CN105017492A - 3D printing material with aldehyde removal property and application thereof - Google Patents
3D printing material with aldehyde removal property and application thereof Download PDFInfo
- Publication number
- CN105017492A CN105017492A CN201510452478.2A CN201510452478A CN105017492A CN 105017492 A CN105017492 A CN 105017492A CN 201510452478 A CN201510452478 A CN 201510452478A CN 105017492 A CN105017492 A CN 105017492A
- Authority
- CN
- China
- Prior art keywords
- aldehydes removal
- printed material
- removal performance
- performance according
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention provides a 3D printing material with aldehyde removal property and application thereof. The material comprises the following components in parts by mass: 1-4 parts of polymerizable aldehyde removal material, 10-88 parts of monomer, 10-88 parts of prepolymer and 0.01-10 parts of initiator. The polymerizable aldehyde removal material introduced into the material has the enol methylene structure, and can react with aldehyde, thereby removing the aldehyde. The material can be subjected to three-dimensional formation on a photocuring-based 3D printing device of which the light source wavelength is 250-1000nm, and the three-dimensional formed object has the aldehyde removal property.
Description
Technical field
The present invention relates to 3D printed material and Application Areas thereof, refer to a kind of 3D printed material and the application thereof with aldehydes removal performance especially.
Background technology
3D prints, i.e. the one of rapid shaping technique, and it is a kind of based on digital model file, uses powdery metal or plastics etc. can jointing material, is carried out the technology of constructed object by the mode successively printed.This technology is at Making mold, jewelry, footwear, industrial design, building, automobile, and aerospace, medical industries, education, geographical information system(GIS) and other field are applied all to some extent.Fusion sediment formula (FDM), layer separated growth (LOM), stereolithography apparatus method (SLA), the manufacture of electron beam free forming (EBF), direct metal laser sintering (DMLS), electron-beam melting shaping (EBM), selective laser melting shaping (SLM), selective thermal sintering (SHS) and selective laser sintering (SLS) etc. is divided into regard to its printing device.Wherein, Stereolithography method (SLA) is exactly the 3D printing technique realized based on photocuring principle.
Indoor pollutant is the major cause causing problem of indoor air quality, and its main source is material of construction and finishing material, fuel combustion, culinary art, smoking, household chemical product etc.Gaseous pollutant is of a great variety, aldehyde pollutants, especially formaldehyde, is more highly toxic material, and on Chinese noxious chemical priority acccess control list, formaldehyde is in second.Formaldehyde has been defined as carcinogenic and cause deformed material by the World Health Organization, be generally acknowledged allergen, is also one of potential strong mutagen.Research shows, formaldehyde has strong carcinogenic and tumor promotion.Long Term Contact low dosage formaldehyde can cause chronic respiratory tract disease, cause nasopharyngeal carcinoma, colorectal carcinoma, brain tumor, menoxenia, nuclear transgenation, commissure and DNA and protein commissure and suppress the reparation of DNA damage, pregnancy syndrome, cause neonatal chromosome disorder, leukemia in DNA single chain, cause teenager's memory and intelligence to decline.
Mainly contain the following method removing formaldehyde at present: ventilation; Charcoal absorption; With water, vinegar, black tea is soaked removes formaldehyde; Photocatalytic method; The fruit such as orange, pineapple formaldehyde adsorption; Plant absorption formaldehyde; Air purifier etc.These methods are all the remedial measuress after finishing, and most effective means is exactly the harm just fully taking into account formaldehyde before finishing in fact, selects environment-friendly materials as far as possible, accomplish to provide for a rainy day in fitment process.
Summary of the invention
The present invention proposes a kind of 3D printed material and the application thereof with aldehydes removal performance, solves the problem that 3D cannot be printed and combine except formaldehyde materials in prior art.
Technical scheme of the present invention is achieved in that
There is a 3D printed material for aldehydes removal performance, the component that the formula of this material comprises and mass ratio as follows:
Polymerizable aldehydes removal material, monomer, performed polymer and initiator, the mass ratio of its component is 1 ~ 40:10 ~ 98:10 ~ 98:0.01 ~ 10.
As preferred technical scheme, described polymerizable aldehydes removal material has enol methylene radical structure.This enol methylene radical structure, can have an effect with aldehyde, remove aldehyde with this.
As preferred technical scheme, described polymerizable aldehydes removal material has the general formula of following structure:
Wherein, R is hydrogen or methyl.Methylene radical in this molecular structure can be had an effect with aldehyde, as hydrogen bond action and condensation reaction, removes aldehyde with this.The aldehyde removed is one or more in formaldehyde, acetaldehyde, propionic aldehyde, butyraldehyde-n, isobutyric aldehyde, phenyl aldehyde.
