CN105001713A - Printing ink for printing packing cases - Google Patents
Printing ink for printing packing cases Download PDFInfo
- Publication number
- CN105001713A CN105001713A CN201510459032.2A CN201510459032A CN105001713A CN 105001713 A CN105001713 A CN 105001713A CN 201510459032 A CN201510459032 A CN 201510459032A CN 105001713 A CN105001713 A CN 105001713A
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- Prior art keywords
- parts
- printing
- ink
- water
- printing ink
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to printing ink for printing packing cases. The printing ink is prepared by the following raw materials including, by weight, 22-25 parts of PEG1450, 0.5-0.8 part of silver chloride, 20-25 parts of water-based pigment, 0.8-1.2 parts of silicone emulsion, 0.2-0.5 part of sorbitan mono-oleic acid ester, 8-12 parts of bisphenol-a-type epoxy resin, 28-32 parts of water-soluble acrylic resin, 5-7 parts of polyoxyethylene, 3-5 parts of ethyl lactate, 7-9 parts of butyl acetate and 25-28 parts of water. According to the printing ink for printing the packing cases, non-toxic and pollution-free solvent is used, harm to a human body cannot be generated in the preparing and using process of the printing ink, the adhesive force and leveling performance of the printing ink are improved, so that the printing effect is better, and the abrasive resistance and heat resistance of the printing ink are improved.
Description
Technical field
The invention belongs to printing supplies field, be specifically related to a kind of ink of printing packaging case.
Background technology
The even slurry like material that water color ink is made up of materials such as low-melting ink vehicle, pigment, auxiliary agents.Low-melting ink vehicle provides the transfer performance of ink necessity, and pigment gives ink with color.The low-melting ink vehicle of water color ink is mainly divided into two types: water dilution type and aqueous dispersion type.The former has a variety of at operable resinous type.The low-melting ink vehicle of aqueous dispersion type is the monomer polymerization gained by emulsification in water, and it is two-phase system, and wherein oil phase disperses in aqueous phase with particulate state, though by water dissolution, can not be diluted by water, so also can think O/w emulsion type.
In fields such as food product pack, there is very high requirement for printing-ink, not only need printing clear, need nontoxic and there is higher stability, preventing ink contamination food.
Summary of the invention
The object of this invention is to provide a kind of ink of printing packaging case, safety non-toxic, have very high stability, sticking power and thermotolerance also obviously promote.
The present invention is achieved through the following technical solutions:
An ink for printing packaging case, is made up by weight ratio of following raw material: PEG1450 22-25 part, silver chloride 0.5-0.8 part, water-based paint 20-25 part, silicone emulsion 0.8-1.2 part, sorbitan oleate 0.2-0.5 part, bisphenol A type epoxy resin 8-12 part, water soluble acrylic resin 28-32 part, polyoxyethylene 5-7 part, ethyl lactate 3-5 part, N-BUTYL ACETATE 7-9 part, water 25-28 part.
Preferably, an ink for printing packaging case, is made up by weight ratio of following raw material: PEG1450 24 parts, silver chloride 0.6 part, water-based paint 24 parts, silicone emulsion 1 part, sorbitan oleate 0.3 part, bisphenol A type epoxy resin 9 parts, water soluble acrylic resin 30 parts, polyoxyethylene 6.8 parts, ethyl lactate 4.2 parts, N-BUTYL ACETATE 8 parts, 26 parts, water.
Polyoxyethylene molecular weight is 100000-250000.
Bisphenol A type epoxy resin of the present invention has excellent cohesiveness, snappiness, sticking power, and system has stronger chemical resistant properties simultaneously, as ethanol-tolerant, acidproof, alkaline-resisting etc.Used in combination with PEG1450, the variation of melting point of ink can be regulated, make the use range of ink wider, and the tack of ink can be promoted, use silicone emulsion as dispersion agent, used in combination with PEG1450, water soluble acrylic resin, N-BUTYL ACETATE, water etc., make the dispersion effect of solvent better, pigment is disperseed in a solvent evenly, and add silver chloride in the feed, not only can increase the polarity of ink, promote the wear resistance of ink, the speed of printing can be promoted, strengthen the adhesion strength between ink and printed matter.Adding ethyl lactate in a solvent can make ink have certain fragrance, and nontoxicity, ethyl lactate and silicone emulsion use jointly, be aided with other solvents of the present invention, the levelling property of ink can be promoted, the planarization of printing is improved greatly, polyoxyethylene add the viscosity improving ink further, make its Adhesion enhancement, use due to add-on and with other solvent simultaneously, ink viscosity can not be caused excessive.
