CN105020743A - Fuel autoxidation splitting and axial staged combustion chamber - Google Patents
Fuel autoxidation splitting and axial staged combustion chamber Download PDFInfo
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- 238000002485 combustion reaction Methods 0.000 title claims abstract description 89
- 239000000446 fuel Substances 0.000 title claims abstract description 33
- 238000006701 autoxidation reaction Methods 0.000 title claims description 5
- 238000005336 cracking Methods 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 6
- 238000010791 quenching Methods 0.000 abstract description 6
- 230000000171 quenching effect Effects 0.000 abstract description 6
- 229910052799 carbon Inorganic materials 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 230000008021 deposition Effects 0.000 abstract description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 4
- 239000008246 gaseous mixture Substances 0.000 abstract description 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 2
- 239000001257 hydrogen Substances 0.000 abstract description 2
- 150000003384 small molecules Chemical class 0.000 abstract description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 14
- 239000003921 oil Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
Abstract
本发明提供一种燃料自氧化裂解轴向分级燃烧室,燃料在燃烧室头部进行自氧化裂解,然后进入燃烧室深度燃烧,进而实现燃料的分级燃烧,燃料进入燃烧室头部与空气混合,与电离通道内产生的高温等离子体接触随之氧化,控制当量比大于1,使燃料在富油状态下进行燃烧,部分燃料燃烧释放的热量被剩余燃料吸收,进而裂解产生易燃烧的甲烷、氢气等气态小分子混合物,以此将燃烧室的富油燃烧区转变为燃料的自氧化裂解区。此后,高温气态混合物进入燃烧室内,与掺混孔进入的空气快速混合产生当量比小于1的混合物,进行贫油燃烧。本发明去除燃烧室淬熄段,提高了转换效率,避免了积碳问题,尤其是降低了燃烧室的NOx排放。
The invention provides an axially graded combustion chamber for autooxidation and cracking of fuel. The fuel undergoes autooxidation and cracking at the head of the combustion chamber, and then enters the combustion chamber for deep combustion, thereby realizing staged combustion of the fuel. The fuel enters the head of the combustion chamber and mixes with air. Contact with the high-temperature plasma generated in the ionization channel and then oxidize, control the equivalence ratio to be greater than 1, so that the fuel is burned in an oil-rich state, and the heat released by part of the fuel combustion is absorbed by the remaining fuel, and then cracked to produce flammable methane and hydrogen The mixture of gaseous small molecules can transform the oil-rich combustion zone of the combustion chamber into the autoxidative cracking zone of the fuel. Thereafter, the high-temperature gaseous mixture enters the combustion chamber, and rapidly mixes with the air entering the mixing hole to produce a mixture with an equivalence ratio of less than 1 for lean combustion. The invention removes the quenching section of the combustion chamber, improves the conversion efficiency, avoids the problem of carbon deposition, and especially reduces the NOx emission of the combustion chamber.
Description
技术领域technical field
本发明涉及热能与动力工程领域,尤其涉及一种燃料自氧化裂解轴向分级燃烧室。The invention relates to the field of thermal energy and power engineering, in particular to an axially graded combustor for fuel autooxidative cracking.
背景技术Background technique
目前,随着环保意识的不断增强,对燃气轮机这种传统动力装置的研究越来越广泛。为满足日益严格的环保法规要求,现代推进动力的发展对发动机的设计提出了更高的要求,低排放技术成为发动机技术发展的趋势之一。At present, with the increasing awareness of environmental protection, the research on gas turbine, a traditional power plant, is becoming more and more extensive. In order to meet the increasingly stringent environmental protection regulations, the development of modern propulsion power puts forward higher requirements for engine design, and low emission technology has become one of the trends in the development of engine technology.
分级和分层燃烧技术是实现低污染燃烧的主要技术手段。分级燃烧技术一般由值班级和主燃级组成。值班级保证火焰稳定,同时尽可能地提高主燃级的空气量,提高主燃级油气之间的掺混。分层燃烧技术是通过对火焰结构分层来组织燃烧,巧妙解决了NOx排放与慢车状态的贫油熄火的矛盾。Staged and stratified combustion technology is the main technical means to achieve low-pollution combustion. The staged combustion technology generally consists of a duty class and a main combustion class. The duty stage ensures flame stability, and at the same time increases the air volume of the main combustion stage as much as possible, and improves the mixing of oil and gas in the main combustion stage. The stratified combustion technology organizes the combustion by layering the flame structure, which cleverly solves the contradiction between NOx emissions and lean fuel flameout in the idle state.
