CN105007892A - Eyelash cosmetic - Google Patents

Eyelash cosmetic Download PDF

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Publication number
CN105007892A
CN105007892A CN201480009528.3A CN201480009528A CN105007892A CN 105007892 A CN105007892 A CN 105007892A CN 201480009528 A CN201480009528 A CN 201480009528A CN 105007892 A CN105007892 A CN 105007892A
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CN
China
Prior art keywords
cosmetic
quality
water
alkyl acrylate
cilia
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201480009528.3A
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Chinese (zh)
Inventor
千叶桐子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
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Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Publication of CN105007892A publication Critical patent/CN105007892A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/10Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/342Alcohols having more than seven atoms in an unbroken chain
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Provided is an emulsion-type eyelash cosmetic (mascara) which can minimize the clogging of a comb without lowering the curling power, which exhibits excellent voluminousness and smoothness in use, and which is removable with hot water. This eyelash cosmetic is characterized by containing (a) 20 to 30 mass% of an alkyl acrylate copolymer emulsion, (b) 3 to 6 mass% of a moisturizing agent and (c) 0.1 to 0.4 mass% of a polyacrylic acid salt. It is preferable that the cosmetic further contains (d) 0.5 to 6 mass% of a water-soluble substance.

Description

Cosmetic for cilia
Technical field
The present invention relates to a kind of cosmetic for cilia.Particularly relate to a kind of mascara, it is the oil-in-water type mascara of the coating tool being applicable to interdigitated electrode structure, and crimp force and use sense excellence, can lay down with hot water.
Background technology
Mascara is make eyelash voluminous elongated or curling thus can show around eyes, main eye cosmetic cosmetics with deep impressionly.Mascara has: the oiliness type being dispersed with wax, resin, coloring agent etc. in volatile oil content; And make the oil-in-water type of the emulsion dispersion such as resin, coloring agent in water composition.
The mascara of oiliness type can adjust the shape of eyelashes securely by the overlay film formed after solvent volatilization, but in order to lay down this overlay film, needs the remover (removing liquid) using solvent as main component.
On the other hand, in the oil-in-water type of oil-in-water type, have though commercially available and there is resistance to water do not use remover and the mascara can laid down simply with hot water and receiving an acclaim.Such as, a kind of oil-in-water type cosmetic for cilia is described in patent documentation 1, it contains: comprise polyvinyl alcohol, (methyl) alkyl acrylate as Component units polymer and comprise the copolymer of NVP, the persistence (comprising the resistance to water to antiperspirant etc.) of excellent dressing effect can not only be kept and also can easily lay down with water.
The oil-in-water type mascara of oil-in-water type is combined with resin emulsion using acrylic monomer as main component usually as overlay film forming component, dry and form the overlay film of resistance to water after coating.Can think, the water-soluble substances such as further hydrous water soluble macromolecular in the mascara easily can laid down with hot water (or water), now because this water-soluble substances is enclosed in resin coating, thus by with hot water contacts and resin coating swelling and softening, become and easily peel off from eyelashes.
Mascara is coated on (for example, referring to patent documentation 2) on eyelashes by the coating tool of usual use brush-type or comb (comb) type.The coating tool of brush-type makes mascara liquid roll by eyelashes Delicatement one by one, and bring plentiful sense, existing oil-in-water type mascara uses the coating tool of brush-type.
On the other hand, the coating tool of interdigitated electrode structure has following feature: by eyelashes from root is upwards combed, to which imparts the long and fluffy sense of gorgeous fibre, and good, the fluffy sense excellence of liquid adhesive, can to obtain separation sense carded for eyelashes comb.
Prior art document
Patent documentation
Patent documentation 1: Japanese Unexamined Patent Publication 2006-257052 publication
Patent documentation 2: No. WO2009/084343rd, International Publication
Summary of the invention
the problem that invention will solve