Beneficial effect of the present invention: use nontoxic, free of contamination solvent in printing-ink provided by the invention, can not produce harm to human body in printing ink to manufacture and use procedure, sticking power and the flow leveling of ink get a promotion, and make the better effects if of printing; And the wear resistance of ink and thermotolerance improve, ink of the present invention is nontoxic, to environment with printed matter is pollution-free, free from extraneous odour, contact with roller evenly during printing, evenly, ink is outer to be drenched in printing, and the good luster of ink printing prints the rear ink of oven dry colour-fast.
Embodiment
Embodiment 1
An ink for printing packaging case, is made up by weight ratio of following raw material: PEG1450 22 parts, silver chloride 0.6 part, water-based paint 23 parts, silicone emulsion 1 part, sorbitan oleate 0.45 part, bisphenol A type epoxy resin 9 parts, water soluble acrylic resin 30.5 parts, polyoxyethylene 6 parts, ethyl lactate 4 parts, N-BUTYL ACETATE 7 parts, 26 parts, water.
Embodiment 2
An ink for printing packaging case, is made up by weight ratio of following raw material: PEG1450 24 parts, silver chloride 0.6 part, water-based paint 24 parts, silicone emulsion 1 part, sorbitan oleate 0.3 part, bisphenol A type epoxy resin 9 parts, water soluble acrylic resin 30 parts, polyoxyethylene 6.8 parts, ethyl lactate 4.2 parts, N-BUTYL ACETATE 8 parts, 26 parts, water.
Embodiment 3
An ink for printing packaging case, is made up by weight ratio of following raw material: PEG1450 24 parts, silver chloride 0.65 part, water-based paint 22 parts, silicone emulsion 0.9 part, sorbitan oleate 0.35 part, bisphenol A type epoxy resin 10 parts, water soluble acrylic resin 30 parts, polyoxyethylene 6 parts, ethyl lactate 3.5 parts, N-BUTYL ACETATE 8.5 parts, 26 parts, water.
Comparative example 1
An ink for printing packaging case, is made up by weight ratio of following raw material: silver chloride 0.6 part, water-based paint 24 parts, silicone emulsion 1 part, sorbitan oleate 0.3 part, bisphenol A type epoxy resin 9 parts, water soluble acrylic resin 30 parts, polyoxyethylene 6.8 parts, ethyl lactate 4.2 parts, N-BUTYL ACETATE 8 parts, 26 parts, water.
Comparative example 2
An ink for printing packaging case, is made up by weight ratio of following raw material: PEG1450 20 parts, silver chloride 0.2 part, water-based paint 23 parts, silicone emulsion 0.9 part, sorbitan oleate 0.4 part, water soluble acrylic resin 28 parts, polyoxyethylene 6 parts, N-BUTYL ACETATE 9 parts, 26 parts, water.
Carry out performance test to ink of the present invention, test is carried out according to national testing standard, and result is as following table:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | |
| Thermotolerance | 7 grades | 8 grades | 7 grades | 7 grades | 6 grades |
| Attachment fastness (PET/NY) | ≥97% | ≥99% | ≥98% | ≤95% | ≤94% |
| Glossiness | 62 | 66 | 64 | 62 | 60 |
| Water tolerance | Nondiscoloration | Do not take off/variable color | Nondiscoloration | Fade serious | Appearance is faded |
| The highest print speed | 320m/min | 350m/min | 320m/min | 280m/min | 290m/min |
| Colo(u)rant dispersion effect | Good | Excellent | Good | In | Difference |
| Rub resistance | Good | Excellent | Excellent | In | Difference |
Table 1
Carry out after ink printing of the present invention, during wearability test, the power of load 175g, paper tape rubs 100 times, and layer of ink is without obvious damage.The carton of the present invention's printing 70 DEG C, place 24h under humidity 90% condition, layer of ink is without obviously coming off or layering.
As shown in Table 1, water color ink resistance toheat of the present invention is good, and attachment fastness is high, and glossiness is good, and chance water can not become flower by rapid dispersion, and after ink printing, wear resistance is good.
