CN105036429B - Papermaking wastewater treatment method - Google Patents

Papermaking wastewater treatment method Download PDF

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Publication number
CN105036429B
CN105036429B CN201510456628.7A CN201510456628A CN105036429B CN 105036429 B CN105036429 B CN 105036429B CN 201510456628 A CN201510456628 A CN 201510456628A CN 105036429 B CN105036429 B CN 105036429B
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papermaking wastewater
minute
stirring
polyoxypropylene diol
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CN105036429A (en
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谢云军
汪祖生
张斌
李文静
曹景怡
吴浩
闫丽杰
涂灿
吴文雯
张翔
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Shenzhen environmental science and Technology Co., Ltd.
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Shenzhen Environmental Science And Technology Co Ltd
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Abstract

The invention relates to a papermaking wastewater treatment method. The papermaking wastewater treatment method comprises the following steps: (1) enabling papermaking wastewater to pass through a grating at first to filter large-sized impurities in wastewater and then to flow into an adjusting sedimentation tank; (2) adding diacetone acrylamide, polyoxyethylene alkyl amine, polyacrylamide and tetradecyl dimethyl ammonium chilride, and leaving to stand after stirring; (3) adding etherified starch, bentonite, potassium alginate and sodium 3-nitrobenzene sulfonate into papermaking wastewater, and leaving to stand after stirring; (4) adding a polyoxypropylene diol I, pentaerythritol, polyoxyethylene fatty alcohol, a polyoxypropylene diol II and alpha-aminoisocaproic acid, leaving to stand after stirring, and carrying out filtering to remove sediments and impurities; (5) feeding filtering clear liquid obtained in the step (4) into an ultraviolet disinfection tank for ultraviolet sterilization and disinfection. The papermaking wastewater treatment method is low in consumption of a treating agent, and particularly suitable for treating high-concentration papermaking wastewater.

