CN105000809A - Organic silicon resin film-forming agent impregnating agent for glass fiber drawing - Google Patents
Organic silicon resin film-forming agent impregnating agent for glass fiber drawing Download PDFInfo
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- CN105000809A CN105000809A CN201510368432.2A CN201510368432A CN105000809A CN 105000809 A CN105000809 A CN 105000809A CN 201510368432 A CN201510368432 A CN 201510368432A CN 105000809 A CN105000809 A CN 105000809A
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- glass fiber
- silicone resin
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- forming agent
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Abstract
The invention provides an organic silicon resin film-forming agent impregnating agent for glass fiber drawing. The impregnating agent improves glass fiber weatherability and spinnability and weaving performances in post processing so that a glass fiber service life is improved. The impregnating agent comprises 0.1-15% of a film forming agent which is an organic silicon resin emulsion with content of 30%. The glass fibers substantially improve weatherability and post processing performances and greatly prolong a glass fiber service life.
Description
Technical field
The present invention relates to glass fiber wire-drawing operation, is use silicone resin as membrane-forming agent when glass fiber wire-drawing specifically.
Background technology
Treating compound to be gone up during glass fiber wire-drawing, treating compound mainly contains membrane-forming agent (vibrin, epoxy resin, PU resin, PVAC resin, acrylate etc.), emulsifying agent, coupling agent and static inhibitor etc., but, above-mentioned several resin and glass fibre affinity bad, and weathering resistance is poor.The embrittlement when low temperature, feels like jelly during high temperature, thus affects glass fibre twisting and weave processing and affect the use properties of goods.
Summary of the invention
For solving the problems of the technologies described above, the object of this invention is to provide a kind for the treatment of compound using silicone resin membrane-forming agent in glass fiber wire-drawing process.
The object of the present invention is achieved like this:
Ingredient Wt per-cent (%)
The silicone resin emulsion 0.1-15 of 30% content
Peregal 1.0
Dibutyl ester 2.0
Glycerol 1.0
Emulsifying agent A6 1.0
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 78.9-93.8.
Using method is: according to above-mentioned formulated the present invention in glass fiber wire-drawing operation; Oil when glass fiber wire-drawing; Silicone resin can be solidified into silicone resin at fiberglass surfacing.
Compared with prior art, the invention has the beneficial effects as follows: because silicone resin has very strong weathering resistance and erosion resistance, subzero 50 DEG C can not embrittlement, above freezing 150 DEG C can not sex change, considerably improve post-treatment and the use properties of glass fibre, substantially prolongs glass fibre and goods thereof work-ing life; Secondly, the silicone resin of the present invention's use and the main component SiO of glass fibre
2all belong to silicon matter, so both affinities are good, difficult drop-off, and other composition as tetrafluoroethylene and glass fibre affinity poor; Again, due in silicone resin emulsion containing solidifying agent, to be coated on glass fibre wire drawing and to deposit in process and continue solidification and aggregate into polymer silicone resin, good to the protected effect of glass fibre; Finally, the price of silicone resin emulsion is significantly less than ptfe emulsion.
Embodiment
Provide six embodiments below, it just realizes reliable illustration of the present invention, and the object enumerating following examples is to illustrate the present invention, and and unrestricted interest field of the present invention.The present invention can have various ways in the scope not exceeding its technical thought.
Compound method is:
1, prepare the present invention, have following six embodiments
Embodiment one
Ingredient Wt per-cent (%)
The silicone resin emulsion 7.0 of 30% content
Peregal 1.0
Dibutyl ester 2.5
Glycerol 1.0
Emulsifying agent A6 1.5
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 85.9.
Embodiment two
Ingredient Wt per-cent (%)
The silicone resin emulsion 8.0 of 30% content
Peregal 1.0
Dibutyl ester 2.0
Glycerol 1.0
Emulsifying agent A6 1.5
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 85.4.
Embodiment three
Ingredient Wt per-cent (%)
The silicone resin emulsion 7.0 of 30% content
Peregal 1.0
Dibutyl ester 2.5
Glycerol 1.0
Emulsifying agent A6 1.0
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 84.4.
Embodiment four
Ingredient Wt per-cent (%)
The silicone resin emulsion 8.0 of 30% content
Peregal 1.0
Dibutyl ester 2.0
Glycerol 1.0
Emulsifying agent A6 1.0
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 85.9.
Embodiment five
Ingredient Wt per-cent (%)
The silicone resin emulsion 9.0 of 30% content
Peregal 1.0
Dibutyl ester 2.0
Glycerol 1.0
Emulsifying agent A6 1.0
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 84.9.
Claims (6)
1. in glass fiber wire-drawing process, use a treating compound for silicone resin membrane-forming agent, it is characterized in that:
Ingredient Wt per-cent (%)
The silicone resin emulsion 0.1-15 of 30% content
Peregal 1.0
Dibutyl ester 2.0
Glycerol 1.0
Emulsifying agent A6 1.0
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 78.9-93.8.
2., according to the treating compound using silicone resin membrane-forming agent in glass fiber wire-drawing process according to claim 1, it is characterized in that:
Ingredient Wt per-cent (%)
The silicone resin emulsion 7.0 of 30% content
Peregal 1.0
Dibutyl ester 2.5
Glycerol 1.0
Emulsifying agent A6 1.5
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 85.9.