RQL(富油燃烧-淬熄-贫油燃烧)燃烧室是分级燃烧降低排放的有效方案之一,燃烧的基本方法是先布置一个富油的燃烧区,然后大量的空气与该燃烧区的产物快速混合,混合后的当量比小于1,在随后的区域进行贫油燃烧,经过完全燃烧后,燃气进入涡轮。其本质上是一个空气分级的低污染燃烧方案。加强对富油区燃烧及冷却和淬熄过程的研究,是当前实现RQL技术的研究重点。RQL (Rich Combustion-Quenching-Lean Combustion) combustion chamber is one of the effective schemes for staged combustion to reduce emissions. The basic method of combustion is to arrange an oil-rich combustion zone first, and then a large amount of air and the products of the combustion zone Rapid mixing, the equivalence ratio after mixing is less than 1, lean combustion is carried out in the subsequent area, and the gas enters the turbine after complete combustion. It is essentially an air-staged, low-pollution combustion solution. Strengthening the research on the combustion, cooling and quenching process in the oil-rich region is the current research focus for realizing RQL technology.
从目前已经应用到发动机上的低污染低排放燃烧技术水平来分析,仅仅应用一种低污染低排放燃烧技术已很难达到当前法规规定的污染物排放标准。因此综合应用多种低污染低排放燃烧技术,充分发挥这些技术各自的优点,是发展当前发动机低污染低排放燃烧技术的必由之路。因此本文以RQL分级燃烧技术为基础,提出一种新的组织燃烧的方式,希冀获得具有良好排放性能的燃烧室设计方案。From the analysis of the level of low-pollution and low-emission combustion technology that has been applied to engines, it is difficult to meet the pollutant emission standards stipulated by current regulations only by applying one low-pollution and low-emission combustion technology. Therefore, the comprehensive application of various low-pollution and low-emission combustion technologies and the full use of the respective advantages of these technologies are the only way to develop the current engine low-pollution and low-emission combustion technology. Therefore, based on RQL staged combustion technology, this paper proposes a new way to organize combustion, hoping to obtain a combustion chamber design scheme with good emission performance.
发明内容Contents of the invention
本发明的目的是为了提供一种转换效率高、可避免积碳问题、去除淬熄过程降低NOx的排放的燃料自氧化裂解轴向分级燃烧室。The object of the present invention is to provide a fuel self-oxidative cracking axial staged combustion chamber which has high conversion efficiency, can avoid the problem of carbon deposition, removes the quenching process and reduces NOx emissions.
本发明的目的是这样实现的:包括裂解器,裂解器的壳体内安装有电极接头,电极接头的端部伸入至喷嘴管道中,且电机接头的端部连接有电极,电极的端部连接有旋流器压杆,旋流器压杆的端部连接有旋流器,喷嘴管道的端部安装有喷嘴,且所述的旋流器安装在喷嘴上,裂解器的上端还竖直安装有进油口,进油口的端部与喷嘴管道相通,所述裂解器上还固连有外筒,所述喷嘴管道上安装有内筒,内筒与喷嘴管道连接的端面上设置有电离通道,内筒与外筒之间形成进行道,内筒的端部与燃烧室本体连接,燃烧室本体上端设置有掺混孔。The purpose of the present invention is achieved in this way: comprising a cracker, the shell of the cracker is equipped with an electrode joint, the end of the electrode joint extends into the nozzle pipeline, and the end of the motor joint is connected with an electrode, and the end of the electrode is connected There is a cyclone pressure rod, the end of the cyclone pressure rod is connected with a cyclone, the end of the nozzle pipe is equipped with a nozzle, and the cyclone is installed on the nozzle, and the upper end of the cracker is also vertically installed There is an oil inlet, the end of the oil inlet communicates with the nozzle pipeline, the cracker is also fixedly connected with an outer cylinder, the nozzle pipeline is equipped with an inner cylinder, and an ionizer is installed on the end surface of the inner cylinder connected to the nozzle pipeline. The passageway is formed between the inner cylinder and the outer cylinder, the end of the inner cylinder is connected with the combustion chamber body, and the upper end of the combustion chamber body is provided with a mixing hole.
本发明还包括这样一些结构特征:The present invention also includes such structural features:
1.所述喷嘴伸入至内筒中。1. The nozzle extends into the inner cylinder.
2.电极接头通过电缆与电源连接。2. The electrode connector is connected to the power supply through a cable.
