CN105017523A - Magnetic-adsorption nylon material - Google Patents
Magnetic-adsorption nylon material Download PDFInfo
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- CN105017523A CN105017523A CN201510455084.2A CN201510455084A CN105017523A CN 105017523 A CN105017523 A CN 105017523A CN 201510455084 A CN201510455084 A CN 201510455084A CN 105017523 A CN105017523 A CN 105017523A
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Abstract
The invention provides a magnetic-adsorption nylon material which comprises 2-7 parts of ferric chloride solution, 3-8 parts of ferrous chloride solution, 3-7 parts of ethyl orthosilicate, 4-10 parts of gamma-aminopropyl triethoxy silane, 5-12 parts of glycidyl methacrylate, 2-4 parts of cuprous bromide, 4-11 parts of copper, 3-5 parts of caprolactam, 4-7 parts of acetone and 10-18 parts of silicon dioxide. The high-polymer adsorbing material Fe3O4.SiO2 is added to enhance the water absorptivity of the nylon material, improve the adsorption capacity and lower the water absorptivity of the material. The magnetic-adsorption nylon material has the advantages of uniformly distributed nylon fibers and higher strength.
Description
Technical field
The present invention relates to macromolecule modified Material Field, especially relate to a kind of magnetic absorption nylon material.
Background technology
Nylon 6 (PA6) is one of most important kind in nylon series product, has the features such as wear-resistant self-lubricating, oil resistant, acid and alkali-resistance and processing fluidity are good.The good mechanical and physical performance of PA6 and superior cost performance, become a kind of purposes engineering plastics very widely.But PA6 water-absorbent is large, poor dimensional stability, molding shrinkage are high, defect, the particularly modulus of pure PA6 are lower to have that low temperature impact strength is not good, toughness is not enough under drying regime, creep-resistant property is poor etc., limit its application in some fields.For making PA6 play a role, necessary to its modification.
Summary of the invention
For solving the problems of the technologies described above, the present invention proposes a kind of magnetic absorption nylon material, comprise following component: ferric chloride Solution 2-7 part, solution of ferrous chloride 3-8 part, tetraethoxy 3-7 part, y-aminopropyl triethoxysilane 4-10 part, glycidyl methacrylate 5-12 part, cuprous bromide 2-4 part, copper 4-11 part, hexanolactam 3-5 part, acetone 4-7 part, silica 1 0-18 part.
Preferably, described ferric chloride Solution is 2-5mol/L.
Preferably, described solution of ferrous chloride is 4-6mol/L.
Preferably, ferric chloride Solution 4-6 part, solution of ferrous chloride 4-6 part, tetraethoxy 5-6 part, y-aminopropyl triethoxysilane 5-9 part, glycidyl methacrylate 5-10 part, cuprous bromide 2-4 part, copper 6-10 part, hexanolactam 3-5 part, acetone 4-6 part, silica 1 2-16 part.
Preferably, ferric chloride Solution 5 parts, solution of ferrous chloride 5 parts, tetraethoxy 6 parts, y-aminopropyl triethoxysilane 8 parts, glycidyl methacrylate 7 parts, cuprous bromide 3 parts, copper 8 parts, hexanolactam 4 parts, 5 parts, acetone, silica 15 parts.
The magnetic absorption nylon material that the present invention proposes has following beneficial effect: the present invention is by adding polymer adsorbing material Fe304SiO2, add nylon material water-absorbent strong, increase adsorptive power, reduce the water-intake rate of material, nylon fiber is evenly distributed, intensity enhancing.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described.
Embodiment 1
A kind of magnetic absorption nylon material, comprises following component: ferric chloride Solution 2 parts, solution of ferrous chloride 3 parts, tetraethoxy 3 parts, y-aminopropyl triethoxysilane 4 parts, glycidyl methacrylate 5-12 part, cuprous bromide 2 parts, copper 4 parts, hexanolactam 3 parts, acetone 4-part, silica 10 part.
Preferably, described ferric chloride Solution is 2mol/L.
Preferably, described solution of ferrous chloride is 4-mol/L.
Embodiment 2
A kind of magnetic absorption nylon material, comprises following component: ferric chloride Solution 5 parts, solution of ferrous chloride 5 parts, tetraethoxy 6 parts, y-aminopropyl triethoxysilane 8 parts, glycidyl methacrylate 7 parts, cuprous bromide 3 parts, copper 8 parts, hexanolactam 4 parts, 5 parts, acetone, silica 15 parts
Embodiment 3
A kind of magnetic absorption nylon material, comprises following component: ferric chloride Solution 7 parts, solution of ferrous chloride 8 parts, tetraethoxy 7 parts, y-aminopropyl triethoxysilane 10 parts, glycidyl methacrylate 12 parts, cuprous bromide 24 parts, copper 11 parts, hexanolactam 5 parts, 7 parts, acetone, silica 18 parts.
By the nylon material absorption Hg ion in above-described embodiment, putting into containing concentration is 10mol/LDE Hg solion, and the logical ion that detects remains content:
| Water-intake rate (%) | Hg ion residue content (mol/L) | |
| Embodiment 1 | 0.93 | 6.8 |
| Embodiment 2 | 0.82 | 3.2 |
| Embodiment 3 | 0.56 | 0.9 |
To be apparent for those skilled in the art to the multiple amendment of embodiment, General Principle as defined herein can without departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention can not be restricted to these embodiments shown in this article, but will meet the widest scope consistent with principle disclosed herein and features of novelty.