3., according to the treating compound using silicone resin membrane-forming agent in glass fiber wire-drawing process according to claim 1, it is characterized in that:
Ingredient Wt per-cent (%)
The silicone resin emulsion 8.0 of 30% content
Peregal 1.0
Dibutyl ester 2.0
Glycerol 1.0
Emulsifying agent A6 1.0
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 85.9.
4., according to the treating compound using silicone resin membrane-forming agent in glass fiber wire-drawing process according to claim 1, it is characterized in that:
Composition weight percent (%)
The silicone resin emulsion 7.0 of 30% content
Peregal 1.0
Dibutyl ester 2.5
Glycerol 1.0
Emulsifying agent A6 1.0
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 84.4.
5., according to the treating compound using silicone resin membrane-forming agent in glass fiber wire-drawing process according to claim 1, it is characterized in that:
Ingredient Wt per-cent (%)
The silicone resin emulsion 8.0 of 30% content
Peregal 1.0
Dibutyl ester 2.0
Glycerol 1.0
Emulsifying agent A6 1.0
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 85.9.
6., according to the treating compound using silicone resin membrane-forming agent in glass fiber wire-drawing process according to claim 1, it is characterized in that:
The silicone resin emulsion 9.0 of 30% content
Peregal 1.0
Dibutyl ester 2.0
Glycerol 1.0
Emulsifying agent A6 1.0
Coupling agent 550 0.5
Glacial acetic acid 0.1
Ethanol 0.5
Water 84.9.
Priority Applications (1)
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CN201510368432.2A CN105000809A (en) | 2015-06-30 | 2015-06-30 | Organic silicon resin film-forming agent impregnating agent for glass fiber drawing |
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CN201510368432.2A CN105000809A (en) | 2015-06-30 | 2015-06-30 | Organic silicon resin film-forming agent impregnating agent for glass fiber drawing |
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CN105000809A true CN105000809A (en) | 2015-10-28 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105734995A (en) * | 2016-04-05 | 2016-07-06 | 常熟江南玻璃纤维有限公司 | Preparation method of high-performance fire blanket |
CN106186729A (en) * | 2016-06-30 | 2016-12-07 | 武汉鑫友泰光电科技有限公司 | Quartz glass fibre organic silicon type wetting agent and preparation method thereof |
CN106634574A (en) * | 2016-12-28 | 2017-05-10 | 河海大学 | Graphene modified organic silicon coating as well as preparation method and application thereof |
CN107476092A (en) * | 2017-08-16 | 2017-12-15 | 淄博丑牛特种纤维科技有限公司 | A kind of varicosity Buran toner, compound method and its colouring method |
CN109486147A (en) * | 2018-10-14 | 2019-03-19 | 金旸(厦门)新材料科技有限公司 | A kind of anti-wire drawing fire retardation PC-ASA alloy and preparation method thereof |
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US4394414A (en) * | 1981-05-29 | 1983-07-19 | Ppg Industries, Inc. | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
CN1671916A (en) * | 2002-06-18 | 2005-09-21 | 罗狄亚化学公司 | Aqueous silicone emulsion for coating woven or nonwoven textile substrates |
CN101519280A (en) * | 2009-02-16 | 2009-09-02 | 江苏九鼎新材料股份有限公司 | Treating compound special for high-performance cord threads and method for preparing same |
CN101613952A (en) * | 2009-07-30 | 2009-12-30 | 中国人民解放军国防科学技术大学 | Finishing oil for manufacturing of continuous silicone carbide fiber and technique for applying thereof |
CN102515570A (en) * | 2011-11-30 | 2012-06-27 | 淄博新力特种纤维科技有限公司 | Pre-processing reinforced type impregnating agent for basalt fiber chopped spun yarn and preparation method of pre-processing reinforced type impregnating agent |
CN103466951A (en) * | 2013-08-23 | 2013-12-25 | 中材科技股份有限公司 | Acid-resistant glass fiber and fabric prepared by glass fiber |
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2015
- 2015-06-30 CN CN201510368432.2A patent/CN105000809A/en active Pending
Patent Citations (7)
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SU411052A1 (en) * | 1972-03-28 | 1974-01-15 | ||
US4394414A (en) * | 1981-05-29 | 1983-07-19 | Ppg Industries, Inc. | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
CN1671916A (en) * | 2002-06-18 | 2005-09-21 | 罗狄亚化学公司 | Aqueous silicone emulsion for coating woven or nonwoven textile substrates |
CN101519280A (en) * | 2009-02-16 | 2009-09-02 | 江苏九鼎新材料股份有限公司 | Treating compound special for high-performance cord threads and method for preparing same |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105734995A (en) * | 2016-04-05 | 2016-07-06 | 常熟江南玻璃纤维有限公司 | Preparation method of high-performance fire blanket |
CN106186729A (en) * | 2016-06-30 | 2016-12-07 | 武汉鑫友泰光电科技有限公司 | Quartz glass fibre organic silicon type wetting agent and preparation method thereof |
CN106634574A (en) * | 2016-12-28 | 2017-05-10 | 河海大学 | Graphene modified organic silicon coating as well as preparation method and application thereof |
CN107476092A (en) * | 2017-08-16 | 2017-12-15 | 淄博丑牛特种纤维科技有限公司 | A kind of varicosity Buran toner, compound method and its colouring method |
CN109486147A (en) * | 2018-10-14 | 2019-03-19 | 金旸(厦门)新材料科技有限公司 | A kind of anti-wire drawing fire retardation PC-ASA alloy and preparation method thereof |
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