Description

A kind of processing method of papermaking wastewater
Technical field
The present invention relates to the processing method of papermaking wastewater, belong to water treatment field.
Background technology
It is raw material that paper industry uses timber, Caulis et Folium Oryzae, phragmites communiss, rag etc., isolates cellulose through High Temperature High Pressure steaming and decocting, Make paper pulp.In process of production, the non-cellulose part finally discharged in raw material becomes black liquid.Contain wooden in black liquor Element, cellulose, VFA etc., heavy metal contaminants, frowziness, contaminative is very strong, can severe contamination water resource, make Become ecological balance, the sewage handling problem in current paper mill is very serious, and high expensive is so that the paper waste in paper mill Become one of great water pollution source, it administers further urgent, and the method administered at present has sedimentation, biological decomposition method, electricity Solution etc., the effect of sedimentation is poor, biological decomposition method is difficult to control to and electrolysis expense is too high it is therefore desirable to a kind of use letter The administering method single, effect is good, expense is low.
Adsorption-flocculation method is a kind of process for treating waste liquid from paper mill of low cost, but flocculant single at present gives up to papermaking In liquid, the treatment effect of simultaneous multiple pollutant is not good.In addition contain aluminium element, to human body in existing flocculant more Health hazard is very big.
Content of the invention
The purpose of the present invention is to overcome the deficiencies in the prior art, provides a kind of processing method of papermaking wastewater, including as follows Process step:
(1) first by papermaking wastewater through grid, filter out large volume impurity in waste liquid, then papermaking wastewater flow into adjust heavy Shallow lake pond;
(2) N-[2-(2-methyl-4-oxopentyl) of 10-20 part, 5-10 part polyoxyethylene, 10- are added in papermaking wastewater 16 parts of polyacrylamide, the tetradecyl chloride base dimethyl benzyl ammonium of 5-10 part, after stirring 30-40 minute, standing 15-25 divides Clock;
(3) add in papermaking wastewater again the etherification starch of 2-6 part, the bentonite of 5-15 part, the potassium alginate of 8-16 part, The m-nitrobenzene sodium sulfonate of 6-12 part, stands 25-35 minute after stirring 45-60 minute;
(4) Polyoxypropylene diol of 4-10 part, the tetramethylolmethane of 10-20 part, 5-10 are added again in papermaking wastewater The fatty alcohol-polyoxyethylene ether of part, the Polyoxypropylene diol of 2-8 part, the alpha-amido isocaproic acid of 5-15 part, stirring 60-90 divides Filter after standing 40-50 minute after clock and remove precipitation and impurity;
(5) cleaner liquid excessively obtaining in step (4) is delivered to and in ultraviolet disinfection pond, carry out ultraviolet-sterilization sterilization;
Step (2), (3), the quality sum of all substances adding in (4) with the ratio of the volume of processed papermaking wastewater are 10mg/l.
Preferably, in step (2), add in papermaking wastewater 15 parts N-[2-(2-methyl-4-oxopentyl), 8 parts of polyethylene glycol oxide alkane Base amine, 12 parts of polyacrylamide, 7 parts of tetradecyl chloride base dimethyl benzyl ammonium.
Preferably, in step (3), add in papermaking wastewater 4 parts etherification starch, 10 parts of bentonite, 12 parts of sea Potassium alginate, 8 parts of m-nitrobenzene sodium sulfonate.
Preferably, in step (4), add in papermaking wastewater 6 parts Polyoxypropylene diol, 15 parts of Ji Wusi Alcohol, 8 parts of fatty alcohol-polyoxyethylene ether, 6 parts of Polyoxypropylene diol, about 10 parts of alpha-amido isocaproic acid.
The method have the advantages that
The paper making waste liquid treatment agent that the present invention provides, can simultaneously work as the effect flocculated, build bridge, adsorb, degrade.Double third Ketone acrylamide, polyoxyethylene, polyacrylamide, several material of tetradecyl chloride base dimethyl benzyl ammonium compound, Create cooperative effect, be greatly improved flocculation and bridging action.Polyoxypropylene diol, tetramethylolmethane, poly alkyl alcohol Oxygen vinyl Ether, Polyoxypropylene diol, several material of alpha-amido isocaproic acid compounding, create cooperative effect, serve good Good oxide degradation effect.Several material of etherification starch, bentonite, potassium alginate, m-nitrobenzene sodium sulfonate compounds, and creates Cooperative effect, is greatly improved the adsorption of water treatment agent, and efficiently eliminates the heavy metal ion in waste liquid.Simultaneously The functional group such as the hydroxyl that has in each component, amido, sulfonic group charge density is high, and breaking is good, good water solubility.The present invention answers The consumption closing the inorganic agent of process for treating waste liquid from paper mill is little, is directly appended in waste liquid, easy to use, processing cost is low, right Cod, bod, ss, the clearance height of heavy metal ion, are particularly well-suited to the process of high concentration papermaking wastewater.The place of the present invention simultaneously Do not contain aluminum in reason agent, secondary pollution will not be produced.