As preferred technical scheme, the mass ratio of described polymerizable aldehydes removal material, monomer, performed polymer, initiator is 10 ~ 40:30 ~ 50:30 ~ 50:2 ~ 5.
As preferred technical scheme, described monomer is selected from one or more in methyl acrylate, ethyl propenoate, methyl methacrylate, β-dimethyl-aminoethylmethacrylate, Hydroxyethyl acrylate, Isooctyl acrylate monomer, Propylene glycol monoacrylate, Methyl 2-cyanoacrylate, epoxy acrylate, urethane acrylate.
As preferred technical scheme, described performed polymer is selected from low-molecular weight polymer or the multipolymer of above-mentioned monomer, and its middle-molecular-weihydroxyethyl is not more than 20,000.
As preferred technical scheme, described initiator is selected from st-yrax, benzoin dimethylether, Benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether, diphenylethan, dimethoxy-α-phenyl acetophenone, diethoxy acetophenone, hydroxyalkyl phenones, amine alkyl phenones, aroyl phosphine oxide, two benzoylphenyl phosphine oxide, benzophenone, dihydroxy benaophenonel, Michler's keton, sulfo-propoxy-thioxanthone, isopropyl thioxanthone, aryl salt, triaryl salt compounded of iodine, alkyl salt compounded of iodine, the luxuriant iron hexafluorophosphate of isopropyl benzene, one or more during fluorinated diphenyl titanium is luxuriant.
The above-mentioned 3D printed material with aldehydes removal performance is applied to three-dimensionally shaped, adopts the 3D printing device of photocuring processes.
As preferred technical scheme, employing optical source wavelength is 250 ~ 1000nm.
Beneficial effect
(1) the 3D printed material with aldehydes removal performance of the present invention is shaping based on applying three-dimensional on the 3D printing device of photocuring processes.
(2) formaldehyde occurred can be removed in indoor by resulting materials of the present invention at any time, does not need additionally increase equipment or consume the energy, more can not produce new pollutent.
Embodiment
Be clearly and completely described to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
In the present invention, as no specific instructions, various raw material of the present invention all can be obtained by commercially available; Or prepare according to the ordinary method of this area.Unless otherwise defined or described herein, all specialties used herein and scientific words and those skilled in the art the same meaning be familiar with.Unless otherwise indicated, new technical scheme can be mutually combined to form between the content range of each component of composition and its preferable range.The present invention is described in detail below in conjunction with embodiment.
Embodiment 1
Have a 3D printed material for aldehydes removal performance, the component of the formula of this material is as follows:
10 grams of polymerizable aldehydes removal materials, 45 grams of methyl methacrylates, 45 grams of epoxy FRP pipe and 3 grams of Benzoin ethyl ethers.
Wherein the structural formula of polymerizable aldehydes removal material is
Its R is methyl.
Namely above-mentioned formula mixing is obtained the 3D printed material with aldehydes removal performance of homogeneous phase.
The above-mentioned 3D printed material with aldehydes removal performance is used for the 3D printer that optical source wavelength is 360nm, obtains the three-dimensionally shaped object with formaldehyde removing rate 84%.
Formaldehyde removing rate adopts JC/T 1074-2008 standard to measure.
Embodiment 2
Have a 3D printed material for aldehydes removal performance, the component of the formula of this material is as follows:
5 grams of polymerizable aldehydes removal materials, 35 grams of methyl acrylates, 60 grams of epoxy FRP pipe and 2 grams of two benzoylphenyl phosphine oxide.
Wherein the structural formula of polymerizable aldehydes removal material is
Its R is methyl.
Namely above-mentioned formula mixing is obtained the 3D printed material with aldehydes removal performance of homogeneous phase.
The above-mentioned 3D printed material with aldehydes removal performance is used for the 3D printer that optical source wavelength is 360nm, obtains the three-dimensionally shaped object with formaldehyde removing rate 72%.
Formaldehyde removing rate adopts JC/T 1074-2008 standard to measure.
Embodiment 3
Have a 3D printed material for aldehydes removal performance, the component of the formula of this material is as follows:
15 grams of polymerizable aldehydes removal materials, 35 grams of methyl acrylates, 50 grams of epoxy FRP pipe and 2 grams of fluorinated diphenyl titaniums are luxuriant.
Wherein the structural formula of polymerizable aldehydes removal material is
Its R is methyl.
Namely above-mentioned formula mixing is obtained the 3D printed material with aldehydes removal performance of homogeneous phase.
