention is adopted to be:
1, after a large amount of inorganic raw material of ceramic applications of the present invention is mixed by different ratios, fired by differing temps, make and there is water purification, the multifunctional ceramic of health care and sterilizing function.
2, the ceramic 24 hours germ-killing efficiencies to streptococcus aureus of the present invention are up to more than 99%, multifunctional ceramic efficient adsorption Fe 3+and Pb 2+heavy metal ion.
3, the present invention's pottery can increase the content of theoflavin in millet paste, compares conventional ceramic, theaflavin content increase about 0.8 times in 10 minutes.
Add Zijin in the raw material of 4, pottery of the present invention and wash mud, make finished product pottery have the effect of purification, sterilization and health care, and technique simply, starting material such as easily to obtain at the advantage.
Accompanying drawing explanation
The pottery powder that Fig. 1 is different mass puts the antibacterial circle diameter that Bacterial Plate is surveyed;
Fig. 2 is the theoflavin concentration that after haydite/bottle put by millet paste, different time detects gained.
Embodiment
Below in conjunction with accompanying drawing, the specific embodiment of the present invention is described.
Embodiment 1
A kind of preparation method of stupalith is: comprise the steps:
Step one, preparation raw material: loess 30 parts, medical stone 12 parts, clay 10 parts, Zijin wash 18 parts, mud, 7 parts, aluminium silica, talcum powder 15 parts, peat soil 8 parts;
Step 2, mudflow journey processed:
Medical stone 12 parts and talcum powder 15 parts are first put into ball mill, add water 500ml and grind 36 hours, cross 250 mesh standard sieves, obtain medical stone and talcous mixed slurry as substantially expecting A, again clay 10 parts, peat soil 8 parts, 7 parts, aluminium silica and loess 30 parts, put into ball milling and grind 40 hours, cross 400 mesh standard sieves, finally add Zijin to wash 18 parts, mud (it is the most important that Zijin washes mud, because there being rare elements, smooth formula effect makes the element of its emperor's matter soil depend on effect), continue grinding 6 hours, obtain coarse fodder, the different shape idiosome that is made by handwork is waited to fire;
Step 3, burn till flow process:
(1) pre-burning: temperature 550 DEG C, 4 hours time, object makes idiosome consolidation; (2) burn till: temperature 850 ~ 900 DEG C, 6 ~ 8 hours time, object makes contained element first time in formula produce new trace element by firing hybrid reaction;
(3) sinter: temperature 1085 DEG C, 4 hours time, object is fixing for the condensation of new trace element, naturally cools to room temperature and obtains stupalith.
Embodiment 2 the present invention pottery is to the water purification from the beginning of containing metal lead ion and 3 valency metallic iron ions
Containing Fe 3+, Pb ion solution stream through haydite chromatography column (particle diameter: 1mm, column diameter 3.0cm, column length 90cm), described haydite is made up of ceramic material of the present invention, to cross before post and sampling detects Fe after flowing through different volumes 3+, Pb ion concentration.Result is as shown in table 1, and after in solution, lead ion crosses post 100mL, concentration is 8.3mg/kg, declines 96% before comparatively crossing post; But after mistake post 350mL, concentration rises to some extent, reaches 33mg/kg, decline about 86% compared with before mistake post.To check after pillar wash-out that the concentration of lead ion in elutriant finds that itself and the plumbum ion concentration after crossing post 350mL differ close to 1 times, the lead ion of declaratives is adsorbed in haydite, does not elute completely during wash-out.Fe 3+situation is similar to lead ion, but the concentration in elutriant is higher than Fe in the solution before upper prop 3+ionic concn, Fe is described 3+ion is combined not tight with haydite, comparatively lead ion easily elutes.
Table 1 aluminium tripoli is to Fe in solution 3+, Pb ionic concn impact
