CN105058934A - Polyester film with high light transmittance and preparation method thereof - Google Patents
Polyester film with high light transmittance and preparation method thereof Download PDFInfo
- Publication number
- CN105058934A CN105058934A CN201510527693.4A CN201510527693A CN105058934A CN 105058934 A CN105058934 A CN 105058934A CN 201510527693 A CN201510527693 A CN 201510527693A CN 105058934 A CN105058934 A CN 105058934A
- Authority
- CN
- China
- Prior art keywords
- polyester film
- transmission rate
- high transmission
- mylar
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920006267 polyester film Polymers 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title claims description 12
- 238000002834 transmittance Methods 0.000 title abstract description 12
- 238000000576 coating method Methods 0.000 claims abstract description 34
- 239000011248 coating agent Substances 0.000 claims abstract description 22
- 239000002131 composite material Substances 0.000 claims abstract description 18
- 229920001225 polyester resin Polymers 0.000 claims abstract description 8
- 239000004645 polyester resin Substances 0.000 claims abstract description 8
- 229920002799 BoPET Polymers 0.000 claims description 23
- 230000005540 biological transmission Effects 0.000 claims description 23
- 239000005041 Mylar™ Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- -1 quaternary ammonium salt compound Chemical class 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 4
- 239000006081 fluorescent whitening agent Substances 0.000 claims description 4
- 239000012760 heat stabilizer Substances 0.000 claims description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 229920005749 polyurethane resin Polymers 0.000 claims description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 4
- 238000004078 waterproofing Methods 0.000 claims description 4
- 239000011247 coating layer Substances 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001558 organosilicon polymer Polymers 0.000 claims description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 11
- 229920000058 polyacrylate Polymers 0.000 abstract description 8
- 239000011527 polyurethane coating Substances 0.000 abstract description 5
- 239000012788 optical film Substances 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 2
- 230000003287 optical effect Effects 0.000 description 15
- 239000010409 thin film Substances 0.000 description 11
- 239000010408 film Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000005375 organosiloxane group Chemical group 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
- B32B2037/243—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention discloses a composite polyester film with high light transmittance, which comprises a polyester film base layer and polyester resin coatings roller-coated on two sides of the polyester film base layer, wherein the refractive index of the polyester film base layer is 1.63-1.73, and the refractive index of the polyester resin coatings roller-coated on two sides of the polyester film is 1.45-1.65. By means of the difference between the refractive index of the polyester film base layer and the refractive index of the double-sided coating, the total transmittance of light on the composite polyester film is larger than or equal to 94.1 percent, the total light transmittance of the composite polyester film is improved by larger than or equal to 5 percent compared with the total light transmittance of the polyester film base layer, and meanwhile, the surface of the composite polyester film coated with the polyurethane coating and the polyacrylate coating has good bonding strength, so that the processing technology of the composite polyester film to become an optical film is easier.
Description
Technical field
The present invention relates to a kind of composite polyester film with high transmission rate and preparation method thereof, be specifically related to a kind of polyester film with coated on both sides for photovoltaic industry and preparation method thereof.
Background technology
Optical thin film is ubiquitous in our life, from accurate and optical device, display apparatus to the optical thin film application daily life; As glasses, digital camera, the various electrical home appliances worn at ordinary times, the anti-counterfeiting technology on mobile phone, computer or banknote, all can be referred to as the application of optical film technique.If there is no optical film technique as development foundation, modern age photoelectricity, communication or radium-shine technology cannot be in progress to some extent, this also demonstrates the importance of optical film technique research and development.Optical thin film means on optical element or separate substrates, and system plates or be coated with the combination of one or more layers dielectric film or metal film or this two classes film, to change the transmission characteristic of light wave, comprises the transmission of light, reflection, absorption, scattering, polarization and phase change.Therefore can the transmitance of modulation different-waveband element surface light via suitable design, in general, the mode of production of optical thin film is mainly divided into dry method and wet method two kinds of production technologies.In daily life see the packaging film of ornamental gold, silver color or tool metal-like, be exactly the product manufactured with dry type coating method.The way that wet is general is that the composition with various function is mixed into liquid coating, is coated on base material with different processing modes, then makes liquid coating dry solidification make product.
