CN105037926A - Polypropylene composite material with high impact resistance - Google Patents
Polypropylene composite material with high impact resistance Download PDFInfo
- Publication number
- CN105037926A CN105037926A CN201510360829.7A CN201510360829A CN105037926A CN 105037926 A CN105037926 A CN 105037926A CN 201510360829 A CN201510360829 A CN 201510360829A CN 105037926 A CN105037926 A CN 105037926A
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- CN
- China
- Prior art keywords
- parts
- high impact
- composite material
- polypropylene
- polypropylene composite
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A polypropylene composite material with high impact resistance is prepared from the following raw materials in parts by weight: 40-60 parts of polypropylene, 14-22 parts of nano calcium carbonate, 2-4 parts of compatilizer, 2-5 parts of fire retardant, 12-17 parts of ammonium tetramolybdate, 2-4 parts of maleic anhydride, 20-35 parts of glass fiber, 6-9 parts of polycarbonate, 2-4 parts of magnesium palmitate soap, 8-14 parts of silicon dioxide, 3-5 parts of copper powder, 4-7 parts of silicon resin, 7-12 parts of ABS, 10-16 parts of micromolecule chain extender and 12-18 parts of oligomer polyhydric alcohols. The polypropylene composite material with high impact resistance has beneficial effects of high impact strength, good mobility, increased rigidity, heat resistance, difficulty in aging and simple preparation method.
Description
Technical field
The present invention relates to a kind of polypropylene composite material of high impact-resistant.
Background technology
Polyacrylic degree of crystallinity is high, compound with regular structure, thus has excellent mechanical property, and the absolute value of Mechanical Properties of PP is higher than polyethylene.Polypropylene has higher tensile strength, but with the raising of isotactic index, the shock strength of material declines to some extent.PP be used for automotive industry there is stronger competitive power, but because of its modulus and thermotolerance lower, shock strength is poor, therefore can not directly be used as auto parts machinery, use polypropylene composite material improve performance, enhancing shock resistance.Polypropylene (PP) is a kind of general-purpose plastics of high comprehensive performance, can obtain high strength, high tenacity PP matrix material by composite.This kind of matrix material is widely used in the fields such as automobile, household electrical appliances, packaging.At automotive field, high-impact PP matrix material has become the main flow of automobile bumper material.In PP blending and modifying, toughening modifying is one of main research direction, both at home and abroad the research report of existing many this respects, and the high-impact PP developed is widely used as material dedicated for bumper.But Polypropylene For Low-temperature Resistance impact is poor in the market, and especially low-temperature impact resistance is more bad, and creep resistant is poor, more aging, make it apply and be limited by very large, require further improvement.
Summary of the invention
For the deficiencies in the prior art, the problem to be solved in the present invention is, provides a kind of polypropylene composite material of high impact-resistant, and shock strength is high, good fluidity, adds the rigidity of matrix material, thermotolerance, and not easily aging, preparation method is simple.
For solving prior art problem, technical scheme provided by the invention is, a kind of polypropylene composite material of high impact-resistant, and it is made up of the raw material of following parts by weight:
Polypropylene 40-60 part, nano-calcium carbonate 14-22 part, compatilizer 2-4 part, fire retardant 2-5 part, ammonium tetramolybdate 12-17 part, maleic anhydride 2-4 part, glass fibre 20-35 part, polycarbonate 6-9 part, palmitinic acid magnesium soap 2-4 part, silicon-dioxide 8-14 part, copper powder 3-5 part, silicone resin 4-7 part, ABS7-12 part, small molecule chain extender 10-16 part, oligomer polyol 12-18 part.
The invention has the beneficial effects as follows: the polypropylene composite material of high impact-resistant of the present invention, shock strength be high, good fluidity, add the rigidity of matrix material, thermotolerance, not easily aging, preparation method is simple.
Embodiment
embodiment 1
A polypropylene composite material for high impact-resistant, it is made up of the raw material of following parts by weight:
Polypropylene 40 parts, nano-calcium carbonate 14 parts, compatilizer 2 parts, fire retardant 2 parts, ammonium tetramolybdate 12 parts, maleic anhydride 2 parts, 20 parts, glass fibre, polycarbonate 6 parts, palmitinic acid magnesium soap 2 parts, silicon-dioxide 8 parts, copper powder 3 parts, silicone resin 4 parts, ABS7 part, small molecule chain extender 10 parts, oligomer polyol 12 parts.
embodiment 2
A polypropylene composite material for high impact-resistant, it is made up of the raw material of following parts by weight:
Polypropylene 60 parts, nano-calcium carbonate 22 parts, compatilizer 4 parts, fire retardant 5 parts, ammonium tetramolybdate 17 parts, maleic anhydride 4 parts, 35 parts, glass fibre, polycarbonate 9 parts, palmitinic acid magnesium soap 4 parts, silica 14 parts, copper powder 5 parts, silicone resin 7 parts, ABS12 part, small molecule chain extender 16 parts, oligomer polyol 18 parts.
Claims (1)
1. a polypropylene composite material for high impact-resistant, is characterized in that: it is made up of the raw material of following parts by weight:
Polypropylene 40-60 part, nano-calcium carbonate 14-22 part, compatilizer 2-4 part, fire retardant 2-5 part, ammonium tetramolybdate 12-17 part, maleic anhydride 2-4 part, glass fibre 20-35 part, polycarbonate 6-9 part, palmitinic acid magnesium soap 2-4 part, silicon-dioxide 8-14 part, copper powder 3-5 part, silicone resin 4-7 part, ABS7-12 part, small molecule chain extender 10-16 part, oligomer polyol 12-18 part.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510360829.7A CN105037926A (en) | 2015-06-26 | 2015-06-26 | Polypropylene composite material with high impact resistance |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510360829.7A CN105037926A (en) | 2015-06-26 | 2015-06-26 | Polypropylene composite material with high impact resistance |
Publications (1)
Publication Number | Publication Date |
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CN105037926A true CN105037926A (en) | 2015-11-11 |
Family
ID=54444923
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201510360829.7A Pending CN105037926A (en) | 2015-06-26 | 2015-06-26 | Polypropylene composite material with high impact resistance |
Country Status (1)
Country | Link |
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CN (1) | CN105037926A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106566086A (en) * | 2016-11-07 | 2017-04-19 | 惠州航创密封件有限公司 | PP modified material and preparation method thereof |
CN107177103A (en) * | 2017-07-18 | 2017-09-19 | 合肥万之景门窗有限公司 | A kind of heat-proof combustion-resistant plastic sheeting and preparation method thereof |
WO2019047405A1 (en) * | 2017-09-06 | 2019-03-14 | 冉宏敏 | Composite material for vehicle bumper and preparation method therefor |
-
2015
- 2015-06-26 CN CN201510360829.7A patent/CN105037926A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106566086A (en) * | 2016-11-07 | 2017-04-19 | 惠州航创密封件有限公司 | PP modified material and preparation method thereof |
CN107177103A (en) * | 2017-07-18 | 2017-09-19 | 合肥万之景门窗有限公司 | A kind of heat-proof combustion-resistant plastic sheeting and preparation method thereof |
WO2019047405A1 (en) * | 2017-09-06 | 2019-03-14 | 冉宏敏 | Composite material for vehicle bumper and preparation method therefor |
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Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20151111 |
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WD01 | Invention patent application deemed withdrawn after publication |