与现有技术相比,本发明的有益效果是:本发明采用燃油预先富油燃烧实现燃料自氧化裂解,然后将未完全燃烧燃气直接喷入燃烧室进行贫油燃烧,去除淬熄过程,利于燃烧的组织,避免积碳问题;径向加轴向分级的燃烧室结构布置,有助于裂解后的气态燃料与空气的混合,提高燃料转换效率,最为重要的是,利用先富油后贫油的燃烧方式,有效降低燃烧室NOx排放。也即本发明可以提高转换效率,避免积碳问题,最重要的是去除了淬熄过程,气态燃料的预混以及偏当量比的燃烧方式又可以降低NOx的排放。Compared with the prior art, the beneficial effect of the present invention is: the present invention adopts pre-rich combustion of fuel oil to realize self-oxidative cracking of fuel, and then injects incomplete combustion gas directly into the combustion chamber for lean fuel combustion, eliminating the quenching process, which is beneficial to Combustion organization to avoid carbon deposits; the radial and axial grading of the combustion chamber structure is conducive to the mixing of cracked gaseous fuel and air to improve fuel conversion efficiency. The combustion method of oil can effectively reduce the NOx emission of the combustion chamber. That is to say, the present invention can improve the conversion efficiency, avoid the problem of carbon deposition, and the most important thing is that the quenching process is eliminated, and the premixing of gaseous fuel and the combustion mode of partial equivalence ratio can reduce the emission of NOx.
附图说明Description of drawings
图1是本发明的结构示意图。Fig. 1 is a schematic structural view of the present invention.
具体实施方式Detailed ways
下面结合附图与具体实施方式对本发明作进一步详细描述。The present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments.
本发明是基于富燃-淬熄-贫燃燃烧技术设计的轴向分级燃烧室,是一种高效燃烧、低排放的燃烧室。The invention is an axially graded combustion chamber designed based on the rich combustion-quenching-lean combustion technology, and is a high-efficiency combustion and low-emission combustion chamber.
结合图1,本发明是一种燃料自氧化裂解轴向分级燃烧室,由裂解器壳体1、电极接头2、电极3、旋流器压杆4、旋流器5、电离通道6、进气道7、掺混孔8、进油口9、喷嘴组件10、内筒11、外筒12及燃烧室本体13组成,电极接头2安装在裂解器的左端,连接电缆以通电;电极3连接在电极接头2上,旋流器5安装在喷嘴9上;旋流器压杆4安装在电极3与旋流器5之间,用来固定旋流器5;进油口9安装在裂解器上端;外筒12与内筒11连接裂解器和喷嘴管道,且内筒与外筒安装在裂解器右端,进气道7位于外筒12与内筒11之间,用于进气;电离通道6位于内外筒之间的进气道末端的内筒端面上,开始工作时电离通道通电,产生电弧,燃烧室本体13安装在内筒11出口,掺混孔8位于燃烧室本体13上。In conjunction with Fig. 1, the present invention is an axially graded combustor for self-oxidative cracking of fuel, consisting of a cracker housing 1, an electrode joint 2, an electrode 3, a cyclone pressure rod 4, a cyclone 5, an ionization channel 6, and a Composed of air passage 7, mixing hole 8, oil inlet 9, nozzle assembly 10, inner cylinder 11, outer cylinder 12 and combustion chamber body 13, electrode connector 2 is installed on the left end of the cracker, and the cable is connected to power on; electrode 3 is connected to On the electrode joint 2, the cyclone 5 is installed on the nozzle 9; the cyclone pressure rod 4 is installed between the electrode 3 and the cyclone 5 to fix the cyclone 5; the oil inlet 9 is installed on the cracker The upper end; the outer cylinder 12 and the inner cylinder 11 are connected to the cracker and the nozzle pipe, and the inner cylinder and the outer cylinder are installed at the right end of the cracker, and the air inlet 7 is located between the outer cylinder 12 and the inner cylinder 11 for air intake; the ionization channel 6. Located on the end face of the inner cylinder at the end of the air inlet between the inner and outer cylinders. When starting to work, the ionization channel is energized to generate an arc. The combustion chamber body 13 is installed at the outlet of the inner cylinder 11. The mixing hole 8 is located on the combustion chamber body 13.
燃料裂解器位于燃烧室前部,内外套筒连接裂解器,内筒与燃烧室相连。空气通过内外筒之间进气道逆向进入,与燃油混合后,在内筒进行氧化裂解,产生的高温混合物进入燃烧室进行深度燃烧。The fuel cracker is located at the front of the combustion chamber, the inner and outer sleeves are connected with the cracker, and the inner sleeve is connected with the combustion chamber. The air enters in reverse through the air inlet between the inner and outer cylinders, and after being mixed with fuel, it undergoes oxidative cracking in the inner cylinder, and the resulting high-temperature mixture enters the combustion chamber for deep combustion.