For increasing the light transmittance of optical thin film, studies in China person adopts the power increasing light source to increase the mode of brightness, but the increase of light source power means the increase of energy consumption, consider the demand that fundamentally can not meet high transmission rate optical thin film fast continual development from the angle of energy-conserving and environment-protective.
The transmitance reducing the reflection increase light of light in the mode by covering one deck diffusion barrier at Optical Coatings Surface is mentioned in Japan Patent JP2006-163378, but the optical thin film adhesion strength of uncoated polyester coatings is poor, brings inconvenience in optical thin film aftertreatment technology; JP-A-Hei5-744633 mentions the resin-coated transmitance promoting light at Optical Coatings Surface with graft modification, owing to not considering the resin-coated adhesion strength problem of graft modification, brings inconvenience equally in optical thin film aftertreatment technology.
Summary of the invention
Technical problem to be solved by this invention is: provide a kind of polyester film with high transmission rate, it can solve the high transmission rate problem of the polyester film for optics industry, can solve the good adhesion strength problem that polyester film needs in aftertreatment technology simultaneously.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is: a kind of composite polyester film with high transmission rate, it comprises polyester film basic unit and the mylar coating of roller coat in polyester film basic unit both sides, the refractive index of described polyester film is 1.63-1.73, roller coat is 1.45-1.65 in the refractive index of the mylar coating of polyester film both sides, is coated with total transmitance >=94.1% of cated polyester film light;
Specific refractivity △ n >=0.05 of described polyester film and mylar coating, polyester coatings thickness is 50nm-150nm.
Described roller coat is the coating that polyurethane resin and/or polyacrylic resin are formed through roller coat in the mylar coating of polyester film both sides.
The side roller coat polyacrylic resin of described polyester film, the opposite side roller coat polyurethane resin of described polyester film.
For the requirement in satisfied different use field, in side mylar coating, add one or more in antistatic additive, ultra-violet absorber, waterproofing agent, levelling agent, heat stabilizer wherein;
Described antistatic additive is quaternary ammonium salt compound (mono-quaternaries, bi-quaternary ammonium salt, three quaternary ammonium salts, multi-quaternary ammonium salt or hyperbranched quaternary ammonium salt), one or more the mixture in Metal Zn, Ni metal, metal M n, metal Fe, metal A g;
Described ultra-violet absorber is benzophenone BP-4, ESCALOL 567, UV-531, benzotriazole UV1130 (BASF), 2-(2 ＇-hydroxyl-3,5 ＇-di-tert-butyl-phenyl) BTA, one or more the mixture in 2-(2 ＇-hydroxyl-3 ＇-tert-butyl group-5 '-aminomethyl phenyl)-5-chlorinated benzotriazole;
Described waterproofing agent is the compound of organosilicon alkanes, one or both mixtures of fluorochemical; Described levelling agent is one or more the mixture in organosilicon polymer EL-2829, EL-2826, EL-2825, EL-2519, EL-2513 of BYK company;
Described heat stabilizer is two (2; 4-di-tert-butyl-phenyl) pentaerythritol diphosphites; diphosphorous acid pentaerythrite distearyl alcohol ester; tricresyl phosphite (2; 4-di-tert-butyl-phenyl) ester; one or more mixture in N, N ＇-bis--(3-(3,5-di-tert-butyl-hydroxy phenyl) propiono) hexamethylene diamine.
For increasing the brightness of polyester film, add fluorescent whitening agent in side mylar coating wherein, described fluorescent whitening agent is the UvitexERH of Ciba company, one or more the mixture in ERN-P, OB-1.
For increasing transmission, in described polyester film preparation process, add one or both in filler-silicon dioxide, titanium dioxide, packing material size is 80-200nm.