Claims (2)
1. the ink of a printing packaging case, it is characterized in that, be made up by weight ratio of following raw material: PEG1450 22-25 part, silver chloride 0.5-0.8 part, water-based paint 20-25 part, silicone emulsion 0.8-1.2 part, sorbitan oleate 0.2-0.5 part, bisphenol A type epoxy resin 8-12 part, water soluble acrylic resin 28-32 part, polyoxyethylene 5-7 part, ethyl lactate 3-5 part, N-BUTYL ACETATE 7-9 part, water 25-28 part.
2. the ink of a kind of printing packaging case according to claim 1, it is characterized in that, be made up by weight ratio of following raw material: PEG1450 24 parts, silver chloride 0.6 part, water-based paint 24 parts, silicone emulsion 1 part, sorbitan oleate 0.3 part, bisphenol A type epoxy resin 9 parts, water soluble acrylic resin 30 parts, polyoxyethylene 6.8 parts, ethyl lactate 4.2 parts, N-BUTYL ACETATE 8 parts, 26 parts, water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510459032.2A CN105001713A (en) | 2015-07-28 | 2015-07-28 | Printing ink for printing packing cases |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510459032.2A CN105001713A (en) | 2015-07-28 | 2015-07-28 | Printing ink for printing packing cases |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105001713A true CN105001713A (en) | 2015-10-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510459032.2A Pending CN105001713A (en) | 2015-07-28 | 2015-07-28 | Printing ink for printing packing cases |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105001713A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325636A (en) * | 2017-08-15 | 2017-11-07 | 南宁东印时代广告有限公司 | A kind of cigarette case printing-ink and preparation method thereof |
| CN107384009A (en) * | 2017-09-11 | 2017-11-24 | 桐城市人和包装有限公司 | A kind of packing case printing ink |
| CN107880640A (en) * | 2017-12-21 | 2018-04-06 | 刘辉 | A kind of high performance heat resistant ink |
| CN112300628A (en) * | 2020-11-16 | 2021-02-02 | 黄展才 | Water-based ink for printing mildew-proof antibacterial packaging carton and production method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844229A (en) * | 2006-05-16 | 2006-10-11 | 广东工业大学 | UV curable aqueous resin composition |
| CN101284965A (en) * | 2007-04-10 | 2008-10-15 | 樊官保 | Water-based intaglio ink equal to plate engraving ink and uses thereof |
| CN103788939A (en) * | 2012-10-31 | 2014-05-14 | 上海晨光文具股份有限公司 | Thermochromic composition, thermochromic erasable neutral ink and pen core filled with the same |
| CN104449039A (en) * | 2014-12-26 | 2015-03-25 | 英科·卡乐油墨(苏州)有限公司 | Food packaging printing solvent-based ink and preparation method thereof |
-
2015
- 2015-07-28 CN CN201510459032.2A patent/CN105001713A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844229A (en) * | 2006-05-16 | 2006-10-11 | 广东工业大学 | UV curable aqueous resin composition |
| CN101284965A (en) * | 2007-04-10 | 2008-10-15 | 樊官保 | Water-based intaglio ink equal to plate engraving ink and uses thereof |
| CN103788939A (en) * | 2012-10-31 | 2014-05-14 | 上海晨光文具股份有限公司 | Thermochromic composition, thermochromic erasable neutral ink and pen core filled with the same |
| CN104449039A (en) * | 2014-12-26 | 2015-03-25 | 英科·卡乐油墨(苏州)有限公司 | Food packaging printing solvent-based ink and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 汪多仁: "《精细化工中间体》", 31 January 2008 * |
| 赵陈超: "《有机硅乳液及其应用》", 30 September 2008 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325636A (en) * | 2017-08-15 | 2017-11-07 | 南宁东印时代广告有限公司 | A kind of cigarette case printing-ink and preparation method thereof |
| CN107384009A (en) * | 2017-09-11 | 2017-11-24 | 桐城市人和包装有限公司 | A kind of packing case printing ink |
| CN107880640A (en) * | 2017-12-21 | 2018-04-06 | 刘辉 | A kind of high performance heat resistant ink |
| CN112300628A (en) * | 2020-11-16 | 2021-02-02 | 黄展才 | Water-based ink for printing mildew-proof antibacterial packaging carton and production method thereof |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151028 |
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| RJ01 | Rejection of invention patent application after publication |