Specific embodiment
Below by embodiment, technical scheme is described in further detail.
Embodiment one:
A kind of processing method of papermaking wastewater, including following process step:
(1) first by papermaking wastewater through grid, filter out large volume impurity in waste liquid, then papermaking wastewater flow into adjust heavy Shallow lake pond;
(2) add in papermaking wastewater 20 parts N-[2-(2-methyl-4-oxopentyl), 10 parts of polyoxyethylene, 16 parts poly- Acrylamide, 10 parts of tetradecyl chloride base dimethyl benzyl ammonium, stand 15-25 minute after stirring 30-40 minute;
(3) add in papermaking wastewater again 6 parts etherification starch, 15 parts of bentonite, 16 parts of potassium alginate, 12 parts M-nitrobenzene sodium sulfonate, stands 25-35 minute after stirring 45-60 minute;
(4) add in papermaking wastewater again 10 parts Polyoxypropylene diol, 20 parts of tetramethylolmethane, 10 parts of fat Polyoxyethylenated alcohol, 8 parts of Polyoxypropylene diol, 15 parts of alpha-amido isocaproic acid, stand 40- after stirring 60-90 minute Filter after 50 minutes and remove precipitation and impurity;
(5) cleaner liquid excessively obtaining in step (4) is delivered to and in ultraviolet disinfection pond, carry out ultraviolet-sterilization sterilization;
Step (2), (3), the quality sum of all substances adding in (4) with the ratio of the volume of processed papermaking wastewater are 10mg/l.
After reaction completely, the clearance of cod is the clearance of 99.1%, bod is 99.5%, and the clearance of total suspended matter is 99.2%, the clearance of colourity is 96%, and the clearance of heavy metal ion is 99.4%.
Embodiment two:
A kind of processing method of papermaking wastewater, including following process step:
(1) first by papermaking wastewater through grid, filter out large volume impurity in waste liquid, then papermaking wastewater flow into adjust heavy Shallow lake pond;
(2) add in papermaking wastewater 10 parts N-[2-(2-methyl-4-oxopentyl), 5 parts of polyoxyethylene, 10 parts poly- Acrylamide, 5 parts of tetradecyl chloride base dimethyl benzyl ammonium, stand 15-25 minute after stirring 30-40 minute;
(3) add in papermaking wastewater again 2 parts etherification starch, 5 parts of bentonite, 8 parts of potassium alginate, between 6 parts Nitrobenzene sodium sulfonate, stands 25-35 minute after stirring 45-60 minute;
(4) add in papermaking wastewater again 4 parts Polyoxypropylene diol, 10 parts of tetramethylolmethane, 5 parts of fatty alcohol Polyoxyethylene ether, 2 parts of Polyoxypropylene diol, 5 parts of alpha-amido isocaproic acid, after stirring 60-90 minute, standing 40-50 divides Filter after clock and remove precipitation and impurity;
(5) cleaner liquid excessively obtaining in step (4) is delivered to and in ultraviolet disinfection pond, carry out ultraviolet-sterilization sterilization;
Step (2), (3), the quality sum of all substances adding in (4) with the ratio of the volume of processed papermaking wastewater are 10mg/l.
After reaction completely, the clearance of cod is the clearance of 96.4%, bod is 97.5%, and the clearance of total suspended matter is 98.4%, the clearance of colourity is 96%, and the clearance of heavy metal ion is 98.9%.
Embodiment three:
A kind of processing method of papermaking wastewater, including following process step:
(1) first by papermaking wastewater through grid, filter out large volume impurity in waste liquid, then papermaking wastewater flow into adjust heavy Shallow lake pond;
(2) add in papermaking wastewater 15 parts N-[2-(2-methyl-4-oxopentyl), 8 parts of polyoxyethylene, 12 parts poly- Acrylamide, 7 parts of tetradecyl chloride base dimethyl benzyl ammonium, stand 15-25 minute after stirring 30-40 minute;
(3) add in papermaking wastewater again 4 parts etherification starch, 10 parts of bentonite, 12 parts of potassium alginate, 8 parts M-nitrobenzene sodium sulfonate, stands 25-35 minute after stirring 45-60 minute;
(4) add in papermaking wastewater again 6 parts Polyoxypropylene diol, 15 parts of tetramethylolmethane, 8 parts of fatty alcohol Polyoxyethylene ether, 6 parts of Polyoxypropylene diol, 10 parts of alpha-amido isocaproic acid, stand 40-50 after stirring 60-90 minute Filter after minute and remove precipitation and impurity;
(5) cleaner liquid excessively obtaining in step (4) is delivered to and in ultraviolet disinfection pond, carry out ultraviolet-sterilization sterilization;
Step (2), (3), the quality sum of all substances adding in (4) with the ratio of the volume of processed papermaking wastewater are 10mg/l.
After reaction completely, the clearance of cod is the clearance of 98.1%, bod is 98.2%, and the clearance of total suspended matter is 99.2%, the clearance of colourity is 96%, and the clearance of heavy metal ion is 99.1%.
Described above has fully disclosed the specific embodiment of the present invention.It is pointed out that being familiar with this field Any change that technical staff is done to the specific embodiment of the present invention is all without departing from the model of claims of the present invention Enclose.Correspondingly, the scope of the claim of the present invention is also not limited only to previous embodiment.