The above-mentioned 3D printed material with aldehydes removal performance is used for the 3D printer that optical source wavelength is 405nm, obtains the three-dimensionally shaped object with formaldehyde removing rate 93%.
Formaldehyde removing rate adopts JC/T 1074-2008 standard to measure.
Embodiment 4
Have a 3D printed material for aldehydes removal performance, the component of the formula of this material is as follows:
1 gram of polymerizable aldehydes removal material, 40 grams of Isooctyl acrylate monomers, 49 grams of polyurethane acrylate prepolymers and 10 donaxine alkyl phenones.
Wherein the structural formula of polymerizable aldehydes removal material is
Its R is hydrogen.
Namely above-mentioned formula mixing is obtained the 3D printed material with aldehydes removal performance of homogeneous phase.
The above-mentioned 3D printed material with aldehydes removal performance is used for the 3D printer that optical source wavelength is 250nm, obtains the three-dimensionally shaped object with formaldehyde removing rate 40%.
Formaldehyde removing rate adopts JC/T 1074-2008 standard to measure.
Embodiment 5
Have a 3D printed material for aldehydes removal performance, the component of the formula of this material is as follows:
40 grams of polymerizable aldehydes removal materials, 30 grams of Methyl 2-cyanoacrylates, 25 grams of methyl acrylate performed polymers and 5 grams of alkyl salt compounded of iodine.
Wherein the structural formula of polymerizable aldehydes removal material is
Its R is hydrogen.
Namely above-mentioned formula mixing is obtained the 3D printed material with aldehydes removal performance of homogeneous phase.
The above-mentioned 3D printed material with aldehydes removal performance is used for the 3D printer that optical source wavelength is 400nm, obtains the three-dimensionally shaped object with formaldehyde removing rate 95%.
Formaldehyde removing rate adopts JC/T 1074-2008 standard to measure.
Embodiment 6
Have a 3D printed material for aldehydes removal performance, the component of the formula of this material is as follows:
20 grams of polymerizable aldehydes removal materials, 10 grams of ethyl propenoates, 70 grams of Propylene glycol monoacrylate performed polymers and 0.01 gram of Michler's keton.
Wherein the structural formula of polymerizable aldehydes removal material is
Its R is hydrogen.
Namely above-mentioned formula mixing is obtained the 3D printed material with aldehydes removal performance of homogeneous phase.
The above-mentioned 3D printed material with aldehydes removal performance is used for the 3D printer that optical source wavelength is 1000nm, obtains the three-dimensionally shaped object with formaldehyde removing rate 85%.
Formaldehyde removing rate adopts JC/T 1074-2008 standard to measure.
Embodiment 7
Have a 3D printed material for aldehydes removal performance, the component of the formula of this material is as follows:
20 grams of polymerizable aldehydes removal materials, 10 grams of ethyl propenoates, 70 grams of Propylene glycol monoacrylate performed polymers and 0.01 gram of Michler's keton.
Wherein the structural formula of polymerizable aldehydes removal material is
Its R is hydrogen.
Namely above-mentioned formula mixing is obtained the 3D printed material with aldehydes removal performance of homogeneous phase.
The above-mentioned 3D printed material with aldehydes removal performance is used for the 3D printer that optical source wavelength is 800nm, obtains the three-dimensionally shaped object with formaldehyde removing rate 80%.
Formaldehyde removing rate adopts JC/T 1074-2008 standard to measure.
Comparative example
45 grams of methyl methacrylates, 45 grams of epoxy FRP pipe, 3 grams of Benzoin ethyl ethers are mixed, namely obtains the 3D printed material with aldehydes removal performance of homogeneous phase.Use it for the 3D printer that optical source wavelength is 360nm, obtain the three-dimensionally shaped object with formaldehyde removing rate nearly 1.4%.Not there is palpability aldehyde and remove using value.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (9)
1. there is a 3D printed material for aldehydes removal performance, it is characterized in that, the component that the formula of this material comprises and mass ratio as follows:
Polymerizable aldehydes removal material, monomer, performed polymer and initiator, the mass ratio of its component is 1 ~ 40:10 ~ 88:10 ~ 88:0.01 ~ 10.
2. a kind of 3D printed material with aldehydes removal performance according to claim 1, is characterized in that, described polymerizable aldehydes removal material has enol methylene radical structure.
3. a kind of 3D printed material with aldehydes removal performance according to claim 1, it is characterized in that, described polymerizable aldehydes removal material has the general formula of following structure:
Wherein, R is hydrogen or methyl.
4. a kind of 3D printed material with aldehydes removal performance according to claim 1, is characterized in that, the mass ratio of described polymerizable aldehydes removal material, monomer, performed polymer, initiator is 10 ~ 40:30 ~ 50:30 ~ 50:2 ~ 5.