Described polyester film is PET film or PC film.
Second technical problem to be solved by this invention is: provide a kind of preparation method with the composite polyester film of high transmission rate.
For solving second technical problem, the technical solution used in the present invention is: a kind of preparation method with the composite polyester film of high transmission rate, the steps include:
1) mylar is prepared by polymerisation, select add or do not add filler in polymerization process as required, the polyester resin solution of synthesis is dry, moisture control is at≤200ppm, dried mylar is put into melt extrude in equipment and cool with 70 ± 5 DEG C/min speed after extrusion molding, cooled mylar is carried out longitudinal stretching under 110 ± 5 DEG C of conditions, cross directional stretch is carried out under 140 ± 5 DEG C of conditions, obtaining thickness after carrying out thermal finalization at 200-235 DEG C is 180-300um, and refractive index is the polyester film of 1.63-1.73;
2) to solid content be 5-20%, viscosity is after the polyester resin solution of 20-60mpa.s enters curing agent, 1 ~ 3h is stirred under normal temperature (20 ~ 30 DEG C), polyester resin solution is rolled onto step 1) the polyester film both sides that obtain, controlling coating layer thickness by the mode of the distance with clearance gauge test roller coat slit is 50-150nm, after solidification to be coated, with WGT-S light transmittance mist degree analyzer test polyester film light transmittance.
Beneficial effect: in roller coat polyurethane coating and the polyacrylate coatings respectively of the polyester film two sides for photovoltaic industry, by means of the difference of the refractive index of polyester film and the refractive index of coated on both sides, make total transmitance >=94.1% of light on the cated polyester film of tool, promote transmitance >=5.0% of light at polyester film.
The polyester film surface simultaneously scribbling polyurethane coating and polyacrylate coatings has good adhesion strength, make polyester film become different purposes optical thin film preparation technology become easy, by continuous online roller coating technology, make the easy industrialization of the optical thin film of high transmission rate.
Detailed description of the invention
Embodiment 1
The preparation of uncoated polyester film
In PETG polymerization process, add the TiO that particle diameter is 100nm
2filler 400ppm, by the PETG after polymerization under 180 DEG C of conditions after dry 9h, put into melt extrude in equipment and cool with 70 ± 5 DEG C/min speed after extrusion molding, cooled PETG is carried out longitudinal stretching under 110 ± 5 DEG C of conditions, under 140 ± 5 DEG C of conditions, carry out cross directional stretch, after carrying out thermal finalization at 200-235 DEG C, obtain required polyester film.
The polyester film test data of preparation is as follows
| Project name | Thickness (um) | Refractive index | Light transmittance |
| Pet film | 200um | 1.64 | 88.3％ |
Embodiment 2
Two sides is coated with the polyester film of polyurethane coating
Be 5.5% to solid content, viscosity is the wetting agent adding 0.1g organosiloxane class in the polyurethane solutions of 20mpa.s, curing agent N, N'-dicyclohexylcarbodiimide 0.12g, after stirred at ambient temperature 1h, be coated in by roll coating model on the polyester film of example 1 by polyurethane solutions spreading rod, after waiting curing of coatings, test polyester film light transmittance is as follows
Embodiment 3
Two sides is coated with the polyester film of polyacrylate coatings
Be 5.5% to solid content, viscosity is the wetting agent adding 0.1g organosiloxane class in the polyacrylate solution of 20mpa.s, melamine-based curing agent 0.15g, after stirred at ambient temperature 1h, polyacrylate solution spreading rod is coated in by roll coating model on the polyester film of example 1, after curing of coatings, test polyester film light transmittance is as follows
Embodiment 4
Two sides is coated with the polyester film of polyacrylate and polyurethane coating respectively
By the polyurethane of preparation in example 2 and example 3, polyacrylate solution, roller coat is on the two sides of polyester film respectively, and after solidification, the light transmittance of testing film is as follows
Claims (10)
1. one kind has the composite polyester film of high transmission rate, it is characterized in that: comprise polyester film basic unit and the mylar coating of roller coat in polyester film basic unit both sides, the refractive index of described polyester film basic unit is 1.63-1.73, and roller coat is 1.45-1.65 in the refractive index of the mylar coating of polyester film both sides;
Specific refractivity △ n >=0.05 of described polyester film basic unit and mylar coating, mylar coating layer thickness is 50nm-150nm.