Note: lead ion content drops to minimum 8.3mg/kg by 230mg/kg before mistake post, and decline close to 30 times, the concentration of 3 valence metal ion iron drops to 0.7mg/kg by 190mg/kg, decrease beyond 270 times.
Embodiment 3 the present invention reduces the concentration of heavy metal ion lead and 3 valence metal ion iron in tap water
Bottleneck is sealed after tap water 500mL poured into by haydite/bottle, described haydite/bottle is made up of ceramics ceramic materials of the present invention, room temperature places 80 days afterwards by GB/T5009.12 ~ 2003 processing sample, ICP ~ MS(" Chinese Pharmacopoeia 2005 version annex Ⅺ D) measure the content that underwater gold belongs to ion, make comparisons with the tap water metal ion content before being positioned over haydite/bottle.
Result is as table 2, and in tap water storage haydite/bottle after 80 days, lead ion content drops to 0.0071mg/kg by storing front 0.058mg/kg, decrease beyond 8 times.The concentration of 3 valence metal ion iron drops to 0.03mg/kg by 0.27mg/kg, decrease beyond 9 times.
Content after heavy metal lead and 3 valency iron ions store different time in haydite/bottle in table 2 water
The propagation (see figure 1) of embodiment 4 the present invention pottery anti-bacteria
It utilizes antibacterial substance globulate stereo structure diffusion in the nutrient agar of coating special test bacterium, the breeding of inhibition test bacterium, formation transparent circle, i.e. inhibition zone around antibacterial substance.Pottery powder is dissolved in aqua sterilisa and makes suspension by this test, described pottery powder is made up of stupalith of the present invention, filter paper is cut into the disk that diameter is 0.5cm, filter paper is put in pottery powder suspension drenched rear air-dry, tightly be flattened on the agar media surface of inoculation test bacterial classification (streptococcus aureus), cultivate 24 hours through 37 DEG C, media surface grows thickly dotted bacterium colony, and have around sample " haloing " of not long bacterium colony.Measure the width of haloing ring, represent with millimeter.
Test-results shows, and with the increase of pottery powder suspension concentration, the diameter also corresponding increase of inhibition zone, under 20mg/mL concentration, maximum antibacterial circle diameter is 26.8mm.
Embodiment 5 pottery of the present invention is used for making tea increases theaflavin content in millet paste
The method of high performance liquid phase is adopted to detect the theaflavin content in millet paste after brewing different time with reference to efficient liquid-phase chromatography method general rule (JY/T024 ~ 1996), relatively millet paste finds after Earthen Bottle with the tea pigment content in millet paste after placing same time in ceramic tea-pot: compared with ceramic tea-pot, brew Leaf of Assam Tea after 5 minutes and 10 minutes in millet paste the content of theoflavin in Earthen Bottle comparatively ceramic tea-pot respectively high 4/5 and 1/4(see Fig. 2), result show Earthen Bottle steep the content of the effective constituent theoflavin in the millet paste of Pu'er higher than ceramic tea-pot.And after making tea in Earthen Bottle 5 or 10 minutes in millet paste the content difference of theoflavin be not more than 30%, from the angle of health care, the health value of the millet paste brewed through Earthen Bottle is far above ceramic tea-pot.
In sum, adopt haydite provided by the present invention, earthen container purifies tap water, effectively can reduce the content of heavy metal lead and 3 valency iron ions in water.It is worth mentioning that, haydite/bottle can reduce the concentration of its heavy metal lead and 3 valency iron ions in the process of making tea, and increases theaflavin content in millet paste.And pottery powder can launch 4 ~ 18 μm of far infrared rayss, and there is the function of restraining and sterilizing bacteria, if be applied to medical textile, can protect from infection and accelerating wound healing.
Finally it should be noted that, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to technical scheme of the present invention or equivalent replacement, and not departing from the spirit and scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.