5. a kind of 3D printed material with aldehydes removal performance according to claim 1, it is characterized in that, described monomer is selected from one or more in methyl acrylate, ethyl propenoate, methyl methacrylate, β-dimethyl-aminoethylmethacrylate, Hydroxyethyl acrylate, Isooctyl acrylate monomer, Propylene glycol monoacrylate, Methyl 2-cyanoacrylate, epoxy acrylate, urethane acrylate.
6. a kind of 3D printed material with aldehydes removal performance according to claim 5, it is characterized in that, described performed polymer is selected from low-molecular weight polymer or the multipolymer of monomer described in claim 5, and its middle-molecular-weihydroxyethyl is not more than 20,000.
7. a kind of 3D printed material with aldehydes removal performance according to claim 1, it is characterized in that, described initiator is selected from st-yrax, benzoin dimethylether, Benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether, diphenylethan, dimethoxy-α-phenyl acetophenone, diethoxy acetophenone, hydroxyalkyl phenones, amine alkyl phenones, aroyl phosphine oxide, two benzoylphenyl phosphine oxide, benzophenone, dihydroxy benaophenonel, Michler's keton, sulfo-propoxy-thioxanthone, isopropyl thioxanthone, aryl salt, triaryl salt compounded of iodine, alkyl salt compounded of iodine, the luxuriant iron hexafluorophosphate of isopropyl benzene, one or more during fluorinated diphenyl titanium is luxuriant.
8. the 3D printed material with aldehydes removal performance as described in a claim as arbitrary in claim 1-7 is applied to three-dimensionally shaped, adopts the 3D printing device of photocuring processes.
9. a kind of 3D printed material with aldehydes removal performance according to claim 8 is applied to three-dimensionally shaped, and it is characterized in that, employing optical source wavelength is 250 ~ 1000nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510452478.2A CN105017492A (en) | 2015-07-28 | 2015-07-28 | 3D printing material with aldehyde removal property and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510452478.2A CN105017492A (en) | 2015-07-28 | 2015-07-28 | 3D printing material with aldehyde removal property and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105017492A true CN105017492A (en) | 2015-11-04 |
Family
ID=54407826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510452478.2A Pending CN105017492A (en) | 2015-07-28 | 2015-07-28 | 3D printing material with aldehyde removal property and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105017492A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105601287A (en) * | 2015-12-24 | 2016-05-25 | 成都新柯力化工科技有限公司 | Binder for 3D printed ceramic material and application of binder |
| CN109232791A (en) * | 2018-08-20 | 2019-01-18 | 珠海赛纳打印科技股份有限公司 | A kind of 3D printing photocuring non-transparent material and preparation method thereof, 3D printing product and 3D printer |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5516453A (en) * | 1993-02-19 | 1996-05-14 | Rohm And Haas Company | Stable ambient-curing composition |
| CN101356204A (en) * | 2006-01-06 | 2009-01-28 | 电气化学工业株式会社 | Photocurable resin composition |
| CN103055465A (en) * | 2011-10-18 | 2013-04-24 | 上海格伦化学科技有限公司 | Formaldehyde scavenging agent with oil solubility and preparation method |
| CN104109328A (en) * | 2014-06-23 | 2014-10-22 | 东莞智维立体成型股份有限公司 | Photocuring wax material used for 3D printing |
| CN104629516A (en) * | 2015-01-26 | 2015-05-20 | 上海交通大学 | Coating capable of scavenging formaldehyde |
| CN104788625A (en) * | 2015-04-27 | 2015-07-22 | 北京印刷学院 | Free radical photo-curing material for manufacturing flexographic plate as well as preparation method and application of photo-curing material |
-
2015
- 2015-07-28 CN CN201510452478.2A patent/CN105017492A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5516453A (en) * | 1993-02-19 | 1996-05-14 | Rohm And Haas Company | Stable ambient-curing composition |
| CN101356204A (en) * | 2006-01-06 | 2009-01-28 | 电气化学工业株式会社 | Photocurable resin composition |
| CN103055465A (en) * | 2011-10-18 | 2013-04-24 | 上海格伦化学科技有限公司 | Formaldehyde scavenging agent with oil solubility and preparation method |