2. a kind of composite polyester film with high transmission rate according to claim 1, is characterized in that: described roller coat is the coating that polyurethane resin and/or polyacrylic resin are formed through roller coat in the mylar coating of polyester film basic unit both sides.
3. a kind of composite polyester film with high transmission rate according to claim 2, is characterized in that: the side roller coat polyacrylic resin of described polyester film basic unit, the opposite side roller coat polyurethane resin of described polyester film basic unit.
4. a kind of composite polyester film with high transmission rate according to claim 1, it is characterized in that: described mylar coating, in the mylar coating of wherein side, add one or more in antistatic additive, ultra-violet absorber, waterproofing agent, levelling agent, heat stabilizer.
5. a kind of composite polyester film with high transmission rate according to claim 4, is characterized in that: described antistatic additive is one or more the mixture in quaternary ammonium salt compound, Metal Zn, Ni metal, metal M n, metal Fe, metal A g;
Described ultra-violet absorber is benzophenone BP-4, ESCALOL 567, UV-531, benzotriazole UV1130,2-(2 ＇-hydroxyl-3,5 ＇-di-tert-butyl-phenyl) BTA, one or more the mixture in 2-(2 ＇-hydroxyl-3 ＇-tert-butyl group-5 ＇-aminomethyl phenyl)-5-chlorinated benzotriazole;
Described waterproofing agent is the compound of organosilicon alkanes, one or both mixture of fluorochemical;
Described levelling agent is one or more the mixture in organosilicon polymer EL-2829, EL-2826, EL-2825, EL-2519, EL-2513;
Described heat stabilizer is two (2; 4-di-tert-butyl-phenyl) pentaerythritol diphosphites; diphosphorous acid pentaerythrite distearyl alcohol ester; tricresyl phosphite (2; 4-di-tert-butyl-phenyl) ester; one or more mixture in N, N ＇-bis--(3-(3,5-di-tert-butyl-hydroxy phenyl) propiono) hexamethylene diamine.
6. a kind of composite polyester film with high transmission rate according to claim 5, is characterized in that: described quaternary ammonium salt compound is one or more the mixture in mono-quaternaries, bi-quaternary ammonium salt, three quaternary ammonium salts, multi-quaternary ammonium salt, hyperbranched quaternary ammonium salt.
7. a kind of composite polyester film with high transmission rate according to claim 1, is characterized in that: described mylar coating, adds fluorescent whitening agent in the mylar coating of wherein side;
Described fluorescent whitening agent is one or more the mixture in UvitexERH, ERN-P, OB-1.
8. one according to claim 1 has high transmission rate polyester film, it is characterized in that: add filler-silicon dioxide and/or titanium dioxide in described polyester film basic unit; Packing material size is 80-200nm.
9. one according to claim 1 has high transmission rate polyester film, it is characterized in that: described polyester film is PET film or PC film.