But there are the following problems for the oil-in-water type mascara of existing oil-in-water type: when namely will use interdigitated electrode structure coating tool to obtain fluffy sense, separation sense, only place the blocking that comb just occurred after several minutes after coating.
By the amount decrement of the resin emulsion be matched with in mascara being suppressed to a certain degree blocking, but become and can not obtain sufficient crimp force.On the other hand, not changing resin emulsion amount by maintaining crimp force, making wetting agent increment can suppress blocking yet, but produce the problem of the slack-off such usability of drying after coating.
In addition, also can reduce blocking by the comb interval (spacing) expanding interdigitated electrode structure coating tool, but be difficult to obtain as the distinctive separating effect of interdigitated electrode structure coating tool.
Therefore, the object of the invention is to, a kind of cosmetic for cilia is provided, it is the oil-in-water type cosmetic for cilia (mascara) be applicable in interdigitated electrode structure coating tool, the blocking of comb can be suppressed and do not reduce crimp force, good fluffy sense, soft and smooth use sense can be obtained, and can lay down with hot water.
for the scheme of dealing with problems
In order to solve above-mentioned problem, the present inventor etc. conduct in-depth research, found that by coordinating polyacrylate in containing resin emulsion, the oil-in-water type mascara that can lay down with hot water, even if use interdigitated electrode structure coating tool also not block thus, can realize that there is the distinctive fluffy sense of interdigitated electrode structure and the eyelashes color make-up being separated sense, thus complete the present invention.
That is, the invention provides a kind of cosmetic for cilia, it is characterized in that, it contains:
(a) 20 ~ 30 quality % alkyl acrylate copolymer emulsion,
(b) 3 ~ 6 quality % wetting agent and
(c) 0.1 ~ 0.4 polyacrylate of quality %.
the effect of invention
The alkyl acrylate copolymer emulsion of cosmetic for cilia of the present invention not only containing q.s for playing excellent crimping eyelash power, and passes through the wetting agent and the polyacrylate that coordinate ormal weight, and interdigitated electrode structure coating tool is not blocked.And then, there is soft and smooth use sense and fast drying, can give eyelashes good fluffy sense, and can easily wash off with hot water.
Detailed description of the invention
Below, to the detailed description of the invention.
(a) alkyl acrylate copolymer emulsion
(composition is a) emulsion of copolymer using the Arrcostab of acrylic or methacrylic acid as main component for the alkyl acrylate copolymer emulsion that uses in the present invention, it can be such as the copolymer formed by methyl methacrylate, acrylic acid-2-ethyl caproite and methacrylic acid, the copolymer formed by methacrylic acid, butyl acrylate and acrylic acid-2-ethyl caproite, the emulsion of alkyl acrylate/styrol copolymer etc., especially preferably display Name is the emulsion of " acrylic acid/alkyl acrylate copolymer ".
The alkyl acrylate copolymer forming emulsion is not particularly limited, but preferably uses the polymer that there are-20 DEG C ~ 100 DEG C, be preferably the glass transition temperature of-5 DEG C ~ 70 DEG C.Emulsion only can comprise a kind of alkyl acrylate copolymer, also can comprise two or more different alkyl acrylate copolymer.
The solid constituent of the alkyl acrylate copolymer (resin) in emulsion is not particularly limited, but is generally 20 ~ 70 quality % of emulsion, be preferably about 40 ~ 60 quality %.
In the present invention, commercially available product can be used as alkyl acrylate copolymer emulsion, such as can enumerate Yodosol GH34F, Yodosol GH810 (Akzo Nobel Co., Ltd system), Daitosol5000A-S (Daito Kasei Kogyo Co., Ltd's system), dash coat CG-1 (Daito Kasei Kogyo Co., Ltd's system) etc. as representative examples.
The use level of the alkyl acrylate copolymer emulsion of cosmetics of the present invention is 20 ~ 30 quality %, and be preferably 22 ~ 28 quality %, the solid constituent as alkyl acrylate copolymer resin is 5 ~ 15 quality %, is preferably 8 ~ 12 quality %.
(b) wetting agent
As the wetting agent be coupled in cosmetics of the present invention (composition b), as long as be usually coupled to the wetting agent in cosmetics etc., be not particularly limited.
Such as, can enumerate: dipropylene glycol, propylene glycol, 1,3 butylene glycol, PEG400, glycerol etc.