| CN104109328A (en) * | 2014-06-23 | 2014-10-22 | 东莞智维立体成型股份有限公司 | Photocuring wax material used for 3D printing |
| CN104629516A (en) * | 2015-01-26 | 2015-05-20 | 上海交通大学 | Coating capable of scavenging formaldehyde |
| CN104788625A (en) * | 2015-04-27 | 2015-07-22 | 北京印刷学院 | Free radical photo-curing material for manufacturing flexographic plate as well as preparation method and application of photo-curing material |
Non-Patent Citations (3)
| Title |
|---|
| TOMASINO等: ""Evaluation of Formaldehyde Scavengers"", 《TEXTILE CHEMIST AND COLORIST》 * |
| 孟庆华，等: ""喷墨打印技术在3D快速成型制造中的应用"", 《信息记录材料》 * |
| 魏桢，等: ""含烯醇-酮结构聚合物的合成及其在除甲醛涂料中的应用"", 《涂料工业》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105601287A (en) * | 2015-12-24 | 2016-05-25 | 成都新柯力化工科技有限公司 | Binder for 3D printed ceramic material and application of binder |
| CN105601287B (en) * | 2015-12-24 | 2018-03-30 | 湖南世纪特邦新材料有限公司 | A kind of 3D printing ceramic material binding agent and its application |
| CN109232791A (en) * | 2018-08-20 | 2019-01-18 | 珠海赛纳打印科技股份有限公司 | A kind of 3D printing photocuring non-transparent material and preparation method thereof, 3D printing product and 3D printer |
| WO2020037888A1 (en) * | 2018-08-20 | 2020-02-27 | 珠海赛纳三维科技有限公司 | 3d printing photo-curable non-transparent material and preparation method thereof, 3d printing product and 3d printer |
| US11535690B2 (en) | 2018-08-20 | 2022-12-27 | Zhuhai Sailner 3D Technology Co., Ltd. | Light curing non-transparent material for 3D printing and a preparation method threrof, a 3D printed product and a 3D printer |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102516866B (en) | Ultraviolet light curing material | |
| TW200720347A (en) | Water-absorbent agent composition and method for manufacturing the same | |
| DE502007001036D1 (en) | METHOD FOR PRODUCING SHAPED PARTS FROM CORK PARTICLES | |
| ATE491729T1 (en) | METHOD FOR PRODUCING WATER-ABSORBING POLYMER PARTICLES BY POLYMERIZING DROPS OF A MONOMER SOLUTION | |
| TW200514583A (en) | Water absorbent resin composition and production method thereof | |
| MX2017006379A (en) | Concentration control in filtration systems, and associated methods. | |
| TW200704650A (en) | Particulate water absorbing agent including polyacrylic acid (polyacrylate) based water absorbing resin as a principal component, method for production thereof, water-absorbent core and absorbing article in which the particulate water absorbing agent is | |
| DE602006015422D1 (en) | METHOD FOR PRODUCING A WATER ABSORBENT MATERIAL WITH A COATING OF ELASTIC FILM-FORMING POLYMERS | |
| ATE501178T1 (en) | METHOD FOR PRODUCING WATER-ABSORBING POLYMER PARTICLES BY POLYMERIZING DROPS OF A MONOMER SOLUTION | |
| CN105017492A (en) | 3D printing material with aldehyde removal property and application thereof | |
| ATE390452T1 (en) | METHOD FOR PRODUCING A POLY(ARYLENE ETHER) | |
| ATE499954T1 (en) | METHOD FOR PRODUCING WATER-ABSORBING POLYMER PARTICLES BY POLYMERIZING DROPS OF A MONOMER SOLUTION | |
| ATE483735T1 (en) | METHOD FOR PRODUCING WATER-ABSORBING POLYMER PARTICLES BY SUSPENSION POLYMERIZATION | |
| MY187456A (en) | Water absorbent resin particles and method for producing same | |
| ATE426621T1 (en) | METHOD FOR CONTROLLING POLYMER FLOW IN A POLYMERIZATION PROCESS | |
| DE502006006980D1 (en) | METHOD FOR PRODUCING WATER ABSORBING POLYMER PARTICLES | |
| DE602005018928D1 (en) | AHREN FOR THE MANUFACTURE OF GRANULES | |
| CN105643931A (en) | Method for preparing organic separating membrane through three-dimensional molding technology | |
| CN104448606A (en) | Hard PVC pipe and preparation method thereof | |
| CN104629170B (en) | Selective laser sintering Quick-forming PP composite materials and preparation method | |
| PL2307531T3 (en) | Grindable pellet | |
| CN105561802A (en) | Preparation method of novel UV (ultraviolet) curing polyoxyethylene semi-interpenetrating network gas separation membrane | |
| JP2004189887A5 (en) | ||
| CN104448625A (en) | Plastic material capable of releasing anions and preparation method of plastic material | |
| WO2013132523A8 (en) | Process for devulcanizing vulcanized fluoroelastomers, fluoroelastomers thereof and their use |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151104 |