Claims (2)

1. a preparation method for stupalith, is characterized in that: comprise the steps:
Step one, preparation raw material: loess 20 ~ 30 parts, Zijin wash 15 ~ 18 parts, mud, medical stone 10 ~ 12 parts, 7 ~ 10 parts, aluminium silica, clay 10 ~ 15 parts, talcum powder 15 ~ 18 parts, peat soil 8 ~ 10 parts;
Step 2, mudflow journey processed:
(1) medical stone 10 ~ 12 parts and talcum powder 15 ~ 18 parts of threading ball mills, adding 500ml water grinding 30 ~ 36 hours, cross 250 mesh standard sieves, obtaining medical stone and talcous mixed slurry as substantially expecting A;
(2) again clay 10 ~ 15 parts, peat soil 8 ~ 10 parts, 7 ~ 10 parts, aluminium silica, loess 20 ~ 30 parts of threading ball mills, grind 36 ~ 40 hours, crossing 400 mesh standard sieves, obtaining mixture powder as substantially expecting B;
(3) basic material A and basic material B puts into stirrer and is uniformly mixed 3 ~ 6 hours, and finally add Zijin and wash 15 ~ 18 parts, mud, continue stirring and obtain coarse fodder in 6 ~ 10 hours, the different shape idiosome that is made by handwork is waited to fire;
Step 3, fire flow process:
(1) pre-burning: temperature 450 ~ 550 DEG C, 4 ~ 6 hours time, object makes idiosome consolidation; (2) burn till: temperature 850 ~ 900 DEG C, 6 ~ 8 hours time, object makes contained element first time in formula produce new trace element by firing hybrid reaction;
(3) sinter: temperature 1085 ~ 1100 DEG C, 4 ~ 6 hours time, object is fixing for the condensation of new trace element, naturally cools to room temperature and obtains stupalith.
2. an application for a kind of stupalith according to claim 1, is characterized in that: stupalith for the manufacture of possessing water purification, heavy metal and improve the ceramic of theaflavin content function in millet paste in health care, sterilization, reduction water.
CN201510508564.0A 2015-08-19 2015-08-19 A kind of preparation method and applications of ceramic material Active CN105060857B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1450019A (en) * 2003-05-03 2003-10-22 潮州绿环陶瓷资源综合利用有限公司 Method for utilizing waste ceramic and the made ceramic mud thereby
CN101555129A (en) * 2009-05-12 2009-10-14 潮州市联源陶瓷制作有限公司 Household strengthen porcelain containing bone substances and production technology thereof
CN102515738A (en) * 2011-12-14 2012-06-27 潮州市海鸿陶瓷制作有限公司 Bone china and preparation method thereof
CN103539430A (en) * 2013-09-26 2014-01-29 广东尚高科技有限公司 Recycling method and application of ceramic waste mud
CN103641445A (en) * 2013-11-22 2014-03-19 广东尚高科技有限公司 Reuse method for waste ceramics

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1450019A (en) * 2003-05-03 2003-10-22 潮州绿环陶瓷资源综合利用有限公司 Method for utilizing waste ceramic and the made ceramic mud thereby
CN101555129A (en) * 2009-05-12 2009-10-14 潮州市联源陶瓷制作有限公司 Household strengthen porcelain containing bone substances and production technology thereof
CN102515738A (en) * 2011-12-14 2012-06-27 潮州市海鸿陶瓷制作有限公司 Bone china and preparation method thereof
CN103539430A (en) * 2013-09-26 2014-01-29 广东尚高科技有限公司 Recycling method and application of ceramic waste mud
CN103641445A (en) * 2013-11-22 2014-03-19 广东尚高科技有限公司 Reuse method for waste ceramics

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Inventor after: Lan Yonghui

Inventor after: Qiu Pengxin

Inventor before: Zhou Jiarong

Inventor before: Qiu Pengxin

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Effective date of registration: 20170531

Address after: Shenzhen City, Guangdong province Baotong building 518101 Baoan District Xin'an Street 13 Bao min road 609 room

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Applicant after: Qiu Pengxin

Address before: Shenzhen City, Guangdong province Baotong building 518101 Baoan District Xin'an Street 13 Bao min road 609 room

Applicant before: SHENZHEN FEISHANG NEW MATERIAL CO., LTD.

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