The use level of the wetting agent (composition b) of cosmetics of the present invention is adjusted to and makes itself and alkyl acrylate copolymer emulsion (ratio of composition use level a) becomes b:a=1:3 ~ 1:8, preferably become 1:4 ~ 1:7, more preferably become about 1:5.Concrete use level is 3 ~ 6 quality %, is preferably 4 ~ 6 quality %.When the use level of wetting agent is less than 3 quality %, become the blocking easily causing comb, when coordinating more than 6 quality %, deposit the tendency that drying is after coating slack-off, usability is deteriorated.
(c) polyacrylate
The polyacrylate (composition c) used in the present invention is the polyacrylic salt that can be coupled to as water-soluble thickener in cosmetics, accurate medicine etc., the such as alkali metal salts or ammonium salt such as sodium salt, potassium salt etc.The molecular weight of polyacrylate is not particularly limited, but preferably uses the polyacrylate with the molecular weight of 1,000,000 ~ about 6,000,000.
The polyacrylate used in the present invention can be commercially available product, such as can enumerate as complete corrective (sodium salt): Aronvis SX (molecular weight 4,000,000 ~ 5,000,000), Aronvis MX (molecular weight 2,000,000 ~ 3,000,000) etc., as part corrective, can enumerate: Aronvis AHX etc. (being Toagosei Co., Ltd's system).
The use level of the polyacrylate of cosmetics of the present invention is 0.1 ~ 0.4 quality %, is preferably 0.15 ~ 0.3 quality %.When the use level of polyacrylate is less than 0.1 quality %, become the blocking easily causing comb, when coordinating more than 0.4 quality %, deposit the tendency that drying is after coating slack-off, usability is deteriorated.
Cosmetic for cilia of the present invention is the cosmetics of the type can washed off with hot water, except aforesaid essential component (a ~ c), the water-soluble substances of (d) water soluble polymer (except polyacrylate) etc. can also be coordinated.
As water soluble polymer, can enumerate: the synthesizing water-solubility macromolecules such as polyvinyl alcohol (PVA); The water-soluble macromolecules such as arabic gum, Tragacanth, galactan, guar gum, tragon, karaya, carrageenan, pectin, agar, Fructus cydoniae oblongae seed glue (Fructus Chaenomelis glue), alginate jelly (Algin), starch (rice, Semen Maydis, Rhizoma Solani tuber osi, Semen Tritici aestivi), glycyrrhizic acid, xanthan gum, glucosan, succinoglucan, pulullan polysaccharide (pullulan), collagen, casein, albumin, gelatin; The semi-synthetic water soluble polymers etc. such as carboxymethyl starch, methylhydroxypropyl starch, sodium alginate, propylene glycol alginate.
The use level of water-soluble substances is preferably 0.5 ~ 6 quality %, is more preferably 1 ~ 5 quality %.When use level is more than 6 quality %, the drying after coating is slack-off, usability reduces.
And then, can ciliation applies some make up, other any composition that especially usually can be coupled in mascara not hindering the scope of effect of the present invention to include.As concrete example, can enumerate: powdered ingredients, liquid fat, solid grease, wax class, hydrocarbon ils, higher fatty acids, higher alcohol, ester oil, silicone oil, anion surfactant, cationic surfactant, amphoteric surfactant, lipophile non-ionic surface active agent, hydrophilic non-ionic surfactant, thickening agent, metal ion chelation agent, lower alcohol, buffer agent, antioxidant, antiseptic, antiinflammatory, various extract, activator etc., but be not limited thereto.
Cosmetic for cilia of the present invention can manufacture according to method normally used in oil-in-water type mascara.In brief, can prepare as follows: by oil-phase component being heated at 90 DEG C and mixing equably and make oil phase A, water-phase component and resin emulsion are at room temperature mixed and made into aqueous phase B equably, stir oil phase A and add aqueous phase B and make its emulsifying, be cooled to room temperature.
Cosmetic for cilia of the present invention is particularly suitable for using interdigitated electrode structure coating tool to be coated with.
Interdigitated electrode structure coating tool has the axle portion of cylindric or polygon column etc. usually, possesses handle part, possess comb portion at the other end in the one end in axle portion.Comb portion is formed as following shape: be vertically arranged with multiple projection tab (comb) (for example, referring to Fig. 4 of patent documentation 2, Fig. 2 etc. of Japanese Unexamined Patent Publication 2011-4804 publication) with axle portion.