本发明的燃料在燃烧室头部进行自氧化裂解,然后进入燃烧室深度燃烧,进而实现燃料的分级燃烧。本发明的目的在于,以RQL(富油燃烧-淬熄-贫油燃烧)分级燃烧技术为基础,提出一种新的组织燃烧的方式。燃料进入燃烧室头部与空气混合,与电离通道内产生的高温等离子体接触随之氧化,控制当量比大于1,使燃料在富油状态下进行燃烧,部分燃料燃烧释放的热量被剩余燃料吸收,进而裂解产生易燃烧的甲烷、氢气等气态小分子混合物,以此将燃烧室的富油燃烧区转变为燃料的自氧化裂解区。此后,高温气态混合物进入燃烧室内,与掺混孔进入的空气快速混合产生当量比小于1的混合物,进行贫油燃烧。本发明去除燃烧室淬熄段,提高了转换效率,避免了积碳问题,尤其是降低了燃烧室的NOx排放The fuel of the present invention undergoes autooxidative cracking at the head of the combustion chamber, and then enters the combustion chamber for deep combustion, thereby realizing staged combustion of the fuel. The object of the present invention is to propose a new way of organizing combustion based on RQL (rich combustion-quenching-lean combustion) staged combustion technology. The fuel enters the head of the combustion chamber and mixes with the air, and then oxidizes upon contact with the high-temperature plasma generated in the ionization channel. The equivalence ratio is controlled to be greater than 1, so that the fuel burns in an oil-rich state, and part of the heat released by fuel combustion is absorbed by the remaining fuel , and then cracked to produce flammable gaseous small molecule mixtures such as methane and hydrogen, so as to transform the oil-rich combustion zone of the combustion chamber into the autoxidative cracking zone of fuel. Thereafter, the high-temperature gaseous mixture enters the combustion chamber, and rapidly mixes with the air entering the mixing hole to produce a mixture with an equivalence ratio of less than 1 for lean combustion. The invention removes the quenching section of the combustion chamber, improves the conversion efficiency, avoids the problem of carbon deposition, and especially reduces the NOx emission of the combustion chamber
结合图1,燃烧室开始工作时,电极接头2接通电缆通电,电离通道6之间的空气被高压电弧击穿后形成电弧,压气机出口的压缩空气通过进气道7,由内外筒之间逆向进入,经过电离通道时,被高温电弧加热电离形成等离子体;燃油通过旋流器5由喷嘴10喷出,与空气混合,油气混合物与高温等离子体接触后,迅速燃烧形成稳定火焰;高温混合物进入内筒11,此时内筒内进行的实际上是富油燃烧,控制空腔内当量比大于1,可使部分燃油燃烧产生的热量被剩余燃油吸收,进行自氧化裂解过程,形成易燃烧的高活性短碳链组分,这一过程的富油态避免了当量比燃烧,有效减少了NOx的生成;裂解后的高温混合物经由内筒出口进入燃烧室本体13,此时高温混合物迅速与由掺混孔进入的空气混合,由富油态迅速转变为贫油态,此时进行二次点火,继续燃烧,燃烧在当量比低于1的条件下进行,再次避开了当量比燃烧,减少NOx生成。Combined with Figure 1, when the combustion chamber starts to work, the electrode connector 2 is connected to the cable and energized, and the air between the ionization channel 6 is broken down by the high-voltage arc to form an arc. When passing through the ionization channel, it is heated and ionized by the high-temperature arc to form plasma; the fuel is sprayed out from the nozzle 10 through the swirler 5, mixed with air, and the oil-gas mixture burns rapidly to form a stable flame after contacting the high-temperature plasma; The mixture enters the inner cylinder 11. At this time, the fuel-rich combustion is actually carried out in the inner cylinder. The equivalence ratio in the cavity is controlled to be greater than 1, so that the heat generated by part of the fuel combustion can be absorbed by the remaining fuel oil, and the process of autoxidation and cracking is carried out, forming an easy Combustion of highly active short carbon chain components, the oil-rich state of this process avoids the equivalent ratio combustion and effectively reduces the generation of NOx; the high-temperature mixture after cracking enters the combustion chamber body 13 through the outlet of the inner cylinder, and the high-temperature mixture rapidly Mixed with the air entering through the mixing hole, the oil-rich state is quickly changed to the lean state. At this time, secondary ignition is carried out to continue combustion. The combustion is carried out under the condition that the equivalence ratio is lower than 1, and the equivalence ratio combustion is avoided again. , to reduce NOx generation.
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