Claims (5)
1. a magnetic absorption nylon material, it is characterized in that, comprise following component: ferric chloride Solution 2-7 part, solution of ferrous chloride 3-8 part, tetraethoxy 3-7 part, y-aminopropyl triethoxysilane 4-10 part, glycidyl methacrylate 5-12 part, cuprous bromide 2-4 part, copper 4-11 part, hexanolactam 3-5 part, acetone 4-7 part, silica 1 0-18 part.
2. magnetic absorption nylon material according to claim 1, is characterized in that, described ferric chloride Solution is 2-5mol/L.
3. magnetic absorption nylon material according to claim 1, is characterized in that, described solution of ferrous chloride is 4-6mol/L.
4. magnetic absorption nylon material according to claim 1, it is characterized in that, ferric chloride Solution 4-6 part, solution of ferrous chloride 4-6 part, tetraethoxy 5-6 part, y-aminopropyl triethoxysilane 5-9 part, glycidyl methacrylate 5-10 part, cuprous bromide 2-4 part, copper 6-10 part, hexanolactam 3-5 part, acetone 4-6 part, silica 1 2-16 part.
5. magnetic absorption nylon material according to claim 1, it is characterized in that, ferric chloride Solution 5 parts, solution of ferrous chloride 5 parts, tetraethoxy 6 parts, y-aminopropyl triethoxysilane 8 parts, glycidyl methacrylate 7 parts, cuprous bromide 3 parts, copper 8 parts, hexanolactam 4 parts, 5 parts, acetone, silica 15 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510455084.2A CN105017523A (en) | 2015-07-29 | 2015-07-29 | Magnetic-adsorption nylon material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510455084.2A CN105017523A (en) | 2015-07-29 | 2015-07-29 | Magnetic-adsorption nylon material |
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| Publication Number | Publication Date |
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| CN105017523A true CN105017523A (en) | 2015-11-04 |
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| CN201510455084.2A Pending CN105017523A (en) | 2015-07-29 | 2015-07-29 | Magnetic-adsorption nylon material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105778489A (en) * | 2016-05-21 | 2016-07-20 | 夏百庆 | Polyamide modified nano silicon dioxide material and preparation method thereof |
| CN105778490A (en) * | 2016-05-24 | 2016-07-20 | 夏百庆 | Hard nano silica material and preparation method thereof |
| CN111876671A (en) * | 2020-07-03 | 2020-11-03 | 无锡市源通传动科技有限公司 | High-impact-resistance wear-resistant gear and preparation method thereof |
| CN113351184A (en) * | 2021-06-16 | 2021-09-07 | 西安理工大学 | Nylon ferroferric oxide adsorbing material containing carboxyl and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5467700A (en) * | 1977-11-10 | 1979-05-31 | Sony Corp | Magnetic recording medium |
| CN102532523A (en) * | 2010-12-30 | 2012-07-04 | 上海杰事杰新材料(集团)股份有限公司 | Method for preparing magnetic polyamide composite material through in-situ hydrolysis |
| CN102827471A (en) * | 2011-06-17 | 2012-12-19 | Ems专利股份公司 | Semiaromatic moulding masses and their applications |
| CN102827473A (en) * | 2012-08-09 | 2012-12-19 | 东莞市信诺橡塑工业有限公司 | Super-tough nylon 6 alloy prepared by using in-situ process and preparation method thereof |
| CN103599751A (en) * | 2013-10-25 | 2014-02-26 | 浙江大学 | Preparation method of thiol-functionalized magnetic silica nano-material |
-
2015
- 2015-07-29 CN CN201510455084.2A patent/CN105017523A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5467700A (en) * | 1977-11-10 | 1979-05-31 | Sony Corp | Magnetic recording medium |
| CN102532523A (en) * | 2010-12-30 | 2012-07-04 | 上海杰事杰新材料(集团)股份有限公司 | Method for preparing magnetic polyamide composite material through in-situ hydrolysis |
| CN102827471A (en) * | 2011-06-17 | 2012-12-19 | Ems专利股份公司 | Semiaromatic moulding masses and their applications |
| CN102827473A (en) * | 2012-08-09 | 2012-12-19 | 东莞市信诺橡塑工业有限公司 | Super-tough nylon 6 alloy prepared by using in-situ process and preparation method thereof |
| CN103599751A (en) * | 2013-10-25 | 2014-02-26 | 浙江大学 | Preparation method of thiol-functionalized magnetic silica nano-material |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105778489A (en) * | 2016-05-21 | 2016-07-20 | 夏百庆 | Polyamide modified nano silicon dioxide material and preparation method thereof |
| CN105778490A (en) * | 2016-05-24 | 2016-07-20 | 夏百庆 | Hard nano silica material and preparation method thereof |
| CN111876671A (en) * | 2020-07-03 | 2020-11-03 | 无锡市源通传动科技有限公司 | High-impact-resistance wear-resistant gear and preparation method thereof |
| CN113351184A (en) * | 2021-06-16 | 2021-09-07 | 西安理工大学 | Nylon ferroferric oxide adsorbing material containing carboxyl and preparation method thereof |
| CN113351184B (en) * | 2021-06-16 | 2022-10-04 | 西安理工大学 | Nylon ferroferric oxide adsorbing material containing carboxyl and preparation method thereof |
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Application publication date: 20151104 |