Cosmetic for cilia of the present invention is especially applicable to using interdigitated electrode structure coating tool, can realize that existing oil-in-water type cosmetic for cilia (mascara) is difficult to obtain fluffy sense be separated sense, and the blocking of comb can be suppressed and do not reduce crimp force.
Therefore, the present invention also provides the eyelashes cosmetic agent box comprising cosmetic for cilia of the present invention, hold the container of these cosmetics and interdigitated electrode structure coating tool.
Embodiment
Below, enumerate concrete example and the present invention is illustrated in further detail, but they do not limit technical scope of the present invention at all.It should be noted that, the use level in following examples etc. is quality % in case of no particular description.
Oil-in-water type mascara is prepared according to the composition recorded in each example of following table 1 ~ 4.
To the mascara obtained in each example, implement by specialty evaluation group member 10 actual service test using interdigitated electrode structure coating tool.Specifically, the mascara of each example is applied on the eyelashes of each evaluation group member, for the speed of the drying on the good degree (fluffy sense) of the crimp force of eyelashes, liquid adhesive, smoothness, eyelashes, evaluate according to following benchmark.
< metewand >
(1) about " crimp force " " good degree (fluffy sense) of liquid adhesive " " smoothness "
In ◎: 10, more than 7 are evaluated as excellence
In zero: 10 more than 5 and it is evaluated as excellence less than 7 stars
In △: 10 more than 3 and it is evaluated as excellence less than 5 stars
×: less than 2 are evaluated as excellence
(2) about " dry speed "
Zero: dry with suitable speed, therefore usability is good
△ (soon): the fast drying after coating and be difficult to use
△ (slowly): the drying after coating is slow and be difficult to use
× (slowly): dried slow after coating and can not using as product
Then, the blocking after at room temperature placing about the interdigitated electrode structure coating tool used in the application of the mascara of each example, evaluates according to following benchmark.
< metewand >
Zero: do not cause blocking, can directly reuse
△: block, but can remove with easy process
×: there is blocking and can not reuse
[table 1]
(*) Aronvis (Toagosei Co., Ltd's system)
(* *) Yodosol GH34F (Akzo Nobel Co., Ltd system)
From result shown in table 1, by alkyl acrylate copolymer emulsion, (composition a), wetting agent (composition b) and polyacrylate (composition c) coordinate with ormal weight, can obtain the result (embodiment 1 ~ 3) that can meet evaluated whole projects thus.In addition, for the compositions of the embodiment 3 of PVA joined together in the existing mascara not having cooperation can lay down with hot water, by also easily being laid down with hot water containing polyacrylate.But when the use level of polyacrylate is more than 0.4 quality %, the drying after coating is slack-off and usability reduces (comparative example 1).
[table 2]
(*) Aronvis (Toagosei Co., Ltd's system)
(* *) Yodosol GH34F (Akzo Nobel Co., Ltd system)
When mismatching polyacrylate, if the use level reducing alkyl acrylate copolymer makes it be less than the comparative example 3 suitable with existing oil-in-water type mascara, then can prevent blocking, but sufficient crimp force (comparative example 2) can not be obtained, on the contrary, if increase the use level of alkyl acrylate copolymer, then crimp force improves, but becomes and easily block, and the drying after coating becomes too fast, lack smoothness, thus usability reduce (comparative example 4 and 5).In addition, in whole examples of table 2, excellent fluffy sense is not obtained.
[table 3]
(*) Aronvis (Toagosei Co., Ltd's system)
(* *) Yodosol GH34F (Akzo Nobel Co., Ltd system)
When mismatching polyacrylate, it is made to be greater than existing (comparative example 3) by increasing moisturizing dosage, thus blocking can be prevented, but the drying after coating becomes extremely slow (comparative example 6 and 7), even if suppress the use level of wetting agent and increase the use level of alkyl acrylate copolymer, excellent fluffy sense (comparative example 8 and 9) can not be obtained.
[table 4]
(*) Aronvis (Toagosei Co., Ltd's system)
(* *) Yodosol GH34F (Akzo Nobel Co., Ltd system)
When mismatching polyacrylate, it is made to be greater than existing (comparative example 3) by the amount increasing water soluble polymer (PVA), thus can prevent blocking, but drying after coating is slack-off and can not obtain sufficient crimp force (comparative example 10 and 11).