Claims (4)

1. a kind of processing method of papermaking wastewater is it is characterised in that include following process step:
(1) first by papermaking wastewater through grid, filter out large volume impurity in waste liquid, then papermaking wastewater flow into adjust precipitation Pond;
(2) N-[2-(2-methyl-4-oxopentyl) of 10-20 part, 5-10 part polyoxyethylene, 10-16 part are added in papermaking wastewater Polyacrylamide, the tetradecyl chloride base dimethyl benzyl ammonium of 5-10 part, stirring 30-40 minute after stand 15-25 minute;
(3) etherification starch of 2-6 part, the bentonite of 5-15 part, the potassium alginate of 8-16 part, 6-12 are added again in papermaking wastewater The m-nitrobenzene sodium sulfonate of part, stands 25-35 minute after stirring 45-60 minute;
(4) Polyoxypropylene diol of 4-10 part, the tetramethylolmethane of 10-20 part, 5-10 part are added again in papermaking wastewater Fatty alcohol-polyoxyethylene ether, the Polyoxypropylene diol of 2-8 part, the alpha-amido isocaproic acid of 5-15 part, after stirring 60-90 minute Filter after standing 40-50 minute and remove precipitation and impurity;
(5) cleaner liquid excessively obtaining in step (4) is delivered to and in ultraviolet disinfection pond, carry out ultraviolet-sterilization sterilization;
Step (2), (3), the quality sum of all substances adding in (4) with the ratio of the volume of processed papermaking wastewater are 10mg/l.
2. processing method according to claim 1 is it is characterised in that in step (2), add 15 parts in papermaking wastewater N-[2-(2-methyl-4-oxopentyl), 8 parts of polyoxyethylene, 12 parts of polyacrylamide, 7 parts of tetradecyl chloride base dimethylbenzyl Base ammonium.
3. processing method according to claim 1 is it is characterised in that in step (3), add 4 parts in papermaking wastewater Etherification starch, 10 parts of bentonite, 12 parts of potassium alginate, 8 parts of m-nitrobenzene sodium sulfonate.
4. processing method according to claim 1 is it is characterised in that in step (4), add 6 parts in papermaking wastewater Polyoxypropylene diol, 15 parts of tetramethylolmethane, 8 parts of fatty alcohol-polyoxyethylene ether, 6 parts of Polyoxypropylene diol, 10 parts of alpha-amido isocaproic acid.
CN201510456628.7A 2015-07-30 2015-07-30 Papermaking wastewater treatment method Active CN105036429B (en)

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CN112919683A (en) * 2021-02-07 2021-06-08 汪波 Advanced biochemical treatment system for papermaking sewage

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1789159A (en) * 2005-12-05 2006-06-21 赵清顺 Sterilization inhibitor for circulated cooling water treatment
EP1950181A1 (en) * 2007-01-25 2008-07-30 GEO - Ground Engineering Operations Produtos e Solucoes de Engenharia e Geotecnia, Lda Chemical composition and process for treating geotechnical slurries

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1789159A (en) * 2005-12-05 2006-06-21 赵清顺 Sterilization inhibitor for circulated cooling water treatment
EP1950181A1 (en) * 2007-01-25 2008-07-30 GEO - Ground Engineering Operations Produtos e Solucoes de Engenharia e Geotecnia, Lda Chemical composition and process for treating geotechnical slurries

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
表面活性剂在造纸中的应用;谢新良等;《黑龙江造纸》;20030630(第2期);第24-25页 *

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Inventor after: Xie Yunjun

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