10. a kind of preparation method with the composite polyester film of high transmission rate according to claim 1, the steps include:
1) mylar is prepared by polymerisation, select add or do not add filler in polymerization process as required, the polyester resin solution of synthesis is dried to moisture content≤200ppm, dried mylar cools with 70 ± 5 DEG C/min speed after extrusion molding by melt extruding in equipment, cooled mylar is carried out longitudinal stretching under 110 ± 5 DEG C of conditions, cross directional stretch is carried out under 140 ± 5 DEG C of conditions, obtaining thickness after carrying out thermal finalization at 200-235 DEG C is 180-300um, and refractive index is the polyester film of 1.63-1.73;
2) to solid content be 5-20%, viscosity is after adding curing agent in the polyester resin solution of 20-60mpa.s, stir 1 ~ 3h at normal temperatures, polyester resin solution is rolled onto step 1) both sides of polyester film that obtain, control coating layer thickness is 50-150nm, obtains the composite polyester film with high transmission rate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510527693.4A CN105058934A (en) | 2015-08-25 | 2015-08-25 | Polyester film with high light transmittance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510527693.4A CN105058934A (en) | 2015-08-25 | 2015-08-25 | Polyester film with high light transmittance and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105058934A true CN105058934A (en) | 2015-11-18 |
Family
ID=54488548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510527693.4A Pending CN105058934A (en) | 2015-08-25 | 2015-08-25 | Polyester film with high light transmittance and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105058934A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106926534A (en) * | 2017-03-09 | 2017-07-07 | 杭州福斯特应用材料股份有限公司 | A kind of functional film of hot melting cohesion |
| CN108384037A (en) * | 2018-03-01 | 2018-08-10 | 苏州维洛克电子科技有限公司 | A kind of polyester film and preparation method thereof containing carbamide |
| CN108559119A (en) * | 2018-01-31 | 2018-09-21 | 苏州维洛克电子科技有限公司 | Flame retardant polyester sheet material of without phosphorus Halogen and preparation method thereof |
| CN109310055A (en) * | 2016-05-30 | 2019-02-05 | 卢德维格斯文松股份公司 | Energy saving greenhouse curtain |
| CN111093361A (en) * | 2017-09-14 | 2020-05-01 | 卢德维格斯文松股份公司 | Greenhouse curtain |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080249226A1 (en) * | 2007-04-09 | 2008-10-09 | Nan Ya Plastics Corporation | Waterborne coating compositions for optical-use polyester film |
| CN102036818A (en) * | 2008-03-31 | 2011-04-27 | 可隆工业株式会社 | Polyester film for optical application |
| CN102514275A (en) * | 2011-11-10 | 2012-06-27 | 合肥乐凯科技产业有限公司 | Optical polyester thin film and preparation method thereof |
| CN103740251A (en) * | 2013-12-17 | 2014-04-23 | 张家港康得新光电材料有限公司 | High-adhesion aqueous coating liquid for optical polyester film |
-
2015
- 2015-08-25 CN CN201510527693.4A patent/CN105058934A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080249226A1 (en) * | 2007-04-09 | 2008-10-09 | Nan Ya Plastics Corporation | Waterborne coating compositions for optical-use polyester film |
| CN102036818A (en) * | 2008-03-31 | 2011-04-27 | 可隆工业株式会社 | Polyester film for optical application |
| CN102514275A (en) * | 2011-11-10 | 2012-06-27 | 合肥乐凯科技产业有限公司 | Optical polyester thin film and preparation method thereof |
| CN103740251A (en) * | 2013-12-17 | 2014-04-23 | 张家港康得新光电材料有限公司 | High-adhesion aqueous coating liquid for optical polyester film |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7004388B2 (en) | 2016-05-30 | 2022-01-21 | エービー ルドヴィグ スヴェンソン | Energy saving greenhouse screen |
| US11723319B2 (en) | 2016-05-30 | 2023-08-15 | Ab Ludvig Svensson | Energy saving greenhouse screen |
| KR102508728B1 (en) | 2016-05-30 | 2023-03-10 | 에이비 루드빅 스벤쏜 | Energy Saving Greenhouse Screens |
| CN109310055A (en) * | 2016-05-30 | 2019-02-05 | 卢德维格斯文松股份公司 | Energy saving greenhouse curtain |