Claims (6)

1. a cosmetic for cilia, is characterized in that, it contains:
(a) 20 ~ 30 quality % alkyl acrylate copolymer emulsion,
(b) 3 ~ 6 quality % wetting agent and
(c) 0.1 ~ 0.4 polyacrylate of quality %.
2. cosmetic for cilia according to claim 1, it also comprises (d) 0.5 ~ 6 water-soluble substances of quality %.
3. cosmetic for cilia according to claim 1 and 2, wherein, it is the alkyl acrylate copolymer resin of 5 ~ 15 quality % relative to cosmetics that described alkyl acrylate copolymer emulsion comprises with solid component meter.
4. the cosmetic for cilia according to any one of claims 1 to 3, wherein, it is one kind or two or more that described wetting agent is selected from the group be made up of dipropylene glycol, propylene glycol, 1,3 butylene glycol, PEG400 and glycerol.
5. the cosmetic for cilia according to any one of Claims 1 to 4, wherein, described polyacrylate is sodium polyacrylate.
6. an eyelashes cosmetic agent box, it comprises: the cosmetic for cilia according to any one of Claims 1 to 5, the container holding these cosmetics and interdigitated electrode structure coating tool.
CN201480009528.3A 2013-02-19 2014-01-17 Eyelash cosmetic Pending CN105007892A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2013030395A JP5681737B2 (en) 2013-02-19 2013-02-19 Eyelash cosmetics
JP2013-030395 2013-02-19
PCT/JP2014/050789 WO2014129240A1 (en) 2013-02-19 2014-01-17 Eyelash cosmetic

Publications (1)

Publication Number Publication Date
CN105007892A true CN105007892A (en) 2015-10-28

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Application Number Title Priority Date Filing Date
CN201480009528.3A Pending CN105007892A (en) 2013-02-19 2014-01-17 Eyelash cosmetic

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JP (1) JP5681737B2 (en)
KR (1) KR101594951B1 (en)
CN (1) CN105007892A (en)
HK (1) HK1212629A1 (en)
TW (1) TWI533892B (en)
WO (1) WO2014129240A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110354020A (en) * 2018-04-11 2019-10-22 株式会社常盘 Oil-in-water type cosmetic for sticking to keratin fiber

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017210437A (en) 2016-05-25 2017-11-30 三菱鉛筆株式会社 Cosmetics for eyelash decoration
KR102421412B1 (en) * 2020-07-31 2022-07-18 한국콜마주식회사 Cosmetic composition for eye makeup

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JPH1179941A (en) * 1997-09-05 1999-03-23 Noevir Co Ltd Mascara composition
CN1767811A (en) * 2003-03-31 2006-05-03 株式会社资生堂 Cosmetic for cilia
JP2007153743A (en) * 2005-11-30 2007-06-21 Kanebo Cosmetics Inc Oil-in-water type cosmetic for eyelash
JP2008273943A (en) * 2007-03-30 2008-11-13 Kose Corp Aqueous makeup cosmetic
CN101711727A (en) * 2008-09-30 2010-05-26 莱雅公司 Eyelash makeup composition and process comprising the application of two compositions
JP2011157289A (en) * 2010-01-29 2011-08-18 Kao Corp Eyelash cosmetic

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US20040197297A1 (en) * 2002-09-06 2004-10-07 Societe L'oreal, S.A. Charging/separating cosmetic makeup compositions for keratin fibers
JP4880912B2 (en) 2005-03-18 2012-02-22 株式会社コーセー Easily washed cosmetic
EP2225963B1 (en) 2007-12-27 2018-04-11 Shiseido Company, Ltd. Mascara applicator

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1179941A (en) * 1997-09-05 1999-03-23 Noevir Co Ltd Mascara composition
CN1767811A (en) * 2003-03-31 2006-05-03 株式会社资生堂 Cosmetic for cilia
JP2007153743A (en) * 2005-11-30 2007-06-21 Kanebo Cosmetics Inc Oil-in-water type cosmetic for eyelash
JP2008273943A (en) * 2007-03-30 2008-11-13 Kose Corp Aqueous makeup cosmetic
CN101711727A (en) * 2008-09-30 2010-05-26 莱雅公司 Eyelash makeup composition and process comprising the application of two compositions
JP2011157289A (en) * 2010-01-29 2011-08-18 Kao Corp Eyelash cosmetic

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110354020A (en) * 2018-04-11 2019-10-22 株式会社常盘 Oil-in-water type cosmetic for sticking to keratin fiber
CN110354020B (en) * 2018-04-11 2023-09-22 株式会社常盘 Cosmetic for oil-in-water type eyelashes

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KR101594951B1 (en) 2016-02-17
JP2014159386A (en) 2014-09-04
TW201438759A (en) 2014-10-16
HK1212629A1 (en) 2016-06-17
TWI533892B (en) 2016-05-21
JP5681737B2 (en) 2015-03-11
WO2014129240A1 (en) 2014-08-28
KR20150098685A (en) 2015-08-28

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