| KR20190015714A (en) * | 2016-05-30 | 2019-02-14 | 에이비 루드빅 스벤쏜 | Energy saving greenhouse screen |
| JP2019517792A (en) * | 2016-05-30 | 2019-06-27 | エービー ルドヴィグ スヴェンソンＡｂ Ｌｕｄｖｉｇ Ｓｖｅｎｓｓｏｎ | Energy saving greenhouse screen |
| AU2017272602B2 (en) * | 2016-05-30 | 2022-08-04 | Ab Ludvig Svensson | Energy saving greenhouse screen |
| CN106926534B (en) * | 2017-03-09 | 2019-07-23 | 杭州福斯特应用材料股份有限公司 | A kind of functional film of hot melting cohesion |
| CN106926534A (en) * | 2017-03-09 | 2017-07-07 | 杭州福斯特应用材料股份有限公司 | A kind of functional film of hot melting cohesion |
| CN111093361A (en) * | 2017-09-14 | 2020-05-01 | 卢德维格斯文松股份公司 | Greenhouse curtain |
| CN111093361B (en) * | 2017-09-14 | 2022-07-01 | 卢德维格斯文松股份公司 | Greenhouse curtain |
| US12108717B2 (en) | 2017-09-14 | 2024-10-08 | Ab Ludvig Svensson | Greenhouse screen |
| CN108559119A (en) * | 2018-01-31 | 2018-09-21 | 苏州维洛克电子科技有限公司 | Flame retardant polyester sheet material of without phosphorus Halogen and preparation method thereof |
| CN108384037A (en) * | 2018-03-01 | 2018-08-10 | 苏州维洛克电子科技有限公司 | A kind of polyester film and preparation method thereof containing carbamide |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105058934A (en) | Polyester film with high light transmittance and preparation method thereof | |
| CN103926637B (en) | Optical laminate, polarizing film, image display device, the manufacturing method of image display device and image display device visibility ameliorative way | |
| Li et al. | Structure, properties and application of a novel low-glossed waterborne polyurethane | |
| CN101208383B (en) | Cellulose ester film, polarizing plate for in-plane-switching mode display and in-plane-switching mode display using the cellulose ester film | |
| CN106414566B (en) | Polyester film, the manufacturing method of polyester film, polarizing film, image display device and liquid crystal display device | |
| CN102725141B (en) | Hyaline membrane and utilization thereof | |
| CN104354362B (en) | A kind of superelevation intercepts transparent alumina-plated film and manufacture method thereof | |
| CN101565919B (en) | Matte release paper for synthetic leather | |
| CN102514275B (en) | A kind of optical polyester film and preparation method thereof | |
| TW200940616A (en) | Polyester film for optical application | |
| EP2377685B1 (en) | Interior film having a mirror-finished surface property and manufacturing method thereof | |
| CN105103014A (en) | Polarizing plate and image display device | |
| CN103738026B (en) | A kind of low water vapor transmittance polyester film of polyurethane-type coating and its preparation method | |
| CN103753924B (en) | A kind of high transparent polyester film and preparation method thereof | |
| CN110305348A (en) | A kind of multilayered structure and its preparation method and application | |
| Wen et al. | Mg‐Doped VO2@ ZrO2 Core− Shell Nanoflakes for Thermochromic Smart Windows with Enhanced Performance | |
| CN107249886B (en) | Stack membrane and its manufacturing method | |
| CN101327480B (en) | Method for producing transparent antistatic polyester film for protecting LCD screen | |
| CN103249539B (en) | Polyester film and manufacture method, backboard used for solar batteries and solar module | |
| CN103165237B (en) | A kind of halogen-free flame retardant copper-plastic composite belt and preparation thereof | |
| CN103753925B (en) | A kind of acrylic type coating low water vapor transmittance mylar and preparation method thereof | |
| CN112321876A (en) | PVOH (polyvinyl alcohol) coating film for protecting printing surface and preparation method thereof | |
| KR101233507B1 (en) | Cr-Free surface treatment compositions, and method for producing galvanized steel sheet using thereof, and galvanized steel sheet | |
| CN102257409B (en) | Light reflector and surface light source apparatus | |
| CN106752321A (en) | White ink with superpower covering performance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20151118 |
|
| WD01 | Invention patent application deemed withdrawn after publication |